CN101012120B - Ecological inorganic composite architectural materials - Google Patents

Ecological inorganic composite architectural materials Download PDF

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Publication number
CN101012120B
CN101012120B CN2007100100194A CN200710010019A CN101012120B CN 101012120 B CN101012120 B CN 101012120B CN 2007100100194 A CN2007100100194 A CN 2007100100194A CN 200710010019 A CN200710010019 A CN 200710010019A CN 101012120 B CN101012120 B CN 101012120B
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inorganic
parts
wastes
naphthalene series
agent
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CN101012120A (en
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谢涛
毕秀新
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2092Resistance against biological degradation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses an ecological inorganic composite architectural material, which comprises the following parts: inorganic gelling material, agricultural straw fiber, three-waste inorganic waste, organic modifier and stirring solution. The invention is compatible with wood property, which is fit for packing, transmitting and decorating professions.

Description

A kind of ecological inorganic composite architectural materials
Technical field
The invention belongs to building materials technology field, relate to a kind of ecological inorganic composite architectural materials.
Background technology
Recycling economy mainly comprises the content of two big systems: cleaner production and regeneration data industry (is main contents with the twice-laid stuff), and the regeneration data industry of China extremely thin a little less than.According to estimates, the regeneration data using gross output value in the whole nation in 2004 only has 10,000,000,000 yuan, these data.Only be 3/1000ths of Japan, 5/1000ths of the U.S..Carry out data regeneration processing, development twice-laid stuff industry is important content and the key breakthrough mouth that China carries out Recycling Economy Construction.Utilize depleted natural plant fiber material and three wastes inorganic wastes to make environment-friendly building materials, it is reconstituted product completely, along with the Rapid Expansion in ecological circulation inorganic composite materials market, the development of this novel ecological circulation inorganic composite materials will be made important contribution to the recycling economy of China.It is closely bound up with recycling economy that three wastes inorganic wastes adds the ecological circulation inorganic composite architectural materials that inorganic composite materials produces, paid attention to by the Chinese government just gradually by product of its operation principle with " minimizing, utilization, recirculation again ", the Political Bureau of the Central Committee of the Chinese Communist Party proposes when disposing economic work in 2005, will " strengthen the people save the meaning knit; save the method energy and valuable source energetically, accelerate development recycling economy ".The President Hu Jintao indicates in the central meeting of the Political Bureau on June 27 in 2005; " promote level of industrial technology with autonomous innovation, walk road for development high in technological content, good in economic efficiency, low in resources consumption, low in the pollution of the environment, that safety is secure, advantage of human resources is not fully exerted." Premier Wen Jiabao also proposes in the government work report and will " greatly develop recycling economy "." greatly develop novel environmental-friendly construction material, replace the high solid clay brick serious with ruining ground of sandstone power consumption, take leave of Qin brick and Han tile, it is native to save each cun ground, benefits the descendants, gives good living environment of the people ".National Development and Reform Commission has determined China's recycling economy 3 big pilot industries especially: ecological industry, the ecological agriculture and the emerging field resource recovery industry that connects production and consumption.The crop stalk vegetable fibre is the inevitable byproduct in the grain-production, and China's annual crop stalk vegetable fibre output is about 600,000,000 T, and major part is wasted by burning, and channels such as a spot of universal feed, fuel, bio-fertilizer, building materials use to reclaim.Highway both sides crop stalk vegetable fibre burns and produces and a large amount of smog, has caused numerous traffic accidents.Because rice, the corn yield of China are big, at present, have 30% by generating, feed, making fiber, carbon black approximately, also the field is done means such as fertilizer and is reused, residue is burned or is discarded.By present 120 yuan of/ton calculating in market price, direct economic loss is just up to 60,000,000,000 yuan.Utilize the agricultural waste material vegetable fibre to make ecological circulation inorganic composite materials product, both can benefit the nation and the people, develop the economy, can reduce pollution again, the protection environment.
Summary of the invention
The objective of the invention is to be building material industry, provide a kind of utilize crop stalk plant fiber powder depleted wood chip, wood powder, rice chaff and various crop plants fiber and three wastes inorganic wastes etc. natural fiber-filled, make tackiness agent with magnesium oxide, calcium sulphate hemihydrate, high-alumina cement synthesizing inorganic gelating material, and the novel ecological circulation inorganic composite architectural materials made of organic materials properties-correcting agent.
Ecological inorganic composite architectural materials content Description of the present invention:
Ecological inorganic composite architectural materials of the present invention is characterized in that: it is made up of inorganic gel material, crop stalk vegetable fibre and three wastes inorganic wastes, organic materials properties-correcting agent and stirred solution four part materials;
The components by weight percent of raw material is:
The inorganic gel material is: 0.2 part of 1 part in magnesium oxide, 0.5 part of calcium sulphate hemihydrate and high-alumina cement;
Crop stalk vegetable fibre and three wastes inorganic wastes are: 1.2 parts of the tankage of crop stalk plant fiber powder or vegetation powder or wood working or wood shavings or wood powders; Comprise with three wastes inorganic wastes: 0.3 part of 0.3 part in flyash and useless foam beads or paper waste or vermiculite power or bagasse or glycyrrhiza residue or Herba Ephedrae slag;
By naphthalene series water reducer NNO, naphthalene series water reducer MF4, wooden calcium sulfonate, emulsifying agent, permeate agent peregal and water, by weight 4: 3: 2: 2.5: 1.5: 13 ratio was formed organic materials properties-correcting agent, 0.026 part of organic materials properties-correcting agent;
By 2.4 parts of the mixed stirred solutions that is made of magnesium chloride and sal epsom, contain in per 1 part: Baume is than the sal epsom 62.5kg of 10 degree, and content is 45% magnesium chloride 37.5kg, and mixed Baume is than being the 25-27 degree.
The making method of organic materials properties-correcting agent:
The naphthalene series water reducer NNO that (1) will make, naphthalene series water reducer MF4, wooden calcium sulfonate, emulsifying agent, permeate agent peregal, by its part by weight be: 4 parts: 3 parts: 2 parts: 1.5 parts: 2.5 parts, the water that adds 13 parts is put into vessel in heating to boiling with water;
(2) naphthalene series water reducer NNO, naphthalene series water reducer MF4, wooden calcium sulfonate are added in the entry successively, add emulsifying agent again after enduring dissolved in the water fully, the permeate agent peregal dissolves and gets final product;
(3) treat to pack into after organic materials properties-correcting agent cools off fully in the container and to use when stirring the inorganic gel material.
Ecological inorganic composite architectural materials of the present invention is very extensive to choosing of natural fiber, not requirement too much, the tankage of crop stalk plant fiber powder, waste and old wood working, wood shavings, wood powder, etc. stem, the bar of natural phant, the paper waste that paper industry produces etc. may be used to manufacture the ecological circulation inorganic composite architectural materials.The ecological circulation inorganic composite architectural materials has kept the advantage of common building material product, solved not only the complicated but also easy anti-halogen characteristic of making of magnesium cement goods, the fragility of sulfate hemihydrate calcium product and non-watertight not fp characteristic and cement products can not lightings, numerous shortcomings that shrinkage coefficient is big.The ecological circulation inorganic composite architectural materials is that magnesium oxide, calcium sulphate hemihydrate, high-alumina cement, four kinds of former gelling material of stirred solution are carried out the NEW TYPE OF COMPOSITE inorganic coagulation material that scientific optimization combines.This complex ecological circulation inorganic materials promptly can add a large amount of three wastes inorganic materials and also play recycling of eubiosis machine ecomaterial owing to apply to the inorganic composite gel material technology.Crucial effects has been played in environment protection.
Embodiment
Ecological inorganic composite architectural materials of the present invention is achieved in that the ecological circulation inorganic composite architectural materials is to form by the components by weight percent of following raw material:
1, inorganic gel material 170kg wherein: magnesium oxide 100kg; Calcium sulphate hemihydrate 50kg and high-alumina cement 20kg.
2, crop plants fiber and three wastes inorganic wastes 180kg are wherein; Stem or bar powder 120kg and the three wastes inorganic wastes of the tankage of crop plants fiber powder or vegetation powder or wood working or wood shavings or wood powder or the farm crop processing remaining chaff skin in back or reed or Sunflower Receptacle: flyash 30kg and useless foam beads or paper waste or vermiculite power or bagasse or glycyrrhiza residue or Herba Ephedrae slag 30kg.
3, organic materials properties-correcting agent; 0.26kg;
Organic materials properties-correcting agent is got naphthalene series water reducer NNO 40g, naphthalene series water reducer MF4
30g, the 20g of wooden calcium sulfonate, emulsifying agent 15g, permeate agent peregal 25g;
4, stirred solution 240kg.
The making method of organic materials properties-correcting agent: the naphthalene series water reducer NNO40g that will make, naphthalene series water reducer MF4 30g, the 20g of wooden calcium sulfonate, emulsifying agent 15g, permeate agent 25g, total amount is 130g, adds the water of 130g, puts into vessel in heating to boiling.Naphthalene series water reducer NNO, naphthalene series water reducer MF4, wooden calcium sulfonate are added in the ebullient water successively, add emulsifying agent successively again after enduring dissolved in the water fully, the permeate agent peregal dissolves and gets final product.Pack into after the agent of standby material modification is cooled off fully in the plastic tank and to use when stirring ecological circulation inorganic compounding building.
The making method of stirred solution:
Stirred solution is to be made magnesium chloride and sal epsom are mixed, and contain in per 1 part: Baume is than the sal epsom 62.5kg of 10 degree, and content is 45% magnesium chloride 37.5kg, and mixed Baume is than being the 25-27 degree.
With the raw material of ecological inorganic composite architectural materials by its formulation ratio after fully mixing, promptly can be made into all kinds of building structural materials.Ecological inorganic composite architectural materials of the present invention has environmental protection and energy saving, light thermal-insulation, flawless, the convergent-divergent coefficient is little, fire prevention, waterproof, moistureproof, characteristics such as mothproof radiationless weather proof erosion and antifungal, add the enhancing of glass fiber cloth by adjusting ecological inorganic composite architectural materials formulation ratio surface, add various mill base masterbatch, promptly can be processed into shades of colour by various moulds, the material of construction of different type body, the simultaneously also compatible good characteristic of timber, as be easy to that nail digs and cutting, fixing, bonding, natural texture is strong, get close to nature, material and asepsis environment-protecting etc., therefore at building materials, packing, transportation, the adnornment industry widespread use, the ecological circulation inorganic composite architectural materials is widely used its main application fields to be had: various building structural materials are as various roofing decorative tiles, the indoor and outdoor decorative sheet, fence, wall dunnage, wallboard, top ceiling, wallboard, sash, high speed and skyway insulating board, building template, all kinds of European structures and gadget, curb slabstone etc.

Claims (2)

1. ecological inorganic composite architectural materials, it is characterized in that: it is made up of inorganic gel material, crop stalk vegetable fibre and three wastes inorganic wastes, organic materials properties-correcting agent and stirred solution four part materials;
The components by weight percent of raw material is:
The inorganic gel material is: 0.2 part of 1 part in magnesium oxide, 0.5 part of calcium sulphate hemihydrate and high-alumina cement;
Crop stalk vegetable fibre and three wastes inorganic wastes are: 1.2 parts of the tankage of crop stalk plant fiber powder or vegetation powder or wood working or wood shavings or wood powders; Comprise with three wastes inorganic wastes: 0.3 part of 0.3 part in flyash and useless foam beads or paper waste or vermiculite power or bagasse or glycyrrhiza residue or Herba Ephedrae slag;
By naphthalene series water reducer NNO, naphthalene series water reducer MF4, wooden calcium sulfonate, emulsifying agent, permeate agent peregal and water, by weight 4: 3: 2: 2.5: 1.5: 13 ratio was formed organic materials properties-correcting agent, 0.026 part of organic materials properties-correcting agent;
By 2.4 parts of the mixed stirred solutions that is made of magnesium chloride and sal epsom, contain in per 1 part: Baume is than the sal epsom 62.5kg of 10 degree, and content is 45% magnesium chloride 37.5kg, and mixed Baume is than being the 25-27 degree.
2. ecological inorganic composite architectural materials according to claim 1 is characterized in that: the making method of described organic materials properties-correcting agent:
The naphthalene series water reducer NNO that (1) will make, naphthalene series water reducer MF4, wooden calcium sulfonate, emulsifying agent, permeate agent peregal, by its part by weight be: 4 parts: 3 parts: 2 parts: 1.5 parts: 2.5 parts, the water that adds 13 parts is put into vessel in heating to boiling with water;
(2) naphthalene series water reducer NNO, naphthalene series water reducer MF4, wooden calcium sulfonate are added in the entry successively, add emulsifying agent again after enduring dissolved in the water fully, the permeate agent peregal dissolves and gets final product;
(3) treat to pack into after organic materials properties-correcting agent cools off fully in the container and to use when stirring the inorganic gel material.
CN2007100100194A 2007-01-10 2007-01-10 Ecological inorganic composite architectural materials Expired - Fee Related CN101012120B (en)

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CN101012120B true CN101012120B (en) 2010-08-11

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CN104326721A (en) * 2014-09-22 2015-02-04 沈礼群 Wall body thermal insulation decontamination disinfection flame retardant plant fiber and preparation method thereof
CN105198370A (en) * 2015-09-16 2015-12-30 安徽省中正农业科技开发有限公司 High-strength biomass wall and production process thereof
CN105294067A (en) * 2015-11-27 2016-02-03 浙江鑫城建材科技有限公司 Ceramsites and self-thermal insulation ceramsite building block production process
CN105731900B (en) * 2016-02-16 2018-05-22 大连华源新型环保材料科技有限公司 Environment protecting paper soil composite material
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KR20190104166A (en) * 2017-01-12 2019-09-06 유로 트레이드 플로어링 에스.엘. Plates to Cover Horizontal and Vertical Surfaces
CN108238778A (en) * 2017-01-19 2018-07-03 浙江农林大学 Chlorine oxygen magnesium-based particieboard and preparation method thereof
CN109665803A (en) * 2018-11-23 2019-04-23 安徽耐特嘉信息科技有限公司 Magnesium oxysulfide is modified board capable of replacing wood board material
CN110436844A (en) * 2019-09-09 2019-11-12 安徽省中坤元新型建材有限公司 A kind of improved environment protection cement plate
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