CN101011060A - Pesticide composition comprising highly effective cypermethrin and hexaflumuron - Google Patents
Pesticide composition comprising highly effective cypermethrin and hexaflumuron Download PDFInfo
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- CN101011060A CN101011060A CN 200710063831 CN200710063831A CN101011060A CN 101011060 A CN101011060 A CN 101011060A CN 200710063831 CN200710063831 CN 200710063831 CN 200710063831 A CN200710063831 A CN 200710063831A CN 101011060 A CN101011060 A CN 101011060A
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- cypermethrin
- beta
- bell urea
- fluorine bell
- fluorine
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Abstract
The invention relates to a pesticide composition comprising synergistically effective dose of highly performance cypermethrin and Hexaflumuron by a preferred weight ratio of 1:1-9:1, more preferably 7:3-8:2. The pesticide composition can be used for controlling common house-flies and Blattidae.
Description
Technical field
The present invention relates to a kind of synergetic pesticide composition, particularly relate to a kind of synergetic pesticide composition that comprises beta-cypermethrin and fluorine bell urea.
Background technology
Beta-cypermethrin (alphamethrin) is a kind of pyrethroid insecticides of efficient, wide spectrum.This medicine is the neural axon conduction depressant drug, belongs to never poison, and effect has the better prevention effect to the various pests on wheat, cotton, vegetables, fruit, the Soybean and Other Crops rapidly, and some insect is also had ovicidal action.The beta-cypermethrin synthesis technique is simple, and use cost is lower, therefore is widely used in agricultural insect management.But beta-cypermethrin also has very significant disadvantages, and it is shorter that is exactly the lasting period, in actual applications because the medication frequency is higher, causes pest resistance to insecticide to produce, and drug effect descends.
Fluorine bell urea (hexafluron) is a kind of novel process for preparation of benzoylurea compounds, and its main mechanism of action is to suppress chitin to synthesize, and the obstruction insect normally casts off a skin and be abnormal.This medical instrument has very high larva and ovicidal activity extremely, and adult is had sterile effect, hinders the growth of ovum.This medicine has action of contace poison concurrently based on stomach poison function, and the power of knocking down is strong, and effect rapidly.It is mainly used in Lepidoptera on the crops such as control cotton, vegetables, fruit tree and coleoptera, Homoptera, Diptera pest.
The applicant is through discovering in a large number, and beta-cypermethrin and fluorine bell urea are used with has unforeseeable control efficiency to preventing and treating sanitary insect pest such as housefly and blattaria, and its synergistic effect is fairly obvious.And, the two use with to sanitary insect pests such as control housefly and blattaria have efficiently, quick-acting is good, the lasting period is long, delay pesticide resistance, environmentally safe etc. characteristics, so is that extraordinary sanitary insect pest is prevented and treated medicament.In addition, the applicant finds by retrieval, still do not have relevant beta-cypermethrin and fluorine bell urea to be mixed at present both at home and abroad and prevent and treat the play-by-play of sanitary insect pest, its relevant report only is to prevent and treat eliminating fish parasites at use fluorine bell urea described in the Chinese patent application 00113613.5 and chlorine cyanogen polyester, but because the active component of itself and the used composition pesticide of the application, controlling object, mixed ratio etc. are all inequality, and it does not provide any synergism test data that are mixed yet.Based on above-mentioned discovery, the applicant has finished the present invention.
Summary of the invention
The object of the present invention is to provide a kind of mixed ratio reasonable, control efficiency is good, the synergetic pesticide composition that drug cost is low.
Another object of the present invention is to provide by formulations such as the formulated missible oil of this composition pesticide, microemulsion, wetting powder, water dispersible granules.
Another object of the present invention is to provide the purposes that this composition pesticide is used to prevent and treat housefly and blattaria.
Technical scheme of the present invention is as described below:
A kind of composition pesticide is characterized in that containing the efficient chlorine cyanogen polyester and the fluorine bell urea of synergy effective dose.
The weight ratio of efficient chlorine cyanogen polyester and fluorine bell urea is preferably 1: 1-9: 1, more preferably 7: 3-8: 2.Composition pesticide of the present invention can be mixed with formulations such as missible oil, microemulsion, wetting powder, water dispersible granules according to those skilled in the art of the present technique's known method.
But used additives has when preparation missible oil:
Solvent and cosolvent have aromatic hydrocarbons, aliphatic hydrocarbon, ethers, phenols, alcohols etc., for example benzene, benzinum, methyl alcohol, dimethylbenzene, ethanol, n-butanol, toluene, isoamyl alcohol, ethyl acetate, chloroform, kerosene, methyl-sulfoxide, phenol, machine oil etc.Wherein the content of solvent and cosolvent generally accounts for 15-90wt%.
Emulsifier has aliphatic alcohol polyethenoxy base ether, alkylphenol polyoxyethylene, styryl phenol polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, castor oil polyoxyethylene ether, fatty acid polyglycol oxy alkylene ester, alkylaryl sulfonates etc., for example 2201, agricultural newborn 0203B, 0201B, 6202B, agricultural newborn OX-2568,500#, 600#, 700#, 6201,602,790,1602,1303,603 etc.Emulsifier can be the mixed of one or more, and general consumption accounts for 10-20wt%.
The pH value conditioning agent has sodium hydroxide, potassium hydroxide, hydrochloric acid, acetic acid etc., and general consumption accounts for 0.5-1wt%.
But used additives has when the preparation microemulsion:
Emulsifier has alkylbenzenesulfonate series, diphenyl phenolic group polyoxyethylene poly-oxygen propylene aether, polyoxyethylene groups talan methyl phenylate, styrenated phenol APEO, polyoxyethylene groups styrene phenolic group ether, alkylphenol polyoxyethylene formaldehyde condensation products, diphenyl phenolic group APEO formaldehyde condensation products, castor oil ethylene oxide adduct and derivative thereof etc., for example agricultural newborn 300#, 700#, OX-2511, farming breast 2201, farming breast 500, agricultural newborn Sorpl KS, peaceful breast 130, NP series etc.Emulsifier can be one or more mixing, and general consumption accounts for 10-30wt%.
Solvent and cosolvent have arene, alcohols, ester class, ketone, amide-type, for example methyl alcohol, ethanol, butanols, acetone, toluene, dimethylbenzene, dimethyl formamide, cyclohexanone, dimethyl sulfoxide (DMSO), pyrrolidones, C
3-6Ketone etc. can be one or more mixtures, and general consumption accounts for 20-60wt%
Antifreezing agent has glycerine, propane diols, ethylene glycol, sodium chloride, urea, glycerine, sorbierite etc., and general consumption accounts for 1-8wt%.
Stabilizing agent has urea, methyl alcohol, benzinum, wettable starch, tolyl glycidic alcohol etc., and general consumption accounts for 0.5-10wt%.
Defoamer has organic silicone oil, methyl alcohol, ethanol, epoxy soybean wet goods, and general consumption accounts for 0.5-8wt%.
But used additives has when the preparation wetting powder:
Carrier (filler) has kaolin, atlapulgite, diatomite, mud coal, precipitated calcium carbonate, white carbon, pyrophillite, talcum powder, calcite etc.Can be one or more mixing, general consumption accounts for 15-75wt%
Dispersant has anionic dispersing agent, sulfurous acid to refer to waste liquid, sodium lignin sulfonate, calcium lignosulfonate, non-ionic surface active agent such as polyoxyethylene polyoxypropylene base ether block copolymers, alkylphenol-polyethenoxy base phosphate etc.Can be one or more mixing, general consumption accounts for 5-35wt%.
Wetting agent has the withered powder of natural products and anionic surfactant such as tea, spaonin powder, SOPA (230,270,235), washing powder, neopelex, draws back powder, No. 2000 series of farming breast, wetting and penetrating agent F etc.Can be one or more mixing, general consumption accounts for 5-30wt%.
Other stabilizing agents, defoamer are equal to microemulsion.
But used additives has when the preparation water dispersible granules:
Wetting agent can be sodium alkyl benzene sulfonate, sodium lignin sulfonate, fatty alcohol, alkyl sulfate, alkylphenol polyoxyethylene, lignosulfite, the withered powder of tea, spaonin powder etc.Can be one or more mixing, general consumption accounts for 5-30wt%.
Dispersant can be ethoxylated dodecyl alcohol, naphthalenesulfonic acid-formaldehyde condensate (N N O), dioctyl sodium sulphosuccinate, acrylate homopolymer sodium salt, JFC etc.Can be one or more mixing, general consumption accounts for 5-10wt%.
Carrier adularescent kaolin, precipitated calcium carbonate, white carbon, montmorillonite, diatomite, rice husk etc.Can be one or more mixing, general consumption accounts for 15-70wt%.
Binding agent has soybean lecithin, gelatin, polyvinyl alcohol, polyethylene glycol, ring essence, rosin, starch etc. recklessly.Can be one or more mixing, general consumption accounts for 1-10wt%.
Disintegrant has bentonite, ammonium sulfate, urea, magnesium chloride, sodium chloride etc.Can be one or more mixing, general consumption accounts for 5-15wt%.
Embodiment:
The invention will be further described below in conjunction with embodiment, but the present invention never is limited to following embodiment.Example of formulations 1: the weight proportion of each component of missible oil
Beta-cypermethrin 8%
Fourth fluorine bell urea 2%
500# 10％
Toluene polishing to 100%
Example of formulations 2: the weight proportion of each component of microemulsion
To imitating cypermethrin 3.5%
Fluorine bell urea 0.5%
Glycerine 5%
Sodium lignin sulfonate 20%
The newborn 0203B 10% of farming
Deionized water polishing to 100%
Example of formulations 3: the weight proportion of each component in the wetting powder
Beta-cypermethrin 4.5%
Fluorine bell urea 2.5%
Neopelex 20%
Calcium lignosulfonate 15%
Atlapulgite polishing to 100%
Biological Examples 1: efficient chlorine cyanogen polyester and fluorine bell urea are used the co-toxicity coefficient measurement result to housefly and blattaria with
Table 1 beta-cypermethrin and fluorine bell urea are used with the housefly virulence
| Medicament (weight ratio) | Y＝a+bx | r | LC 50μg/ml | 95% confidence limit μ g/ml | Co-toxicity coefficient |
| Beta-cypermethrin | Y＝2.7782+1.2737x | 0.9923 | 55.1 | 38.9～78.0 | - |
| Fluorine bell urea | Y＝1.8341+1.4726x | 0.9812 | 137.6 | 104.0～182.2 | - |
| Beta-cypermethrin: fluorine bell urea (1: 1) | Y＝2.5429+1.3674x | 0.9868 | 62.3 | 45.6～85.0 | 126 |
| Beta-cypermethrin: fluorine bell urea (3: 2) | Y＝3.0670+1.3082x | 0.9727 | 32.0 | 22.7～45.3 | 227 |
| Beta-cypermethrin: fluorine bell urea (7: 3) | Y＝2.6002+1.7517x | 0.9779 | 23.5 | 18.3～30.2 | 286 |
| Beta-cypermethrin: fluorine bell urea (8: 2) | Y＝3.7826+0.9898x | 0.9880 | 22.2 | 14.0～35.2 | 282 |
| Beta-cypermethrin: fluorine bell urea (9: 1) | Y＝3.1635+1.3397x | 0.9676 | 24.6 | 17.8～34.1 | 238 |
Table 2 beta-cypermethrin and fluorine bell urea are used with the blattaria virulence
| Medicament (weight ratio) | Y＝a+bx | r | LC 50 μg/ml | 95% confidence limit μ g/ml | Co-toxicity coefficient |
| Beta-cypermethrin | Y＝1.3654+1.5664x | 0.9882 | 208.3 | 160.5～270.3 | - |
| Fluorine bell urea | Y＝1.2189+1.2816x | 0.9696 | 861.2 | 616.6～1202.9 | - |
| Beta-cypermethrin: fluorine bell urea (1: 1) | Y＝0.1416+2.0681x | 0.9508 | 219.9 | 177.0～273.1 | 153 |
| Beta-cypermethrin: fluorine bell urea (3: 2) | Y＝2.7928+0.9830x | 0.9651 | 176.8 | 116.4～268.6 | 169 |
| Beta-cypermethrin: fluorine bell urea (7: 3) | Y＝1.7513+1.5038x | 0.9799 | 142.5 | 106.9～190.1 | 189 |
| Beta-cypermethrin: fluorine bell urea (8: 2) | Y＝2.2430+1.3014x | 0.9553 | 128.3 | 92.63～177.7 | 192 |
| Beta-cypermethrin: fluorine bell urea (9: 1) | Y＝1.8806+1.4926x | 0.9546 | 120.7 | 90.49～161.1 | 187 |
Biological Examples 2: the test of pesticide effectiveness result of beta-cypermethrin and fluorine bell urea mixture
5% high chlorine fluorine suspending agent, 10% high chlorine fluorine missible oil and 7% high chlorine fluorine wetting powder are diluted 400,800 and 1200 times respectively to housefly spraying processing, 12,48 hours investigation preventive effects behind the medicine, the result is as follows:
400,800,1200 times of 5% high chlorine fluorine suspending agent dilutions, 12 hours preventive effects are respectively 93%, 76%, 65% behind the medicine; Preventive effect was respectively 97%, 95%, 90% in 48 hours.
400,800,1200 times of 10% high chlorine fluorine missible oil dilutions, 12 hours preventive effects are respectively 98%, 82%, 67% behind the medicine; Preventive effect was respectively 96%, 94%, 92% in 48 hours.
400,800,1200 times of 7% high chlorine fluorine wettable powder dilution agents, 12 hours preventive effects are respectively 92%, 74%, 63% behind the medicine; Preventive effect was respectively 95%, 90%, 87% in 48 hours.
Claims (5)
1. composition pesticide is characterized in that containing the beta-cypermethrin and the fluorine bell urea of synergy effective dose.
2. according to the composition pesticide of claim 1, it is characterized in that the weight ratio of beta-cypermethrin and fluorine bell urea is 1: 1～9: 1.
3. according to the composition pesticide of claim 2, it is characterized in that the weight ratio of beta-cypermethrin and fluorine bell urea is 7: 3～8: 2.
4. according to the described composition pesticide of arbitrary claim formulated missible oil, microemulsion, wetting powder or the water dispersible granules of claim 1 to 3.
5. the purposes that the described composition pesticide of arbitrary claim of claim 1 to 3 is used for anti-housefly and blattaria.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100638313A CN100508754C (en) | 2007-02-12 | 2007-02-12 | Pesticide composition comprising highly effective cypermethrin and hexaflumuron |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100638313A CN100508754C (en) | 2007-02-12 | 2007-02-12 | Pesticide composition comprising highly effective cypermethrin and hexaflumuron |
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| Publication Number | Publication Date |
|---|---|
| CN101011060A true CN101011060A (en) | 2007-08-08 |
| CN100508754C CN100508754C (en) | 2009-07-08 |
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| CNB2007100638313A Expired - Fee Related CN100508754C (en) | 2007-02-12 | 2007-02-12 | Pesticide composition comprising highly effective cypermethrin and hexaflumuron |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102379306A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultra-low volume liquid agent containing hexaflumuron |
| CN105685023A (en) * | 2016-02-19 | 2016-06-22 | 河北岗恩生物科技有限公司 | Beta-cypermethrin-containing aromatic-free emulsifiable concentrate and preparation method thereof |
| CN106719780A (en) * | 2016-12-26 | 2017-05-31 | 中国农业科学院植物保护研究所 | A kind of synergetic pesticide composition containing gamma cyhalothrin Yu HEXAFLUMURON |
-
2007
- 2007-02-12 CN CNB2007100638313A patent/CN100508754C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102379306A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultra-low volume liquid agent containing hexaflumuron |
| CN105685023A (en) * | 2016-02-19 | 2016-06-22 | 河北岗恩生物科技有限公司 | Beta-cypermethrin-containing aromatic-free emulsifiable concentrate and preparation method thereof |
| CN106719780A (en) * | 2016-12-26 | 2017-05-31 | 中国农业科学院植物保护研究所 | A kind of synergetic pesticide composition containing gamma cyhalothrin Yu HEXAFLUMURON |
| CN106719780B (en) * | 2016-12-26 | 2019-04-02 | 中国农业科学院植物保护研究所 | A kind of synergetic pesticide composition containing gamma cyhalothrin and flubenzuron |
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| Publication number | Publication date |
|---|---|
| CN100508754C (en) | 2009-07-08 |
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Granted publication date: 20090708 Termination date: 20130212 |