CN101010241A - Liquid dispensing method and system with headspace gas removal - Google Patents

Liquid dispensing method and system with headspace gas removal Download PDF

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Publication number
CN101010241A
CN101010241A CNA200580011316XA CN200580011316A CN101010241A CN 101010241 A CN101010241 A CN 101010241A CN A200580011316X A CNA200580011316X A CN A200580011316XA CN 200580011316 A CN200580011316 A CN 200580011316A CN 101010241 A CN101010241 A CN 101010241A
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gas
endogenous pyrogen
liquid
empty
amount
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Chinese (zh)
Inventor
凯文·T·欧多尔蒂
拉塞尔·F·奥伯芝
约瑟夫·P·门宁
格雷戈里·B·诶登
唐纳德·C·格兰特
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Advanced Technology Materials Inc
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Advanced Technology Materials Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D7/00Apparatus or devices for transferring liquids from bulk storage containers or reservoirs into vehicles or into portable containers, e.g. for retail sale purposes
    • B67D7/02Apparatus or devices for transferring liquids from bulk storage containers or reservoirs into vehicles or into portable containers, e.g. for retail sale purposes for transferring liquids other than fuel or lubricants
    • B67D7/0238Apparatus or devices for transferring liquids from bulk storage containers or reservoirs into vehicles or into portable containers, e.g. for retail sale purposes for transferring liquids other than fuel or lubricants utilising compressed air or other gas acting directly or indirectly on liquids in storage containers
    • B67D7/0255Apparatus or devices for transferring liquids from bulk storage containers or reservoirs into vehicles or into portable containers, e.g. for retail sale purposes for transferring liquids other than fuel or lubricants utilising compressed air or other gas acting directly or indirectly on liquids in storage containers squeezing collapsible or flexible storage containers
    • B67D7/0261Apparatus or devices for transferring liquids from bulk storage containers or reservoirs into vehicles or into portable containers, e.g. for retail sale purposes for transferring liquids other than fuel or lubricants utilising compressed air or other gas acting directly or indirectly on liquids in storage containers squeezing collapsible or flexible storage containers specially adapted for transferring liquids of high purity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Sampling And Sample Adjustment (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
  • Loading And Unloading Of Fuel Tanks Or Ships (AREA)
  • Packages (AREA)

Abstract

A liquid dispensing method and system for dispensing from a container including an outer container and an inner container, a portion of the inner container occupied by the liquid, a remainder of the inner container occupied by a headspace gas. The system includes a probe having a flow passage therein and a gas passage communicating between the interior of the inner container and an exterior of the outer container. Fluid (such as air or nitrogen) is caused to flow under pressure into a space between inner walls of the outer container and the inner container to force the headspace gas out of the inner container via the gas passage and to force liquid out of the inner container through the flow passage in the probe to a manufactuaring process.

Description

Fluid dispensation method that headspace gas removes and system
Technical field
The present invention relates to a kind of be used for liquid deposit and distribute deposit and distribution system.More specifically, the present invention relates to a kind of being used for liquid from comprising the method and system that the headspace gas containers is assigned to manufacturing process.
Background technology
Some manufacturing process need be used such as liquid chemical such as acid, solvent, alkali, photoresist (photoresist), dopant (dopant), inorganic solution, organic solution, biological solution, medicine and radio chemistry goods.Depositing with distribution system allows to use selectable container so that liquid chemical at the appointed time is dispensed to manufacturing process.These process liquids are distributed from depositing with dispense container of pressurization by special monoplunger pump (dispensing pump) usually.
After these containers were filled at the pad device place, container typically was transported to the position of using in manufacturing process.In case at manufacturing process equipment place, before being connected to manufacturing process, these containers can be by long-term storage.Yet when the above chemicals of enumerating during by long-term storage, the purity of the chemicals of enumerating more than some trends towards decay.For example, in the manufacturing of thin film transistor flat-panel monitor, owing to be released between transportation and storage period as the free radical (free radical) in the employed color filter of the result of temperature fluctuation (colorfilter) chemicals, employed color filter chemicals trends towards decay.Take place here for anti-, the part of the sky of container is called head room, is filled with headspace gas.The decay that chemical reaction prevents liquid chemical takes place by being suppressed at during storage in headspace gas in the liquid.For example, under the situation of color filter chemicals, the headspace gas that comprises oxygen is imported in the container at the pad device place, because oxygen trends towards extracting free radical in the chemicals when free radical is released, thereby prevents the decay of color filter chemicals.
When container is connected to manufacturing process, no longer needs or require headspace gas.Therefore, before distributing the liquid to manufacturing process, must remove headspace gas.Yet, must be noted that when discharging headspace gas and will avoid stirring container or headspace gas being pushed in the liquid chemical.Gas imported can cause forming bubble in the chemicals in chemicals, this can be used in the liquid chemical defectiveness in the manufacturing process.
In addition, preferably after the removing of headspace gas, a small amount of gas is stayed in the container.When all liq during from container allocation, this a small amount of empty gas that detects is assigned with device and detects to show that container is empty.In legacy system, the amount that is retained in the sky detection gas in the container is wayward.
Therefore, need a kind of system, this system allows headspace gas to remove easily, and if desired, makes the sky that is retained in after headspace gas removes in the container detect gas flow and regulate easily.
Summary of the invention
The present invention is dispensed to the method and system of manufacturing process with liquid chemical from container a kind of being used for, and described container comprises outer container and endogenous pyrogen, and the part of endogenous pyrogen is occupied by liquid chemical, and the remainder of endogenous pyrogen is occupied by headspace gas.This system comprises pipeline (probe) and gas passage, and described pipeline has flow channel therein, and described pipeline can insert the inside of internal container, and described gas passage makes between the outside of the inside of endogenous pyrogen and outer container and is communicated with.This system further comprises device, described device is communicated with the inwall of outer container and the space fluid between the endogenous pyrogen, be used for fluid under the authorized pressure and flow into the inwall of outer container and the space between the endogenous pyrogen, arrive manufacturing process by ducted flow channel headspace gas extruded endogenous pyrogen, to be extruded endogenous pyrogen to the headspace gas discharge orifice and with liquid via gas passage.
In a preferred embodiment, this system further comprises the discharge-service valve that is connected between headspace gas discharge orifice and the gas passage.Discharge-service valve has the open position, and described open position can be selected to allow headspace gas to be expelled to the headspace gas discharge orifice via gas passage.Discharge-service valve also has off position, when headspace gas when the inside of endogenous pyrogen is drained described off position can select.System also preferably includes liquid sensor, and described sensor is connected when liquid chemical begins to flow to indicate headspace gas to be drained from the inside of endogenous pyrogen to detect between gas passage and the headspace gas discharge orifice in gas passage.
System also preferably includes the sky detecting device, and described empty detecting device is used to detect when liquid chemical is drained from endogenous pyrogen.In one embodiment, empty detecting device is the empty gas sensor that detects.In use, be right after liquid chemical is assigned to before the manufacturing process in a spot of empty inside of detecting gas importing content device.When liquid chemical during from vessel empty, the empty gas sensor that detects detects this sky and detects gas.When sky detection gas was detected by sky detection gas sensor, liquid was interrupted to the distribution of manufacturing process.In another embodiment, empty detecting device comprises scale, and described scale is used for the weight of weighing fluid container when liquid is assigned to manufacturing process, and the distribution of liquid is interrupted when reaching as the measured predetermined bare weight amount of scale with convenient fluid container.
Description of drawings
Fig. 1 is the scheme drawing of system according to a preferred embodiment of the invention, and this system is used for liquid from the container allocation that comprises headspace gas to manufacturing process, described headspace gas be provided to the transportation of container and storage period the chien shih liquid stabilising;
Fig. 2 is the scheme drawing of system according to another preferred embodiment of the invention, and this system is used for liquid from the container allocation that comprises headspace gas to manufacturing process, described headspace gas be provided to the transportation of container and storage period the chien shih liquid stabilising.
The specific embodiment
Fig. 1 is the scheme drawing of system 10 according to a preferred embodiment of the invention, and described system 10 is used for liquid 12 is dispensed to manufacturing process 13 from container 14, and described container 14 comprises the head room 16 that is filled with headspace gas 18.Container 16 comprises flexible inner 20 and rigid outer container 22.System 10 further comprises pressurized air or source nitrogen (supply) 30, compressed air channel 32, headspace gas passage 34, discharge-service valve 36, liquid sensor 38, headspace gas discharge orifice 40, flow channel 42, receptacle balance (scale) 44 and system controller 46.
Compressed air source 30 is connected to compression space 31 (that is the space between the outside face of the inwall of outer container 22 and endogenous pyrogen 20) by compressed air channel 32.The inside of endogenous pyrogen 20 is connected to headspace gas discharge orifice 40 by gas passage 34.Discharge-service valve 36 and liquid sensor 38 are connected between the inside of endogenous pyrogen 20 and headspace gas discharge orifice 40 along gas passage 34.At last, the inside of endogenous pyrogen 20 is communicated with manufacturing process 13 fluids by flow channel 42.
Gas passage 34 preferably is combined in the single connector assembly (package) with flow channel 42 and is communicated with so that one of the inner utilization of endogenous pyrogen 20 is connected with headspace gas discharge orifice 40 and manufacturing process 13 fluids.Flow channel 42 typically is arranged in the pipeline (probe), and the port that described pipeline can pass container inserts in the endogenous pyrogen 20 to provide the fluid between liquid 12 and the manufacturing process 13 to be communicated with.
Outer container 22 provides flexible inner 20 (for example, flexible polymer bag) in filling, transmission, processing and desired mechanical support and protection between allotment period.Outer container 22 typically is made of metal, but also can use other material that comprises plastic material according to the government regulation standard of the processing of waiting to be included in container 14 in-to-in special liquids.Preferably, container 14 is the US Patent .No.5 that authorize Osgar as on August 9th, 1994, the container shown in 335,821, and described patent No.5,335,821 are merged in by reference herein.
The system controller 46 that is preferably based on the control system of microprocessor is connected to compressed air source 30, discharge-service valve 36, liquid sensor 38 and receptacle balance 44.The operation of the whistle control system 10 that system controller 46 receives according to the various elements from system 10.
Before being connected in manufacturing process 13, container 14 is filled at the pad device place.During filling, endogenous pyrogen 20 is at first charged into the gas such as nitrogen.Liquid 12 is imported into to fill the endogenous pyrogen 20 in the outer container 22 by the port in the container 14 then.
When long-term storage, especially when standing temperature fluctuation, the purity of some chemicalss trends towards decay.For example, in the manufacturing of thin film transistor flat-panel monitor, because the free radical in the color filter chemicals is released between transportation and storage period, so employed color filter chemicals trends towards decay or cross linkage.Take place here for anti-, the part of the sky of container, head room 16 is filled headspace gas 18.Headspace gas 18 is by suppressing the decay that liquid 12 takes place to prevent chemical reaction in liquid 12 in the transportation of container 14 with between storage period.For example, under the situation of color filter chemicals, because oxygen trends towards extracting the free radical in the chemicals when free radical is released, the headspace gas 18 that therefore comprises oxygen is imported in the endogenous pyrogen 20 at the pad device place, thereby prevents the decay or the cross linkage of color filter chemicals.
When container 14 will be connected to manufacturing process 13, no longer need or require headspace gas 18.Therefore, must before liquid 12 is dispensed to manufacturing process 13, headspace gas 18 be removed.At first, compressed air channel 32, gas passage 34 and flow channel 42 are connected to container 14.The system controller 46 that is preferably then based on microprocessor system sends signal to open discharge-service valve 36.This produces fluid and connects between the inside of endogenous pyrogen 20 and headspace gas discharge orifice 40.Subsequently, pressure fluid, preferred compressed air or nitrogen are supplied to compression space 31 by compressed air source 30 and pass through gas passage 34 to promote headspace gas 18, and by liquid sensor 38, arrive headspace gas discharge orifice 40.When headspace gas 18 when the endogenous pyrogen 20 of container 14 withdraws from, air is allowed to enter compression space 31, thus shrinkage flexible inner 20.Although endogenous pyrogen 20 preferably utilizes the forced air shrinkage, any can all can being used with the device of promotion headspace gas 18 by gas passage 34 by shrinkage endogenous pyrogen 20 comprises the device based on hydraulic pressure or machinery.As selection, the pump that is connected in gas passage 34 can be extracted headspace gas 18 out from container 14.
In headspace gas 18 after endogenous pyrogen 20 emptyings, along with compressed air source 30 provides air to compression space 31 continuously, liquid 12 beginning inflow gas passages 34.When liquid 12 arrived liquid sensor 38, signal was sent to system controller 46 to close discharge-service valve 36.This has interrupted the inside of endogenous pyrogen 20 and the connection between the headspace gas discharge orifice 40.As selection, but user's vision of system 10 determine when liquid 12 beginning inflow gas passages 34, and manual-lock discharge-service valve 36 is to interrupt to the connection of headspace gas discharge orifice 40.
When the inside of endogenous pyrogen 20 and the connection between the headspace gas discharge orifice 40 be interrupted, along with compressed air source 30 is supplied to pressurized air compression space 31 continuously, liquid 12 was pushed upwardly by flow channel 42.Along with the flexible inner 20 of liquid 12 from container 14 withdraws from, air is allowed to enter compression space 31, thereby makes endogenous pyrogen 20 shrinkages.Although endogenous pyrogen 20 preferably utilizes the forced air shrinkage, any can all can being used with the device of promotion liquid by flow channel 42 by shrinkage endogenous pyrogen 20 comprises the device based on hydraulic pressure or machinery.As selection, the pump or the Venturi tube that are connected in flow channel 42 can be extracted liquid 12 out from container 14.
Here, importantly be noted that, will begin in the pass into solution according to Henry theorem (Henry ' s law) headspace gas 18 if headspace gas 18 is not removed before liquid 12 is dispensed to manufacturing process 13.The Henry theorem is: in steady temperature, the amount that is dissolved in the gas in the solution is directly proportional with the pressure of the gas of solution top.Therefore, because endogenous pyrogen 20 is compressed 30 shrinkages of air source so that liquid 12 is released endogenous pyrogen 20, so the pressure of headspace gas 18 will increase in this process.This will make headspace gas 18 dissolve in liquid 12, thereby cause the generation of harmful bubble when liquid 12 is transported to process 13.
Along with liquid 12 just is being assigned to manufacturing process 13, the weight of container 14 reduces.Receptacle balance 44 claims the weight of container 14 to determine when container 14 reaches predetermined bare weight amount continuously when liquid 12 is assigned to manufacturing process 13.The bare weight amount of container 14 is meant that inside has the weight of the outer container 22 of empty endogenous pyrogen 20.By 44 pairs of bare weight amounts of receptacle balance determine guarantee that all liq 12 is assigned with from endogenous pyrogen 20.
When receptacle balance 44 determined that container 14 is empty, system controller 46 sent signal to turn off compressed air source 30.Subsequently, compressed air channel 32, gas passage 34 and flow channel 42 and empty container 14 disconnections, empty container 14 removes from system 10, and the new container 14 that comprises liquid 12 and headspace gas 18 is connected in system 10.Distribution from the liquid 12 of container 14 restarts then.
Fig. 2 is the scheme drawing of system 50 according to another preferred embodiment of the invention, and described system 50 is used for liquid 12 is dispensed to manufacturing process 13 from container 14.Container 14 comprises headspace gas 18, described headspace gas 18 be provided to the transportation of container 14 and storage period chien shih liquid 12 stable.Container 16 comprises flexible inner 20 and rigid outer container 22.Similar to the system 10 shown in Fig. 1, system 50 comprises compressed gas source 30, compressed air channel 32, headspace gas passage 34, liquid sensor 38, headspace gas discharge orifice 40, flow channel 42 and system controller 46.In addition, system 50 comprises the empty gas source 52 that detects, setting device (regulator gauge) 54, the first shutdown valves 55, amount of gas controller 56, the second shutdown valves 58, selector valve 60 and the empty gas sensor 62 that detects.
Compressed air source 30 is connected in compression space 31 via compressed air channel 32.Selector valve 60 is three port valve, and described selector valve 60 is connected in device with the inside (via gas passage 34) of endogenous pyrogen 20, and described device is connected to selector valve port 60a or selector valve port 60b according to the location status of selector valve 60.More specifically, in primary importance selector valve 60 in the inside of endogenous pyrogen 20 be connected between the device of port 60a (being liquid sensor 38 and headspace gas discharge orifice 40) and provide fluid to connect.Liquid sensor 38 is connected between selector valve 60 and the headspace gas discharge orifice 40.In the second place, selector valve 60 is in the inside of endogenous pyrogen 20 and be connected between the device of port 60b (promptly empty gas source 52, setting device 54, the first shutdown valves 55, the amount of gas controller 56, and second shutdown valve 58 of detecting) the fluid connection is provided.Setting device 54, the first shutdown valves 55, the amount of gas controller 56 and second shutdown valve 58 are connected empty the detection between gas source 52 and the selector valve 60.At last, the inside of endogenous pyrogen 20 is communicated with manufacturing process 13 fluids via flow channel 42.The empty moving passage 42 of gas sensor 62 longshore currents that detects is connected.
Gas passage 34, flow channel 42 and selector valve 60 preferably are combined in the single connector assembly so that utilize one to be connected internal connection with endogenous pyrogen 20 in headspace gas discharge orifice 40, empty gas source 52 and the manufacturing process 13 of detecting.Flow channel 42 typically is arranged in the pipeline, and described pipeline can pass the port of container and insert in the endogenous pyrogen 20 to provide fluid to be communicated with between liquid 12 and manufacturing process 13.
In the embodiment shown in Fig. 2, system controller 46 is connected to compressed air source 30, liquid sensor 38, setting device 54, the first shutdown valves 55, the second shutdown valves 58, selector valve 60 and the empty gas sensor 62 that detects.The operation of the whistle control system 50 that system controller 46 receives according to the various elements from system 50.
As mentioned above, when container 14 will be connected to manufacturing process 13, no longer need or require headspace gas 18.Therefore, before being dispensed to manufacturing process 13, liquid 12 headspace gas 18 must be removed.It is the same with process system 10 to remove the process of headspace gas 18 from container 14 in system 50.At first, compressed air channel 32, gas passage 34 and flow channel 42 are connected to container 14.System controller 46 sends a signal to selector valve 60 then, and the primary importance that makes selector valve 60 go to it connects with (via selector valve port 60a) generation fluid between the inside and headspace gas discharge orifice 40 of endogenous pyrogen 20.The user of system 50 also can manually go to selector valve 60 its primary importance.Subsequently, pressure fluid, preferred compressed air or nitrogen are supplied to compression space 31 to promote headspace gas 18 by gas passage 34 by compressed air source 30, by liquid sensor 38 and arrive headspace gas discharge orifice 40.Along with the endogenous pyrogen 20 of headspace gas 18 from container 14 withdraws from,, thereby make flexible inner 20 shrinkages so air is allowed to enter compression space 31.Although endogenous pyrogen 20 preferably utilizes the forced air shrinkage, any endogenous pyrogen 20 shrinkages can be used to promote the device of headspace gas 18 by gas passage 34, comprise device based on hydraulic pressure or machinery.As selection, the pump or the Venturi tube that are connected in gas passage 34 can be extracted headspace gas 18 out from container 14.
In headspace gas 18 after endogenous pyrogen 20 emptyings, along with compressed air source 30 supplies air to compression space 31 continuously, liquid 12 beginning inflow gas passages 34.When liquid 12 arrived liquid sensor 38, system controller 46 was made response by selector valve 60 is gone to the second place.This has interrupted the inside of endogenous pyrogen 20 and the connection between the headspace gas discharge orifice 40, and opens the inside of endogenous pyrogen 20 and the connection between the selector valve port 60b.As selection, but user's vision of system 50 ground determines when liquid 12 begins inflow gas passage 34 and also manually selector valve 60 is gone to the second place to interrupt the connection of headspace gas discharge orifice 40.
What want once more that emphasis notes here, is if headspace gas 18 was not removed before liquid 12 is dispensed to manufacturing process 13, will begin in the pass into solution according to Henry theorem headspace gas 18 so.Because endogenous pyrogen 20 is compressed 30 shrinkages of air source so that liquid 12 is released endogenous pyrogen 20, so the pressure of headspace gas 18 will increase during this process.This will make headspace gas 18 dissolve in the liquid 12, thereby cause the formation of harmful bubble in liquid 12 when liquid 12 is transferred into process 13.
In many fluid dispensing systems, preferably after the removing of headspace gas 18, in container 14, leave a small amount of gas.When all liq 12 when container 14 is assigned with, this a small amount of gas (being called the empty gas that detects) is empty by sensor (for example, the sky among Fig. 2 detects gas sensor 62) detection to indicate container.In traditional system, be difficult for measuring owing to just be discharged to the amount of the gas of headspace gas discharge orifice 40, the amount that is retained in the sky detection gas in the container 14 is wayward.
In system 50, add the empty gas that detects and in endogenous pyrogen 20, detect gas source 52, setting device 54, first shutdown valve 55, amount of gas controller 56 and 56 controls of second shutdown valve by sky.At first, system controller 46 is opened first shutdown valve 55 and is produced the fluid connection between gas source 52 and the gas quantity controller 56 to detect at sky.The empty gas that detects begins to detect the gas source 52 inflow gas quantity controllers 56 from sky then.Along with amount of gas controller 56 is filled the empty gas that detects, the pressure in the amount of gas controller 56 increases.This pressure is adjusted by setting device 54 and can be measured by the pressure sensor (transducer) that is integrally formed in amount of gas controller 56.The amount that sky in the inflow gas quantity controller 56 detects gas depends on the volume of amount of gas controller 56 and the pressure that the sky in the gas quantity controller 56 detects gas.Based on these factors, empty detect gas source 52 continuous flows are filled institute's required amount until amount of gas controller 56 gas (for example, 100 pounds (gauge pressure)) per square inch.
When the gas of institute's required amount had been packed into amount of gas controller 56, system controller 46 was closed first shutdown valve 55 to interrupt the empty connection that detects between gas source 52 and the gas quantity controller 56.Subsequently or simultaneously, system controller 46 is opened second shutdown valve 58 and connected to produce fluid between the inside of amount of gas controller 56 and endogenous pyrogen 20.This sky detection gas that allows to be included in the amount of gas controller 56 flows in the inside of endogenous pyrogen 20.If compressed air source 30 is closed when empty detection gas is from amount of gas controller 56 inflow endogenous pyrogens 20, the sky detection gas that is included in so in the amount of gas controller 56 will flow in the endogenous pyrogen 20.If compressed air source 30 keeps working when empty detection gas is from amount of gas controller 56 inflow endogenous pyrogens 20, the so empty gas that detects will reach equilibrium of pressure between the pressure in compressed air source 30 and gas quantity controller 56 from amount of gas controller 56 inflow endogenous pyrogens 20.Typically, whether compressed air source 30 works by being connected the logical or triple valve control of two between compressed air source 30 and the compression space 31.Usually, the sky from amount of gas controller 56 inflow endogenous pyrogens 20 detects the amount of gas based on the difference of pressure between the pressure size, amount of gas controller 56 and the compression space 31 of amount of gas controller 56.
Detect gas at sky and stopped when amount of gas controller 56 flows out, system controller 46 is closed second shutdown valve 58 to interrupt from amount of gas controller 56 to endogenous pyrogen 20 connection.After second shutdown valve 58 is closed, along with being compressed air source 30, pressurized air is supplied to compression space 31, and liquid 12 is pushed upwardly by flow channel 42.Along with the flexible inner 20 of liquid 12 from container 14 withdraws from, air is allowed to enter compression space 31, thereby makes endogenous pyrogen 20 shrinkages.Although endogenous pyrogen 20 preferably utilizes the forced air shrinkage, any endogenous pyrogen 20 shrinkages so that being promoted, liquid can be used by the device of flow channel 42, comprise device based on hydraulic pressure or machinery.As selection, the pump or the Venturi tube that are connected in flow channel 42 can be extracted liquid 12 out from container 14.
Along with endogenous pyrogen 20 is compressed air source 30 shrinkages, liquid 12 uninterrupted flows to manufacturing process 13 up to liquid 12 from endogenous pyrogen 20 emptyings., only emptyly detect gas and be retained in the endogenous pyrogen 20 after endogenous pyrogen 20 emptyings at liquid 12.Along with compressed air source 30 continuous compressed content devices 20, the empty gas that detects is pushed towards manufacturing process 13 by flow channel 42.Pass emptyly when detecting gas sensor 62 when sky detects gas, the empty gas sensor 62 that detects sends a signal to system controller 46 turning off compressed air source 30, thus the operation of interrupt system 50.Subsequently, compressed air channel 32, gas passage 34 and flow channel 42 disconnects with empty container 14, and empty container 14 removes from system 50, and the new container 14 that comprises liquid 12 and headspace gas 18 is connected to system 50.Restart then from the distribution of the liquid 12 of container 14.
In a word, when long-term storage, especially when standing temperature fluctuation, the purity of some chemicalss trends towards decay or crosslinked.Be anti-decay or crosslinked generation here, the part of container sky (being called head room) is filled headspace gas.The decay that chemical reaction prevents liquid chemical takes place by being suppressed at during storage in headspace gas in the liquid.When container will be connected in manufacturing process, no longer need or require headspace gas.Conventional distribution systems does not consider to remove easily headspace gas before the dispense liquid chemicals.The present invention is a kind of method and system, be used for liquid chemical is dispensed to manufacturing process from container, described container comprise outer container, endogenous pyrogen and with the port of the internal communication of endogenous pyrogen, the part of endogenous pyrogen is occupied by liquid chemical, and the remainder of endogenous pyrogen is connected to manufacturing process by the decay that headspace gas occupies to prevent liquid chemical up to container.This system comprises pipeline and gas passage, and described pipeline has flow channel therein, and described gas passage is communicated with between the outside of the inside of endogenous pyrogen and outer container.This system further comprises device, described device is communicated with the inwall of outer container and the compression space fluid between the endogenous pyrogen with the fluid under the authorized pressure and flows into the inwall of outer container and the space between the endogenous pyrogen will force headspace gas outside endogenous pyrogen, to the headspace gas discharge orifice and force liquid outside endogenous pyrogen, arrive manufacturing process via gas passage by ducted flow channel.
Though the present invention has been described, has persons of ordinary skill in the art will recognize that and under the situation of the spirit and scope that do not deviate from invention, can make the change of form and details with reference to preferred embodiment.

Claims (23)

1. the method for a dispense liquid, this method comprises:
Fluid container with outer container and endogenous pyrogen is provided, and the part of described endogenous pyrogen is occupied by liquid, and the remainder of described endogenous pyrogen is occupied by headspace gas;
Discharge described headspace gas from described endogenous pyrogen; And
Apply pressure to described endogenous pyrogen with force liquid from described endogenous pyrogen to manufacturing process.
2. method according to claim 1 wherein applies pressure to described endogenous pyrogen and comprises:
Supplied with pressurised fluid is to be dispensed to manufacturing process with liquid from described endogenous pyrogen between described endogenous pyrogen and described outer container.
3. method according to claim 1, wherein before discharging described headspace gas, this method further comprises:
Adaptor union is connected in described fluid container, and described adaptor union comprises the pipeline that wherein has flow channel, and described adaptor union further is included in the gas passage that is communicated with between the outside of the inside of described endogenous pyrogen and described outer container.
4. method according to claim 3, wherein discharge described headspace gas and comprise:
Discharge-service valve is connected between headspace gas discharge orifice and the described gas passage;
Open described discharge-service valve and be expelled to described headspace gas discharge orifice via described gas passage to allow described headspace gas; And
When beginning to flow into described gas passage, described liquid closes described discharge-service valve.
5. method according to claim 4, wherein before closing described discharge-service valve, this method further comprises:
In supplied with pressurised fluid between described endogenous pyrogen and the described outer container to force described headspace gas outside the described endogenous pyrogen, via described gas passage to described headspace gas discharge orifice.
6. method according to claim 4 comprises:
Liquid sensor is connected when liquid begins to flow into described gas passage to detect between described gas passage and the described headspace gas discharge orifice.
7. method according to claim 1, wherein before supplied with pressurised fluid between described endogenous pyrogen and the described outer container, this method further comprises:
A certain amount of empty gas that detects is imported in the described endogenous pyrogen.
8. method according to claim 7 wherein imports a certain amount of empty gas that detects in the described endogenous pyrogen and comprises:
First shutdown valve, amount of gas controller and second shutdown valve are connected empty the detection between gas source and the described gas passage;
Opening described first shutdown valve flows into the described amount of gas controller from the described empty gas source that detects to allow the described empty gas that detects;
When detecting, the sky of measured quantity closes described first shutdown valve when gas has been filled described amount of gas controller; And
Open described second shutdown valve to allow described empty gas flows into described endogenous pyrogen via described gas passage from described amount of gas controller the inside of detecting.
9. method according to claim 8, wherein close described first shutdown valve when gas has been filled described amount of gas controller and comprise when the sky of measured quantity detects:
Pressure regulation device is connected described empty the detection between gas source and the described amount of gas controller, is used for when described empty detection gas is imported into described amount of gas controller, adjusting the pressure in the described amount of gas controller; And
When the sky detection gas of measured quantity has been imported in the described amount of gas controller according to the pressure in the described amount of gas controller, close described first shutdown valve.
10. method according to claim 7 further comprises:
When described liquid detects the described empty gas that detects during from described endogenous pyrogen emptying; And
When described air body is detected, interrupt of the distribution of described liquid to described manufacturing process.
11. method according to claim 1 further comprises:
When described liquid is assigned to described manufacturing process, the weight of the described fluid container of weighing;
When described fluid container reaches the bare weight amount, interrupt of the distribution of described liquid to described manufacturing process.
12. one kind is used for liquid is dispensed to the system of manufacturing process from container, described container comprises outer container and endogenous pyrogen, and described endogenous pyrogen is occupied by described liquid and headspace gas, and described system comprises:
Pipeline, described pipeline can insert in the described endogenous pyrogen and described pipeline has flow channel therein;
Gas passage, described gas passage is communicated with between the outside of the inside of described endogenous pyrogen and described outer container;
Device, described device is used to force described headspace gas outside described endogenous pyrogen, to the headspace gas discharge orifice, and be used to force liquid to arrive outside the described endogenous pyrogen via described gas passage, by described ducted described flow channel to described manufacturing process.
13. system according to claim 12 further comprises:
Discharge-service valve, described discharge-service valve is connected between described headspace gas discharge orifice and the described gas passage, described discharge-service valve has open position and off position, described open position can be selected allowing described headspace gas to be expelled to described headspace gas discharge orifice via described gas passage, described off position can be selected during from the inside emptying of described endogenous pyrogen when described headspace gas.
14. system according to claim 13 further comprises:
Liquid sensor, described liquid sensor are connected between described gas passage and the described headspace gas discharge orifice to detect liquid when and begin to flow into described gas passage to indicate described headspace gas from the inside emptying of described endogenous pyrogen.
15. system according to claim 12 further comprises:
Empty detecting device, described empty detecting device are used for detecting when described liquid is drained from described endogenous pyrogen.
16. system according to claim 15, wherein:
Described empty detecting device is the empty gas sensor that detects, and is right after described liquid is dispensed to before the described manufacturing process, and the described empty gas sensor that detects detects the empty gas that detects of the in-to-in that is imported into described endogenous pyrogen.
17. system according to claim 16 further comprises:
The amount of gas controller;
Be connected empty first shutdown valve that detects between gas source and the described amount of gas controller, described first shutdown valve has open position and off position, described open position can be selected to allow the described empty gas that detects to flow into the described amount of gas controller from the described empty gas source that detects, and described off position can be selected when the sky detection gas of measured quantity has been imported in the described amount of gas controller; With
Be connected second shutdown valve between the inside of described amount of gas controller and described endogenous pyrogen, described second shutdown valve has open position and off position, described open position can be selected allowing the described empty gas that detects to flow to the inside of described endogenous pyrogen from described amount of gas controller, empty described off position can be selected when detecting gas from described amount of gas controller emptying when described.
18. system according to claim 17 further comprises:
Pressure regulation device, described pressure regulation device is connected described empty the detection between gas source and the described amount of gas controller to adjust the pressure in the described amount of gas controller when described empty detection gas is imported in the described amount of gas controller, when detecting gas and be imported into described amount of gas controller according to the sky of the measured quantity of pressure in the described amount of gas controller with box lunch, described first shutdown valve is closed.
19. system according to claim 17 further comprises:
Selector valve, described selector valve has the in-to-in port that is connected in described shutdown valve, described headspace gas discharge orifice and described endogenous pyrogen, and wherein said selector valve allows described shutdown valve to be connected to the selectable fluid of the in-to-in of described endogenous pyrogen with described headspace gas discharge orifice.
20. system according to claim 15, wherein:
Described empty detecting device comprises scale, and this scale is used for the weight of the described fluid container of weighing when described liquid is assigned to described manufacturing process, and the distribution of described liquid is interrupted when reaching the measured predetermined weight of described scale with the described fluid container of box lunch.
21. a liquid processing system comprises:
Container, described container comprises:
Outer container;
Has the in-to-in endogenous pyrogen; And
The part of wherein said endogenous pyrogen is occupied by liquid, and the remainder of described endogenous pyrogen is occupied by headspace gas;
Can be connected in the adaptor union of described container, described adaptor union comprises pipeline, described pipeline can insert in the described endogenous pyrogen and wherein have flow channel, and described adaptor union further comprises gas passage, and described gas passage is communicated with between the outside of the inside of described endogenous pyrogen and described outer container; With
The fluid air source, described fluid air source is communicated with the inwall of described outer container and the space fluid between the described endogenous pyrogen, the inwall and the space between the described endogenous pyrogen that are used for making pressure fluid flow into described outer container are arrived outside the described endogenous pyrogen to force described headspace gas, arrive the headspace gas discharge orifice via described gas passage, and force liquid outside described endogenous pyrogen, arrive described manufacturing process by described ducted flow channel.
22. system according to claim 21 further comprises:
Liquid sensor, described liquid sensor are connected between described gas passage and the described headspace gas discharge orifice to detect liquid when and begin to flow into described gas passage to indicate described headspace gas from the inside emptying of described endogenous pyrogen.
23. system according to claim 21 further comprises:
Empty detecting device, described empty detecting device are used for detecting when described liquid is from described endogenous pyrogen emptying.
CNA200580011316XA 2004-04-13 2005-04-13 Liquid dispensing method and system with headspace gas removal Pending CN101010241A (en)

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WO2005100203A3 (en) 2007-03-22
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EP1737758A2 (en) 2007-01-03
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EP1737758A4 (en) 2010-11-10
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US20050224523A1 (en) 2005-10-13
EP1737758B1 (en) 2012-02-22

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