CN101003703A - Composite white printing ink in use for fabricating aqueous flexible plate and intaglio plate - Google Patents
Composite white printing ink in use for fabricating aqueous flexible plate and intaglio plate Download PDFInfo
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- CN101003703A CN101003703A CN 200610096103 CN200610096103A CN101003703A CN 101003703 A CN101003703 A CN 101003703A CN 200610096103 CN200610096103 CN 200610096103 CN 200610096103 A CN200610096103 A CN 200610096103A CN 101003703 A CN101003703 A CN 101003703A
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- white ink
- compound white
- flexible plate
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- aqueous flexible
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Abstract
This invention relates to composite white ink for preparing aqueous flexographic plate and gravure. The composite white ink comprises water-soluble polyurethane resin, stabilizer, titanium dioxide, aqueous acrylic resin, water, dispersant, scratch inhibitor, antifoamer, and ethanol. The composite white ink has little air pollution, thus is harmless to printing workers when used to print packaging materials. More importantly, the packaging materials printed with the composite white ink, do not produce toxic or harmful substances, and the packaged products are environmentally friendly, safe and nontoxic.
Description
Technical field
The present invention relates to a kind of compound white ink, particularly relate to a kind of compound white ink that is used to make aqueous flexible plate and intaglio plate, this compound white ink is generally used for the packing of edible product.
Background technology
In the prior art, the packing of products such as candy, food, medicine adopts mostly by the direct wrapped product of the wrapping material (wrapping paper) of solvent borne white ink printing, this wrapping material printing adaptability is relatively good, but in printing process, easily produce a large amount of easily air-polluting benzene class and ketone gases, and long-term suction of pressman easily produces occupational illness.This kind solvent borne white ink material easily produces hazardous and noxious substances behind wrapped product, when product packaged good after, benzene class and ketone chemical substance will be enclosed within the wrapped product, thereby the quality of product is affected even is compromised.
Summary of the invention
The purpose of this invention is to provide high being used to of a kind of safety performance and make the compound white ink of aqueous flexible plate and intaglio plate, use thus the wrapping material of compound white ink printing do not produce hazardous and noxious substances basically behind wrapped product.
The present invention can be implemented by the following technical programs:
A kind of compound white ink of making aqueous flexible plate and intaglio plate, it comprises following moiety: water-soluble polyurethane resin, stablizer, titanium dioxide, water-based acrylic acid resin, water.
Described moiety also comprises dispersion agent, anti-zoned dose, defoamer, ethanol.
The weight percentage of described each moiety is: described water-soluble polyurethane resin 7-11%, described stablizer 6-10%, described titanium dioxide 30-35%, described water-based acrylic acid resin 20-25%, described water 12～15%, described dispersion agent 2-3%, described anti-zoned dose of 0.5-1%, described defoamer 0.15-0.6%, described ethanol 5-10.5%.
Described dispersion agent is a phosphoric acid ester.
Described anti-zoned dose is a kind of in modified polyethylene wax, polyethylene wax, the Poly Propylene Wax.
Described defoamer is a modified silicon oil.
Described concentration of ethanol is more than or equal to 99%.
Described concentration of ethanol is more than or equal to 99.7%.
Described stablizer is an alkaline solution.
Described stablizer is an ammoniacal liquor, and the concentration of described ammoniacal liquor is 28～35%.
Compared with the prior art the present invention has following advantage: this compound white ink can polluted air, with this compound white ink printed apcksging material the time, human body to the pressman does not have harm, can not produce hazardous and noxious substances behind the wrapping material wrapped product with compound white ink printing thus when most important, make packaged products reach the environmentally-friendly sanitary standard, safety has no side effect.
Embodiment
Embodiment 1:
A kind of compound white ink of making aqueous flexible plate and intaglio plate, it is made up of following moiety: the water-soluble polyurethane resin, dispersion agent, stablizer, titanium dioxide, water-based acrylic acid resin, anti-zoned dose, defoamer, concentration is 99.7% ethanol, water, wherein the weight fraction of each moiety is: water-soluble polyurethane resin 10%, dispersion agent 2.5%, stablizer 8%, titanium dioxide 32%, water-based acrylic acid resin 23%, anti-zoned dose 0.8%, defoamer 0.5%, ethanol 8%, all the other are water, described dispersion agent is a phosphoric acid ester, described stablizer is the ammoniacal liquor of concentration 33%, described defoamer is the silicone oil of physically modified, and described anti-zoned dose is polyethylene wax.
The following describes concrete a kind of compound white ink according to manufacture method, its step is as follows:
The first step: with the component of following weight part: 50 parts of water-soluble polyurethane resins, concentration are 33% 2 parts of 25 parts of ammoniacal liquor, modified silicon oils, 23 parts in water, are placed in the sad temperature reaction ax and stir at a slow speed 3-4 hour, make A;
Second step: the A that gets 18 weight parts is placed in the sad temperature reaction ax, the component that adds following weight part again in the reaction ax: 32 parts of titanium dioxides (titanium dioxide), 6 parts in water, 1 part in polyethylene wax, 2.5 parts of phosphoric acid ester, concentration are 2.5 parts of 33% ammoniacal liquor, the component that adds following weight part after high-speed stirring 2-3 hour again: 22 parts of water-based acrylic acid resins, 8 parts in water, 8 parts of ethanol, stirring reaction makes compound white ink of the present invention.
After testing, the parameters of compound white ink of the present invention following (temperature is 20 degrees centigrade):
| Test item | Parameter value | Unit |
| Form and aspect (white) | Same mark | |
| Fineness | ＜4 | μm |
| Gloss | 80 | ％ |
| Viscosity | 40～70 | S |
| Dissolvent residual (ethanol) | Do not have | mg/m 2 |
| Dissolvent residual (Virahol) | Do not have | mg/m 2 |
| Dissolvent residual (n-propyl alcohol) | Do not have | mg/m 2 |
| Tinting strength | 100(±5) | ％ |
| Attachment fastness | 100 | ％ |
| First dryness | ≥14 | mm |
| Stripping strength | 5～6 | N |
Show the following advantage of having of this product by above data analysis:
1, fineness and first dryness are that main value shows that this product has good printing adaptability among the result.
2, the value of dissolvent residual shows and utilizes this product can not produce peculiar smell to corresponding food product pack after printing finished product.
3, tinting strength mainly shows the titanium dioxide what contain in the printing ink, and the depth of shade of printing ink is just found out from data to be higher than dense dose of property printing ink far away.
4, viscosity shows that printing ink has good mobility, and flowability mainly is that machine 2# with industry standard when printing examines the flowability that the grace cup is measured its printing ink, and flowing property brings packing material perfect pattern.
5, gloss shows the brightness on printing ink top layer, sees that from the result it can replace dense dose of property printing ink fully.
The usage quantity of compound white ink of the present invention shows by test in addition, needs to use the coating rod in printing process, is half of dense dose to the coating rod degree of depth of this water color ink, thus on quantity of ink the consumption of far away little dense dose of property.
Claims (10)
1, a kind of compound white ink of making aqueous flexible plate and intaglio plate, it is characterized in that: it comprises following moiety: water-soluble polyurethane resin, stablizer, titanium dioxide, water-based acrylic acid resin, water.
2, the compound white ink of manufacturing aqueous flexible plate according to claim 1 and intaglio plate is characterized in that: described moiety also comprises dispersion agent, anti-zoned dose, defoamer, ethanol.
3, the compound white ink of manufacturing aqueous flexible plate according to claim 2 and intaglio plate, it is characterized in that: the weight percentage of described each moiety is: described water-soluble polyurethane resin 7-11%, described stablizer 6-10%, described titanium dioxide 30-35%, described water-based acrylic acid resin 20-25%, described water 12～15%, described dispersion agent 2-3%, described anti-zoned dose of 0.5-1%, described defoamer 0.15-0.6%, described ethanol 5-10.5%.
4, the compound white ink of manufacturing aqueous flexible plate according to claim 2 and intaglio plate is characterized in that: described dispersion agent is a phosphoric acid ester.
5, the compound white ink of manufacturing aqueous flexible plate according to claim 2 and intaglio plate is characterized in that: described anti-zoned dose of a kind of in the modified polyethylene wax, polyethylene wax, Poly Propylene Wax.
6, the compound white ink of manufacturing aqueous flexible plate according to claim 2 and intaglio plate is characterized in that: described defoamer is a modified silicon oil.
7, the compound white ink of manufacturing aqueous flexible plate according to claim 2 and intaglio plate, it is characterized in that: described concentration of ethanol is more than or equal to 99%.
8, the compound white ink of manufacturing aqueous flexible plate according to claim 7 and intaglio plate, it is characterized in that: described concentration of ethanol is more than or equal to 99.7%.
9, the compound white ink of manufacturing aqueous flexible plate according to claim 1 and intaglio plate is characterized in that: described stablizer is an alkaline solution.
10, the compound white ink of manufacturing aqueous flexible plate according to claim 9 and intaglio plate is characterized in that: described stablizer is an ammoniacal liquor, and the concentration of described ammoniacal liquor is 28～35%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610096103 CN101003703B (en) | 2006-09-15 | 2006-09-15 | Composite white printing ink in use for fabricating aqueous flexible plate and intaglio plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610096103 CN101003703B (en) | 2006-09-15 | 2006-09-15 | Composite white printing ink in use for fabricating aqueous flexible plate and intaglio plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101003703A true CN101003703A (en) | 2007-07-25 |
| CN101003703B CN101003703B (en) | 2010-05-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610096103 Active CN101003703B (en) | 2006-09-15 | 2006-09-15 | Composite white printing ink in use for fabricating aqueous flexible plate and intaglio plate |
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| CN (1) | CN101003703B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805540A (en) * | 2010-04-09 | 2010-08-18 | 周贤永 | Water-based plastic inner printing chalk and preparation method thereof |
| CN103408994A (en) * | 2013-08-26 | 2013-11-27 | 深圳扬丰印刷有限公司 | Water-based gloss oil and preparation method thereof |
| CN104031468A (en) * | 2014-06-30 | 2014-09-10 | 柳江县联华纸制品厂 | Water-based gravure ink |
| CN104356754A (en) * | 2014-10-14 | 2015-02-18 | 安徽澳雅合金有限公司 | Antibacterial flexible acrylic resin offset printing ink |
| CN104804531A (en) * | 2015-04-23 | 2015-07-29 | 黎司华 | Environmental-friendly water-soluble composite printing ink and preparation method thereof |
| CN111058310A (en) * | 2019-12-25 | 2020-04-24 | 珠海市东昌颜料有限公司 | Water-based white ink and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1233759C (en) * | 2003-11-07 | 2005-12-28 | 中山大学 | Aqueous plastic compound ink |
| JP2005225083A (en) * | 2004-02-13 | 2005-08-25 | Toyo Ink Mfg Co Ltd | Printing structure |
-
2006
- 2006-09-15 CN CN 200610096103 patent/CN101003703B/en active Active
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805540A (en) * | 2010-04-09 | 2010-08-18 | 周贤永 | Water-based plastic inner printing chalk and preparation method thereof |
| CN103408994A (en) * | 2013-08-26 | 2013-11-27 | 深圳扬丰印刷有限公司 | Water-based gloss oil and preparation method thereof |
| CN104031468A (en) * | 2014-06-30 | 2014-09-10 | 柳江县联华纸制品厂 | Water-based gravure ink |
| CN104356754A (en) * | 2014-10-14 | 2015-02-18 | 安徽澳雅合金有限公司 | Antibacterial flexible acrylic resin offset printing ink |
| CN104804531A (en) * | 2015-04-23 | 2015-07-29 | 黎司华 | Environmental-friendly water-soluble composite printing ink and preparation method thereof |
| CN111058310A (en) * | 2019-12-25 | 2020-04-24 | 珠海市东昌颜料有限公司 | Water-based white ink and preparation method thereof |
| CN111058310B (en) * | 2019-12-25 | 2023-01-03 | 珠海东昌色彩科技有限公司 | Water-based white ink and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101003703B (en) | 2010-05-12 |
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Effective date of registration: 20230712 Address after: 432000 No. 6, Fazhan 3rd road, Saifu Industrial Park, Changjiang Bu street, Yingcheng City, Xiaogan City, Hubei Province Patentee after: Inkkale ink (Hubei) Co.,Ltd. Address before: 215321 No. 5 South Binjiang Road, Zhang Pu town, Kunshan City, Jiangsu Province Patentee before: Yingke Kale Ink (Suzhou) Co.,Ltd. |
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