CN100551715C - The compound colour band of peelable temperature-sensitive - Google Patents
The compound colour band of peelable temperature-sensitive Download PDFInfo
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- CN100551715C CN100551715C CNB2006101073486A CN200610107348A CN100551715C CN 100551715 C CN100551715 C CN 100551715C CN B2006101073486 A CNB2006101073486 A CN B2006101073486A CN 200610107348 A CN200610107348 A CN 200610107348A CN 100551715 C CN100551715 C CN 100551715C
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Abstract
The invention discloses the compound colour band of a kind of peelable temperature-sensitive, constitute by the thermal transfer ink layer that is coated with on tape base and the tape base, thermal transfer ink layer is divided into bottom and surface layer two parts, and bottom comprises following component by weight percentage: resin 5～10%, filler 30～50%, auxiliary agent 1～5%, solvent 30～50%, colouring agent 5～10%; Surface layer comprises following component by weight percentage: Tissuemat E 4～7%, filler 4～8%, solvent 85～89%.What thermal transfer ink layer adopted among the present invention is duplex coating, be characterized in that bottom and tape base have adhesive force preferably, what surface layer adopted is Tissuemat E, on can be after the transfer printing attached to various material, and with stock very moderate adhesive force is arranged, so whole thermal transfer ink layer can reach the effect of easily peeling off after being transferred on the stock.
Description
Technical field
The invention belongs to the compound colour band of the peelable temperature-sensitive of a kind of hot transfer printing, be particularly useful for all kinds of paper instruments that needs encrypt, PVC card, PE card etc.
Background technology
The existing abroad commodity selling of the compound colour band of peelable temperature-sensitive, but still belong to blank at home, bill, card are used quite general on the market now, to this type of colour band demand is very big, external imported product selling at exorbitant prices, and having technical deficiency, coating and basement membrane adhesive force are not enough, and the defective that comes off is easily arranged.
Summary of the invention
Problem to be solved by this invention is to overcome the deficiencies in the prior art, provide a kind of can fine transfer printing on paper instruments, PVC card and PE card, and on stock, be difficult for friction and come off, and the compound colour band of temperature-sensitive that can easily peel off of transfer printing layer.
For achieving the above object, the technical solution adopted in the present invention is: the compound colour band of a kind of peelable temperature-sensitive, constitute by the thermal transfer ink layer that is coated with on tape base and the tape base, it is characterized in that: thermal transfer ink layer is divided into bottom and surface layer two parts, and bottom comprises following component by the bottom total weight percent: resin 5～10%, filler 30～50%, auxiliary agent 1～5%, solvent 30～50%, colouring agent 5～10%; Surface layer comprises following component by the surface layer total weight percent: Tissuemat E 4～7%, filler 4～8%, solvent 85～89%.
Resin in the described bottom is the mixture of phenolic resins and abietic resin, and phenolic resins and abietic resin two components account for bottom gross weight percentage and are respectively: phenolic resins 2.5～5%, abietic resin 2.5～5%; Or the mixture of polystyrene resin and Petropols, polystyrene resin and Petropols two components account for bottom gross weight percentage and are respectively: polystyrene resin 3～6%, Petropols 2～4%; Or the mixture of polystyrene resin and Petropols and abietic resin, polystyrene resin and Petropols and abietic resin three components account for bottom gross weight percentage and are respectively: polystyrene resin 3～6%, Petropols 1.5～3%, abietic resin 0.5～1%.
Auxiliary agent in the described bottom is a silicone oil, and the solvent in the described bottom is the mixed solvent that toluene and butanone are formed, and two components account for the bottom total weight percent and are respectively: toluene 15～25%, butanone 15～25%; Solvent in the described surface layer is the mixed solvent that toluene and dimethylbenzene are formed, and two components account for the surface layer total weight percent and are respectively: toluene 42～44%, dimethylbenzene 43～45%.
Filler in the described bottom is powdered whiting or talcum powder or wollastonite.
Colouring agent in the described bottom is the mixture of iron oxide black or iron oxide black and titanium dioxide, and two components account for the bottom percentage by weight and are respectively in the mixture of described iron oxide black and titanium dioxide: iron oxide black 3.5～7.5%, titanium dioxide 1.5～2.5%.
Tissuemat E is micro mist wax or modified poly ethylene micro mist wax in the described surface layer.
Filler in the described surface layer is a talcum powder.
Described tape base is made of the BOPET material of thickness 12～14 μ m.
What thermal transfer ink layer adopted among the present invention is duplex coating, be characterized in that bottom and tape base have adhesive force preferably, what surface layer adopted is Tissuemat E, on can be after the transfer printing attached to various material, and with stock very moderate adhesive force is arranged, so whole thermal transfer ink layer can reach the effect of easily peeling off after being transferred on the stock.
The specific embodiment
Further specify the present invention below in conjunction with embodiment.
Composition of the present invention is mainly tape base and hot transfer printing coating, tape base is BOPET, coating has two-layer, is respectively bottom and surface layer, and wherein bottom comprises following component: resin 5～10%, filler 30～50%, auxiliary agent 1～5%, solvent 30～50%, colouring agent 5～10%.
In above-mentioned each component, resin plays skeleton, bridging agent and transfer printing effect for the main component of this layer, promptly is close to the corresponding part of colour band transfer printing layer at thermal printer head, when the local heating of heat-transferring head reaches uniform temperature, resin impels its layer fusing in the thermal transfer ink layer, is transferred on the object plane of undertaking the printing of; Filler can reduce transfer printing layer and the adhesive force of undertaking the printing of on the object plane, reaches and easily peels off effect; Organic additive can reduce resin softening point and promote transfer printing; Mixed solvent is used for dissolving resin and regulates the transfer printing layer viscosity.
Wherein resin can be phenolic resins and abietic resin, also can be polystyrene resin and Petropols, can also be polystyrene resin and Petropols and abietic resin.Filler is powdered whiting or talcum powder or wollastonite.Auxiliary agent is a silicone oil.Solvent is toluene and butanone.Colouring agent (pigment) can be iron oxide black and titanium dioxide, also can be iron oxide black.
Surface layer comprises following component: Tissuemat E 4～7%, filler 4～8%, solvent 85～89%.Wherein Tissuemat E plays skeleton, bridging agent and transfer printing effect for the main component of this layer, and filler can reduce the adhesive force on transfer printing layer and the object plane of undertaking the printing of, and reaches and easily peels off effect.
Wherein Tissuemat E is micro mist wax or modified poly ethylene micro mist wax.Filler is a talcum powder.Solvent is toluene and dimethylbenzene.
Technology of the present invention is as follows:
By above-mentioned coating bottom prescription weighing material, carry out sand milling then earlier, sand milling 24 hours makes various materials fully dissolve pulverizing, be uniformly dispersed.Fineness of grind reaches below the 7 μ m, then this compound is passed through 100 order sieves, leaches large granular impurity.Compound after filtering is placed airtight container, and the subbing configuration is finished.The coating that configures poured in the coating machine chalk line reel be coated with, coating speed is 15～20m/min, and coating layer thickness is at 10～12 μ m, by the oven dry of 70～80 drying tunnels, rolling.
By above-mentioned coat side layer formula weighing material, carry out sand milling then, sand milling 36 hours makes various materials fully dissolve pulverizing, be uniformly dispersed.Fineness of grind reaches below the 5 μ m, is coated with on bottom then, and coating speed is 15～20m/min, and coating layer thickness is at 1～2 μ m, and by the oven dry of 70～80 drying tunnels, rolling is cut, and just obtains the peelable temperature-sensitive compound colour band of thickness in 25～26 mu m ranges.
Be the component tabulation of some embodiment below, wherein among the embodiment 1～3, base thick is that the BOPET material of 12 μ m constitutes, and the underlayer thickness of transfer printing layer is 11 μ m, and surface thickness is 2 μ m.Among the embodiment 4～6, base thick is that the BOPET material of 12 μ m constitutes, and the underlayer thickness of transfer printing layer is 12 μ m, and surface thickness is 1 μ m.Among the embodiment 7～9, base thick is that the BOPET material of 12 μ m constitutes, and the underlayer thickness of transfer printing layer is 12 μ m, and surface thickness is 2 μ m.Among the embodiment 10～12, base thick is that the BOPET material of 13 μ m constitutes, and the underlayer thickness of transfer printing layer is 10 μ m, and surface thickness is 2 μ m.Among the embodiment 13～15, base thick is that the BOPET material of 13 μ m constitutes, and the underlayer thickness of transfer printing layer is 11 μ m, and surface thickness is 1 μ m.Among the embodiment 16～18, base thick is that the BOPET material of 13 μ m constitutes, and the underlayer thickness of transfer printing layer is 11 μ m, and surface thickness is 2 μ m.Among the embodiment 19～21, base thick is that the BOPET material of 13 μ m constitutes, and the underlayer thickness of transfer printing layer is 12 μ m, and surface thickness is 1 μ m.Among the embodiment 22～27, base thick is that the BOPET material of 14 μ m constitutes, and the underlayer thickness of transfer printing layer is 10 μ m, and surface thickness is 1 μ m.Among the embodiment 28～30, base thick is that the BOPET material of 14 μ m constitutes, and the underlayer thickness of transfer printing layer is 10 μ m, and surface thickness is 2 μ m.Among the embodiment 31～34, base thick is that the BOPET material of 14 μ m constitutes, and the underlayer thickness of transfer printing layer is 11 μ m, and surface thickness is 1 μ m.
Embodiment 1
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Embodiment 33
Embodiment 34
Claims (6)
1, the compound colour band of a kind of peelable temperature-sensitive, constitute by the thermal transfer ink layer that is coated with on tape base and the tape base, it is characterized in that: thermal transfer ink layer is divided into bottom and surface layer two parts, and bottom comprises following component by the bottom total weight percent: resin 5～10%, filler 30～50%, auxiliary agent 1～5%, solvent 30～50%, colouring agent 5～10%; Surface layer comprises following component by the surface layer total weight percent: Tissuemat E 4～7%, filler 4～8%, solvent 85～89%;
Resin in the described bottom is the mixture of phenolic resins and abietic resin, and phenolic resins and abietic resin two components account for bottom gross weight percentage and are respectively: phenolic resins 2.5～5%, abietic resin 2.5～5%; Or the mixture of polystyrene resin and Petropols, polystyrene resin and Petropols two components account for bottom gross weight percentage and are respectively: polystyrene resin 3～6%, Petropols 2～4%; Or the mixture of polystyrene resin and Petropols and abietic resin, polystyrene resin and Petropols and abietic resin three components account for bottom gross weight percentage and are respectively: polystyrene resin 3～6%, Petropols 1.5～3%, abietic resin 0.5～1%;
Auxiliary agent in the described bottom is a silicone oil, and the solvent in the described bottom is the mixed solvent that toluene and butanone are formed, and two components account for the bottom total weight percent and are respectively: toluene 15～25%, butanone 15～25%; Solvent in the described surface layer is the mixed solvent that toluene and dimethylbenzene are formed, and two components account for the surface layer total weight percent and are respectively: toluene 42～44%, dimethylbenzene 43～45%.
2, the compound colour band of peelable temperature-sensitive as claimed in claim 1 is characterized in that: the filler in the described bottom is powdered whiting or talcum powder or wollastonite.
3, the compound colour band of peelable temperature-sensitive as claimed in claim 1, it is characterized in that: the colouring agent in the described bottom is the mixture of iron oxide black or iron oxide black and titanium dioxide, two components account for the bottom percentage by weight and are respectively in the mixture of described iron oxide black and titanium dioxide: iron oxide black 3.5～7.5%, titanium dioxide 1.5～2.5%.
4, the compound colour band of peelable temperature-sensitive as claimed in claim 1 is characterized in that: Tissuemat E is micro mist wax or modified poly ethylene micro mist wax in the described surface layer.
5, the compound colour band of peelable temperature-sensitive as claimed in claim 1, it is characterized in that: the filler in the described surface layer is a talcum powder.
6, as the compound colour band of the arbitrary described peelable temperature-sensitive of claim 1 to 5, it is characterized in that: described tape base is made of the BOPET material of thickness 12～14 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101073486A CN100551715C (en) | 2006-10-26 | 2006-10-26 | The compound colour band of peelable temperature-sensitive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101073486A CN100551715C (en) | 2006-10-26 | 2006-10-26 | The compound colour band of peelable temperature-sensitive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101168329A CN101168329A (en) | 2008-04-30 |
| CN100551715C true CN100551715C (en) | 2009-10-21 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101073486A Expired - Fee Related CN100551715C (en) | 2006-10-26 | 2006-10-26 | The compound colour band of peelable temperature-sensitive |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101537744B (en) * | 2009-04-21 | 2010-08-04 | 焦作市卓立烫印材料有限公司 | Digital banner printing thermal transfer ribbon and preparation method thereof |
| CN101648468B (en) * | 2009-09-18 | 2012-10-03 | 天津市赢事达办公用品厂 | Environmental friendly heat transfer printing ribbon for printing cloth mark by scroll machine and preparation method thereof |
| CN102211478A (en) * | 2011-04-02 | 2011-10-12 | 泉州市山水电脑耗材有限公司 | Thermal transfer wax ribbon |
| CN102431327B (en) * | 2011-09-09 | 2013-06-12 | 杭州天地数码科技有限公司 | Waterborne date printing ribbon and preparation method thereof |
| CN110776835B (en) * | 2019-11-08 | 2021-11-26 | 焦作卓立膜材料有限责任公司 | Marking film for hard smooth substrate surface |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4710782A (en) * | 1985-08-29 | 1987-12-01 | Seiko Epson Corporation | Current-applying thermal transfer film |
-
2006
- 2006-10-26 CN CNB2006101073486A patent/CN100551715C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4710782A (en) * | 1985-08-29 | 1987-12-01 | Seiko Epson Corporation | Current-applying thermal transfer film |
Non-Patent Citations (2)
| Title |
|---|
| 热转印油墨及其色带的制备方法. 刘长春，姚巧玲，张蝉音.包装工程，第25卷第4期. 2004 |
| 热转印油墨及其色带的制备方法. 刘长春，姚巧玲，张蝉音.包装工程，第25卷第4期. 2004 * |
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| CN101168329A (en) | 2008-04-30 |
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Owner name: HENAN ZHUOLI IMAGING TECHNOLOGY CO., LTD. Free format text: FORMER NAME: ZHUOLI THERMOPRINTING MATERIAL CO., LTD., JIANZUO CITY |
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Address after: 454003 No. 2758 Shenzhou Road, hi tech Zone, Henan, Jiaozuo Patentee after: Henan Zhuoli Imaging Technology Co., Ltd. Address before: 454003 No. 2 Shenzhou Road, hi tech Zone, Henan, Jiaozuo Patentee before: Zhuoli Thermoprinting Material Co., Ltd., Jianzuo City |
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Effective date of registration: 20191204 Address after: No. 959, Nanhai West Road, Jiaozuo demonstration area, Henan Province (in the hospital of Henan Zhuoli membrane materials Co., Ltd.) Patentee after: Jiaozuo Zhuoli membrane materials Co., Ltd Address before: 454003 No. 2758 Shenzhou Road, hi tech Zone, Henan, Jiaozuo Patentee before: Henan Zhuoli Imaging Technology Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20091021 Termination date: 20201026 |
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