CN101537744B - Digital banner printing thermal transfer ribbon and preparation method thereof - Google Patents
Digital banner printing thermal transfer ribbon and preparation method thereof Download PDFInfo
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- CN101537744B CN101537744B CN2009100646959A CN200910064695A CN101537744B CN 101537744 B CN101537744 B CN 101537744B CN 2009100646959 A CN2009100646959 A CN 2009100646959A CN 200910064695 A CN200910064695 A CN 200910064695A CN 101537744 B CN101537744 B CN 101537744B
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- butanone
- link stuff
- banner printing
- carbon ribbon
- dimethylbenzene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/38207—Contact thermal transfer or sublimation processes characterised by aspects not provided for in groups B41M5/385 - B41M5/395
- B41M5/38214—Structural details, e.g. multilayer systems
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/02—Dye diffusion thermal transfer printing (D2T2)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/36—Backcoats; Back layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/38—Intermediate layers; Layers between substrate and imaging layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/392—Additives, other than colour forming substances, dyes or pigments, e.g. sensitisers, transfer promoting agents
- B41M5/395—Macromolecular additives, e.g. binders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
- B41M5/443—Silicon-containing polymers, e.g. silicones, siloxanes
Abstract
The invention belongs to the technical field of thermoprinting materials, and particularly discloses a digital banner printing thermal transfer ribbon and a preparation method thereof. The digital banner printing thermal transfer ribbon consists of a ribbon base, a back coating and a thermal transfer layer, wherein the back coating and the thermal transfer layer are respectively coated on two sides of the ribbon base, the thermal transfer layer is divided into three parts, and a release layer, a color layer and a connecting layer are sequentially arranged on the surface of one side of the ribbon base from inside to outside. The preparation method of the digital banner printing carbon ribbon comprises the steps of preparing a back coating and coating the back coating on one side of a ribbon base, and then preparing the back coating, the color layer and the connecting layer in sequence and coating the release layer, the color layer and the connecting layer on the other side of the ribbon base to form the digital banner printing carbon ribbon. The digital banner printing thermal transfer ribbon has reasonable design, simple and convenient preparation method and easy popularization and application. The invention renovates the complex process of the traditional scroll production, can realize the one-time production of the scroll, not only enables the scroll production to be simpler, quicker, more economic and more efficient, but also meets the requirements of the digitalized and personalized design of the finished product, namely the computer design and printing.
Description
Technical field
The invention belongs to technical field of hot stamping materials, be specifically related to a kind of digital banner printing carbon ribbon and preparation method thereof.
Background technology
At present, domestic vertically hung scroll manufacture craft has manual drafting at quarter to make vertically hung scroll, serigraphy vertically hung scroll and hot transfer printing vertically hung scroll.The common ground of this several method is the profile that need produce vertically hung scroll information as requested, and then mechanical or cutting type matrix, handles at last again and makes finished product on the vertically hung scroll.These several vertically hung scroll manufacture crafts not only complexity but also vertically hung scroll to make design limited, equipment investment is many, speed of production is slow, the cost height, serigraphy is also restricted to the batch that vertically hung scroll is made.Therefore, how to realize disposable printing the vertically hung scroll finished product obviously be extremely urgent, problem demanding prompt solution.For can realize disposable printing the vertically hung scroll finished product, associated digital banner printing carbon ribbon and preparation method thereof Study on Technology is beyond doubt very necessary and urgent.But yet there are no up to now, the relevant report of digital banner printing carbon ribbon and preparation method thereof.
Summary of the invention
For overcoming the deficiencies in the prior art part, the purpose of this invention is to provide a kind of reasonable in design, the preparation method is easy, the digital banner printing carbon ribbon that is easy to apply and preparation method thereof.
The present invention is achieved through the following technical solutions above-mentioned purpose:
A kind of digital banner printing carbon ribbon, by tape base and back coating and the thermal transfer ink layer of coating the tape base both sides respectively constitute, described thermal transfer ink layer is divided into three parts, is followed successively by abscission layer, color layers, binder couse from inside to outside by tape base one side surface.
Further, described back coating is made by following weight percentages: link stuff 80～90%, auxiliary agent 10～20%; Described abscission layer is made by following weight percentages: link stuff 93～97%, auxiliary agent 3～7%; Described color layers is made by following weight percentages: link stuff 20～40%, pigment 30～45%, filler 30～35%; Described binder couse is made by following weight percentages: link stuff 75～85%, inserts 13～23%, auxiliary agent 1～2%.
Further, in the described back coating, link stuff is an organic siliconresin, and auxiliary agent is the organosilicon inserts; In the described abscission layer, link stuff is the modified acrylic polyurethane resin, and auxiliary agent is chlorinated paraffin wax wax slurry; In the described color layers, link stuff is a phenolic resins, and pigment does not limit, and can be white, redness, yellow, blueness, green etc., and filler is a talcum powder; In the described binder couse, link stuff is EVA resin and superchlorinated polyvinyl chloride resin, and both account for the binder couse total weight percent and are respectively EVA resin 55～60% and superchlorinated polyvinyl chloride resin 20～25%, and inserts is an OP wax, and auxiliary agent is the titanate ester surfactant.
Further, tape base is the high-strength polyester film.
Preferably, in the back coating, organic siliconresin is preferably phenyl trichlorosilane, diphenyl dichlorosilane, methyl trichlorosilane or phenyl siloxane, and the organosilicon inserts is preferably methyl hydrogen siloxane or platinum chloric acid; Phenolic resins is preferably rosin modified phenolic resin, phenol formaldehyde resin, tert-butyl group formaldehyde resin; The modified acrylic polyurethane resin is preferably urethane diacrylate, polyurethane triacrylate, polyurethane tetraacrylate or polyurethane six acrylate; The titanate ester surfactant is preferably dodecyl benzene sulfonyl titanate esters, isopropyl triisostearoyltitanate, isopropyl three oleoyl titanate esters or isopropoxy three different caprylyl titanate esters; Described high-strength polyester film is preferably biaxial tension PET film.
A kind of preparation method of digital banner printing carbon ribbon may further comprise the steps:
The link stuff of a, the back coating that will take by weighing in proportion with gasoline and auxiliary agent diluted mixture evenly after, be coated on tape base one side surface, oven dry forms back coating and enters into subsequent processing;
The link stuff of b, the abscission layer that will take by weighing in proportion with butanone and butyl ester and auxiliary agent diluted mixture evenly after, be coated on the other side surface of tape base, oven dry forms abscission layer and enters into subsequent processing;
After link stuff, pigment and the fillers dilute of c, the color layers that will take by weighing in proportion with dimethylbenzene mixes, grinds, coat the abscission layer outside, oven dry forms color layers and enters into subsequent processing;
Link stuff, inserts and auxiliary agent diluted mixture in d, the binder couse that will take by weighing in proportion with dimethylbenzene and butanone are even, are coated on the outside of color layers, and oven dry promptly forms digital banner printing carbon ribbon of the present invention.
Further, among the step a: earlier with gasoline with the link stuff diluted mixture evenly after, add auxiliary agent in proportion in 30 minutes before use then and mix; Among the step b:, and then add auxiliary agent in proportion and mix at first with the link stuff dissolving of butanone and butyl ester with abscission layer; Among the step c: at first phenolic resins is dissolved, add filler in proportion again and pigment grinds with dimethylbenzene; In the steps d: with dimethylbenzene and butanone the link stuff in the binder couse is dissolved, and then add inserts and auxiliary agent in proportion, mix and form the binder couse coating fluid.
Again further, among the step c, after the grinding, the pigment fineness is less than 5 μ m; In the steps d, the binder couse coating fluid is under 25 ℃ of conditions, and viscosity is 14～16 seconds.
Again further, bake out temperature is 80～100 ℃ among the step a, back coating thickness 0.2～0.5 μ m; Bake out temperature is 60～80 ℃ among the step b, abscission layer thickness 1～3 μ m; Bake out temperature is 80～100 ℃ among the step c, color layers thickness 8～20 μ m; Bake out temperature is 40～60 ℃ in the steps d, binder couse thickness 4～10 μ m; Base thick 4～6 μ m, the gross thickness of digital banner printing carbon ribbon is 17.2～39.5 μ m.
Further, by weight, the consumption of gasoline is a gasoline: link stuff=9: 1 among the step a; By weight, total consumption of butanone and butyl ester is butanone-butyl ester among the step b: link stuff=5: 1, and in butanone-butyl ester, butanone: butyl ester=3～4: 1; By weight, the consumption of dimethylbenzene is a dimethylbenzene: phenolic resins=5: 1 among the step c; By weight, total consumption of dimethylbenzene and butanone is dimethylbenzene-butanone in the steps d: link stuff=5: 1, and in dimethylbenzene-butanone, dimethylbenzene: butanone=3～4: 1.
Digital banner printing carbon ribbon of the present invention is reasonable in design, and the preparation method is easy, be easy to apply.The digital banner printing carbon ribbon that adopts technical solution of the present invention to make can be transferred to abscission layer, color layers and binder couse on the bar web materials through vertically hung scroll carbon ribbon printer, realizes the disposable making of vertically hung scroll.The present invention has reformed the complicated technology that traditional vertically hung scroll is made, and not only makes vertically hung scroll make simple and fast, economical and efficient more, and to have satisfied that computer design prints be digitlization, the personalized design requirement of finished product.
The specific embodiment:
Below with specific embodiment technical scheme of the present invention is described, but protection scope of the present invention is not limited thereto:
Embodiment 1
The preparation method of digital banner printing carbon ribbon: a, with gasoline with the link stuff diluted mixture evenly after, adding auxiliary agent in preceding 30 minutes on probation mixes, be coated in tape base one side surface then, oven dry forms back coating under 91 ℃ temperature, require this layer thickness 0.4 μ m, enter into subsequent processing afterwards; Wherein by weight, the consumption of gasoline is a gasoline: link stuff=9: 1;
B, at first with butanone-butyl ester with the dissolving of the link stuff of abscission layer, and then add auxiliary agent in proportion and mix, being coated in the other side surface of tape base then, oven dry forms abscission layer under 80 ℃ temperature, require this layer thickness 2.0 μ m, enter into subsequent processing afterwards; Wherein by weight, total consumption of butanone and butyl ester is butanone-butyl ester: link stuff=5: 1, and in butanone-butyl ester, butanone: butyl ester=4: 1;
C, at first phenolic resins is dissolved with dimethylbenzene, add filler and pigment more in proportion and make the color layers coating fluid through fully grinding, require that pigment will be uniformly dispersed, fineness is less than 5 μ m, be applied to the abscission layer outside again, oven dry forms color layers under 80 ℃ temperature, require this layer thickness 14 μ m, guarantee bright in luster clean; Wherein by weight, the consumption of dimethylbenzene is a dimethylbenzene: phenolic resins=5: 1;
D, usefulness dimethylbenzene-butanone dissolve the link stuff in the binder couse, and then add inserts in proportion and auxiliary agent fully mixes, be formed on viscosity under 25 ℃ of conditions and be 14～16 seconds, uniform and stable binder couse coating fluid, be coated in the outside of color layers then, thoroughly oven dry under 60 ℃ temperature, making this layer thickness is 6 μ m, becomes solid-state tough film at normal temperatures; By weight, total consumption of dimethylbenzene and butanone is dimethylbenzene-butanone: link stuff=5: 1, and in dimethylbenzene-butanone, dimethylbenzene: butanone=3: 1; Promptly form digital banner printing carbon ribbon of the present invention this moment.
In the present embodiment, tape base is the thick biaxial tension PET films of 4 μ m, and the gross thickness of digital banner printing carbon ribbon is 26.4 μ m.Percentage by weight one hurdle of link stuff divides two subfields up and down in the binder couse, and last subfield is the percentage by weight of shared layer of each concrete component thing, and following subfield is the percentage by weight of shared layer of link stuff.Below each embodiment identical therewith.
Embodiment 2
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 80 ℃ among the step a, back coating thickness 0.2 μ m; Bake out temperature is 60 ℃ among the step b, butanone: butyl ester=3: 1, abscission layer thickness 1 μ m; Bake out temperature is 80 ℃ among the step c, color layers thickness 8 μ m; Bake out temperature is 40 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 4.0 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 4 μ m, and the gross thickness of digital banner printing carbon ribbon is 17.2 μ m.
Embodiment 3
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 81 ℃ among the step a, back coating thickness 0.5 μ m; Bake out temperature is 60 ℃ among the step b, butanone: butyl ester=3.5: 1, abscission layer thickness 3 μ m; Bake out temperature is 100 ℃ among the step c, color layers thickness 20 μ m; Bake out temperature is 60 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 10 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 6 μ m, and the gross thickness of digital banner printing carbon ribbon is 39.5 μ m.
Embodiment 4
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 80 ℃ among the step a, back coating thickness 0.5 μ m; Bake out temperature is 80 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 1.5 μ m; Bake out temperature is 90 ℃ among the step c, color layers thickness 15 μ m; Bake out temperature is 43 ℃ in the steps d, dimethylbenzene: butanone=3.2: 1, binder couse thickness 8 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 30 μ m.
Embodiment 5
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 88 ℃ among the step a, back coating thickness 0.3 μ m; Bake out temperature is 63 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 2.7 μ m; Bake out temperature is 83 ℃ among the step c, color layers thickness 10 μ m; Bake out temperature is 46 ℃ in the steps d, dimethylbenzene: butanone=3.4: 1, binder couse thickness 10 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 28 μ m.
Embodiment 6
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 80 ℃ among the step a, back coating thickness 0.5 μ m; Bake out temperature is 60 ℃ among the step b, butanone: butyl ester=3.2: 1, abscission layer thickness 1 μ m; Bake out temperature is 80 ℃ among the step c, color layers thickness 13.5 μ m; Bake out temperature is 46 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 5 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 4.5 μ m, and the gross thickness of digital banner printing carbon ribbon is 24.5 μ m.
Embodiment 7
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 82 ℃ among the step a, back coating thickness 0.4 μ m; Bake out temperature is 70 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 1.6 μ m; Bake out temperature is 80 ℃ among the step c, color layers thickness 18 μ m; Bake out temperature is 55 ℃ in the steps d, dimethylbenzene: butanone=3.8: 1, binder couse thickness 4 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 4.5 μ m, and the gross thickness of digital banner printing carbon ribbon is 28.5 μ m.
Embodiment 8
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 96 ℃ among the step a, back coating thickness 0.3 μ m; Bake out temperature is 73 ℃ among the step b, butanone: butyl ester=3.8: 1, abscission layer thickness 2.2 μ m; Bake out temperature is 89 ℃ among the step c, color layers thickness 10.5 μ m; Bake out temperature is 50 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 7.7 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 6 μ m, and the gross thickness of digital banner printing carbon ribbon is 26.7 μ m.
Embodiment 9
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 80 ℃ among the step a, back coating thickness 0.4 μ m; Bake out temperature is 63 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 2 μ m; Bake out temperature is 83 ℃ among the step c, color layers thickness 9 μ m; Bake out temperature is 42 ℃ in the steps d, dimethylbenzene: butanone=3.7: 1, binder couse thickness 6 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 4 μ m, and the gross thickness of digital banner printing carbon ribbon is 21.4 μ m.
Embodiment 10
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 93 ℃ among the step a, back coating thickness 0.3 μ m; Bake out temperature is 63 ℃ among the step b, butanone: butyl ester=3.3: 1, abscission layer thickness 1.8 μ m; Bake out temperature is 90 ℃ among the step c, color layers thickness 15.3 μ m; Bake out temperature is 56 ℃ in the steps d, dimethylbenzene: butanone=3.6: 1, binder couse thickness 6.8 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 4 μ m, and the gross thickness of digital banner printing carbon ribbon is 28.2 μ m.
Embodiment 11
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 80 ℃ among the step a, back coating thickness 0.5 μ m; Bake out temperature is 80 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 1 μ m; Bake out temperature is 82 ℃ among the step c, color layers thickness 9 μ m; Bake out temperature is 60 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 4.7 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 4.5 μ m, and the gross thickness of digital banner printing carbon ribbon is 19.7 μ m.
Example 12
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 83 ℃ among the step a, back coating thickness 0.4 μ m; Bake out temperature is 68 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 1 μ m; Bake out temperature is 85 ℃ among the step c, color layers thickness 9.9 μ m; Bake out temperature is 53 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 4.5 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 20.8 μ m.
Example 13
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 100 ℃ among the step a, back coating thickness 0.2 μ m; Bake out temperature is 80 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 1 μ m; Bake out temperature is 100 ℃ among the step c, color layers thickness 11 μ m; Bake out temperature is 60 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 4 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 21.2 μ m.
Example 14
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 80 ℃ among the step a, back coating thickness 0.2 μ m; Bake out temperature is 60 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 1.5 μ m; Bake out temperature is 80 ℃ among the step c, color layers thickness 12.3 μ m; Bake out temperature is 40 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 6 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 25 μ m.
Example 15
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 92 ℃ among the step a, back coating thickness 0.2 μ m; Bake out temperature is 63 ℃ among the step b, butanone: butyl ester=3.7: 1, abscission layer thickness 1.5 μ m; Bake out temperature is 88 ℃ among the step c, color layers thickness 15.3 μ m; Bake out temperature is 56 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 8.4 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 30.4 μ m.
Example 16
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 85 ℃ among the step a, back coating thickness 0.4 μ m; Bake out temperature is 65 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 1.7 μ m; Bake out temperature is 86 ℃ among the step c, color layers thickness 14.5 μ m; Bake out temperature is 45 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 9.3 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 30.9 μ m.
Example 17
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 80 ℃ among the step a, back coating thickness 0.5 μ m; Bake out temperature is 70 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 2.6 μ m; Bake out temperature is 100 ℃ among the step c, color layers thickness 17.3 μ m; Bake out temperature is 60 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 9.1 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 34.5 μ m.
Example 18
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 90 ℃ among the step a, back coating thickness 0.3 μ m; Bake out temperature is 60 ℃ among the step b, butanone: butyl ester=3: 1, abscission layer thickness 2.5 μ m; Bake out temperature is 80 ℃ among the step c, color layers thickness 17 μ m; Bake out temperature is 50 ℃ in the steps d, dimethylbenzene: butanone=4: 1, binder couse thickness 9.2 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 34 μ m.
Example 19
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 100 ℃ among the step a, back coating thickness 0.2 μ m; Bake out temperature is 80 ℃ among the step b, butanone: butyl ester=3: 1, abscission layer thickness 2.7 μ m; Bake out temperature is 90 ℃ among the step c, color layers thickness 20 μ m; Bake out temperature is 52 ℃ in the steps d, dimethylbenzene: butanone=3: 1, binder couse thickness 10 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 37.9 μ m.
Example 20
Among the preparation method of digital banner printing carbon ribbon: bake out temperature is 85 ℃ among the step a, back coating thickness 0.5 μ m; Bake out temperature is 75 ℃ among the step b, butanone: butyl ester=4: 1, abscission layer thickness 2.8 μ m; Bake out temperature is 93 ℃ among the step c, color layers thickness 20 μ m; Bake out temperature is 50 ℃ in the steps d, dimethylbenzene: butanone=3: 1, binder couse thickness 10 μ m; Other is all with embodiment 1.
In the present embodiment, tape base is the thick biaxial tension PET films of 5 μ m, and the gross thickness of digital banner printing carbon ribbon is 38.3 μ m.
Claims (8)
1. digital banner printing carbon ribbon is characterized in that: by tape base and back coating and the thermal transfer ink layer of coating the tape base both sides respectively constitute, described thermal transfer ink layer is divided into three parts, is followed successively by abscission layer, color layers, binder couse from inside to outside by tape base one side surface; Described back coating is made by following weight percentages: link stuff 80～90%, and auxiliary agent 10～20%, link stuff are organic siliconresin, auxiliary agent is the organosilicon inserts; Described abscission layer is made by following weight percentages: link stuff 93～97%, and auxiliary agent 3～7%, link stuff are the modified acrylic polyurethane resin, auxiliary agent is chlorinated paraffin wax wax slurry; Described color layers is made by following weight percentages: link stuff 20～40%, and pigment 30～45%, filler 30～35%, link stuff are phenolic resins, filler is a talcum powder; Described binder couse is made by following weight percentages: link stuff 75～85%, inserts 13～23%, auxiliary agent 1～2%, link stuff is EVA resin and superchlorinated polyvinyl chloride resin, both account for the binder couse total weight percent and are respectively EVA resin 55～60% and superchlorinated polyvinyl chloride resin 20～25%, inserts is an OP wax, and auxiliary agent is the titanate ester surfactant.
2. digital banner printing carbon ribbon according to claim 1 is characterized in that: tape base is the high-strength polyester film.
3. digital banner printing carbon ribbon according to claim 2, it is characterized in that: in the back coating, organic siliconresin is phenyl trichlorosilane, diphenyl dichlorosilane, methyl trichlorosilane or phenyl siloxane, and the organosilicon inserts is methyl hydrogen siloxane or platinum chloric acid; In the abscission layer, the modified acrylic polyurethane resin is urethane diacrylate, polyurethane triacrylate, polyurethane tetraacrylate or polyurethane six acrylate; In the color layers, phenolic resins is rosin modified phenolic resin, phenol formaldehyde resin, tert-butyl group formaldehyde resin; In the binder couse, the titanate ester surfactant is dodecyl benzene sulfonyl titanate esters, isopropyl triisostearoyltitanate, isopropyl three oleoyl titanate esters or isopropoxy three different caprylyl titanate esters; The high-strength polyester film is a biaxial tension PET film.
4. method for preparing each described digital banner printing carbon ribbon of claim 1～3 is characterized in that may further comprise the steps:
The link stuff of a, the back coating that will take by weighing in proportion with gasoline and auxiliary agent diluted mixture evenly after, be coated on tape base one side surface, oven dry forms back coating and enters into subsequent processing;
The link stuff of b, the abscission layer that will take by weighing in proportion with butanone and butyl ester and auxiliary agent diluted mixture evenly after, be coated on the other side surface of tape base, oven dry forms abscission layer and enters into subsequent processing;
After link stuff, pigment and the fillers dilute of c, the color layers that will take by weighing in proportion with dimethylbenzene mixes, grinds, coat the abscission layer outside, oven dry forms color layers and enters into subsequent processing;
Link stuff, inserts and auxiliary agent diluted mixture in d, the binder couse that will take by weighing in proportion with dimethylbenzene and butanone are even, are coated on the outside of color layers, and oven dry promptly forms digital banner printing carbon ribbon.
5. the preparation method of digital banner printing carbon ribbon according to claim 4 is characterized in that: among the step a: earlier with gasoline with the link stuff diluted mixture evenly after, add auxiliary agent in proportion in 30 minutes before use then and mix; Among the step b:, and then add auxiliary agent in proportion and mix at first with the link stuff dissolving of butanone and butyl ester with abscission layer; Among the step c: at first phenolic resins is dissolved, add filler in proportion again and pigment grinds with dimethylbenzene; In the steps d: with dimethylbenzene and butanone the link stuff in the binder couse is dissolved, and then add inserts and auxiliary agent in proportion, mix and form the binder couse coating fluid.
6. the preparation method of digital banner printing carbon ribbon according to claim 5, it is characterized in that: among the step c, after the grinding, the pigment fineness is less than 5 μ m; In the steps d, the binder couse coating fluid is under 25 ℃ of conditions, and viscosity is 14～16 seconds.
7. the preparation method of digital banner printing carbon ribbon according to claim 6, it is characterized in that: bake out temperature is 80～100 ℃ among the step a, back coating thickness 0.2～0.5 μ m; Bake out temperature is 60～80 ℃ among the step b, abscission layer thickness 1～3 μ m; Bake out temperature is 80～100 ℃ among the step c, color layers thickness 8～20 μ m; Bake out temperature is 40～60 ℃ in the steps d, binder couse thickness 4～10 μ m; Base thick 4～6 μ m, the gross thickness of digital banner printing carbon ribbon is 17.2～39.5 μ m.
8. the preparation method of digital banner printing carbon ribbon according to claim 7, it is characterized in that: by weight, the consumption of gasoline is a gasoline: link stuff=9: 1 among the step a; By weight, total consumption of butanone and butyl ester is butanone-butyl ester among the step b: link stuff=5: 1, and in butanone-butyl ester, butanone: butyl ester=(3～4): 1; By weight, the consumption of dimethylbenzene is a dimethylbenzene: phenolic resins=5: 1 among the step c; By weight, total consumption of dimethylbenzene and butanone is dimethylbenzene-butanone in the steps d: link stuff=5: 1, and in dimethylbenzene-butanone, dimethylbenzene: butanone=(3～4): 1.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100646959A CN101537744B (en) | 2009-04-21 | 2009-04-21 | Digital banner printing thermal transfer ribbon and preparation method thereof |
| PCT/CN2009/072766 WO2010121449A1 (en) | 2009-04-21 | 2009-07-15 | Digital scroll printing carbon ribbon and method for preparing the same |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2009100646959A CN101537744B (en) | 2009-04-21 | 2009-04-21 | Digital banner printing thermal transfer ribbon and preparation method thereof |
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| CN102653189B (en) * | 2012-04-16 | 2014-09-10 | 河南卓立膜材料股份有限公司 | Thermal transfer ribbon for edge-pressing printer and preparation method thereof |
| CN102658736A (en) * | 2012-05-18 | 2012-09-12 | 焦作市卓立烫印材料有限公司 | Thermal transfer ribbon for transferring image text to have noctilucent effect and preparation method thereof |
| CN102658735B (en) * | 2012-05-31 | 2014-12-10 | 河南卓立膜材料股份有限公司 | Flat-pressing resin-based bar code printing thermal transfer ribbon and preparation method thereof |
| CN105058999A (en) * | 2015-08-12 | 2015-11-18 | 河南卓立膜材料股份有限公司 | Thermal transfer ribbon with night luminous function and preparation method thereof |
| CN106564305B (en) * | 2016-11-11 | 2019-06-21 | 马鞍山纽盟知识产权管理服务有限公司 | A kind of thermal dye sublimation transfer printing special colored |
| CN110776835B (en) * | 2019-11-08 | 2021-11-26 | 焦作卓立膜材料有限责任公司 | Marking film for hard smooth substrate surface |
| CN111499909A (en) * | 2020-05-29 | 2020-08-07 | 曲阜市玉樵夫科技有限公司 | Low-temperature-resistant high-firmness banner color band |
| CN112009127A (en) * | 2020-07-23 | 2020-12-01 | 泉州市福采转印科技有限公司 | Transfer printing film for EVA slipper transfer printing and transfer printing method |
| CN112477451B (en) * | 2020-12-03 | 2023-08-11 | 安徽维森智能识别材料有限公司 | Mixed base heat transfer carbon belt suitable for various printing stock |
| CN113752713A (en) * | 2021-09-15 | 2021-12-07 | 河南亿思达数码材料有限公司 | Scroll ribbon and preparation process thereof |
| CN114274682A (en) * | 2021-12-23 | 2022-04-05 | 湖南鼎一致远科技发展有限公司 | Carbon ribbon with protective layer for reflective film and preparation method thereof |
| CN114228355B (en) * | 2021-12-27 | 2024-01-12 | 湖南鼎一致远科技发展有限公司 | Resin ribbon suitable for multiple types of base materials and preparation method thereof |
| CN115157895B (en) * | 2022-07-22 | 2024-01-02 | 浙江龙游道明光学有限公司 | Color ribbon and manufacturing method thereof |
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| US5525569A (en) * | 1994-03-07 | 1996-06-11 | Moore Business Forms, Inc. | Self-contained transfer tape |
| US5939207A (en) * | 1997-05-30 | 1999-08-17 | International Imaging Materials, Inc. | Thermal transfer ribbon for high density/high resolution bar code applications |
| JP2001180126A (en) * | 1999-12-27 | 2001-07-03 | Dainippon Printing Co Ltd | Thermal transfer ribbon |
| CN1217288C (en) * | 2001-06-11 | 2005-08-31 | 孟晓静 | Method for preparing encrypted bar code and its reader |
| CN1242888C (en) * | 2002-09-29 | 2006-02-22 | 张振宇 | Blanching pattern mark carbon band |
| CN1485379A (en) * | 2002-09-29 | 2004-03-31 | 张振宇 | Printing ink paint |
| JP4401938B2 (en) * | 2004-11-25 | 2010-01-20 | 株式会社宝來社 | Thermocompression mark with nonwoven fabric, taffeta, ponji, etc. |
| CN101112808B (en) * | 2006-07-24 | 2010-11-24 | 焦作市卓立烫印材料有限公司 | Water-washing identification tape and preparation method thereof |
| CN100551715C (en) * | 2006-10-26 | 2009-10-21 | 焦作市卓立烫印材料有限公司 | The compound colour band of peelable temperature-sensitive |
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| CN101537744A (en) | 2009-09-23 |
| WO2010121449A1 (en) | 2010-10-28 |
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