CN106274118A - Hot stamping foil with low-temperature printing and high-temperature sterilization performance and preparation method thereof - Google Patents
Hot stamping foil with low-temperature printing and high-temperature sterilization performance and preparation method thereof Download PDFInfo
- Publication number
- CN106274118A CN106274118A CN201610649666.9A CN201610649666A CN106274118A CN 106274118 A CN106274118 A CN 106274118A CN 201610649666 A CN201610649666 A CN 201610649666A CN 106274118 A CN106274118 A CN 106274118A
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- CN
- China
- Prior art keywords
- protective layer
- temperature
- performance
- high temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Abstract
The invention belongs to the technical field of hot stamping materials, and particularly discloses a hot stamping foil with low-temperature printing and high-temperature sterilization performance, which comprises a strip base and a thermal transfer layer coated on the other side surface of the strip base, wherein the thermal transfer layer comprises a nano protective layer and a color layer which are sequentially coated on the surface of the strip base; the nano protective layer is prepared from the following raw materials in percentage by weight: 80-90% of binder and 10-20% of assistant. The hot stamping foil is provided with the nano protective layer, the contents are printed by the hot stamping machine, the printed protective layer covers the surface of the color layer, and the hot stamping foil has the excellent performances of low-temperature printing at the temperature lower than 120 ℃, high-temperature sterilization resistance at the temperature of 121 ℃ and the like of the printed contents, and is widely used for printing information such as character pattern marks, medicine monitoring codes, production dates, batch numbers and the like on the surfaces of various medical transfusion soft bags.
Description
Technical field
The invention belongs to technical field of hot stamping materials, be specifically related to a kind of possess low temperature print and high temperature sterilize performance scald
Print paper tinsel and preparation method thereof, its mark that can be used for transfusion flexible bag is printed.
Background technology
At present, the mark of domestic transfusion flexible bag is printed major part and is used hot stamping technology, but it is high generally to there is print temperature
The defect of (150 DEG C ~ 180 DEG C).Print temperature height not only causes the probability that in production process, soft bag is punched relatively big, and percent defective is high,
Energy consumption cost is the highest simultaneously.Additionally, part possess the product of low temperature printing function exist again non-refractory sterilizing (121 DEG C),
The problems such as sterilizing decolouring.
Summary of the invention
For overcoming the deficiencies in the prior art, present invention aim at providing one to possess low temperature and print and high temperature sterilize performance
Stamping systems and preparation method thereof.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of possess low temperature printing and the stamping systems of high temperature sterilize performance, tape base and the heat coating tape base opposite side surface turn
Print layer is constituted, and wherein, described thermal transfer ink layer is made up of the nanometer protective layer sequentially coating band primary surface and color layers；Described receive
Rice protective layer is made up of the raw material of following weight percentage ratio: link stuff 80 ~ 90%, auxiliary agent 10 ~ 20%.
Concrete, the link stuff in nanometer protective layer is polystyrene resin, and auxiliary agent is nano silicon.
Described color layers is made up of the raw material of following weight percentage ratio: link stuff 30 ~ 50%, pigment 30 ~ 40%, and filler 10 ~
30%.Link stuff in color layers can be softening point hypothermia thermoplastic resin between 80 ~ 100 DEG C；Filler is inorganic filling out
Material.
To account in terms of color layers total weight percent, hypothermia thermoplastic resin by acrylic resin 0 ~ 20%, rosin resin 0 ~
20% and Corvic 0 ~ 10% composition.Described inorganic filler is Pulvis Talci, calcium carbonate or barium sulfate.
Acrylic resin, rosin resin, Corvic are softening point low-temperature thermoplastic between 80 ~ 100 DEG C
Resin.Object lesson as rosin resin has: rosin glyceride, disproportionated rosin, disproportionated rosin glyceride, hydrogenated rosin, hydrogen
Change rosin glyceride, natural rosin, polymerized rosin glycerol ester, rosin pentaerythritol ester glyceride, limed rosin, maleic acid pine
Fragrant glyceride.Inorganic filler is to well known to a person skilled in the art customary filler, and the object lesson as inorganic filler has: Talcum
Powder, calcium carbonate or barium sulfate etc..
The preparation method of a kind of above-mentioned stamping systems possessing low temperature printing and high temperature sterilize performance, it comprises the steps:
A, by after the link stuff heating and melting of nanometer protective layer, be proportionally added into auxiliary agent, mix homogeneously forms protective layer ink, is coated with
Cloth, on the surface of tape base opposite side, is dried and is formed nanometer protective layer and enter into subsequent processing；
B, with the butanone of weight ratio 3 ~ 5:1 and butyl ester as mixed solvent, by each raw material of color layers (i.e. link stuff, filler and
Pigment) dilute mixing in proportion, ground make color layers ink, be coated on nanometer protective layer, dry and form color layers,
Must possess low temperature to print and the stamping systems of high temperature sterilize performance.
When preparing color layers, first butanone and butyl ester are mixed to obtain mixed solvent by the weight ratio of 3 ~ 5:1, simultaneously with fourth
Ketone and the mixed solvent of butyl ester: the mass ratio range of link stuff=8 ~ 10:1, with the mixed solvent of butanone and butyl ester by the company of color layers
Ramming material dissolves, then is proportionally added into filler and pigment, grinds and makes color layers ink, dries and forms color layers.Preferably, butanone
The temperature dissolving link stuff with the mixed solvent of butyl ester is 50 ~ 60 DEG C；After grinding, it is desirable to pigment to be uniformly dispersed, fineness is little
In 5 μm, described fineness does not comprise 0 μm；Drying temperature is 60 ~ 80 DEG C.
Base thick 12 m, nanometer protective layer thickness 1 ~ 2 m, color layers thickness 1 ~ 2 μm, the gross thickness of tape base and coating is
14~16μm.The preferred mylar of tape base, more preferably biaxial tension polyethylene terephthalate (BOPET) thin film.
The present invention possesses the stamping systems of low temperature printing and high temperature sterilize performance and is designed with nanometer protective layer and low-temperature transfer printing face
Chromatograph, prints content by hot stamping machine, and after printing, nanometer protective layer is covered in color layers surface, and therefore this stamping systems possesses low
The premium properties such as, printing content resistance to 121 DEG C high temperature sterilizes printable in 120 DEG C of low temperature, solve the most existing thermoprint
The probability that in paper tinsel product print temperature high (150 DEG C ~ 180 DEG C), production process, soft bag is punched is relatively big, percent defective is high, energy consumption cost
The problems such as height, high temperature sterilize (121 DEG C) decolouring, can be widely used for the character pattern mark on various medical transfusion soft bag surface, medicine
The printing of the information such as prison code, date of manufacture and lot number.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail, but protection scope of the present invention is also
It is not limited to this.
In following example, the link stuff in nanometer protective layer is polystyrene resin, and manufacturer is Changhai, Taicang
Petrochemical industry company limited；The nano silicon of selection of auxiliary particle diameter 10 ~ 25nm, manufacturer is that the good nanometer in Weifang three is limited
Company.In color layers, link stuff selects softening point acrylic resin, rosin resin and polrvinyl chloride between 80 ~ 100 DEG C
Resin, it is hypothermia thermoplastic resin, and manufacturer is respectively Mitsubishi chemical Co., Ltd, famine river, Wuzhou, Guangxi chemical industry
Company limited and Qi Qing raw material Chemical Co., Ltd..Tape base is biaxial tension polyethylene terephthalate (BOPET) thin film,
Thick 12 m of tape base.
Embodiment 1 ~ 10 be of the present invention possess low temperature print and the stamping systems of high temperature sterilize performance.
Embodiment 1
The preparation method of the above-mentioned stamping systems possessing low temperature printing and high temperature sterilize performance, it comprises the steps:
A, by the link stuff of nanometer protective layer under conditions of 140 ~ 150 DEG C after heating and melting, be proportionally added into auxiliary agent, mixing is all
Even formation protective layer ink, is coated on the surface of tape base opposite side, dries and forms nanometer protective layer, it is desirable to should at a temperature of 30 DEG C
Nanometer protective layer thickness 1 m, enters into subsequent processing；
B, first butanone and butyl ester are mixed to obtain mixed solvent by weight, with the mixed solvent of butanone and butyl ester by color layers
Link stuff dissolves (temperature 60 C), then is proportionally added into filler and pigment, grinds and makes color layers ink, it is desirable to pigment to disperse
Uniformly, fineness less than 5 μm, coat nanometer protective layer, dry at 80 DEG C and form color layers, it is desirable to this color layers thickness 1 μ
m；Now the gross thickness of tape base and coating is 14 μm, is i.e. formed and of the present invention possess low temperature and print and high temperature sterilize performance
Stamping systems.
Embodiment 2
Preparation process: drying temperature in step a is 31 DEG C, nanometer protective layer thickness 2 m；In step b, solution temperature 59 DEG C, dry
Dry temperature is 78 DEG C, color layers thickness 2 m；Other is all with embodiment 1, gained possess low temperature print and high temperature sterilize performance scald
The gross thickness of print paper tinsel is 16 m.
Embodiment 3
Preparation process: drying temperature in step a is 30 DEG C, nanometer protective layer thickness 1.5 m；In step b, solution temperature 60 DEG C,
Drying temperature is 80 DEG C, color layers thickness 1.5 m；Other is all with embodiment 1, and gained possesses low temperature and prints and high temperature sterilize performance
The gross thickness of stamping systems be 15 m.
Embodiment 4
Preparation process: drying temperature in step a is 29 DEG C, nanometer protective layer thickness 1 m；In step b, solution temperature 60 DEG C, dry
Dry temperature is 81 DEG C, color layers thickness 1.5 m；Other is all with embodiment 1, and gained possesses low temperature and prints and high temperature sterilize performance
The gross thickness of stamping systems is 14.5 m.
Embodiment 5
Preparation process: drying temperature in step a is 29 DEG C, nanometer protective layer thickness 1.2 m；In step b, solution temperature 60 DEG C,
Drying temperature is 80 DEG C, color layers thickness 2 m；Other is all with embodiment 1, and gained possesses low temperature and prints and high temperature sterilize performance
The gross thickness of stamping systems is 15.2 m.
Embodiment 6
Preparation process: drying temperature in step a is 30 DEG C, nanometer protective layer thickness 2 m；In step b, solution temperature 59 DEG C, dry
Dry temperature is 80 DEG C, color layers thickness 1 m；Other is all with embodiment 1, gained possess low temperature print and high temperature sterilize performance scald
The gross thickness of print paper tinsel is 15 m.
Embodiment 7
Preparation process: drying temperature in step a is 30 DEG C, nanometer protective layer thickness 1.5 m；In step b, solution temperature 60 DEG C,
Drying temperature is 80 DEG C, color layers thickness 1.2 m；Other is all with embodiment 1, and gained possesses low temperature and prints and high temperature sterilize performance
The gross thickness of stamping systems be 14.7 m.
Embodiment 8
Preparation process: drying temperature in step a is 31 DEG C, nanometer protective layer thickness 1 m；In step b, solution temperature 59 DEG C, dry
Dry temperature is 80 DEG C, color layers thickness 1.8 m；Other is all with embodiment 1, and gained possesses low temperature and prints and high temperature sterilize performance
The gross thickness of stamping systems is 14.8 m.
Embodiment 9
Preparation process: drying temperature in step a is 29 DEG C, nanometer protective layer thickness 1 m；In step b, solution temperature 59 DEG C, dry
Dry temperature is 79 DEG C, color layers thickness 2 m；Other is all with embodiment 1, gained possess low temperature print and high temperature sterilize performance scald
The gross thickness of print paper tinsel is 15 m.
Embodiment 10
Preparation process: drying temperature in step a is 30 DEG C, nanometer protective layer thickness 1.5 m；In step b, solution temperature 60 DEG C,
Drying temperature is 80 DEG C, color layers thickness 2 m；Other is all with embodiment 1, and gained possesses low temperature and prints and high temperature sterilize performance
The gross thickness of stamping systems is 15.5 m.
The performance of the stamping systems that the various embodiments described above 1 ~ 10 gained possesses low temperature printing and high temperature sterilize performance see table.
Claims (7)
1. possess low temperature to print and a stamping systems for high temperature sterilize performance, by tape base and the heat coating tape base opposite side surface
Transfer printing layer is constituted, it is characterised in that described thermal transfer ink layer is by nanometer protective layer and the color layers structure sequentially coating band primary surface
Become；Described nanometer protective layer is made up of the raw material of following weight percentage ratio: link stuff 80 ~ 90%, auxiliary agent 10 ~ 20%.
Possess low temperature the most according to claim 1 to print and the stamping systems of high temperature sterilize performance, it is characterised in that: nanometer is protected
Link stuff in Ceng is polystyrene resin, and auxiliary agent is nano silicon.
Possess low temperature the most according to claim 1 to print and the stamping systems of high temperature sterilize performance, it is characterised in that: described color
Layer is made up of the raw material of following weight percentage ratio: link stuff 30 ~ 50%, pigment 30 ~ 40%, filler 10 ~ 30%.
Possess low temperature the most according to claim 3 to print and the stamping systems of high temperature sterilize performance, it is characterised in that: in color layers
Link stuff be softening point hypothermia thermoplastic resin between 80 ~ 100 DEG C；Filler is inorganic filler.
Possess low temperature the most according to claim 4 to print and the stamping systems of high temperature sterilize performance, it is characterised in that: to account for color
Layer total weight percent meter, hypothermia thermoplastic resin is by acrylic resin 0 ~ 20%, rosin resin 0 ~ 20% and Corvic 0
~ 10% composition.
Possess low temperature the most according to claim 4 to print and the stamping systems of high temperature sterilize performance, it is characterised in that: described inorganic
Filler is Pulvis Talci, calcium carbonate or barium sulfate.
7. claim 1 ~ 6 arbitrarily described in possess low temperature and print and the preparation method of stamping systems for high temperature sterilize performance, its
It is characterised by, comprises the steps:
A, by after the link stuff heating and melting of nanometer protective layer, be proportionally added into auxiliary agent, mix homogeneously forms protective layer ink, is coated with
Cloth, on the surface of tape base opposite side, is dried and is formed nanometer protective layer and enter into subsequent processing；
Each raw material of color layers, as mixed solvent, is diluted mixing, warp by b, the butanone using weight ratio 3 ~ 5:1 and butyl ester in proportion
Color layers ink is made in grinding, is coated on nanometer protective layer, dries and forms color layers, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610649666.9A CN106274118B (en) | 2016-08-10 | 2016-08-10 | Hot stamping foil with low-temperature printing and high-temperature sterilization performance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610649666.9A CN106274118B (en) | 2016-08-10 | 2016-08-10 | Hot stamping foil with low-temperature printing and high-temperature sterilization performance and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106274118A true CN106274118A (en) | 2017-01-04 |
| CN106274118B CN106274118B (en) | 2018-08-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201610649666.9A Active CN106274118B (en) | 2016-08-10 | 2016-08-10 | Hot stamping foil with low-temperature printing and high-temperature sterilization performance and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384012A (en) * | 2017-08-22 | 2017-11-24 | 河南卓立膜材料股份有限公司 | Cold-printed cable coding tape and preparation method thereof |
| CN111698801A (en) * | 2020-06-17 | 2020-09-22 | 山东英科环保再生资源股份有限公司 | Constant-temperature energy-saving heating system for polystyrene hot stamping and hot stamping process |
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| CN101423000A (en) * | 2007-10-31 | 2009-05-06 | 焦作市卓立烫印材料有限公司 | Metal thermoprinting foil and preparation method thereof |
| CN101570091A (en) * | 2009-06-05 | 2009-11-04 | 焦作市卓立烫印材料有限公司 | Hot stamping foil for blood transfusion bag and preparation method thereof |
| CN101570092A (en) * | 2009-06-05 | 2009-11-04 | 焦作市卓立烫印材料有限公司 | Thermoprinting foil for syringe and its preparing process |
| CN201427446Y (en) * | 2009-06-05 | 2010-03-24 | 焦作市卓立烫印材料有限公司 | Special thermal transfer film of medical plastic transfusion bag |
-
2016
- 2016-08-10 CN CN201610649666.9A patent/CN106274118B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5582663A (en) * | 1978-12-20 | 1980-06-21 | Canon Inc | Recording medium liquid jet recording method by heat energy |
| CN101423000A (en) * | 2007-10-31 | 2009-05-06 | 焦作市卓立烫印材料有限公司 | Metal thermoprinting foil and preparation method thereof |
| CN101570091A (en) * | 2009-06-05 | 2009-11-04 | 焦作市卓立烫印材料有限公司 | Hot stamping foil for blood transfusion bag and preparation method thereof |
| CN101570092A (en) * | 2009-06-05 | 2009-11-04 | 焦作市卓立烫印材料有限公司 | Thermoprinting foil for syringe and its preparing process |
| CN201427446Y (en) * | 2009-06-05 | 2010-03-24 | 焦作市卓立烫印材料有限公司 | Special thermal transfer film of medical plastic transfusion bag |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384012A (en) * | 2017-08-22 | 2017-11-24 | 河南卓立膜材料股份有限公司 | Cold-printed cable coding tape and preparation method thereof |
| CN107384012B (en) * | 2017-08-22 | 2020-11-03 | 河南卓立膜材料股份有限公司 | Cold-printed cable coding tape and preparation method thereof |
| CN111698801A (en) * | 2020-06-17 | 2020-09-22 | 山东英科环保再生资源股份有限公司 | Constant-temperature energy-saving heating system for polystyrene hot stamping and hot stamping process |
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| Publication number | Publication date |
|---|---|
| CN106274118B (en) | 2018-08-07 |
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Effective date of registration: 20220128 Address after: 454000 No. 959, Nanhai West Road, demonstration zone, Jiaozuo City, Henan Province Patentee after: Jiaozuo Zhuoli membrane materials Co.,Ltd. Address before: No.2758, Shenzhou Road, high tech Zone, Jiaozuo City, Henan Province Patentee before: ZHUOLI IMAGING TECHNOLOGY Co.,Ltd. |
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Address after: 454000 No. 959, Nanhai West Road, demonstration zone, Jiaozuo City, Henan Province Patentee after: Jiaozuo Zhuoli film material Co.,Ltd. Address before: 454000 No. 959, Nanhai West Road, demonstration zone, Jiaozuo City, Henan Province Patentee before: Jiaozuo Zhuoli membrane materials Co.,Ltd. |