CN100506751C - 整体型纳米碳纤维复合多孔材料及其制备方法 - Google Patents
整体型纳米碳纤维复合多孔材料及其制备方法 Download PDFInfo
- Publication number
- CN100506751C CN100506751C CNB2007100382059A CN200710038205A CN100506751C CN 100506751 C CN100506751 C CN 100506751C CN B2007100382059 A CNB2007100382059 A CN B2007100382059A CN 200710038205 A CN200710038205 A CN 200710038205A CN 100506751 C CN100506751 C CN 100506751C
- Authority
- CN
- China
- Prior art keywords
- carbon
- weight
- resol
- fiber
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 129
- 229920000049 Carbon (fiber) Polymers 0.000 title claims description 61
- 239000004917 carbon fiber Substances 0.000 title claims description 61
- 239000002131 composite material Substances 0.000 title claims description 39
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 239000011148 porous material Substances 0.000 title description 24
- 229910021392 nanocarbon Inorganic materials 0.000 title description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 49
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 44
- 239000011248 coating agent Substances 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 27
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 14
- 238000003763 carbonization Methods 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- 239000002134 carbon nanofiber Substances 0.000 claims description 64
- 239000011159 matrix material Substances 0.000 claims description 50
- 229920003987 resole Polymers 0.000 claims description 45
- 239000007789 gas Substances 0.000 claims description 37
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- 230000003197 catalytic effect Effects 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- 238000010792 warming Methods 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- -1 haloid Chemical compound 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 239000012159 carrier gas Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 40
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 10
- 150000001875 compounds Chemical class 0.000 abstract description 10
- 238000006555 catalytic reaction Methods 0.000 abstract description 6
- 239000005011 phenolic resin Substances 0.000 abstract description 5
- 239000007772 electrode material Substances 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 3
- 229920001568 phenolic resin Polymers 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 27
- 239000007787 solid Substances 0.000 description 17
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 12
- 238000001816 cooling Methods 0.000 description 8
- 238000009413 insulation Methods 0.000 description 8
- 239000004570 mortar (masonry) Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000010453 quartz Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000005303 weighing Methods 0.000 description 8
- 229960000935 dehydrated alcohol Drugs 0.000 description 7
- 239000000126 substance Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000002041 carbon nanotube Substances 0.000 description 4
- 229910021393 carbon nanotube Inorganic materials 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000003610 charcoal Substances 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 101100365087 Arabidopsis thaliana SCRA gene Proteins 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000007792 gaseous phase Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000002114 nanocomposite Substances 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000001467 acupuncture Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229960004756 ethanol Drugs 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000007770 graphite material Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Images
Landscapes
- Carbon And Carbon Compounds (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2007100382059A CN100506751C (zh) | 2007-03-19 | 2007-03-19 | 整体型纳米碳纤维复合多孔材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2007100382059A CN100506751C (zh) | 2007-03-19 | 2007-03-19 | 整体型纳米碳纤维复合多孔材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101070250A CN101070250A (zh) | 2007-11-14 |
CN100506751C true CN100506751C (zh) | 2009-07-01 |
Family
ID=38897689
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2007100382059A Expired - Fee Related CN100506751C (zh) | 2007-03-19 | 2007-03-19 | 整体型纳米碳纤维复合多孔材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100506751C (zh) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8951631B2 (en) | 2007-01-03 | 2015-02-10 | Applied Nanostructured Solutions, Llc | CNT-infused metal fiber materials and process therefor |
US8951632B2 (en) | 2007-01-03 | 2015-02-10 | Applied Nanostructured Solutions, Llc | CNT-infused carbon fiber materials and process therefor |
US9005755B2 (en) | 2007-01-03 | 2015-04-14 | Applied Nanostructured Solutions, Llc | CNS-infused carbon nanomaterials and process therefor |
CN101289329B (zh) * | 2008-05-26 | 2010-09-29 | 华东理工大学 | 一种块体碳纳米纤维复合材料的制备方法 |
CN101325825B (zh) * | 2008-06-26 | 2011-12-14 | 东港载友电热电器有限公司 | 纳米碳纤维发热体及其制造方法 |
CN101462075A (zh) * | 2009-01-13 | 2009-06-24 | 中国石化扬子石油化工有限公司 | 一种提高纳米碳纤维成型体耐磨性能的方法 |
WO2010141130A1 (en) | 2009-02-27 | 2010-12-09 | Lockheed Martin Corporation | Low temperature cnt growth using gas-preheat method |
US20100227134A1 (en) | 2009-03-03 | 2010-09-09 | Lockheed Martin Corporation | Method for the prevention of nanoparticle agglomeration at high temperatures |
CN101921174B (zh) * | 2009-06-10 | 2013-06-12 | 华东理工大学 | 一种氢解山梨醇制备乙二醇和1,2-丙二醇的方法 |
KR20120036890A (ko) | 2009-08-03 | 2012-04-18 | 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. | 복합재 섬유에 나노입자의 결합 |
BR112013005802A2 (pt) | 2010-09-14 | 2016-05-10 | Applied Nanostructured Sols | substratos de vidro com nanotubos de carbono crescidos sobre os mesmos e métodos para sua produção |
EP2619133A1 (en) | 2010-09-22 | 2013-07-31 | Applied NanoStructured Solutions, LLC | Carbon fiber substrates having carbon nanotubes grown thereon and processes for production thereof |
CN102531659A (zh) * | 2011-11-09 | 2012-07-04 | 西安航天复合材料研究所 | 一种c/c复合材料用碳纤维灰分的处理方法 |
CN103193495A (zh) * | 2013-03-01 | 2013-07-10 | 辽阳金谷碳纤维科技有限公司 | 拉晶炉用保温材料的生产方法 |
CN103233299A (zh) * | 2013-05-20 | 2013-08-07 | 大连交通大学 | 多孔中空碳纳米纤维及其制备方法和应用 |
CN103253652B (zh) * | 2013-05-22 | 2015-02-18 | 华东理工大学 | 一种泡沫炭/堇青石复合材料的制备方法 |
CN103342574A (zh) * | 2013-07-25 | 2013-10-09 | 华东理工大学 | 增强型块体纳米碳纤维/碳复合材料及其制备方法 |
CN112023880B (zh) * | 2020-08-17 | 2021-12-03 | 盐城工学院 | 一种氮掺杂活性炭纤维毡的制备方法及其应用 |
CN118877875A (zh) * | 2024-08-16 | 2024-11-01 | 南京航空航天大学 | 一种环境友好型的多孔碳材料及其制备方法 |
-
2007
- 2007-03-19 CN CNB2007100382059A patent/CN100506751C/zh not_active Expired - Fee Related
Non-Patent Citations (2)
Title |
---|
Fe催化PAN炭纤维原位生长纳米炭纤维. 朱东波.新型炭材料,第17卷第3期. 2002 * |
基体预处理对石墨毡上纳米碳纤维生长量的影响. 李亭等.工业催化,第13卷第增刊期. 2005 * |
Also Published As
Publication number | Publication date |
---|---|
CN101070250A (zh) | 2007-11-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100506751C (zh) | 整体型纳米碳纤维复合多孔材料及其制备方法 | |
Pan et al. | Advanced oxygen reduction electrocatalyst based on nitrogen-doped graphene derived from edible sugar and urea | |
Xu et al. | Catalytic behavior of carbon supported Ni–B, Co–B and Co–Ni–B in hydrogen generation by hydrolysis of KBH4 | |
Wang et al. | Co–VN encapsulated in bamboo-like N-doped carbon nanotubes for ultrahigh-stability of oxygen reduction reaction | |
Junke et al. | Characterization and analysis of carbon deposited during the dry reforming of methane over Ni/La2O3/Al2O3 catalysts | |
Fang et al. | Methane dry reforming over coke‐resistant mesoporous Ni‐Al2O3 catalysts prepared by evaporation‐induced self‐assembly method | |
Cho et al. | Synthesis of cobalt-impregnated carbon composite derived from a renewable resource: Characterization and catalytic performance evaluation | |
Tong et al. | Trace level Co–N doped graphite foams as high-performance self-standing electrocatalytic electrodes for hydrogen and oxygen evolution | |
JP6646317B2 (ja) | カーボンナノチューブ被覆触媒粒子 | |
CN103249482B (zh) | 用于氢气生产的碳催化剂、制备催化剂的方法、和采用催化剂生产氢气的方法 | |
Zhang et al. | Mesoporous carbon prepared from direct coal liquefaction residue for methane decomposition | |
Tian et al. | Synthesis of biomimetic monolithic biochar-based catalysts for catalytic decomposition of biomass pyrolysis tar | |
Zhang et al. | Nitrogen‐Decorated Porous Carbon Supported AgPd Nanoparticles for Boosting Hydrogen Generation from Formic Acid | |
Qi et al. | Synthesis of graphitic mesoporous carbons with high surface areas and their applications in direct methanol fuel cells | |
Li et al. | Radio-frequency thermal plasma-induced novel chainmail-like core-shell MoO2 as highly stable catalyst for converting syngas to higher alcohols | |
CN106283272B (zh) | 一种低碳烃催化裂解制备碳纤维和氢气的方法 | |
CN102600877A (zh) | 一种用于萘加氢制备四氢萘反应的高选择性催化剂及其制备方法 | |
Yang et al. | Aligned N-doped carbon nanotube bundles prepared via CVD using zeolite substrates | |
CN110538669B (zh) | 一种用于合成气制含氧化学品铜–钴金属碳化物催化剂及其制备方法 | |
Wang et al. | Preparation of bush-like Ru/NiO-Ni foam catalyst and its performance in hydrogen production from sodium borohydride alcoholysis | |
Yu et al. | A Facile Synthesis of C‐N Hollow Nanotubes as High Electroactivity Catalysts of Oxygen Reduction Reaction Derived from Dicyandiamide | |
Sun et al. | Synthesis of 3D N-doped graphene/carbon nanotube hybrids with encapsulated Ni NPs and their catalytic application in the hydrogenation of nitroarenes | |
Wang et al. | Chemical induced fragmentation of MOFs for highly efficient Ni-based hydrogen evolution catalysts | |
CN103395767A (zh) | 一种含硫碳材料的制备方法及其制备的含硫碳材料 | |
Wang et al. | Hydrogen production by thermocatalytic methane decomposition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Shanghai Yueke Composite Co., Ltd. Assignor: East China University of Science and Technology Contract fulfillment period: 2009.8.1 to 2015.7.31 Contract record no.: 2009310000209 Denomination of invention: Integrated nano carbon-fiber composite porous materila and preparing method Granted publication date: 20090701 License type: Exclusive license Record date: 20090910 |
|
LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.8.1 TO 2015.7.31; CHANGE OF CONTRACT Name of requester: SHANGHAI YUEKE COMPOUND MATERIALS CO., LTD. Effective date: 20090910 |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090701 Termination date: 20190319 |
|
CF01 | Termination of patent right due to non-payment of annual fee |