CN100496250C - Agricultural sterilizing and disinfecting composition, preparation method and application thereof - Google Patents
Agricultural sterilizing and disinfecting composition, preparation method and application thereof Download PDFInfo
- Publication number
- CN100496250C CN100496250C CNB2007101203893A CN200710120389A CN100496250C CN 100496250 C CN100496250 C CN 100496250C CN B2007101203893 A CNB2007101203893 A CN B2007101203893A CN 200710120389 A CN200710120389 A CN 200710120389A CN 100496250 C CN100496250 C CN 100496250C
- Authority
- CN
- China
- Prior art keywords
- sodium
- weight portion
- agricultural
- synergist
- agricultural disinfection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention relates to an agricultural sterilization combination, the preparation method and application of which. The agricultural sterilization combination comprises sodium dichloro isocyanurate, potassium dichloroisocyanurate and other active components, as well as addition agent, synergistic agent or combustion improver. The agricultural sterilization combination can significantly slow down the generation of drug resistance; while in reducing the dosage, the utilization efficiency can be improved and the use-cost can be reduced, thereby the invention has obvious economic benefits.
Description
[technical field]
The present invention relates to agricultural disinfection product technical field, more specifically, the present invention relates to agricultural disinfection composition, their preparation method and purposes.
[background technology]
Progress of modern technology and Agricultural Development, promoted improving constantly of living standards of the people, the medicament residue of food such as fruit, vegetables is required also more and more stricter, therefore by crop disease control provides efficiently, the bactericide of safety, low-residual is paid close attention to by people day by day.This demand researchs and develops in order to solve just in the present invention.
For example CN94105892.1 discloses a kind of disinfectant of high-efficiency broad spectrum, and it is formed by tpn, sodium dichloro cyanurate and trace element built.Trichoderma, Neurospora, green mold bacterium and living contaminants to edible mushroom all have better prevention and inhibitory action, are the Compositional type plant sterilization synergist of a kind of broad-spectrum high efficacy, low residual hazard.
In addition, CN97107698.7 discloses a kind of disinfactant for silkworm, and it is made up of sodium dichloro cyanurate, levamisol, CaO, β-fluorine agent, has the effect of wide spectrum, efficient, economic uniqueness.
CN00115919.4 discloses a kind of disinfectant that is used for culture fishery, the product of being made up of sodium dichloro cyanurate, sodium bromide, sodium sulphate, sodium carboxymethylcellulose.This product both can effectively be killed algae, virus, bacterium and protozoa, was easily decomposed no residual hazard again by the enzyme of multiple biology.
CN200310111679.3 discloses a kind of disinfectant that is used for seed-soaking sterilization usefulness.This disinfectant is made up of sodium dichloro cyanurate and glauber salt.This product is efficient, broad-spectrum disinfectant, microorganisms such as capable of killing virus, fungi, gemma.
But these products all have some defectives, and practical effect can not satisfy actual needs, therefore all also need a kind of not only economic, safe but also environment amenable disinfectant in agricultural, livestock breeding, fishery etc.For this reason, the inventor has carried out big quantity research, obtains challenging result.
[summary of the invention]
[technical problem that will solve]
The purpose of this invention is to provide agricultural disinfection composition.
Another object of the present invention provides described agricultural disinfection preparation of compositions method.
Another object of the present invention provides the purposes of described agricultural disinfection composition.
[technical scheme]
The present invention is achieved through the following technical solutions.
A kind of agricultural disinfection composition is characterized in that it contains by the following component in weight portion:
A, one or more are selected from active component 1-90 part of sodium dichloro cyanurate, potassium dichloroisocyanurate, sym-closene, BCDMH, C5H6Br2N2O2, DBNPA (di-bromonitrilopropiona,ide);
B, auxiliary agent 2-50 part;
C, synergist 2-10 part;
D, stabilizing agent 10-80 part;
Preferably, composition of the present invention contains by the following component in weight portion:
A, one or more are selected from active component 10-60 part of sodium dichloro cyanurate, sym-closene, BCDMH, C5H6Br2N2O2, DBNPA;
B, auxiliary agent 6-30 part;
C, synergist 2-10 part;
D, stabilizing agent 20-60 part;
More preferably, composition of the present invention contains by the following component in weight portion:
A, one or more are selected from active component 10-60 part of sodium dichloro cyanurate, sym-closene, BCDMH, C5H6Br2N2O2, DBNPA;
B, auxiliary agent 6-20 part;
C, synergist 2-8 part;
D, stabilizing agent 40-60 part;
According to meaning of the present invention, described active component should be appreciated that it is the active ingredient of killing pathogenic bacteria.
Sodium dichloro cyanurate is a kind of extremely strong disinfectant, oxidant and chlorinating agent, is a kind of efficient, low toxicity, wide spectrum, disinfection sanitizer fast, can kill various bacteriums, fungi, brood cell, mould, comma bacillus effectively fast.Can be used for seed and soak, prevent fungal infection, also can be used for the sterilization treatment behind the bacterial infection of vegetative period, fruiting period of vegetables, fruit tree.
DCCK is the New-type wide-spectrum bactericide, efficient, nontoxic, noresidue, no pesticide resistance.The catabolite that DCCK is sprayed on the plant leaf blade has hypochlorous acid, carbonic acid gas, potassium ion, ammonium ion, hypochlorous acid is the sterilization active principle, acting on pathogen causes in its short time dead, potassium ion, ammonium ion are absorbed by plant leaf blade or fruit surface, directly strengthen photosynthesis, for plant provides nutrient component, promote fruit growth.DCCK has the better prevention effect to the disease that fungi, bacterium, virus etc. cause.
Described sodium dichloro cyanurate, potassium dichloroisocyanurate are by production and sales such as Tengzhou, Shandong silver Feng Huagong Co., Ltds.
Sym-closene is promoted in the world at present a kind of efficient, low toxicity, wide spectrum, disinfection sanitizer fast, and this product has the effect of algae removal, deodorizing, water purification, bleaching, and people and animals are had no harm, non-secondary pollution.
Described sym-closene is by production and sales such as Nanning chemical industry Co., Ltds.
BCDMH can constantly discharge active Br-ion and active Cl-ion by dissolving in water, form hypobromous acid and hypochlorous acid, and this hypobromous acid and hypochlorous acid have strong oxidizing property, the biology enzyme oxidation in the microbial body are reached the purpose of sterilization.In various dissimilar water bodys, use BCDMH all can obtain gratifying Disinfection Effect, but kill bacteria, fungi, germ, gemma and virus are environmentally friendly.
C5H6Br2N2O2 is a kind of efficient, safe disinfection sanitizer, has the effect of killing fungi, bacterium and virus strongly, also is crucial bromating agent.Its good stability, brominated amount height, reactivity are strong, are widely used in industries such as medicine, chemical industry and agricultural.
Described BCDMH, C5H6Br2N2O2 are the products by production and sales such as Hebei Yaguang Fine Chemical Co., Ltd..
DBNPA (di-bromonitrilopropiona,ide) is white or light yellow crystalline powder.It can penetrate the cells of microorganisms film rapidly, and act on cell protein as the biocide of broad-spectrum high efficacy, makes protein denaturation, thereby causes cell death.This product has good stripping performance, non-foam during use, and fluid product can be arbitrarily than dissolving each other low toxicity with water.
Described DBNPA is the LG-DOW imported product.
When described sodium dichloro cyanurate, potassium dichloroisocyanurate, sym-closene, BCDMH, C5H6Br2N2O2, DBNPA are commercially available products, need not to handle and just can use.
Except the above-mentioned active component of listing, the present invention can also use and can realize the object of the invention normally used other active component in agricultural, livestock breeding, for example: bromine symclosene, tetrachloroglycine urea etc.
Except using described active component, also use other component in the present invention, comprising auxiliary agent, synergist, stabilizing agent.
According to meaning of the present invention, described auxiliary agent should be appreciated that it is the solvability that increases active ingredient, strengthens the stability of storage, transportation etc.
According to an embodiment of the invention, the auxiliary agent in the described agricultural disinfection composition is one or more auxiliary agents that are selected from sodium bicarbonate, sodium carbonate, sodium phosphate trimer, potash, boric acid, citric acid.
Preferably, described auxiliary agent is selected from sodium bicarbonate, sodium carbonate, sodium phosphate trimer, potash or boric acid.
More preferably, described auxiliary agent is selected from sodium bicarbonate, sodium carbonate or sodium phosphate trimer.
Except the above-mentioned auxiliary agent of listing, the present invention can also use and can realize the object of the invention normally used other auxiliary agent in agricultural, livestock breeding, for example: carboxymethyl cellulose, cyclodextrin, sodium bromide, sodium chloride, sodium hydrogensulfite etc.
These auxiliary agents that use among the present invention all are product solds on market.
According to meaning of the present invention, described synergist should be appreciated that and is: reduce surface tension, increase drug solubility, improve the result of use of active ingredient, reduce the usage amount of active ingredient.
According to an embodiment of the invention, the synergist in the described agricultural disinfection composition is that one or more are selected from lauryl sodium sulfate, neopelex, azone
Or the synergist of copper sulphate.
Preferably, described synergist is one or more synergist that are selected from lauryl sodium sulfate, neopelex and/or copper sulphate.
More preferably, described synergist is one or more synergist that are selected from lauryl sodium sulfate, copper sulphate.
Except the above-mentioned synergist of listing, the present invention can also use and can realize the object of the invention normally used other synergist, for example sodium bromide, sodium chloride, niter cake, organosilicon auxiliary agent etc. in agricultural, livestock breeding.
These synergist that use among the present invention all are product solds on market.
According to an embodiment of the invention, the stabilizing agent in the described agricultural disinfection composition is one or more stabilizing agents that are selected from glauber salt, magnesium sulfate, magnesium chloride, zinc sulphate, sodium sulphate, potassium sulphate, copper sulphate.
Preferably, described stabilizing agent is one or more stabilizing agents that are selected from glauber salt, magnesium sulfate, zinc sulphate, potassium sulphate.
More preferably, described stabilizing agent is one or more stabilizing agents that are selected from glauber salt, magnesium sulfate.
Except the above-mentioned stabilizing agent of listing, the present invention can also use and can realize the object of the invention normally used other stabilizing agent, for example diatomite, concavo-convex rod, zeolite powder etc. in agricultural, livestock breeding.
These stabilizing agents that use among the present invention all are product solds on market.
According to an embodiment of the invention, described agricultural disinfection composition also contains 1-10 part combustion adjuvant by weight, and described combustion adjuvant is one or more combustion adjuvants that are selected from rosin, white sugar, sulphur, paraffin.Said composition can be made fumicants and use.
Preferably, described combustion adjuvant is one or more combustion adjuvants that are selected from rosin, white sugar, sulphur,
More preferably, described combustion adjuvant is one or more combustion adjuvants that are selected from rosin, white sugar.
Except the above-mentioned combustion adjuvant of listing, the present invention can also use and can realize the object of the invention normally used other combustion adjuvant in agricultural, livestock breeding, for example: wood chip, nitrate etc.
These combustion adjuvants that use among the present invention all are product solds on market.
A kind of agricultural disinfection preparation method of composition is characterized in that this method comprises the steps:
At first, take by weighing one or more active components among sodium dichloro cyanurate, potassium dichloroisocyanurate, sym-closene, BCDMH, C5H6Br2N2O2, the DBNPA of being selected from of 1-90 weight portion, evenly obtain a kind of mixture through mechanical mixture;
Then, take by weighing respectively described auxiliary agent, the 2-10 weight portion of 2-50 weight portion described synergist, 10-80 weight portion stabilizing agent or with the combustion adjuvant of 1-10 weight portion, evenly obtain another kind of mixture through mechanical mixture;
At last, foregoing two kinds of mixtures are carried out mechanical agitation mix, obtain described agricultural disinfection composition.
The mechanical mixing equipment that uses in this method is the equipment that those skilled in the art know, for example two dimensional motion mixer, the efficient mixer of V-type, cone-type mixer, trough-type mixture machine etc.
The agricultural disinfection composition of the present invention can be made various preparations, for example pulvis, wetting powder, granule, tablet etc.The preparation method of these preparations is the method that those skilled in the art know.
These preparations can be used for spraying, soak seed, dress seed, dust, water and application process such as spill, fumigate.
The invention still further relates to that described agricultural disinfection composition is withered at control fruit tree, cotton, paddy rice, wheat and vegetables anthracnose, downy mildew, powdery mildew, rust, fusarium wilt, damping off, striped leaf, the purposes in the rice blast, powdery mildew.
In addition, the invention still further relates to the purposes of described agricultural disinfection composition in the sterilization of livestock and poultry house.
In addition, the invention still further relates to the purposes of described agricultural disinfection composition in booth vegetable, livestock and poultry house, mushroom inoculation, plantation fumigation.
[beneficial effect]
The present invention is on the basis of original single sodium dichloro cyanurate active component, compound one or more efficient or disinfecting active components, and auxiliary agent, synergist etc. have been added, slowed down drug-fast generation significantly, when reducing dosage, improve result of use, reduced use cost, on agricultural, had very significantly economic benefit.
[embodiment]
Embodiment 1 agricultural disinfection preparation of compositions
At first, take by weighing 20 weight portion sodium dichloro cyanurates and 15 weight portion BCDMH, use the two dimensional motion mixer, mix obtaining a kind of uniform mixture by mechanical agitation;
Then, take by weighing 20 weight portion sodium bicarbonates, 6 weight portion lauryl sodium sulfate, 50 weight portion glauber salt respectively, use cone-type mixer, mix obtaining a kind of uniform mixture by mechanical agitation;
At last, foregoing two kinds of mixtures are carried out mechanical agitation mix, obtain described agricultural disinfection composition.
According to test method common in the technical field of pesticide, use this product according to routine dose, control vegetables downy mildew, the efficient of powdery mildew can reach more than 87%.
Embodiment 2 agricultural disinfection preparation of compositions
At first, take by weighing 50 weight portion sodium dichloro cyanurates and 10 weight portion BCDMH, use the efficient mixer of V-type, mix obtaining a kind of uniform mixture by mechanical agitation;
Then, take by weighing 30 weight portion sodium carbonate, 6 weight portion lauryl sodium sulfate, 40 weight portion glauber salt respectively, use trough-type mixture machine to mix and obtain a kind of uniform mixture by mechanical agitation;
At last, foregoing two kinds of mixtures are carried out mechanical agitation mix, obtain described agricultural disinfection composition.
According to test method common in the technical field of pesticide, use this product according to routine dose, efficient can the reaching more than 86% of control oranges and tangerines rot.
Embodiment 3 agricultural disinfection preparation of compositions
At first, take by weighing 40 weight portion sodium dichloro cyanurates and 15 weight portion C5H6Br2N2O2s, use trough-type mixture machine, mix obtaining a kind of uniform mixture by mechanical agitation;
Then, take by weighing 30 weight portion sodium carbonate, 6 weight portion lauryl sodium sulfate, 40 weight portion glauber salt respectively, use the two dimensional motion mixer, mix obtaining a kind of uniform mixture by mechanical agitation;
At last, foregoing two kinds of mixtures are carried out mechanical agitation mix, obtain described agricultural disinfection composition.
According to test method common in the technical field of pesticide, use this product according to routine dose, control rice blast, the efficient of cotton wilt can reach more than 86%.
Embodiment 4 agricultural disinfection preparation of compositions
At first, take by weighing 20 weight portion potassium dichloroisocyanurates and 20 weight portion C5H6Br2N2O2s, use the efficient mixer of V-type, mix obtaining a kind of uniform mixture by mechanical agitation;
Then, take by weighing 15 weight portion sodium phosphate trimers, 6 weight portion neopelexes, 20 weight portion sodium chloride and 20 weight portion glauber salt respectively, use the two dimensional motion mixer, mix obtaining a kind of uniform mixture by mechanical agitation;
At last, foregoing two kinds of mixtures are carried out mechanical agitation mix, obtain described agricultural disinfection composition.
According to test method common in the technical field of pesticide, use this product according to routine dose, efficient can the reaching more than 88% of the fusarium wilt of control cotton, the rust of wheat etc.
Embodiment 5 agricultural disinfection preparation of compositions
At first, take by weighing 10 weight portion potassium dichloroisocyanurates, 40 weight portion sym-closenes and 10 weight portion C5H6Br2N2O2s, use trough-type mixture machine, mix obtaining a kind of uniform mixture by mechanical agitation;
Then, take by weighing 40 weight portion sodium phosphate trimers, 6 weight portion neopelexes, 25 weight portion magnesium sulfate respectively, use trough-type mixture machine, mix obtaining a kind of uniform mixture by mechanical agitation;
At last, foregoing two kinds of mixtures are carried out mechanical agitation mix, obtain described agricultural disinfection composition.
According to test method common in the technical field of pesticide, use this product according to routine dose, control mushroom green mold bacterium, the efficient of Trichoderma can reach more than 95%.
Embodiment 6 agricultural disinfection preparation of compositions
At first, take by weighing 10 weight portion potassium dichloroisocyanurates, 40 weight portion sym-closenes and 10 weight portion DBNPA, use the two dimensional motion mixer, mix obtaining a kind of uniform mixture by mechanical agitation;
Then, take by weighing 20 weight portion sodium bicarbonates, 8 weight portion copper sulphate, 5 weight portion neopelexes, 25 weight portion magnesium chlorides respectively, use the two dimensional motion mixer, mix obtaining a kind of uniform mixture by mechanical agitation;
At last, foregoing two kinds of mixtures are carried out mechanical agitation mix, obtain described agricultural disinfection composition.
According to test method common in the technical field of pesticide, use this product according to routine dose, rot, the efficient of anthracnose of control fruit tree can reach more than 95%.
Embodiment 7 agricultural disinfection preparation of compositions
At first, take by weighing 10 weight portion potassium dichloroisocyanurates, 30 weight portion sym-closenes and 10 weight portion DBNPA, use the two dimensional motion mixer, mix obtaining a kind of uniform mixture by mechanical agitation;
Then, take by weighing 5 weight portion potash, 6 weight portion copper sulphate, 25 weight portion glauber salt and 6 weight portion sulphur, 10 weight portion white sugar respectively, use the two dimensional motion mixer, mix obtaining a kind of uniform mixture by mechanical agitation;
At last, foregoing two kinds of mixtures are carried out mechanical agitation mix, obtain described agricultural disinfection composition.
According to test method common in the technical field of pesticide, use this product according to routine dose, efficient can the reaching more than 98% of mushroom transfer room sterilization.
Embodiment 8 agricultural disinfection preparation of compositions
At first, take by weighing 60 weight portion sodium dichloro cyanurates;
Then, take by weighing 10 weight portion sodium carbonate, 6 weight portion copper sulphate, 25 weight portion zinc sulphate and 6 weight portion paraffin, 10 weight portion sulphur respectively, use trough-type mixture machine, mix obtaining a kind of uniform mixture by mechanical agitation;
At last, foregoing sodium dichloro cyanurate is carried out mechanical agitation with a kind of mixture in back mix, obtain described agricultural disinfection composition.
Adopt and the described method of embodiment 1-7, according to test method common in the technical field of pesticide, according to the product that routine dose uses present embodiment to prepare, downy mildew, the efficient of powdery mildew of control vegetables can reach to 62%; The efficient of rot of control oranges and tangerines reaches 66%; Control rice blast, the efficient of cotton wilt reach 61%; The efficient of the fusarium wilt of control cotton, the rust of wheat etc. reaches 78%; Control mushroom green mold bacterium, the efficient of Trichoderma reach 82%; Rot, the efficient of anthracnose of control fruit tree reach 85%; The efficient of transfer room sterilization that be used to pester reaches 88%.
Claims (7)
1, a kind of agricultural disinfection composition is characterized in that it contains following component in weight portion:
A, sodium dichloro cyanurate, sym-closene and be selected from C5H6Br2N2O2 and DBNPA in active component 1-90 part of a kind of composition;
B, auxiliary agent 2-50 part;
C, synergist 2-10 part;
D, stabilizing agent 10-80 part;
Wherein auxiliary agent is one or more auxiliary agents that are selected from sodium bicarbonate, sodium carbonate, sodium phosphate trimer, potash, boric acid and citric acid; Synergist is one or more synergist that are selected from lauryl sodium sulfate, neopelex, azone and copper sulphate; Stabilizing agent is one or more stabilizing agents that are selected from glauber salt, magnesium sulfate, magnesium chloride, zinc sulphate, sodium sulphate and potassium sulphate.
2, agricultural disinfection composition according to claim 1 is characterized in that
A, sodium dichloro cyanurate, sym-closene and be selected from C5H6Br2N2O2 and DBNPA in active component 10-60 part of a kind of composition;
B, auxiliary agent 6-30 part;
C, synergist 2-10 part;
D, stabilizing agent 20-60 part.
3, agricultural disinfection preparation of compositions method according to claim 1 and 2 is characterized in that this method comprises the steps:
At first, take by weighing active component, evenly obtain a kind of mixture through mechanical mixture according to described umber;
Then, take by weighing described auxiliary agent, synergist and stabilizing agent respectively, evenly obtain another kind of mixture through mechanical mixture according to umber;
At last, foregoing two kinds of mixtures are carried out mechanical agitation mix, obtain described agricultural disinfection composition.
4, the purposes in agricultural disinfection composition according to claim 1 and 2, rice blast withered or the powdery mildew at control fruit tree, cotton, paddy rice, wheat and vegetables anthracnose, downy mildew, powdery mildew, rust, fusarium wilt, damping off, striped leaf.
5, the purposes of agricultural disinfection composition according to claim 1 and 2 in the sterilization of livestock and poultry house.
6, agricultural disinfection composition according to claim 1 and 2 is characterized in that it also contains in weight portion 1-10 part combustion adjuvant, and described combustion adjuvant is one or more combustion adjuvants that are selected from rosin, white sugar, sulphur and paraffin.
7, the purposes of agricultural disinfection composition according to claim 6 in booth vegetable, livestock and poultry house, mushroom inoculation or plantation fumigation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007101203893A CN100496250C (en) | 2007-08-17 | 2007-08-17 | Agricultural sterilizing and disinfecting composition, preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007101203893A CN100496250C (en) | 2007-08-17 | 2007-08-17 | Agricultural sterilizing and disinfecting composition, preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101103728A CN101103728A (en) | 2008-01-16 |
| CN100496250C true CN100496250C (en) | 2009-06-10 |
Family
ID=38997973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007101203893A Active CN100496250C (en) | 2007-08-17 | 2007-08-17 | Agricultural sterilizing and disinfecting composition, preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100496250C (en) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2011000621A (en) * | 2008-07-15 | 2011-02-25 | Dow Global Technologies Inc | Biocidal composition and method. |
| CN101336630B (en) * | 2008-08-12 | 2010-12-15 | 闫现广 | Fumigant for silkworm |
| CN101796948B (en) * | 2010-03-16 | 2013-01-16 | 成都奇锐医疗器械用品有限公司 | Smoke type disinfectant, preparation method and application thereof |
| US8518941B2 (en) | 2010-08-19 | 2013-08-27 | American Sterilizer Company | Extreme temperature aqueous decontamination composition |
| CN102001881A (en) * | 2010-10-09 | 2011-04-06 | 徐坤 | Preparation for preventing and curing ginger bacterial wilt |
| CN102461513A (en) * | 2010-11-17 | 2012-05-23 | 天津百胜化工有限公司 | Preparation and method for controlling plant pathogenic nematodes |
| CN102197805B (en) * | 2011-04-01 | 2013-08-28 | 秦震毅 | High-concentration high-stability dibromohydantoin disinfectant |
| CN102197824B (en) * | 2011-04-08 | 2014-03-05 | 安徽省黄淮兽药有限公司 | Chlorine dioxide disinfector and preparation method thereof |
| CN102246751A (en) * | 2011-05-18 | 2011-11-23 | 上海未来企业有限公司 | Sterilizing synergistic agent for oxidizing biocide |
| CN102511485A (en) * | 2011-12-23 | 2012-06-27 | 上海隆犇卫生用品有限公司 | Manufacturing method of 1,3-dibromo-5,5-dimethylhydantoin disinfectant |
| CN103891727A (en) * | 2012-12-25 | 2014-07-02 | 南京莱因医药科技有限公司 | Preparation method of stable compound halogen organic disinfectant |
| CN103007768B (en) * | 2012-12-31 | 2014-11-12 | 辽宁莱特莱德环境工程有限公司 | Composite antisludging agent of reverse osmosis/nanofiltration system |
| CN103875677A (en) * | 2014-04-14 | 2014-06-25 | 宋巍 | Water-soluble and smoking dual-use disinfectant |
| CN105028475A (en) * | 2015-06-07 | 2015-11-11 | 王新军 | Pesticide composition for treating yellowing of oyster mushroom |
| CN105028418A (en) * | 2015-08-08 | 2015-11-11 | 江苏神涛环保科技有限公司 | Chemical fiber oil sterilization preservative and preparation method thereof |
| CN104973986A (en) * | 2015-08-11 | 2015-10-14 | 刘彬 | Production method of microelement liquid water-soluble fertilizer capable of preventing greenhouse moss |
| CN104973987A (en) * | 2015-08-11 | 2015-10-14 | 刘彬 | Production method of humic acid-containing water-soluble fertilizer capable of preventing greenhouse moss |
| CN106172437B (en) * | 2016-07-07 | 2018-06-19 | 江苏辉丰农化股份有限公司 | A kind of microbicide compositions |
| CN107242238B (en) * | 2016-12-12 | 2020-11-10 | 中国农业科学院棉花研究所 | Application of isocyanuric acid in preventing and treating corn top rot |
| CN108477293B (en) * | 2018-03-30 | 2021-11-05 | 山东省农药检定所 | Garlic sprout fresh-keeping smoke agent |
| CN109511587B (en) * | 2018-11-01 | 2021-03-30 | 浙江海洋大学 | Disinfectant for cage-incubated pseudorasbora parva |
| CN110122496B (en) * | 2019-06-19 | 2020-10-13 | 中国农业科学院植物保护研究所 | Pharmaceutical composition containing sodium dichloroisocyanurate and oxine-copper and application thereof |
| CN110800738A (en) * | 2019-11-11 | 2020-02-18 | 福州科理技术开发有限公司 | Deodorizing and pest killing spray liquid for kitchen garbage and its prepn |
| WO2021162736A1 (en) * | 2020-02-14 | 2021-08-19 | Collidion, Inc. | Compositions, kits, methods and uses for cleaning, disinfecting, sterilizing and/or treating |
| CN111226982A (en) * | 2020-02-17 | 2020-06-05 | 四川水王子环境科技有限公司 | Sewage disinfection powder and preparation method and use method thereof |
| CN111657294A (en) * | 2020-07-15 | 2020-09-15 | 利民化学有限责任公司 | Thiram and sodium dichloroisocyanurate compound sterilization composition and application thereof |
| CN112450217A (en) * | 2020-12-18 | 2021-03-09 | 湖南幻影三陆零科技有限公司 | Disinfectant and disinfectant composition containing same |
| CN112741094A (en) * | 2020-12-30 | 2021-05-04 | 上海洗霸科技股份有限公司 | Solid chlorine disinfectant and preparation method and application thereof |
| CN114766509A (en) * | 2022-05-16 | 2022-07-22 | 深圳市玛斯特威科技开发有限公司 | Aviation disinfectant and preparation method thereof |
-
2007
- 2007-08-17 CN CNB2007101203893A patent/CN100496250C/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN101103728A (en) | 2008-01-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100496250C (en) | Agricultural sterilizing and disinfecting composition, preparation method and application thereof | |
| EP1592301B1 (en) | Crop protecting and improving lignosulfonate compositions | |
| CN103430797B (en) | A kind of method of preventing and treating cucumber fungal disease | |
| CN102172240A (en) | Bactericidal composition containing benziothiazolinone and methoxyl acrylic ester type bactericides | |
| CN101057586A (en) | Germicide for agricultural and forest crop except legumes | |
| KR101073887B1 (en) | Sulfur fermentain liquid fertilizer and method for producing the same, plant disease and method for producing the same | |
| CN102318625A (en) | Preparation of leather composite bactericidal mould inhibitor | |
| CN102239853A (en) | Thifluzamide-containing composite bacteriacide | |
| CN102835403B (en) | Bactericidal composition, and preparation and application thereof | |
| CN102461514A (en) | Bactericidal composition containing chlorothalonil and tebuconazole as well as application thereof | |
| CN101632371A (en) | Compound sterilization composition | |
| Silimela et al. | Evaluation of pre-harvest Bacillus licheniformis sprays to control mango fruit diseases | |
| JP2002180047A (en) | Soil-improving agent and method for producing the same | |
| CN109792991A (en) | A kind of fungicide containing epsilon-polylysine and amino-oligosaccharide | |
| CN101755836B (en) | Bactericidal composite taking fluazinam as main ingredient | |
| CN103210926A (en) | Bactericide for preventing and treating sclerotinia rot of colza and preparation method thereof | |
| CN1114904A (en) | Disinfecting germicide | |
| CN102318634A (en) | Preparation method of compound leather bactericidal and mildew-proof agent | |
| CN103988847B (en) | Bactericidal composition containing chitosan oligosaccharide and dithiocyano-methane | |
| CN1327769C (en) | Bactericide composition containing prochloraz manganese salt and copper acetate for crops | |
| CN1270608C (en) | Trichloro-isocyanuric acid wettable powder | |
| CN105475356B (en) | A kind of composition pesticide containing Propineb and prochloraz-manganese chloride complex | |
| CN108617666A (en) | A kind of fungicide and its preparation method and application containing epsilon-polylysine and epoxiconazole | |
| CN102696647A (en) | Sterilizing composite containing pyraclostrobin and pyrimethanil and application | |
| CN107810956B (en) | Bactericidal composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |