CN100478416C - Water-base grinding fluid for on-line electrolytic grinding - Google Patents

Water-base grinding fluid for on-line electrolytic grinding Download PDF

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Publication number
CN100478416C
CN100478416C CNB2007100568109A CN200710056810A CN100478416C CN 100478416 C CN100478416 C CN 100478416C CN B2007100568109 A CNB2007100568109 A CN B2007100568109A CN 200710056810 A CN200710056810 A CN 200710056810A CN 100478416 C CN100478416 C CN 100478416C
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China
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water
grinding
sodium
dressing
grinding fluid
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Expired - Fee Related
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CNB2007100568109A
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CN101020810A (en
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任成祖
武震华
刘春明
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Tianjin University
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Tianjin University
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Abstract

The present invention discloses one kind of water-base grinding fluid for on-line electrolytic grinding, and belongs to the field of precise grinding fluid technology. The water-base grinding fluid consists of sodium molybdate 0.2-0.6 wt%, sodium carbonate 0.1-0.5 wt%, sodium silicate 0.3-0.8 wt%, borax 0.1-0.4 wt%, sodium benzoate 0.2-1.2 wt%, sodium chloride 0.01-0.1 wt%, water for the rest and boric acid ester in 0.7-1.2 vol% of water. The present invention has the advantages of environment friendship, low cost, high use performance and simple preparation process.

Description

The water-based milling liquid that a kind of online electrolytic dressing grinding is used
Technical field
The present invention relates to the water-based milling liquid that a kind of online electrolytic dressing grinding is used, belong to the grinding fluid technology that mechanical precision grinding machining is used.
Background technology
Online electrolytic dressing (Electrolytic In-process Dressing is called for short ELID) grinding technique just has been subjected to paying attention to and application in accurate and ultraprecise manufacture field with its significant advantage from the eighties appearance in last century.ELID grinding system essentially consist comprises: ELID special purpose grinder, metal matrix micro mist emery wheel, high frequency pulse power supply and ELID electrolysis special grinding fluid.Raising along with mechanical processing technique and electronic technology, grinding machine, emery wheel and the power supply of present stage production can be good at satisfying the requirement of ELID technology, and because the ELID technology to the particular requirement of grinding fluid, makes the technology of the special-purpose grinding fluid of ELID become the bottleneck of ELID technical development.
ELID grinding technique principle is: grinding process medium cast iron base grinding wheel is as anode, make negative electrode with truing electrode, in the gap of emery wheel outer round surface and electrode by the special-purpose grinding fluid of electrolysis ability is arranged, at the effect lower grinding wheel anode metal matrix of pulsed electrical energy constantly by electrolysis, and the abrasive particle in the emery wheel can not sustain damage, thereby plays the effect of emery wheel dressing.Yet online electrolysis is a kind of sex change dressing, promptly at the emery wheel metallic matrix by the electrolytic while, the electrochemical action by grinding fluid forms the passive film that can hold a large amount of abrasive particles that one deck has certain elasticity, certain thickness, certain intensity at wheel face.What play material removal effect in the ELID grinding process is the abrasive particle that is dipped in the passive film, so the thickness of passive film, compactness and sticking power all have a significant impact its grinding quality and working (machining) efficiency.Passive film also will have formation speed faster in addition, remedies the requirement that passive film consumes thereby can satisfy in grinding process, to reach a dynamic balance state.The character of the generative process of wheel face passive film and generation passive film all depends on the performance of the special-purpose grinding fluid of ELID to a great extent.
The article of the special-purpose grinding fluid of research ELID seldom, abroad have than proven technique, but because its technical know-how was not all delivered, the mechanism of domestic research ELID grinding has all carried out corresponding research to its electrolytic grinding liquid basically, wherein Harbin Institute of Technology's research early, the relevant series product of oneself have been arranged now, comprised coventional type, HDMY-10, HDMY-20 etc.Other research institutions have: Changchun Institute of Optics and Fine Mechanics, Beijing University of Technology, Hunan University, Dalian University of Technology etc.
Present stage, commercially available online electrolytic grinding liquid was difficult to control in the passivation film thickness of wheel face generation, can not well satisfy the requirement of ELID grinding under the different condition, and the passive film insulating power of generation is relatively poor, makes wheel life reduce.All contain NaNO in most of grinding fluids 2Or chromate ion, along with to the improving constantly of environmental protection requirement, these grinding fluids will be no longer suitable.
Summary of the invention
The water-based milling liquid that the object of the present invention is to provide a kind of online electrolytic dressing grinding to use, this grinding fluid is environmentally friendly, and preparation cost is low, and use properties is good.
The present invention is realized that by the following technical programs the water-based milling liquid that a kind of online electrolytic dressing grinding is used is characterized in that, contains following component and mass percentage content thereof in quality is 100 parts water:
Sodium orthomolybdate: 0.2~0.6%; Yellow soda ash: 0.1~0.5%; Water glass: 0.3~0.8%; Borax: 0.1~0.4%; Sodium Benzoate: 0.2~1.2%; Sodium-chlor: 0.01~0.1%; And to contain volume percent with water be 0.7~1.2% boric acid ester.
Advantage of the present invention: the water-based milling liquid that provides has overcome in this grinding fluid of present stage and has contained Sodium Nitrite, and objectionable constituent such as chromate ion do not contain easy pollution and harmful material, can satisfy the environmental characteristics requirement; Can satisfy ELID grinding requirement under the various conditions, the thickness of the passive film that generates is adjustable in 10~120 mu m ranges, it is adjustable in 20~50min scope that the emery wheel dressing reaches balance time, and the passive film strong adhesion that generates, electrical insulating property good (equalizing current generally remains in the scope of 0.4~1.0A) has compactness and certain elasticity preferably; Its compound method is simple, and cost is low, and rust-preventing characteristic, cooling property and lubricity are good, and SOLUTION PROPERTIES is stable.
Embodiment:
Embodiment 1:
Measure the 10000ml deionized water with beaker, pour in the Glass Containers, heating makes its temperature remain on 29 ℃~31 ℃, take by weighing Sodium orthomolybdate 25g, yellow soda ash 10g, water glass 50g, borax 15g, phenylformic acid successively and receive 30g and sodium-chlor 1.5g, under continuous condition of stirring, progressively be added to the water, stir until whole dissolvings, and then the boric acid ester of adding 100ml, mix and obtain the water-based milling liquid that online electrolytic dressing grinding is used.Use this grinding fluid that cast iron base diamond micro mist emery wheel is carried out dressing, the passivation film thickness that wheel face generates is about 10 μ m, and passivation film thickness is less, therefore is applicable to the adamantine ELID grinding than small grain size (≤5 microns); The dressing starting time is about 25min, and the formation speed of passive film is very fast; The dressing equalizing current is about 0.8A.According to The above results, this proportioning composition is suitable for the mirror grinding in superfinishing stage as can be known.
Embodiment 2:
Measure the 10000ml deionized water with beaker, pour in the Glass Containers, heating makes its temperature remain on 29 ℃~31 ℃, take by weighing Sodium orthomolybdate 30g successively, yellow soda ash 25g, water glass 45g, borax 10g, phenylformic acid is received 40g, and sodium-chlor 2g is under continuous condition of stirring, progressively be added to the water, stirring is until whole dissolvings, and then the boric acid ester of adding 90ml, mixes and obtains the water-based milling liquid that online electrolytic dressing grinding is used.Use this grinding fluid that cast iron base diamond micro mist emery wheel is carried out dressing, the passivation film thickness that wheel face generates is about 25 μ m; The dressing starting time is about 32min, and the formation speed of passive film is very fast; The dressing equalizing current is about 0.7A.
Embodiment 3:
Measure the 10000ml deionized water with beaker, pour in the Glass Containers, heating makes its temperature remain on 29 ℃~31 ℃, take by weighing Sodium orthomolybdate 40g successively, yellow soda ash 40g, water glass 35g, borax 20g, phenylformic acid is received 60g, and sodium-chlor 1.5g is under continuous condition of stirring, progressively be added to the water, stirring is until whole dissolvings, and then the boric acid ester of adding 80ml, mixes and obtains the water-based milling liquid that online electrolytic dressing grinding is used.Use this grinding fluid that cast iron base diamond micro mist emery wheel is carried out dressing, the passivation film thickness that wheel face generates is about 50 μ m; The dressing starting time is about 35min, and the formation speed of passive film is very fast; The dressing equalizing current is about 0.5A.
Embodiment 4:
Measure the 10000ml deionized water with beaker, pour in the Glass Containers, heating makes its temperature remain on 29 ℃~31 ℃, take by weighing Sodium orthomolybdate 45g successively, yellow soda ash 50g, water glass 30g, borax 30g, phenylformic acid is received 75g, and sodium-chlor 3g is under continuous condition of stirring, progressively be added to the water, stirring is until whole dissolvings, and then the boric acid ester of adding 80ml, mixes and obtains the water-based milling liquid that online electrolytic dressing grinding is used.Use this grinding fluid that cast iron base diamond micro mist emery wheel is carried out dressing, the passivation film thickness that wheel face generates is about 70 μ m; The dressing starting time is about 45min, and the formation speed of passive film is very fast; The dressing equalizing current is about 0.5A.
Embodiment 5:
Measure the 10000ml deionized water with beaker, pour in the Glass Containers, heating makes its temperature remain on 29 ℃~31 ℃, take by weighing Sodium orthomolybdate 55g successively, yellow soda ash 20g, water glass 40g, borax 25g, phenylformic acid is received 100g, and sodium-chlor 4g is under continuous condition of stirring, progressively be added to the water, stirring is until whole dissolvings, and then the boric acid ester of adding 70ml, mixes and obtains the water-based milling liquid that online electrolytic dressing grinding is used.Use this grinding fluid that cast iron base diamond micro mist emery wheel is carried out dressing, the passivation film thickness that wheel face generates is about 110 μ m; The dressing starting time is about 45min, and the formation speed of passive film is very fast; The dressing equalizing current is about 1.0A.

Claims (1)

1. the water-based milling liquid that online electrolytic dressing grinding is used is characterized in that, the quality that contains following component and each component thereof in quality is 100 parts deionized water with deionized water quality ratio is: Sodium orthomolybdate: 0.2~0.6%; Yellow soda ash: 0.1~0.5%; Water glass: 0.3~0.8%; Borax: 0.1~0.4%; Sodium Benzoate: 0.2~1.2%; Sodium-chlor: 0.01~0.1%, and to contain with the deionized water volume ratio be 0.7~1.2% boric acid ester.
CNB2007100568109A 2007-02-14 2007-02-14 Water-base grinding fluid for on-line electrolytic grinding Expired - Fee Related CN100478416C (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106591921B (en) * 2016-12-07 2018-09-21 湖南科技大学 A kind of ELID for copper base brazing grinding wheel is ground electrolyte
CN108796583B (en) * 2018-06-27 2019-10-29 大连理工大学 A kind of preparation method of the super-hydrophobic passivating film of Pure Iron Surface corrosion resistance

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1233808C (en) * 2004-04-06 2005-12-28 北京工业大学 Grinding fluid in use for superhard abrasive grinding wheel of metal binding agent electrolyzable online, and preparation method
CN1786131A (en) * 2005-12-21 2006-06-14 湖南大学 High speed on line electrolysis sharpening grinding liquid suitable for bronze binding agent ultra hard abrasive

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1233808C (en) * 2004-04-06 2005-12-28 北京工业大学 Grinding fluid in use for superhard abrasive grinding wheel of metal binding agent electrolyzable online, and preparation method
CN1786131A (en) * 2005-12-21 2006-06-14 湖南大学 High speed on line electrolysis sharpening grinding liquid suitable for bronze binding agent ultra hard abrasive

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ELID磨削专用磨削液的研究. 仇中君,张飞虎,谢大纲.工具技术,第34卷第8期. 2000
ELID磨削专用磨削液的研究. 仇中君,张飞虎,谢大纲.工具技术,第34卷第8期. 2000 *

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