CN100457257C - 催化剂用含氧化锆载体材料 - Google Patents
催化剂用含氧化锆载体材料 Download PDFInfo
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- CN100457257C CN100457257C CNB2004800372278A CN200480037227A CN100457257C CN 100457257 C CN100457257 C CN 100457257C CN B2004800372278 A CNB2004800372278 A CN B2004800372278A CN 200480037227 A CN200480037227 A CN 200480037227A CN 100457257 C CN100457257 C CN 100457257C
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- Prior art keywords
- catalyst
- carrier material
- palladium
- surface area
- gold
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 271
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 239000000463 material Substances 0.000 title claims abstract description 46
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 280
- 239000010931 gold Substances 0.000 claims abstract description 121
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 96
- 238000000034 method Methods 0.000 claims abstract description 92
- 229910052737 gold Inorganic materials 0.000 claims abstract description 51
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 50
- 230000009467 reduction Effects 0.000 claims abstract description 45
- 239000010948 rhodium Substances 0.000 claims abstract description 45
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 38
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 claims abstract description 24
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 17
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 15
- 239000012876 carrier material Substances 0.000 claims description 172
- 239000002243 precursor Substances 0.000 claims description 71
- 238000007598 dipping method Methods 0.000 claims description 63
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 54
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 50
- 239000007789 gas Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 23
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
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- 235000011056 potassium acetate Nutrition 0.000 claims description 16
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 13
- 238000005470 impregnation Methods 0.000 claims description 9
- 239000012696 Pd precursors Substances 0.000 claims description 7
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
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- PZKNFJIOIKQCPA-UHFFFAOYSA-N oxalic acid palladium Chemical compound [Pd].OC(=O)C(O)=O PZKNFJIOIKQCPA-UHFFFAOYSA-N 0.000 claims description 2
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- KTEDZFORYFITAF-UHFFFAOYSA-K rhodium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Rh+3] KTEDZFORYFITAF-UHFFFAOYSA-K 0.000 description 12
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 11
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical group [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 5
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- 238000006424 Flood reaction Methods 0.000 description 4
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- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 3
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- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
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- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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- B01J29/00—Catalysts comprising molecular sieves
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- C—CHEMISTRY; METALLURGY
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- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J35/399—Distribution of the active metal ingredient homogeneously throughout the support particle
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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- B01J35/613—10-100 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J37/16—Reducing
Landscapes
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- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
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| US53148603P | 2003-12-19 | 2003-12-19 | |
| US60/531,486 | 2003-12-19 |
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| CN1894035A CN1894035A (zh) | 2007-01-10 |
| CN100457257C true CN100457257C (zh) | 2009-02-04 |
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| EP (1) | EP1694436A1 (pt) |
| JP (1) | JP4772695B2 (pt) |
| KR (1) | KR100886048B1 (pt) |
| CN (1) | CN100457257C (pt) |
| AU (1) | AU2004305515C1 (pt) |
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| UA (1) | UA96563C2 (pt) |
| WO (1) | WO2005061107A1 (pt) |
| ZA (1) | ZA200604362B (pt) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8168562B2 (en) | 2006-02-02 | 2012-05-01 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalysts |
| DE102007025358A1 (de) * | 2007-05-31 | 2009-01-08 | Süd-Chemie AG | Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators |
| DE102007025362A1 (de) | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025443A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025442B4 (de) | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
| DE102007025223A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025356A1 (de) * | 2007-05-31 | 2009-01-08 | Süd-Chemie AG | Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
| DE102007025444A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007043446B4 (de) | 2007-09-12 | 2013-08-22 | Süd-Chemie Ip Gmbh & Co. Kg | Katalysatorträger mit erhöhter Wärmeleitfähigkeit |
| DE102007043447B4 (de) | 2007-09-12 | 2014-02-13 | Süd-Chemie Ip Gmbh & Co. Kg | Katalysatorträger mit erhöhter thermischer Leitfähigkeit |
| DE102008058971A1 (de) * | 2008-11-25 | 2010-07-15 | Süd-Chemie AG | Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung |
| DE202008017277U1 (de) * | 2008-11-30 | 2009-04-30 | Süd-Chemie AG | Katalysatorträger |
| DE102008059340A1 (de) | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Katalysatorträger, Verfahren zu seiner Herstellung sowie dessen Verwendung |
| DE102008059342A1 (de) | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung |
| DE102010026462A1 (de) * | 2010-07-08 | 2012-01-12 | Süd-Chemie AG | Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
| CN102153189A (zh) * | 2010-12-16 | 2011-08-17 | 哈尔滨工业大学 | 浮石催化臭氧化去除水中有机物的方法 |
| DE102012008714A1 (de) * | 2012-05-03 | 2013-11-07 | Clariant Produkte (Deutschland) Gmbh | Vorimprägnierung von Schalenkatalysatoren mit einem Acetat |
| CN106215561B (zh) * | 2016-08-31 | 2018-04-20 | 苏州贝捷环保设备有限公司 | 一种燃煤烟气处理方法 |
| CN107096532B (zh) * | 2017-05-16 | 2019-12-10 | 嘉兴学院 | 一种Au-ZrO2催化剂及其应用 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5808136A (en) * | 1995-01-23 | 1998-09-15 | Degussa Aktiengesellschaft | Catalyst, method of its production and its use for the production of vinyl acetate monomer |
| JP2000093797A (ja) * | 1998-09-24 | 2000-04-04 | Degussa Huels Ag | ビニルモノマ―の製造用担持触媒、その製造方法及びその使用 |
| US6057260A (en) * | 1997-12-12 | 2000-05-02 | Celanese International Corporation | Vinyl acetate catalyst comprising palladium, gold, copper and any of certain fourth metals |
| US6358882B1 (en) * | 1998-12-08 | 2002-03-19 | The Standard Oil Company | Fluid bed vinyl acetate catalyst |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6015769A (en) * | 1998-06-02 | 2000-01-18 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate |
| DE10030039A1 (de) * | 2000-06-17 | 2002-01-10 | Celanese Chem Europe Gmbh | Katalysator zur Herstellung von Vinylacetat und Verfahren zur Herstellung des Katalysators |
-
2004
- 2004-11-19 NZ NZ547072A patent/NZ547072A/en not_active IP Right Cessation
- 2004-11-19 BR BRPI0417185-3A patent/BRPI0417185A/pt not_active Application Discontinuation
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2011
- 2011-07-26 RU RU2011131292/04A patent/RU2011131292A/ru not_active Application Discontinuation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5808136A (en) * | 1995-01-23 | 1998-09-15 | Degussa Aktiengesellschaft | Catalyst, method of its production and its use for the production of vinyl acetate monomer |
| US6057260A (en) * | 1997-12-12 | 2000-05-02 | Celanese International Corporation | Vinyl acetate catalyst comprising palladium, gold, copper and any of certain fourth metals |
| JP2000093797A (ja) * | 1998-09-24 | 2000-04-04 | Degussa Huels Ag | ビニルモノマ―の製造用担持触媒、その製造方法及びその使用 |
| US6358882B1 (en) * | 1998-12-08 | 2002-03-19 | The Standard Oil Company | Fluid bed vinyl acetate catalyst |
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| WO2005061107A1 (en) | 2005-07-07 |
| CA2547187C (en) | 2010-11-02 |
| CN1894035A (zh) | 2007-01-10 |
| AU2004305515B2 (en) | 2008-08-28 |
| CA2547187A1 (en) | 2005-07-07 |
| AU2004305515A1 (en) | 2005-07-07 |
| RU2006119185A (ru) | 2007-12-20 |
| RU2011131292A (ru) | 2013-02-10 |
| KR20060103514A (ko) | 2006-10-02 |
| NO20062531L (no) | 2006-07-03 |
| AU2004305515C1 (en) | 2009-06-25 |
| ZA200604362B (en) | 2007-11-28 |
| JP4772695B2 (ja) | 2011-09-14 |
| EP1694436A1 (en) | 2006-08-30 |
| KR100886048B1 (ko) | 2009-02-26 |
| PL215127B1 (pl) | 2013-10-31 |
| NZ547072A (en) | 2010-05-28 |
| UA96563C2 (ru) | 2011-11-25 |
| BRPI0417185A (pt) | 2007-03-06 |
| PL380021A1 (pl) | 2006-12-11 |
| JP2007514543A (ja) | 2007-06-07 |
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