CN100457257C - 催化剂用含氧化锆载体材料 - Google Patents

催化剂用含氧化锆载体材料 Download PDF

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Publication number
CN100457257C
CN100457257C CNB2004800372278A CN200480037227A CN100457257C CN 100457257 C CN100457257 C CN 100457257C CN B2004800372278 A CNB2004800372278 A CN B2004800372278A CN 200480037227 A CN200480037227 A CN 200480037227A CN 100457257 C CN100457257 C CN 100457257C
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CN
China
Prior art keywords
catalyst
carrier material
palladium
surface area
gold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB2004800372278A
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English (en)
Chinese (zh)
Other versions
CN1894035A (zh
Inventor
T·王
L·E·韦德
V·翁
D·M·洛
A·哈迈耶
J·韩
V·索科洛夫斯基
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Celanese International Corp
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Celanese International Corp
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Publication of CN1894035A publication Critical patent/CN1894035A/zh
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Expired - Fee Related legal-status Critical Current
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066Zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007Mixed salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • B01J37/18Reducing with gases containing free hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/04Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/397Egg shell like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/398Egg yolk like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/399Distribution of the active metal ingredient homogeneously throughout the support particle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/612Surface area less than 10 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB2004800372278A 2003-12-19 2004-11-19 催化剂用含氧化锆载体材料 Expired - Fee Related CN100457257C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53148603P 2003-12-19 2003-12-19
US60/531,486 2003-12-19

Publications (2)

Publication Number Publication Date
CN1894035A CN1894035A (zh) 2007-01-10
CN100457257C true CN100457257C (zh) 2009-02-04

Family

ID=34710229

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2004800372278A Expired - Fee Related CN100457257C (zh) 2003-12-19 2004-11-19 催化剂用含氧化锆载体材料

Country Status (14)

Country Link
EP (1) EP1694436A1 (pt)
JP (1) JP4772695B2 (pt)
KR (1) KR100886048B1 (pt)
CN (1) CN100457257C (pt)
AU (1) AU2004305515C1 (pt)
BR (1) BRPI0417185A (pt)
CA (1) CA2547187C (pt)
NO (1) NO20062531L (pt)
NZ (1) NZ547072A (pt)
PL (1) PL215127B1 (pt)
RU (2) RU2006119185A (pt)
UA (1) UA96563C2 (pt)
WO (1) WO2005061107A1 (pt)
ZA (1) ZA200604362B (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8168562B2 (en) 2006-02-02 2012-05-01 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalysts
DE102007025362A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025356A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025223A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025442B4 (de) * 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025358A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators
DE102007025444A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007043447B4 (de) 2007-09-12 2014-02-13 Süd-Chemie Ip Gmbh & Co. Kg Katalysatorträger mit erhöhter thermischer Leitfähigkeit
DE102007043446B4 (de) 2007-09-12 2013-08-22 Süd-Chemie Ip Gmbh & Co. Kg Katalysatorträger mit erhöhter Wärmeleitfähigkeit
DE102008058971A1 (de) * 2008-11-25 2010-07-15 Süd-Chemie AG Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung
DE102008059340A1 (de) 2008-11-30 2010-06-10 Süd-Chemie AG Katalysatorträger, Verfahren zu seiner Herstellung sowie dessen Verwendung
DE102008059342A1 (de) * 2008-11-30 2010-06-10 Süd-Chemie AG Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung
DE202008017277U1 (de) * 2008-11-30 2009-04-30 Süd-Chemie AG Katalysatorträger
DE102010026462A1 (de) * 2010-07-08 2012-01-12 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
CN102153189A (zh) * 2010-12-16 2011-08-17 哈尔滨工业大学 浮石催化臭氧化去除水中有机物的方法
DE102012008714A1 (de) * 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Vorimprägnierung von Schalenkatalysatoren mit einem Acetat
CN106215561B (zh) * 2016-08-31 2018-04-20 苏州贝捷环保设备有限公司 一种燃煤烟气处理方法
CN107096532B (zh) * 2017-05-16 2019-12-10 嘉兴学院 一种Au-ZrO2催化剂及其应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5808136A (en) * 1995-01-23 1998-09-15 Degussa Aktiengesellschaft Catalyst, method of its production and its use for the production of vinyl acetate monomer
JP2000093797A (ja) * 1998-09-24 2000-04-04 Degussa Huels Ag ビニルモノマ―の製造用担持触媒、その製造方法及びその使用
US6057260A (en) * 1997-12-12 2000-05-02 Celanese International Corporation Vinyl acetate catalyst comprising palladium, gold, copper and any of certain fourth metals
US6358882B1 (en) * 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate
DE10030039A1 (de) * 2000-06-17 2002-01-10 Celanese Chem Europe Gmbh Katalysator zur Herstellung von Vinylacetat und Verfahren zur Herstellung des Katalysators

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5808136A (en) * 1995-01-23 1998-09-15 Degussa Aktiengesellschaft Catalyst, method of its production and its use for the production of vinyl acetate monomer
US6057260A (en) * 1997-12-12 2000-05-02 Celanese International Corporation Vinyl acetate catalyst comprising palladium, gold, copper and any of certain fourth metals
JP2000093797A (ja) * 1998-09-24 2000-04-04 Degussa Huels Ag ビニルモノマ―の製造用担持触媒、その製造方法及びその使用
US6358882B1 (en) * 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst

Also Published As

Publication number Publication date
CA2547187A1 (en) 2005-07-07
ZA200604362B (en) 2007-11-28
RU2006119185A (ru) 2007-12-20
JP2007514543A (ja) 2007-06-07
KR100886048B1 (ko) 2009-02-26
BRPI0417185A (pt) 2007-03-06
AU2004305515B2 (en) 2008-08-28
NO20062531L (no) 2006-07-03
CA2547187C (en) 2010-11-02
CN1894035A (zh) 2007-01-10
RU2011131292A (ru) 2013-02-10
KR20060103514A (ko) 2006-10-02
PL215127B1 (pl) 2013-10-31
AU2004305515C1 (en) 2009-06-25
UA96563C2 (ru) 2011-11-25
AU2004305515A1 (en) 2005-07-07
WO2005061107A1 (en) 2005-07-07
JP4772695B2 (ja) 2011-09-14
EP1694436A1 (en) 2006-08-30
PL380021A1 (pl) 2006-12-11
NZ547072A (en) 2010-05-28

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Granted publication date: 20090204

Termination date: 20131119