CN100381549C - Cleaning agent for flush toilet - Google Patents
Cleaning agent for flush toilet Download PDFInfo
- Publication number
- CN100381549C CN100381549C CNB2004100190854A CN200410019085A CN100381549C CN 100381549 C CN100381549 C CN 100381549C CN B2004100190854 A CNB2004100190854 A CN B2004100190854A CN 200410019085 A CN200410019085 A CN 200410019085A CN 100381549 C CN100381549 C CN 100381549C
- Authority
- CN
- China
- Prior art keywords
- detergent
- slowly
- water closet
- releasing
- vehicle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Detergent Compositions (AREA)
Abstract
The present invention relates to a detergent for a water closet, which belongs to the field of sanitary installations for cleaning and washing. The present invention is mainly characterized in that alkyl benzene sulfonic acid which is a negative ion activity precursor substance with low price and easy obtainment is used, and a neutralization reaction is carried out between the negative ion activity precursor substance and an alkali substance; therefore, a surface activity cleaning agent of negative ions, namely, alkyl benzene sodium sulfonate is generated. 1 to 2 multifunctional slow-release agents and excipient are used, a sterilizing function is realized by suing inorganic antibacterial nanometer powder as an antibacterial material, and modified nanometer essence is used for a perfume discharging function. The detergent prepared in the way has the advantages of novelty, uniqueness, obvious effect and low price. The effect of the detergent reaches or is superior to that of a foreign product. Therefore, the detergent has strong competitive power and popularization value on markets at home and abroad.
Description
Affiliated field
The invention belongs to sanitary facility cleaning washing class field, especially a kind of detergent for water closet.
Background technology
The similar sanitising agent of production and sales in the market is generally blue look block, is made up of materials such as kinds of surface activity, solid agent, sustained release dosages.More external patent documentation reports have: as day disclosure 90-272100 patent, its raw material adopts the polyethers of the higher butylene oxide ring of price, propylene oxide, oxyalkylated molecular weight 2560 etc.; 654487 of U.S. Pat have adopted a kind of anion surfactant, for sulfonic group, straight chain primary alcohol, binding agent adopt Natvosol etc.This kind sanitising agent just was widely used in toilets such as family, hotel, aircraft, steamer before a lot of years abroad, and the domestic market is sold this kind product and had for many years, and market is still in continuous expansion.Shortcoming is that cost is higher, goes to distinguish the flavor of, scale suppression, effect antibacterial, cleaning be very general.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of detergent for water closet is provided, this product has added inorganic nano antiseptic powder and modified Nano essence on the basis of adopting the general sanitising agent that raw material constituted, what strengthened sanitising agent effectively removes flavor, scale suppression, antibacterial, cleaning effect, and cost is lower.
Content of the present invention is:
The component and the weight percent that constitute this detergent for water closet are:
Sodium hydroxide 4～10%
Water 4～10%
Alkyl benzene sulphonate (ABS) 15～40%
Slowly-releasing-vehicle I 5～15%
Slowly-releasing-vehicle II 5～15%
Acid blue dye 2～10%
Inorganic nano antiseptic powder 0.1～1.0%
Sodium sulfate anhydrous.min(99) 20～40%
Modified Nano essence 0.5～3%.
Above-mentioned sodium hydroxide is the industrial sodium hydroxide solid preparation, and alkyl benzene sulphonate (ABS) is the commercially available prod, and acid blue dye is acid lake blue or edible light blue, and Sodium sulfate anhydrous.min(99) is the commercially available prod;
Above-mentioned slowly-releasing-vehicle I is xanthan gum and stearic mixture, and slowly-releasing-vehicle II is the mixture of xanthan gum and copper sulfate.The xanthan gum content that constitutes slowly-releasing-vehicle I is 45～55%, and stearic content is 38～48%; The content that constitutes the xanthan gum of slowly-releasing-vehicle II is 50～60%, and the content of copper sulfate is 30～45%.
Above-mentioned inorganic nano antiseptic powder be commercially available and by zinc salt or/and silver salt, nano titanium oxide and rare earth element form through co-precipitation; Above-mentioned modified Nano essence is commercially available and by the transparent paste that nano silicon oxide, nano titanium oxide and essence constituted, the odor type of this modified Nano essence can be spices such as pine, Song Shan, green grass.
Advantage of the present invention and positively effect are:
The cleaning agent for flush toilet product adopts price comparison cheap, a kind of anion active precursor substance alkyl benzene sulphonate (ABS) that is easy to get, carrying out neutralization reaction and generate a kind of anion surface activity clean-out system one with alkaloid substance (as sodium hydroxide) is sodium alkyl benzene sulfonate, and adopt 1～2 kind of multifunctional slow-release-excipient, germicidal action adopts the inorganic nano antiseptic powder as anti-biotic material, put the nano essence that modification is adopted in fragrant effect, this product novelty of Zu Chenging like this, unique, effect is obvious, and low price, its effect reaches or is better than external product, and certain competitive power and promotional value are at home and abroad arranged on the market.
Consider the commercially available piece of in the past detergent for water closet heavy only be 50 grams, and require in water tank, to soak the long period, its time is within 1 month.Calculate according to daily water consumption, the clean-out system of 50g only, each active substance that discharges approximately has only 20mg/l, goes flavor, cleaning, antimicrobial effect in order to reach ideal, and this product has added the antibiotic powder of nano inorganic and the modified Nano essence of environmental protection.Because its particle is very little, surface-area is very big, after therefore soaking in water, can be scattered in well in the water, and the suction of so just having given play to these nano materials fully distinguishes the flavor of, the good action of antibiotic, scale suppression.
The present invention is that a kind of toilet water closet that utilizes removes flavor, scale suppression, antibacterial sanitising agent, and this product is put into toilet flush, discharges effective active matter in water, reach when flushing the toilet distinguish the flavor of, scale suppression, antibacterial, the cleaning effect.
The present invention is without phosphorus prescription, can not produce second environmental pollution.
Embodiment
Below the embodiment of the invention is further described:
The component of detergent for water closet and weight percent are:
Sodium hydroxide 4～10%
Water 4～10%
Alkyl benzene sulphonate (ABS) 15～40%
Slowly-releasing-vehicle I 5～15%
Slowly-releasing-vehicle II 5～15%
Acid blue dye 2～10%
Inorganic nano antiseptic powder 0.1～1.0%
Sodium sulfate anhydrous.min(99) 20～40%
Modified Nano essence 0.5～3%.
The technology of concrete this detergent for water closet of preparation is (present embodiment is narrated realizing this product in 100 kilograms of finished products):
Accurately take by weighing 5 kilograms of tap water, put into stainless steel cask, the limit is slowly stirred the limit and is put into 4.1 kilograms of industrial sodium hydroxides, after treating the sodium hydrate solid dissolving, slowly pour in the kneader with agitating heater again, under slowly stirring, pour 26.0 kilograms of sodium alkyl benzene sulfonates into, produce chemical reaction and produce heat in the kneader this moment, adds acid blue dye while hot successively--4.0 kilograms of acid lake blues, 2.0 kilograms of edible light blues, sustained release dosage I11 kilogram, sustained release dosage II10.5 kilogram, 0.9 kilogram in inorganic nano antiseptic powder, 35 kilograms of Sodium sulfate anhydrous.min(99), keep the interior Heating temperature of kneader 40～80 ℃ of scopes, stirring the kneading time is 0.5～1.0 hour, and naturally cooling adds 1.5 kilograms in modified Nano essence then afterwards, the continuation stirring is mediated to lotion even, subsequently the machine-shaping finished product.
The sodium hydroxide that adopts is the industrial sodium hydroxide solid preparation, and alkyl benzene sulphonate (ABS) is commercially available product commonly used, and acid blue dye adopts acid lake blue, edible light blue, and the two can use simultaneously, also can use separately, is use simultaneously in the present embodiment; Sodium sulfate anhydrous.min(99) is the commercially available prod.
At this some attached material are carried out technical specification:
1. slowly-releasing-vehicle I and slowly-releasing-vehicle II:
Slowly-releasing-vehicle I is xanthan gum and stearic mixture, and its content is that xanthan gum is 45～55%, and stearic content is 38～48%, and the two stirs by simple mixing and gets final product; Slowly-releasing-vehicle II is the mixture of xanthan gum and copper sulfate, and wherein the content of xanthan gum is 50～60%, and the content of copper sulfate is 30～45%, and the two stirs by simple mixing and gets final product.
2. inorganic nano antiseptic powder:
The inorganic nano antiseptic powder,, needn't be elaborated at this because of it is commercially available product or/and silver salt (as zinc nitrate, Silver Nitrate or zinc chloride etc.), nano titanium oxide and rare earth element (as lanthanum, cerium, praseodymium etc.) form through co-precipitation by zinc salt.
3. modified Nano essence:
Modified Nano essence has sale by the transparent paste that nano silicon oxide, nano titanium oxide and essence constituted on market, needn't give unnecessary details.The odor type of this modified Nano essence can be spices such as pine, Song Shan, green grass.
The preparation method's of cleaning agent for flush toilet of the present invention evident characteristic is: operating procedure is simple, product Have plasticity, be easy to processing, owing to adopted nano material, it has unique removing peculiar smell Function, simultaneously owing to added the nano essence of modification, so can slowly release again make us the heart happy big from Right fragrance.
Claims (7)
1. detergent for water closet is characterized in that:
Its component and weight percent are:
Sodium hydroxide 4～10%
Water 4～10%
Alkyl benzene sulphonate (ABS) 15～40%
Slowly-releasing-vehicle I 5～15%
Slowly-releasing-vehicle II 5～15%
Acid blue dye 2～10%
Inorganic nano antiseptic powder 0.1～1.0%
Sodium sulfate anhydrous.min(99) 20～40%
Modified Nano essence 0.5～3%.
2. detergent for water closet according to claim 1, it is characterized in that: described sodium hydroxide is the industrial sodium hydroxide solid preparation, described alkyl benzene sulphonate (ABS) is the commercially available prod, described acid blue dye is acid lake blue or edible light blue, and described Sodium sulfate anhydrous.min(99) is the commercially available prod.
3. described detergent for water closet according to claim 1 is characterized in that: described slowly-releasing-vehicle I is xanthan gum and stearic mixture, and described slowly-releasing-vehicle II is the mixture of xanthan gum and copper sulfate.
4. described detergent for water closet according to claim 1 is characterized in that: described inorganic nano antiseptic powder be commercially available and by zinc salt or/and silver salt, nano titanium oxide and rare earth element form through co-precipitation.
5. described detergent for water closet according to claim 1 is characterized in that: described modified Nano essence is commercially available and by transparent paste that nano silicon oxide, nano titanium oxide and essence constituted.
6. according to claim 1 or 3 described detergent for water closet, it is characterized in that: the xanthan gum content of described formation slowly-releasing-vehicle I is 45～55%, and stearic content is 38～48%; The content of the xanthan gum of described formation slowly-releasing-vehicle II is 50～60%, and the content of copper sulfate is 30～45%.
7. described according to claim 1 or 5 detergent for water closet is characterized in that: the odor type of described modified Nano essence can be pine, Song Shan, green grass spices.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100190854A CN100381549C (en) | 2004-04-27 | 2004-04-27 | Cleaning agent for flush toilet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100190854A CN100381549C (en) | 2004-04-27 | 2004-04-27 | Cleaning agent for flush toilet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1690182A CN1690182A (en) | 2005-11-02 |
| CN100381549C true CN100381549C (en) | 2008-04-16 |
Family
ID=35345941
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100190854A Expired - Fee Related CN100381549C (en) | 2004-04-27 | 2004-04-27 | Cleaning agent for flush toilet |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100381549C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101773374B (en) * | 2009-01-08 | 2012-10-17 | 3M创新有限公司 | Cleaning tool |
| CN101732202B (en) * | 2009-12-03 | 2011-07-27 | 陈罘杲 | Nano composite micro-emulsion type antibacterial deodorant |
| CN102260598B (en) * | 2011-06-24 | 2013-04-24 | 东莞爱屋氏日用品有限公司 | Sterilizing toilet cleaning block |
| CN102994286A (en) * | 2012-11-27 | 2013-03-27 | 启东市隆腾电气有限公司 | Cleaning agent for flush toilets |
| CN106085629A (en) * | 2016-05-24 | 2016-11-09 | 常山县鑫晖清洁用品有限公司 | A kind of detergent for water closet and manufacture method thereof |
| CN106635441A (en) * | 2016-12-16 | 2017-05-10 | 嘉兴德扬生物科技有限公司 | Antibacterial lasting fragrant laundry detergent and preparation technology thereof |
| CN107057608A (en) * | 2017-04-27 | 2017-08-18 | 龚彩萍 | A kind of white glue with vinyl binder and preparation method thereof |
| CN107474980A (en) * | 2017-08-29 | 2017-12-15 | 佛山绿能咨询服务有限公司 | A kind of New-type toilet cleaning supplies and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044493A (en) * | 1989-01-25 | 1990-08-08 | 程丽波 | The preparation method of durably effective cleaning agent for flush toilet |
| CN1048726A (en) * | 1989-07-14 | 1991-01-23 | 徐云英 | Detergent for water closet |
| CN1077219A (en) * | 1992-04-10 | 1993-10-13 | 吕平 | A kind of use in toilet clean-out system |
| CN1140755A (en) * | 1995-07-18 | 1997-01-22 | 上海合成洗涤剂厂 | Lumpy cleaning agent for automatic toilet flushing and its producing process |
| WO2003020863A1 (en) * | 2001-08-31 | 2003-03-13 | Reckitt Benckiser Inc | Thickened toilet bowl cleaner |
-
2004
- 2004-04-27 CN CNB2004100190854A patent/CN100381549C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044493A (en) * | 1989-01-25 | 1990-08-08 | 程丽波 | The preparation method of durably effective cleaning agent for flush toilet |
| CN1048726A (en) * | 1989-07-14 | 1991-01-23 | 徐云英 | Detergent for water closet |
| CN1077219A (en) * | 1992-04-10 | 1993-10-13 | 吕平 | A kind of use in toilet clean-out system |
| CN1140755A (en) * | 1995-07-18 | 1997-01-22 | 上海合成洗涤剂厂 | Lumpy cleaning agent for automatic toilet flushing and its producing process |
| WO2003020863A1 (en) * | 2001-08-31 | 2003-03-13 | Reckitt Benckiser Inc | Thickened toilet bowl cleaner |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1690182A (en) | 2005-11-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103805367A (en) | High-efficiency sterilization laundry detergent | |
| CN102198059B (en) | Novel cleaning material | |
| CN100381549C (en) | Cleaning agent for flush toilet | |
| CN102978034A (en) | Antimicrobial nano-silver transparent soap and preparation method thereof | |
| CN102766542A (en) | Detergent containing tea saponin | |
| CN102051274B (en) | Solid water-saving toilet cleaner | |
| CN104017661A (en) | Tea saponin dishwashing liquid and preparation method thereof | |
| CN1421519A (en) | Lamelliform sanitory washing article and its making process and use | |
| CN102206556A (en) | Multipurpose efficient environmental-friendly deodorant | |
| CN103493847B (en) | Environment-friendly immersing and spraying liquid and preparation method thereof | |
| CN102399653A (en) | Washing powder formula | |
| CN103756802B (en) | Preparation method of efficient sterilization safe detergent | |
| CN103834513A (en) | Multifunctional liquid detergent and production process thereof | |
| CN105542974A (en) | Skin-care washing powder and preparation method and application thereof | |
| CN101402901B (en) | Plaster shaped decontaminating agent of silicon dioxide with disinfection function and method of producing the same | |
| CN102899199A (en) | Sterilization particle and preparation method thereof | |
| CN1106253A (en) | Artificial tooth cleaning agent | |
| JP6241948B2 (en) | Cleaning composition | |
| CN109439452B (en) | Deodorizing and descaling agent for toilet and preparation method thereof | |
| CN103013691A (en) | Detergent | |
| CN110157552A (en) | A kind of high-effective cleansing of natural green washes the dishes salt and preparation method thereof | |
| CN108721128A (en) | A kind of Tea Saponin hand cleanser and preparation method thereof | |
| CN107129873A (en) | A kind of detergent of closet ball | |
| CN1291636A (en) | Multifunctional solid detergent and its preparing process | |
| CN1978611A (en) | Phosphorus-free toxicity-free strong disinfecting detergent powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Guangzhou Nanshun Cleaning Products Co., Ltd. Assignor: Tianjin University of Science & Technology Contract record no.: 2010440000502 Denomination of invention: Thickened cleaning agent for toilet Granted publication date: 20080416 License type: Exclusive License Open date: 20051102 Record date: 20100517 |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080416 Termination date: 20110427 |