CN1421519A - Lamelliform sanitory washing article and its making process and use - Google Patents

Lamelliform sanitory washing article and its making process and use Download PDF

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Publication number
CN1421519A
CN1421519A CN 01139384 CN01139384A CN1421519A CN 1421519 A CN1421519 A CN 1421519A CN 01139384 CN01139384 CN 01139384 CN 01139384 A CN01139384 A CN 01139384A CN 1421519 A CN1421519 A CN 1421519A
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sanitary washing
washing article
laminar
agent
content
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CN 01139384
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Chinese (zh)
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吕秀娟
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Individual
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Priority to CN 01139384 priority Critical patent/CN1421519A/en
Priority to JP2002067992A priority patent/JP2003166000A/en
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Abstract

The lamelliform sanitary washing article is produced with PVA or PVP as substrate, composite surfactant, moistening agent, antiseptic, stuffing, essence, pigment, etc. and through specific treatment to form sheet product. Its production process includes material preparation, compounding, mixing with pigment, stoving, punching, and other steps. The use of the product is also disclosed.

Description

Laminar sanitary washing article, manufacture method and uses thereof
One, technical field
The present invention relates to a kind of laminar sanitary washing article (being also referred to as instant fragrant soap flakes), the manufacture method of described laminar sanitary washing article, with and uses thereof; This product is particularly useful for cleaning each position of human body, uses in being particluarly suitable for taking a shower, and can be used for washing clothes.
Two, background technology
Traditional Personal hygiene articles for washing includes: for example perfumed soap, body wash, hand cleaner etc., the kind of these products in market is extensive, and be in a great variety, and differ from one another, though they are accepted by most consumers or like, still there is its shortcoming in described traditional product.
1. perfumed soap
Active constituent is sodium soap (potassium) soap, and stability in hard water is poor, will have the soap scum of indissoluble to produce in the use, and stick on the bath wall, is difficult to cleaning.Contact soap surface, back with hard water and can form the indissoluble soap scum, make us feeling that in use harsh feeling is arranged.Because perfumed soap repeatedly uses repeatedly, in storage process, have " sticking with paste/sticking " or crack performance and take place simultaneously.And perfumed soap directly contacts with human body in use, may cause pathophoresis, and therefore, perfumed soap usually should not be in public places as sanitizing agent
2. body wash or hand cleaner
This class washing product adopts complexed surfactant, has allocated various skin care ingredients and other additives into, has overcome some shortcomings of perfumed soap, advantages such as having good anti-performance of hard water, lowly stimulate, foam is abundant.Because of it is a liquid, usage quantity is bigger, and finished product adopts the large-volume receptacle packing more, and inconvenience is transported and carried.
In view of the foregoing, in washing composition, cosmetic field, need that exploitation a kind ofly can keep perfumed soap, the dew of bathing, washing composition advantage, can overcome its shortcoming again, and it is low to have a cost, consumption is few, the product of portable characteristics, this product both had been fit to do personal hygiene article, also was suitable for washing clothes, still was suitable for the popular sanitary product that the public place uses simultaneously.
Three, summary of the invention
The inventor through concentrating on studies and the basis of a large amount of cut-and-try works on, develop a kind of laminar articles for washing, can satisfy the demand.
Therefore, the purpose of this invention is to provide a kind of laminar sanitary washing article, particularly a kind of instant fragrant soap flakes, this product can be used for cleaning each position of human body, uses in being particluarly suitable for taking a shower, and can be used for washing clothes.
Another object of the present invention provides the manufacture method of described laminar sanitary washing article.
The composition of laminar sanitary washing article is to be matrix with the polymkeric substance, and one-tenth such as complexed surfactant, wetting agent, antiseptic-germicide, weighting agent, essence, pigment are dispensed into wherein, through processing treatment, becomes laminar or scraps of paper shape product.
The polymkeric substance that is used for the laminar sanitary washing article of the present invention is preferably various film-forming properties polymkeric substance, also preferably have anti-soil dirt resedimentation, this polymkeric substance particularly is selected from polyvinyl alcohol (PVP), polyvinylpyrrolidone (PVP) and combination of polymers thereof.In the gross weight of the laminar sanitary washing article of the present invention, the consumption of polymkeric substance is 8%-30%, preferred 10%-21%.
The tensio-active agent that is used for the laminar sanitary washing article of the present invention is selected from anion surfactant, nonionogenic tenside, zwitterionics and combination thereof.Wherein, described anion surfactant is to have the active tensio-active agent of decontamination, and it is selected from the anion sulfate acid salt surfactant, comprises straight chain and side chain, primary and secondary alkyl-sulphate, dithionate, alkyl alcohol sulfate.
Particularly preferably be sodium laurylsulfate (sodium lauryl sulphate), fatty acid alkyl amide, alkyl betaine etc. and combination thereof.
In the gross weight of the laminar sanitary washing article of the present invention, the consumption of tensio-active agent is 25%-72%, most preferably is 34%-62%.Employed tensio-active agent is preferably compound, promptly comprises anion surfactant, the combination of nonionogenic tenside and zwitterionics, and their consumption is respectively: 28-50%, 3%-6% and 3%-6%, preferred 40%, 5% and 5%.
The wetting agent that is used for the laminar sanitary washing article of the present invention can be any wetting action, and especially having has the composition that moistens and preserve moisture, for example glycerine to skin.In the gross weight of the laminar sanitary washing article of the present invention, the consumption of wetting agent is 1%-10%, is preferably 2%-6%.
The antiseptic-germicide that is used for the laminar sanitary washing article of the present invention can be the various reagent antibiotic, preservative activity that have, preferred Tegosept M, propylben and combination thereof, and wallantoin (allantion).Gross weight in the laminar sanitary washing article of the present invention, the consumption of antiseptic-germicide is 0.1%-2.0%, preferred 0.3%-0.8%, and preferred Tegosept M and propylben and wallantoin are used in combination, wherein Tegosept M and propylben are as antibiotic antiseptic, and wallantoin is as the moisture-keeping bacterium-restraining agent.
The antiseptic-germicide that is used for the laminar sanitary washing article of the present invention can be various reagent with antioxygenation, preferred 2,6 ditertiary butyl p cresol.In the gross weight of the laminar sanitary washing article of the present invention, the consumption of antioxidant is 0.05%-0.3%, preferred 0.1%-0.2%.
The weighting agent that is used for the laminar sanitary washing article of the present invention can for example be starch or talcum powder, and in the gross weight of the laminar sanitary washing article of the present invention, the consumption of weighting agent is 15%-40%, preferred 25%-35%.
Can also comprise the PH conditioning agent in the laminar sanitary washing article of the present invention, as inorganic or organic acid, in order to regulate the pH value of product, described acid for example is phosphoric acid, citric acid, oxysuccinic acid, tartrate, xitix etc., preferred organic acid, particularly citric acid.In the gross weight of the laminar sanitary washing article of the present invention, the consumption of acid is 0.05%-1%, preferred 0.1%-0.5%.
Can also comprise other additives in the laminar sanitary washing article of the present invention, for example essence, pigment etc., the adding of essence can be selected according to required odor type, and the adding of pigment can be satisfied different human consumers' hobby.The consumption of these additives is that those of ordinary skill in the art knows, and can regulate on demand, and the consumption of essence is generally 0.05%-10%, and the consumption of pigment is generally 0.05%-5%.
Can also comprise natural extracts such as aloe in the laminar sanitary washing article of the present invention.Its consumption is generally 0.05%-3%.
Preparation in accordance with the present invention comprises part material and water mixing glue, adds other batch mixes then, color matching, drying, punching press is composed fragrant, packing obtains the laminar sanitary purpose washing finished product of the present invention, and wherein matching colors, compose perfume (or spice) and packaging step is step optional or that preferably include.The preparation method specifically comprises wetting agent, polymkeric substance added in the entry, and slowly is warming up to certain temperature (more than 50 ℃ below 100 ℃), is stirred to the feed liquid homogeneous transparent and obtains glue under this temperature, after treating that glue is cold slightly, in constantly slowly stirring down to wherein adding tensio-active agent, antibiotic antiseptic, weighting agent etc., and optional PH conditioning agent, pigment etc., leave standstill froth breaking after stirring, oven dry, punching press is chosen wantonly and is composed perfume (or spice), and is packaged to be finished product.For increasing the visual artistic treat of user, usually product is made colourful shape, comprise planeform or three-dimensional contouring etc., to satisfy different human consumers' needs.
Laminar sanitary washing article according to the present invention has following advantage: in light weight, consumption is few, can be scattered in the water fast, foam abundant, anti-hard water, lowly stimulate, go that sweat is good, antibiotic, smell is fragrant, be easy to carry and preservation etc.Compare with perfumed soap, body wash and traditional washing composition, product of the present invention is higher because of its activity substance content, so in use consumption is less just can reach good cleaning and result of use, no matter is to use, still use all very suitable in public places at home; Product of the present invention is applicable to multiple washing purposes, personal cleanliness's health for example, aspects such as washing clothes.
Five, embodiment
According to a kind of special preferred embodiment of the present invention, the composition of laminar sanitary washing article comprises polyvinyl alcohol, glycerine, Tegosept M, propylben, 2, the 6-ditertbutylparacresol, wallantoin, sodium laurylsulfate or sodium lauryl sulfate, fatty acid alkyl amide, Varion CDG-K, talcum powder or starch, and optional citric acid, essence and pigment etc.
A kind of particularly preferred embodiment according to the present invention, the prescription of the laminar sanitary washing article of the present invention form and per-cent as follows, in the gross weight of laminar sanitary washing article:
1. polyvinyl alcohol: membrane-forming agent, the anti-soil dirt is deposition agent again, prescription consumption 10%-21%;
2. glycerine: wetting agent, and have skin moisten, moisture-keeping efficacy, prescription consumption 2%-6%;
3. Tegosept M: antibiotic antiseptic, prescription consumption 0.1%-0.4%;
4. propylben: antibiotic antiseptic, prescription consumption 0.1%-0.2%;
5.2,6-ditertbutylparacresol (BHT): oxidation inhibitor, prescription consumption 0.1%-0.2%;
6. wallantoin: moisture-keeping bacterium-restraining agent, prescription consumption 0.1%-0.2%;
7. sodium laurylsulfate or sodium lauryl sulphate: tensio-active agent has the decontamination effect, prescription consumption 28%-50%;
8. fatty acid alkyl amide: nonionogenic tenside has surely bubble effect of decontamination, prescription consumption 3%-6%;
9. empgen BB comprises Varion CDG-K (BS-12), and amphoterics has antistaticly, and the effect of conditioning skin has bacteria resistance function concurrently.Prescription consumption 3%-6%;
10. starch or talcum powder: weighting agent, prescription consumption 25%-35%;
11. citric acid: pH value conditioning agent, prescription consumption 0.1-0.5%;
12. other: are as essence, pigment, and auxiliary agent such as benzophenone, an amount of.2. manufacture method is summarized as follows:
Glycerine is dropped in the water, under continuous stirring, progressively add polyvinyl alcohol (PVA), and slowly be warming up to about 70-90 ℃, preferred 80-85 ℃, under this temperature, be stirred to the feed liquid homogeneous transparent and promptly get glue.The cold slightly back of glue is in constantly slowly stirring down to the unclassified stores that wherein adds except that essence, leave standstill after stirring, pack behind the froth breaking, oven dry (90-105 ℃), punching press, tax perfume (or spice) finished product.
Following examples are made more detailed description to the present invention and manufacture method thereof, but are not construed as limiting the invention.
Embodiment 1-3
Sequence number Name of material Charging capacity (Kg)
Example 1 Example 2 Example 3
??1 Polyvinyl alcohol (PVA-217) ????18.0 ????18.0 ????16.0
??2 Glycerine ????3.3 ????3.0 ????3.0
??3 Purified Water ????111 ????110 ????118
??4 2,6 ditertiary butyl p cresol (BHT) ????0.1 ????0.1 ????0.1
??5 Tegosept M ????0.2 ????0.2 ????0.2
??6 Propylben ????0.1 ????0.1 ????0.1
??7 Wallantoin ????0.1 ????0.1 ????0.1
??8 Alcohol ????1.7 ????2.0 ????3.0
??9 Sodium lauryl sulphate (K12) ????33.5 ????34.0 ????33
??10 Fatty acid alkyl amide (6S01) ????3.5 ????3.5 ????3.0
??11 Empgen BB or dodecyl methyl trimethyl-glycine (BS-12) ????3.5 ????3.5 ????3.0
??12 Starch ????25 ????22 ????16.3
??13 Talcum powder ????0 ????3 ????3
??14 The food dye aqueous solution In right amount In right amount In right amount
??15 Citric acid ????0 ????0 ????0.8
??16 Benzophenone ????0 ????0.5 ????0.4
??17 Essence In right amount In right amount In right amount
Production process: a. throws material 2,1 in 3, is warming up to 80-85 ℃ under constantly stirring, and keeps 2 hours under this temperature, to the material clear, cools off standby.B. throw material 4,5,6,7 in material 8, be stirred to solution and be homogeneous transparent, standby.C. the clear material with step a gained changes in another still that is mixed, and slowly stirs and drops into material 9,10,11,12,13,15,16 down, fully is uniformly dispersed to material.D. the solution with step b gained drops in the mixture of step c gained, continues to stir (slowly) evenly.E. as required material 14 is dropped in the mixture of steps d gained, continue to stir.F. start roller dryer, after temperature rises to 90 ℃-105 ℃, the mixture of step e gained is evenly coated on the dryer through hopper, dry with appropriate rotating speed, and in time product is taken off from drying cylinder.G. the product of step f gained is delivered to punch press, select cutting die as required, this product stamping-out is become the work in-process of desired shape, scrap stock utilization to be recycled.H. with in the mixing machine of packing into after the metering of step g gained work in-process, spray into required essence as required, mix.I. the product that step h is made send packaging process, and metering packing obtains finished product.
The equipment that uses in the above-mentioned manufacture method can be relevant device conventional in this area, for example can specifically select following equipment for use: 1. join the glue still: 1/stainless steel 300L, and electrically heated, frame stirs, 80 rev/mins of rotating speeds; 2. join the slurry still: 1/stainless steel 400L, electrically heated, frame stirs, 50 rev/mins of rotating speeds; 3. color matching still: 6/stainless steel 200L, frame stirs, 50 rev/mins of rotating speeds; 4. basin: vertical, 200L, 6; 5. papermaking dryer: tube external diameter 1000mm, the wide 600mm of tube; 6. mixing machine: 1, drum-type, volume 100L, stainless steel.
Embodiment 4
Repeat embodiment 1-3, just polyvinyl alcohol wherein replaces with polyvinylpyrrolidone, obtains laminar sanitary washing article of the present invention.
Embodiment 5
Repeat embodiment 1-3, just 1/3 of polyvinyl alcohol wherein amount replaces with polyvinylpyrrolidone, and citric acid replaces with tartrate, and 1/2 amount of empgen BB replaces with Aloe extract, obtains laminar sanitary washing article of the present invention.

Claims (18)

1. laminar sanitary washing article, it is characterized in that: be matrix with the polymeric film, this polymeric film contains tensio-active agent, antibiotic antiseptic, wetting agent, weighting agent.
2. sanitary washing article according to claim 1 is characterized in that: polymkeric substance is polyvinyl alcohol or polyvinylpyrrolidone, and in the gross weight of laminar sanitary washing article, its content is 8%-30%.
3. sanitary washing article according to claim 1 is characterized in that: wetting agent is a glycerine, and in the gross weight of laminar sanitary washing article, its total content is 1%-10%.
4. sanitary washing article according to claim 1 is characterized in that: tensio-active agent is the composition of negatively charged ion, nonionic and zwitterionics, and in the gross weight of laminar sanitary washing article, its total content is 25%-72%.
5. sanitary washing article according to claim 4 is characterized in that: tensio-active agent is sodium laurylsulfate or sodium lauryl sulphate, fatty acid alkyl amide, the combination of empgen BB or Varion CDG-K.
6. sanitary washing article according to claim 1 is characterized in that: antibiotic antiseptic is a Tegosept M, propylben, and 2,6 ditertiary butyl p cresol, wallantoin, in the gross weight of laminar sanitary washing article, its total content is 0.1%-2%.
7. sanitary washing article according to claim 1 is characterized in that: weighting agent is starch or talcum powder, and in the gross weight of laminar sanitary washing article, its total content is 15%-40%.
8. sanitary washing article according to claim 1 is characterized in that: this polymeric film also contains PH conditioning agent, essence, pigment, and in the gross weight of laminar sanitary washing article, the content of PH conditioning agent is 0.05%-1%.
9. sanitary washing article according to claim 1 is characterized in that: this polymeric film also contains whitening agent, sun-screening agent, Aloe extract.
10. sanitary washing article according to claim 1, it is characterized in that: in the gross weight of laminar sanitary washing article, the content of polymkeric substance is 8%-30%, the content of tensio-active agent is 28%-72%, the content of wetting agent is 1%-10%, the content of antibiotic antiseptic is 0.1%-2%, and the content of weighting agent is 15%-40%.
11. sanitary washing article according to claim 10, it is characterized in that: in the gross weight of laminar sanitary washing article, the content of polymkeric substance is 10%-21%, the content of tensio-active agent is 34%-62%, the content of wetting agent is 2%-6%, the content of antibiotic antiseptic is 0.3%-0.8%, and the content of weighting agent is 25%-35%.
12. sanitary washing article according to claim 1 is characterized in that: in the gross weight of laminar sanitary washing article, it contains following composition: polyvinyl alcohol or polyvinylpyrrolidone 10%-21%; Glycerine 2%-6%; Tegosept M 0.1%-0.4%; Propylben 0.1%-0.2%; 2,6 ditertiary butyl p cresol 0.1%-0.2%; Wallantoin 0.1%-0.2%; Sodium laurylsulfate or sodium lauryl sulphate 28%-50%; Fatty acid alkyl amide 3%-6%; Varion CDG-K 3%-6%; Starch or talcum powder 25%-35%; Citric acid 0.1-0.5%; And an amount of essence and pigment.
13. sanitary washing article according to claim 12 is characterized in that: it also contains whitening agent, sun-screening agent, Aloe extract.
14. require arbitrary described sanitary washing article according to aforesaid right, it is characterized in that: this sanitary washing article is the product with multiple color of certain planeform or three-dimensional contouring.
15. the manufacture method of the laminar sanitary washing article of a claim 1, it is characterized in that comprising the steps: wetting agent, polymkeric substance are added in the entry, and slowly be warming up to more than 50 ℃ below 100 ℃, under this temperature, be stirred to the feed liquid homogeneous transparent and obtain glue, treat that glue is cold slightly after, in constantly slowly stirring down to wherein adding tensio-active agent, antibiotic antiseptic, and weighting agent leave standstill after stirring, oven dry, punching press obtains finished product.
16. according to the manufacture method of claim 16, it is characterized in that slowly being warming up to 80-85 ℃, and bake out temperature is 90-105 ℃.
17., it is characterized in that also comprising the step of composing perfume and color matching according to the manufacture method of claim 16 or 17.
18. according to the purposes of the described sanitary washing article of claim 1-14 in personal cleanliness's sanitary product and washing clothes.
CN 01139384 2001-11-23 2001-11-23 Lamelliform sanitory washing article and its making process and use Pending CN1421519A (en)

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CN 01139384 CN1421519A (en) 2001-11-23 2001-11-23 Lamelliform sanitory washing article and its making process and use
JP2002067992A JP2003166000A (en) 2001-11-23 2002-03-13 Slice-like sanitary laundry item, manufacturing method therefor and its use

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