CN100358943C - 一种碳纳米管/聚苯乙烯纳米导电复合材料的制备方法 - Google Patents
一种碳纳米管/聚苯乙烯纳米导电复合材料的制备方法 Download PDFInfo
- Publication number
- CN100358943C CN100358943C CNB2005100623183A CN200510062318A CN100358943C CN 100358943 C CN100358943 C CN 100358943C CN B2005100623183 A CNB2005100623183 A CN B2005100623183A CN 200510062318 A CN200510062318 A CN 200510062318A CN 100358943 C CN100358943 C CN 100358943C
- Authority
- CN
- China
- Prior art keywords
- nano
- polystyrene
- carbon nano
- cholate
- tube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 239000002131 composite material Substances 0.000 title abstract description 18
- 229910052799 carbon Inorganic materials 0.000 title abstract description 8
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000004793 Polystyrene Substances 0.000 claims abstract description 35
- 229920002223 polystyrene Polymers 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 25
- 229940099352 cholate Drugs 0.000 claims abstract description 16
- BHQCQFFYRZLCQQ-OELDTZBJSA-N cholic acid Chemical compound C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(O)=O)C)[C@@]2(C)[C@@H](O)C1 BHQCQFFYRZLCQQ-OELDTZBJSA-N 0.000 claims abstract description 16
- 239000003960 organic solvent Substances 0.000 claims abstract description 11
- 239000002041 carbon nanotube Substances 0.000 claims description 66
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 66
- 239000002114 nanocomposite Substances 0.000 claims description 25
- 239000011259 mixed solution Substances 0.000 claims description 24
- 229920001447 polyvinyl benzene Polymers 0.000 claims description 23
- 239000011159 matrix material Substances 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 17
- 239000002048 multi walled nanotube Substances 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 14
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical group CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 9
- FHHPUSMSKHSNKW-SMOYURAASA-M sodium deoxycholate Chemical compound [Na+].C([C@H]1CC2)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC([O-])=O)C)[C@@]2(C)[C@@H](O)C1 FHHPUSMSKHSNKW-SMOYURAASA-M 0.000 claims description 9
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 6
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 21
- 238000002156 mixing Methods 0.000 abstract description 9
- 239000006185 dispersion Substances 0.000 abstract description 3
- 230000035484 reaction time Effects 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000005303 weighing Methods 0.000 description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- 239000006227 byproduct Substances 0.000 description 5
- 239000012043 crude product Substances 0.000 description 5
- 229960003964 deoxycholic acid Drugs 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000001291 vacuum drying Methods 0.000 description 5
- 239000012190 activator Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000011231 conductive filler Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- -1 carbon nano tube compound Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100623183A CN100358943C (zh) | 2005-12-29 | 2005-12-29 | 一种碳纳米管/聚苯乙烯纳米导电复合材料的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100623183A CN100358943C (zh) | 2005-12-29 | 2005-12-29 | 一种碳纳米管/聚苯乙烯纳米导电复合材料的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1793216A CN1793216A (zh) | 2006-06-28 |
CN100358943C true CN100358943C (zh) | 2008-01-02 |
Family
ID=36804874
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2005100623183A Expired - Fee Related CN100358943C (zh) | 2005-12-29 | 2005-12-29 | 一种碳纳米管/聚苯乙烯纳米导电复合材料的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100358943C (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100439886C (zh) * | 2006-06-30 | 2008-12-03 | 浙江大学 | 一种用于温度测量的电加热复合材料及其制备方法 |
CN101899185A (zh) * | 2010-06-21 | 2010-12-01 | 中国科学院苏州纳米技术与纳米仿生研究所 | 一种碳纳米管/聚苯乙烯复合导电材料的制作方法 |
CN106700297A (zh) * | 2015-11-18 | 2017-05-24 | 天津工业大学 | 一种羧基化碳纳米管与聚苯乙烯的复合材料的制备方法 |
CN105733112A (zh) * | 2016-03-10 | 2016-07-06 | 中国科学院深圳先进技术研究院 | 一种聚合物导电复合材料及其制备方法 |
CN110697684B (zh) * | 2018-07-10 | 2022-05-31 | 中国科学院金属研究所 | 一种干法制备包覆型碳纳米管导电微球的方法及其应用 |
CN113072036B (zh) * | 2021-03-08 | 2023-07-21 | 常州大学 | 超疏水碳纳米管薄膜的制备方法 |
CN116199937B (zh) * | 2023-03-16 | 2023-12-19 | 深圳烯湾科技有限公司 | 碳纳米管分散体和聚苯乙烯复合材料的制备方法以及应用 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004097853A1 (en) * | 2003-04-24 | 2004-11-11 | Carbon Nanotechnologies, Inc. | Conductive carbon nanotube-polymer composite |
-
2005
- 2005-12-29 CN CNB2005100623183A patent/CN100358943C/zh not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004097853A1 (en) * | 2003-04-24 | 2004-11-11 | Carbon Nanotechnologies, Inc. | Conductive carbon nanotube-polymer composite |
Non-Patent Citations (1)
Title |
---|
碳纳米管/聚合物功能复合材料的研究进展. 刘家琴,吴玉程,薛茹君,胡小晔.兵器材料科学与工程,第29卷第6期. 2005 * |
Also Published As
Publication number | Publication date |
---|---|
CN1793216A (zh) | 2006-06-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100358943C (zh) | 一种碳纳米管/聚苯乙烯纳米导电复合材料的制备方法 | |
CN103160049B (zh) | 一种纳米银/碳纳米管/聚乙烯醇复合导电薄膜的制备方法 | |
EP3150550B1 (en) | Method for producing carbon nanotube dispersion and carbon nanotube dispersion, method for producing composition for composite material and method for producing composite material, and composite material and composite material molded article | |
Zhao et al. | Electrical conductivity of poly (vinylidene fluoride)/carbon nanotube composites with a spherical substructure | |
JP6358254B2 (ja) | カーボンナノチューブ分散液の製造方法、複合材料用組成物の製造方法および複合材料の製造方法、並びに、複合材料および複合材料成形体 | |
CN102424705A (zh) | 聚合物/石墨烯纳米复合材料的制备方法 | |
CN106674825B (zh) | 一种石墨烯/pvc复合材料用母料的制备方法及母料 | |
WO2019128484A1 (zh) | 用于3d打印的碳纳米管改性tpu材料及其制备方法 | |
CN105060268B (zh) | 一种碳纳米管微球的制备方法 | |
KR20150135090A (ko) | 탄소 나노 튜브의 제조 방법과, 탄소 나노 튜브의 분산 조성물 | |
KR101576658B1 (ko) | 유동층 다중벽 탄소나노튜브를 적용한 탄소나노튜브-고분자 나노 복합체 및 그 제조방법 | |
CN103570946A (zh) | 一种聚酰亚胺微球的制备方法 | |
KR20110087456A (ko) | 전도성이 향상된 고분자-탄소나노튜브 복합체 제조방법 | |
CN103740053B (zh) | 高含量碳纳米管改性环氧树脂基导电防腐复合材料的制备方法 | |
CN105331062A (zh) | 一种碳纳米管/聚乳酸导电复合材料及制备方法 | |
Zhang et al. | Mono-dispersion decorated ultra-long single-walled carbon nanotube/aramid nanofiber for high-strength electromagnetic interference shielding film with Joule heating properties | |
CN100427511C (zh) | 碳纳米管基磁性材料在聚合物中分散及定向排列的方法 | |
CN113421695A (zh) | 一种水性碳纳米管分散液、导电浆料及其制备方法 | |
Kim et al. | Nylon 610/functionalized multiwalled carbon nanotubes composites by in situ interfacial polymerization | |
JP2013180900A (ja) | カーボンナノ材料集合体分散液の製造方法 | |
Lu et al. | MOFs/PVA hybrid membranes with enhanced mechanical and ion-conductive properties | |
Kong et al. | Templated synthesis of polyaniline nanotubes with Pd nanoparticles attached onto their inner walls and its catalytic activity on the reduction of p-nitroanilinum | |
Yang et al. | Multiwalled carbon nanotubes grafted with polyamidoamine (PAMAM) dendrimers and their influence on polystyrene supercritical carbon dioxide foaming | |
CN109705401B (zh) | 一种复合抗静电塑料浓缩母料及其制备方法 | |
Yan et al. | Anchoring conductive polyaniline on the surface of expandable polystyrene beads by swelling-based and in situ polymerization of aniline method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: SHANGHAI HUASHI NANO MATERIALS CO., LTD. Free format text: FORMER OWNER: HUANG DEHUAN Effective date: 20080314 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20080314 Address after: A building, Xin Mei Industrial Zone, No. 260 Lian Cao Road, Shanghai, Minhang District Patentee after: Shanghai Huashi Nano Material Co., Ltd. Address before: Room 13, No. 288, Lane 301, Macao Road, Shanghai, Putuo District Patentee before: Huang Dehuan |
|
C19 | Lapse of patent right due to non-payment of the annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |