CN100357353C - Flame-retarded resin anchoring agent - Google Patents
Flame-retarded resin anchoring agent Download PDFInfo
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- CN100357353C CN100357353C CNB200610088189XA CN200610088189A CN100357353C CN 100357353 C CN100357353 C CN 100357353C CN B200610088189X A CNB200610088189X A CN B200610088189XA CN 200610088189 A CN200610088189 A CN 200610088189A CN 100357353 C CN100357353 C CN 100357353C
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- clay
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- resin anchoring
- antimonous oxide
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Abstract
The present invention relates to a flame-retarded resin anchoring agent prepared from clay and a curing agent, wherein the clay is prepared from the unsaturation resin of polyester, dimethylaniline, white carbon black obtained by a gas-phase method, stone powder, stone bromine phenyl ether and antimonous oxide; the curing agent is prepared from water, stone powder, benzoyl peroxide, sodium carboxymethyl cellulose and antimonous oxide. Because a fire retardant is added to the clay and the curing agent, so that the flame-retarded resin anchoring agent has favorable fire retardant performance. The flame-retarded resin anchoring agent has the advantages of simple preparation process and convenient use, and can satisfy the needs of various occasions which have specific requirements to the fire retardant performance.
Description
Technical field:
The present invention relates to binding agent, particularly a kind ofly be widely used in that roadway support under the coal mine, pit gear are installed, building aseismicity is reinforced, the pedestal of equipment is fixed, the resin anchoring agent of engineerings such as hydro project bank protection, underground power house supporting and tunnel support.
Background technology:
Resin anchoring agent is as a kind of anchoring product, early is to be used under the coal mine in the supporting tunnel, but because its anchor force reaches easy construction by force, so also obtained using widely and promoting in other place.And when some special occasions is used, fixing as some equipment bases, for to requirement of safe production, just the flame retardant properties to resin anchoring agent has had requirement, just requires resin anchoring agent to have flame retardant properties.The resin anchoring agent of present domestic use is formed by clay and solidifying agent two portions, generally also is called two component glue.During use clay and solidifying agent are mixed, clay and solidifying agent blended weight ratio are 1: 0.06~0.08; It is settable cementitious after for some time.One of major ingredient of clay is the polyester unsaturated polyester, and one of main raw material of solidifying agent is benzoyl peroxide (BPO), and the polyester unsaturated polyester is inflammable, and (BPO) is explosive for benzoyl peroxide.That is to say that the resin anchoring agent of present domestic use does not all possess flame retardant properties.
Summary of the invention:
The present invention is for avoiding above-mentioned existing in prior technology weak point, a kind of flame-retarded resin anchoring agent being provided, to improve the security that mine is produced.
The technical scheme that technical solution problem of the present invention is adopted is:
Flame-retarded resin anchoring agent of the present invention is made up of by 1: 0.06~0.08 weight ratio clay and solidifying agent, is characterized in:
Described clay consisting of by weight:
Polyester unsaturated polyester 1000, xylidine 5~14, thermal silica 5~10,
Stone flour 4000~4500, decabromodiphynly oxide 100~150, antimonous oxide 100~150;
Described solidifying agent consisting of by weight:
Water 1000, stone flour 1000, benzoyl peroxide 50~80, Xylo-Mucine 200~300,
Antimonous oxide 100~150.
Compared with the prior art, beneficial effect of the present invention is embodied in:
The present invention has been owing to added fire retardant decabromodiphynly oxide, antimonous oxide in clay, thereby makes clay have good flame retardancy, and is same, added the fire retardant antimonous oxide in solidifying agent, makes solidifying agent also possess good flame retardancy.Manufacture craft of the present invention is simple, and is easy to use, when having the excellent flame retardancy energy, also has excellent mechanical intensity, can satisfy the various demands that flame retardant properties had the production place of particular requirement.
Verification experimental verification flame retardant properties of the present invention, when test specimen of the present invention is made the alcohol blast burner combustion test, after alcohol blast burner is removed, the flaming combustion temporal summation of every group of 6 test specimens is no more than 30s, the flaming combustion time of wherein any test specimen is no more than 15s, the flameless combustion temporal summation of every group of 6 test specimens is no more than 120s, and the flameless combustion time of wherein any test specimen is no more than 60s, has satisfied coal mine downhole safety production and has reached the fire-retardant application that the particular requirement occasion is arranged.Intensity of the present invention is not compared with prior art and is changed, and satisfies the requirement that colliery downhole production and other industry are used fully.
Embodiment:
The preparation clay
1, get the raw materials ready by any prescription of following weight part:
Polyester unsaturated polyester 1000, xylidine 5~14, thermal silica 5~10,
Stone flour 4000~4500, decabromodiphynly oxide 100~150, antimonous oxide 100~150;
2, aqueous material is dropped in the agitator stir earlier, powder is dropped in the agitator successively stir then, stir well even finished product, can is standby.
The preparation solidifying agent
1, get the raw materials ready by any prescription of following weight part:
Water 1000, stone flour 1000, benzoyl peroxide 50~80, Xylo-Mucine 200~300,
Antimonous oxide 100~150.
2, Xylo-Mucine is put into water by prescription requirements, soaks after 48 hours other material of input and stir jointly, put into colloidal mill after stirring and grind, be finished product until the one-tenth toothpaste-like, can is standby.
Embodiment 1:
Clay consisting of by weight:
Polyester unsaturated polyester 1000, xylidine 14, thermal silica 10, stone flour 4500,
Decabromodiphynly oxide 150, antimonous oxide 150;
Solidifying agent consisting of by weight:
Water 1000, stone flour 1000, benzoyl peroxide 80, Xylo-Mucine 300, antimonous oxide 150.
During use, clay: solidifying agent mixed by weight 1: 0.08 and fully stirs evenly.
Present embodiment ultimate compression strength is 60MPa, and the presetting period is 8~41 seconds, and its flame retardant properties can satisfy the coal mine downhole safety production requirement, and cost is lower simultaneously.
Embodiment 2:
In this enforcement, clay consisting of by weight:
Polyester unsaturated polyester 1000, the basic aniline 5 of diformazan, thermal silica 5, stone flour 4000,
Decabromodiphynly oxide 100, antimonous oxide 100;
Solidifying agent consisting of by weight:
Water 1000, stone flour 1000, benzoyl peroxide 50, Xylo-Mucine 200, antimonous oxide 100.
During use, clay: solidifying agent mixed by weight 1: 0.07 and fully stirs evenly.
Present embodiment ultimate compression strength is 65MPa, and the presetting period is 41~90 seconds, and its flame retardant properties can satisfy the coal mine downhole safety production requirement.
Embodiment 3:
Clay consisting of by weight in the present embodiment:
Polyester unsaturated polyester 1000, xylidine 12, thermal silica 8, stone flour 4200,
Decabromodiphynly oxide 130, antimonous oxide 120;
Solidifying agent consisting of by weight:
Water 1000, stone flour 1000, benzoyl peroxide 70, Xylo-Mucine 250, antimonous oxide 120.
During use, clay: solidifying agent mixed by weight 1: 0.06 and fully stirs evenly.
Present embodiment anchoring agent intensity is 75MPa, and the presetting period is 91~180 seconds, and its flame retardant properties can satisfy the coal mine downhole safety production requirement.
Solidifying agent mainly influences set time of the present invention to what of clay add-on, and when the solidifying agent add-on was big, shortened set time, and intensity slightly descends, otherwise prolongs set time, and intensity slightly raises; The add-on of stone flour is also slightly influential to intensity of the present invention in the clay, and when the stone flour add-on was big, intensity slightly descended, otherwise intensity slightly rises.In actual the use,, take the circumstances into consideration to change the blending ratio of prescription and clay and solidifying agent, satisfy the requirement of various production scenes according to processing requirement and envrionment temperature.
Claims (4)
1, a kind of flame-retarded resin anchoring agent is made up of by 1: 0.06~0.08 weight ratio clay and solidifying agent, it is characterized in that:
Described clay consisting of by weight:
Polyester unsaturated polyester 1000, xylidine 5~14, thermal silica 5~10, stone flour 4000~4500, decabromodiphynly oxide 100~150, antimonous oxide 100~150;
Described solidifying agent consisting of by weight:
Water 1000, stone flour 1000, benzoyl peroxide 50~80, Xylo-Mucine 200~300, antimonous oxide 100~150.
2, flame-retarded resin anchoring agent according to claim 1 is characterized in that,
Described clay consisting of by weight:
Polyester unsaturated polyester 1000, xylidine 14, thermal silica 10, stone flour 4500, decabromodiphynly oxide 150, antimonous oxide 150;
Described solidifying agent consisting of by weight:
Water 1000, stone flour 1000, benzoyl peroxide 80, Xylo-Mucine 300, antimonous oxide 150.
3, flame-retarded resin anchoring agent according to claim 1 is characterized in that,
Described clay consisting of by weight:
Polyester unsaturated polyester 1000, the basic aniline 5 of diformazan, thermal silica 5, stone flour 4000, decabromodiphynly oxide 100, antimonous oxide 100;
Described solidifying agent consisting of by weight:
Water 1000, stone flour 1000, benzoyl peroxide 50, Xylo-Mucine 200, antimonous oxide 100.
4, flame-retarded resin anchoring agent according to claim 1 is characterized in that,
Described clay consisting of by weight:
Polyester unsaturated polyester 1000, xylidine 12, thermal silica 8, stone flour 4200, decabromodiphynly oxide 130, antimonous oxide 120;
Described solidifying agent consisting of by weight:
Water 1000, stone flour 1000, benzoyl peroxide 70, Xylo-Mucine 250, antimonous oxide 120.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB200610088189XA CN100357353C (en) | 2006-06-30 | 2006-06-30 | Flame-retarded resin anchoring agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CNB200610088189XA CN100357353C (en) | 2006-06-30 | 2006-06-30 | Flame-retarded resin anchoring agent |
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CN1876713A CN1876713A (en) | 2006-12-13 |
CN100357353C true CN100357353C (en) | 2007-12-26 |
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CNB200610088189XA Expired - Fee Related CN100357353C (en) | 2006-06-30 | 2006-06-30 | Flame-retarded resin anchoring agent |
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Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101041745B (en) * | 2007-02-13 | 2010-12-01 | 耿会英 | Water-resistant type resin anchoring agent |
CN102531455A (en) * | 2011-12-29 | 2012-07-04 | 安徽淮河化工股份有限公司 | Curing agent for resin anchoring agent |
CN102796481B (en) * | 2012-08-30 | 2013-07-10 | 山东华能冷却技术股份有限公司 | Adhesive for air duct of glass fiber reinforced plastic cooling tower |
CN104230206A (en) * | 2014-08-21 | 2014-12-24 | 淮南市金德实业有限公司 | High-strength tempered anchoring agent |
CN106280350A (en) * | 2016-08-08 | 2017-01-04 | 梁冬 | A kind of good toughness long resin in service life Anchor Agent |
CN106280351A (en) * | 2016-08-08 | 2017-01-04 | 梁冬 | A kind of Heat stability is good coal mining anchoring agent |
CN106189155A (en) * | 2016-08-08 | 2016-12-07 | 梁冬 | A kind of colliery high density high mechanical properties Anchor Agent |
CN106243660A (en) * | 2016-08-08 | 2016-12-21 | 梁冬 | A kind of waterproof ageing-resistant resin anchoring agent |
CN106189156A (en) * | 2016-08-08 | 2016-12-07 | 梁冬 | A kind of ageing-resistant resin anchoring agent of underground mine use |
CN106189157A (en) * | 2016-08-08 | 2016-12-07 | 梁冬 | A kind of fire-resistant waterproof resin anchoring agent |
CN106189152A (en) * | 2016-08-08 | 2016-12-07 | 梁冬 | A kind of corrosion-resistant rub resistance type resin anchoring agent |
CN110499038A (en) * | 2019-08-29 | 2019-11-26 | 淮南市金德实业有限公司 | A kind of intelligent CAP-B control system for resin anchoring agent production |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1078977A (en) * | 1993-05-20 | 1993-12-01 | 孙长松 | Super strong quick hardening mastic and prescription thereof and preparation method |
JP2001115100A (en) * | 1999-10-15 | 2001-04-24 | Hitachi Chem Co Ltd | Adhesive composition |
CN1319638A (en) * | 2000-10-20 | 2001-10-31 | 珠海保税区宝丽杜邦建材有限公司 | Method for making solid surface material adhesive |
-
2006
- 2006-06-30 CN CNB200610088189XA patent/CN100357353C/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1078977A (en) * | 1993-05-20 | 1993-12-01 | 孙长松 | Super strong quick hardening mastic and prescription thereof and preparation method |
JP2001115100A (en) * | 1999-10-15 | 2001-04-24 | Hitachi Chem Co Ltd | Adhesive composition |
CN1319638A (en) * | 2000-10-20 | 2001-10-31 | 珠海保税区宝丽杜邦建材有限公司 | Method for making solid surface material adhesive |
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CN1876713A (en) | 2006-12-13 |
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