CN106243660A - A kind of waterproof ageing-resistant resin anchoring agent - Google Patents
A kind of waterproof ageing-resistant resin anchoring agent Download PDFInfo
- Publication number
- CN106243660A CN106243660A CN201610643970.2A CN201610643970A CN106243660A CN 106243660 A CN106243660 A CN 106243660A CN 201610643970 A CN201610643970 A CN 201610643970A CN 106243660 A CN106243660 A CN 106243660A
- Authority
- CN
- China
- Prior art keywords
- parts
- waterproof
- ageing
- coal ash
- resistant resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000032683 aging Effects 0.000 title claims abstract description 22
- 238000004873 anchoring Methods 0.000 title claims abstract description 22
- 229920005989 resin Polymers 0.000 title claims abstract description 21
- 239000011347 resin Substances 0.000 title claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 51
- 239000010883 coal ash Substances 0.000 claims abstract description 31
- 239000004927 clay Substances 0.000 claims abstract description 27
- 239000004575 stone Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229920006305 unsaturated polyester Polymers 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 19
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 claims abstract description 12
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000002148 esters Chemical class 0.000 claims abstract description 11
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 11
- JTYRXXKXOULVAP-UHFFFAOYSA-N 1,2-dibromo-3-phenoxybenzene Chemical compound BrC1=CC=CC(OC=2C=CC=CC=2)=C1Br JTYRXXKXOULVAP-UHFFFAOYSA-N 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000008119 colloidal silica Substances 0.000 claims abstract description 8
- 239000003517 fume Substances 0.000 claims abstract description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 8
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 claims abstract description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 21
- -1 Methyl Hydrogen Chemical compound 0.000 claims description 19
- 239000010881 fly ash Substances 0.000 claims description 14
- 238000000227 grinding Methods 0.000 claims description 14
- 229920002545 silicone oil Polymers 0.000 claims description 13
- 229960000583 acetic acid Drugs 0.000 claims description 11
- 239000012362 glacial acetic acid Substances 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- 229920000136 polysorbate Polymers 0.000 claims description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 10
- 239000012530 fluid Substances 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims 1
- 239000003094 microcapsule Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 8
- 239000003063 flame retardant Substances 0.000 abstract description 5
- 239000003245 coal Substances 0.000 abstract description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229940031098 ethanolamine Drugs 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920006337 unsaturated polyester resin Polymers 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D20/00—Setting anchoring-bolts
- E21D20/02—Setting anchoring-bolts with provisions for grouting
- E21D20/025—Grouting with organic components, e.g. resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mining & Mineral Resources (AREA)
- Medicinal Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of waterproof ageing-resistant resin anchoring agent, the weight ratio including clay and firming agent, clay and firming agent is 1:0.2 0.4；Clay includes by weight: adjacent benzene-type unsaturated polyester (UP) 20 60 parts, modified coal ash 5 15 parts, dimethylaniline 14 parts, stone dibromodiphenyl ether 16 parts, graphene nanometer sheet 5 15 parts, fume colloidal silica 10 20 parts, nano silicon 5 15 parts；Firming agent includes by weight: cyclohexanone peroxide dibutyl ester sticks with paste 10 30 parts, sodium lignin sulfonate 5 10 parts, microencapsulated powder oil 5 15 parts, stone powder 10 20 parts, 30 60 parts of water.The waterproof ageing-resistant resin anchoring agent that the present invention proposes, not only adhesion strength is high, cured strength is very big, and waterproof, ageing-resistant and adhesion strength is the most excellent with mechanical performance, can meet coal mine downhole safety production and apply with having particular/special requirement occasion waterproof, fire-retardant.
Description
Technical field
The present invention relates to Anchor Agent technical field, particularly relate to a kind of waterproof ageing-resistant resin anchoring agent.
Background technology
The main side that roadway surrounding rock reinforcing is current colliery tunnel support is carried out with anchor pole and anchor cable cooperation resin anchoring agent
Formula, the resin anchoring agent used also is substantially using unsaturated polyester resin as adhesives, with stone powder as filler, with mistake
Oxide is firming agent, but owing to unsaturated polyester resin resistance to water is poor, can not when aquifer water-bearing stratum particularly anchoring underwater
Thering is provided effective anchor force, the fire-retardant and mechanical performance of the most existing Anchor Agent is the most in urgent need to be improved.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of waterproof ageing-resistant resin anchoring agent, not only
Adhesion strength is high, and cured strength is very big, and waterproof, ageing-resistant and adhesion strength is the most excellent with mechanical performance, can expire
Foot coal mine downhole safety produces and applies with having particular/special requirement occasion waterproof, fire-retardant.
The waterproof ageing-resistant resin anchoring agent of one that the present invention proposes, including clay and firming agent, clay and firming agent
Weight ratio is 1:0.2-0.4；Clay includes by weight: adjacent benzene-type unsaturated polyester (UP) 20-60 part, modified coal ash 5-15 part,
Dimethylaniline 1-4 part, stone dibromodiphenyl ether 1-6 part, graphene nanometer sheet 5-15 part, fume colloidal silica 10-20 part, nanometer two
Silicon oxide 5-15 part；Firming agent includes by weight: cyclohexanone peroxide dibutyl ester sticks with paste 10-30 part, sodium lignin sulfonate 5-10
Part, microencapsulated powder oil 5-15 part, stone powder 10-20 part, water 30-60 part.
Preferably, modified coal ash use following technique prepare: by methyl-silicone oil, Methyl Hydrogen Polysiloxane Fluid, span, tween,
Glacial acetic acid, water mix and blend, add triethanolamine, polyvinyl alcohol uniformly, add flyash mixed grinding, dry, pulverize
Obtain modified coal ash.
Preferably, modified coal ash uses following technique to prepare: by weight by 5-15 part methyl-silicone oil, 1-5 part methyl
Containing hydrogen silicone oil, 1-2 part span, 1-2 part tween, 0.2-0.6 part glacial acetic acid, 30-60 part water mix and blend, add 0.1-0.8 part
Triethanolamine, 0.5-1.2 part polyvinyl alcohol are uniform, add 20-40 part flyash mixed grinding, dry, pulverize and changed
Property flyash.
Preferably, modified coal ash uses following technique to prepare: by weight by 5-15 part methyl-silicone oil, 1-5 part methyl
Containing hydrogen silicone oil, 1-2 part span, 1-2 part tween, 0.2-0.6 part glacial acetic acid, 30-60 part water mix and blend 20-50min, stirring temperature
Degree is 40-50 DEG C, adds 0.1-0.8 part triethanolamine, 0.5-1.2 part polyvinyl alcohol uniformly, adds 20-40 part flyash
Mixed grinding 50-100min, grinding temperature is 55-65 DEG C, dry, pulverize and obtain modified coal ash.
Preferably, the weight ratio of clay and firming agent is 1:0.25-0.35.
Preferably, cyclohexanone peroxide dibutyl ester is stuck with paste and the weight ratio of sodium lignin sulfonate is 15-25:7-9.
Preferably, the weight ratio of modified coal ash, stone dibromodiphenyl ether and graphene nanometer sheet is 8-12:2-4:10-13.
The present invention, using adjacent benzene-type unsaturated polyester (UP) as bonding major ingredient, coordinates work with the sodium lignin sulfonate in firming agent
With, and add cyclohexanone peroxide dibutyl ester and stick with paste and solidify, not only adhesion strength is high, and cured strength is very big, further
Add modified coal ash mating reaction, can effectively promote adjacent benzene-type unsaturated polyester (UP), sodium lignin sulfonate and cyclohexanone peroxide
Dibutyl ester is miscible between sticking with paste, and each other dispersion is fabulous, makes the present invention waterproof, ageing-resistant and adhesion strength and mechanical performance pole
For excellence；Modified coal ash waterproof, anti-deformation, acid-proof alkaline are good, and anti-wear performance is excellent, free from environmental pollution, cost
Low, based on flyash, with methyl-silicone oil, Methyl Hydrogen Polysiloxane Fluid effect under span, tween, glacial acetic acid effect, not only may be used
Aggregate into network waterproof membrane, and emulsifying effectiveness is good, cross-link with triethanolamine, polyvinyl alcohol further, its network structure
Effectively penetrating into inside flyash, waterproof effect further enhances, the siliconoxygen bond wherein formed and the group being connected on silicon atom
Between formed unique texture, antioxidation, acid and alkali-resistance, good waterproof performance are fabulous；And modified coal ash can effectively promote stone bromine in clay
Diphenyl ether, graphene nanometer sheet and microencapsulated powder oil effect in firming agent, can effectively promote to dissolve each other each other, can effectively strengthen
Fire-retardant and water resistance, mechanical performance further enhances, the nano silicon added further and stone powder, not only can effectively drop
Low goods cost, products machinery performance is the most excellent, and the present invention can meet coal mine downhole safety and produces and have spy to waterproof, fire-retardant
Apply with very requiring occasion.
Compared to the prior art the mechanical strength of the present invention is obviously enhanced, and can fully meet underground coal mine and produce and other row
The requirement that industry uses.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
The waterproof ageing-resistant resin anchoring agent of one that the present invention proposes, including clay and firming agent, clay and firming agent
Weight ratio is 1:0.2；Clay includes by weight: adjacent benzene-type unsaturated polyester (UP) 60 parts, modified coal ash 5 parts, dimethylaniline 4
Part, stone dibromodiphenyl ether 1 part, graphene nanometer sheet 15 parts, fume colloidal silica 10 parts, nano silicon 15 parts；Firming agent is pressed
Weight portion includes: cyclohexanone peroxide dibutyl ester sticks with paste 10 parts, sodium lignin sulfonate 10 parts, microencapsulated powder oil 5 parts, stone powder 20
Part, 30 parts of water.
Embodiment 2
The waterproof ageing-resistant resin anchoring agent of one that the present invention proposes, including clay and firming agent, clay and firming agent
Weight ratio is 1:0.4；Clay includes by weight: adjacent benzene-type unsaturated polyester (UP) 20 parts, modified coal ash 15 parts, dimethylaniline
1 part, stone dibromodiphenyl ether 6 parts, graphene nanometer sheet 5 parts, fume colloidal silica 20 parts, nano silicon 5 parts；Firming agent is by weight
Amount part includes: cyclohexanone peroxide dibutyl ester sticks with paste 30 parts, sodium lignin sulfonate 5 parts, microencapsulated powder oil 15 parts, stone powder 10 parts,
60 parts of water.
Modified coal ash use following technique prepare: by methyl-silicone oil, Methyl Hydrogen Polysiloxane Fluid, span, tween, glacial acetic acid,
Water mix and blend, adds triethanolamine, polyvinyl alcohol uniformly, adds flyash mixed grinding, dry, pulverize and obtain modification
Flyash.
Embodiment 3
The waterproof ageing-resistant resin anchoring agent of one that the present invention proposes, including clay and firming agent, clay and firming agent
Weight ratio is 1:0.25；Clay includes by weight: adjacent benzene-type unsaturated polyester (UP) 50 parts, modified coal ash 8 parts, dimethylaniline
3 parts, stone dibromodiphenyl ether 2 parts, graphene nanometer sheet 13 parts, fume colloidal silica 15 parts, nano silicon 10 parts；Firming agent is pressed
Weight portion includes: cyclohexanone peroxide dibutyl ester sticks with paste 15 parts, sodium lignin sulfonate 9 parts, microencapsulated powder oil 6 parts, stone powder 16 parts,
40 parts of water.
Modified coal ash uses following technique to prepare: by weight by 15 parts of methyl-silicone oils, 1 part of Methyl Hydrogen Polysiloxane Fluid, 2 parts
Span, 1 part of tween, 0.6 part of glacial acetic acid, 30 parts of water mix and blend 50min, whipping temp is 40 DEG C, adds 0.8 part of three ethanol
Amine, 0.5 part of polyvinyl alcohol are uniform, add 40 parts of flyash mixed grinding 50min, and grinding temperature is 65 DEG C, dry, pulverize
Obtain modified coal ash.
Embodiment 4
The waterproof ageing-resistant resin anchoring agent of one that the present invention proposes, including clay and firming agent, clay and firming agent
Weight ratio is 1:0.35；Clay includes by weight: adjacent benzene-type unsaturated polyester (UP) 30 parts, modified coal ash 12 parts, dimethyl benzene
Amine 2 parts, stone dibromodiphenyl ether 4 parts, graphene nanometer sheet 10 parts, fume colloidal silica 18 parts, nano silicon 6 parts；Firming agent
Include by weight: cyclohexanone peroxide dibutyl ester sticks with paste 25 parts, sodium lignin sulfonate 7 parts, microencapsulated powder oil 9 parts, stone powder 13
Part, 50 parts of water.
Modified coal ash uses following technique to prepare: by weight by 5 parts of methyl-silicone oils, 5 parts of Methyl Hydrogen Polysiloxane Fluids, 1 part
Span, 2 parts of tweens, 0.2 part of glacial acetic acid, 60 parts of water mix and blend 20min, whipping temp is 50 DEG C, adds 0.1 part of three ethanol
Amine, 1.2 parts of polyvinyl alcohol are uniform, add 20 parts of flyash mixed grinding 100min, and grinding temperature is 55 DEG C, is dried, powder
Broken obtain modified coal ash.
Embodiment 5
The waterproof ageing-resistant resin anchoring agent of one that the present invention proposes, including clay and firming agent, clay and firming agent
Weight ratio is 1:0.3；Clay includes by weight: adjacent benzene-type unsaturated polyester (UP) 40 parts, modified coal ash 10 parts, dimethylaniline
2.5 parts, stone dibromodiphenyl ether 3 parts, graphene nanometer sheet 12 parts, fume colloidal silica 16 parts, nano silicon 8 parts；Firming agent
Include by weight: cyclohexanone peroxide dibutyl ester sticks with paste 20 parts, sodium lignin sulfonate 8 parts, microencapsulated powder oil 7 parts, stone powder 14
Part, 45 parts of water.
Modified coal ash uses following technique to prepare: by weight by 10 parts of methyl-silicone oils, 3 parts of Methyl Hydrogen Polysiloxane Fluids, 1.5
Part span, 1.3 parts of tweens, 0.4 part of glacial acetic acid, 45 parts of water mix and blends, add 0.5 part of triethanolamine, 0.8 part PVA mixed
Close uniformly, add 30 parts of flyash mixed grindings, dry, pulverize and obtain modified coal ash.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. a waterproof ageing-resistant resin anchoring agent, it is characterised in that include the weight of clay and firming agent, clay and firming agent
Ratio is 1:0.2-0.4；
Clay includes by weight: adjacent benzene-type unsaturated polyester (UP) 20-60 part, modified coal ash 5-15 part, dimethylaniline 1-4
Part, stone dibromodiphenyl ether 1-6 part, graphene nanometer sheet 5-15 part, fume colloidal silica 10-20 part, nano silicon 5-15 part；
Firming agent includes by weight: cyclohexanone peroxide dibutyl ester sticks with paste 10-30 part, sodium lignin sulfonate 5-10 part, microcapsule
Change red phosphorus 5-15 part, stone powder 10-20 part, water 30-60 part.
The most waterproof ageing-resistant resin anchoring agent, it is characterised in that modified coal ash uses following technique
Preparation: by methyl-silicone oil, Methyl Hydrogen Polysiloxane Fluid, span, tween, glacial acetic acid, water mix and blend, adds triethanolamine, polyethylene
Alcohol mix homogeneously, adds flyash mixed grinding, dry, pulverize and obtain modified coal ash.
Waterproof ageing-resistant resin anchoring agent the most according to claim 1 or claim 2, it is characterised in that modified coal ash uses as follows
Prepared by technique: by weight by 5-15 part methyl-silicone oil, 1-5 part Methyl Hydrogen Polysiloxane Fluid, 1-2 part span, 1-2 part tween, 0.2-
0.6 part of glacial acetic acid, 30-60 part water mix and blend, addition 0.1-0.8 part triethanolamine, 0.5-1.2 part polyvinyl alcohol are equal
Even, add 20-40 part flyash mixed grinding, dry, pulverize and obtain modified coal ash.
4. according to ageing-resistant resin anchoring agent waterproof described in any one of claim 1-3, it is characterised in that modified coal ash uses
Prepared by following technique: by weight by 5-15 part methyl-silicone oil, 1-5 part Methyl Hydrogen Polysiloxane Fluid, 1-2 part span, 1-2 part tween,
0.2-0.6 part glacial acetic acid, 30-60 part water mix and blend 20-50min, whipping temp is 40-50 DEG C, adds 0.1-0.8 part three second
Hydramine, 0.5-1.2 part polyvinyl alcohol are uniform, add 20-40 part flyash mixed grinding 50-100min, and grinding temperature is
55-65 DEG C, dry, pulverize and obtain modified coal ash.
5. according to ageing-resistant resin anchoring agent waterproof described in any one of claim 1-4, it is characterised in that clay and firming agent
Weight ratio is 1:0.25-0.35.
6. according to ageing-resistant resin anchoring agent waterproof described in any one of claim 1-4, it is characterised in that cyclohexanone peroxide two
Butyl ester is stuck with paste and the weight ratio of sodium lignin sulfonate is 15-25:7-9.
7. according to ageing-resistant resin anchoring agent waterproof described in any one of claim 1-4, it is characterised in that modified coal ash, stone
The weight ratio of dibromodiphenyl ether and graphene nanometer sheet is 8-12:2-4:10-13.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610643970.2A CN106243660A (en) | 2016-08-08 | 2016-08-08 | A kind of waterproof ageing-resistant resin anchoring agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610643970.2A CN106243660A (en) | 2016-08-08 | 2016-08-08 | A kind of waterproof ageing-resistant resin anchoring agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106243660A true CN106243660A (en) | 2016-12-21 |
Family
ID=58079173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610643970.2A Pending CN106243660A (en) | 2016-08-08 | 2016-08-08 | A kind of waterproof ageing-resistant resin anchoring agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106243660A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107721290A (en) * | 2017-11-27 | 2018-02-23 | 倪修俊 | Compound thermal insulation mortar of the wheat stalk granular polystyrene of a kind of waterproof fireproofing and preparation method thereof |
| CN108048017A (en) * | 2017-11-30 | 2018-05-18 | 安徽坤大化学锚固有限公司 | A kind of mining flame-retardant type polyurethane Anchor Agent and its preparation process |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1876713A (en) * | 2006-06-30 | 2006-12-13 | 王厚东 | Flame-retarded resin anchoring agent |
| CN1876714A (en) * | 2006-06-30 | 2006-12-13 | 王厚东 | Antistatic resin anchoring agent |
| CN101508540A (en) * | 2009-04-07 | 2009-08-19 | 晋城宏圣科威矿用材料有限公司 | Resin mastic cement for anchorage agent and anchorage agent thereof |
-
2016
- 2016-08-08 CN CN201610643970.2A patent/CN106243660A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1876713A (en) * | 2006-06-30 | 2006-12-13 | 王厚东 | Flame-retarded resin anchoring agent |
| CN1876714A (en) * | 2006-06-30 | 2006-12-13 | 王厚东 | Antistatic resin anchoring agent |
| CN101508540A (en) * | 2009-04-07 | 2009-08-19 | 晋城宏圣科威矿用材料有限公司 | Resin mastic cement for anchorage agent and anchorage agent thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张雄: "《建筑功能外加剂》", 31 January 2004, 化学工业出版社 * |
| 郑重远，黄乃炯: "《树脂锚杆及锚固剂》", 30 April 1983, 煤炭工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107721290A (en) * | 2017-11-27 | 2018-02-23 | 倪修俊 | Compound thermal insulation mortar of the wheat stalk granular polystyrene of a kind of waterproof fireproofing and preparation method thereof |
| CN108048017A (en) * | 2017-11-30 | 2018-05-18 | 安徽坤大化学锚固有限公司 | A kind of mining flame-retardant type polyurethane Anchor Agent and its preparation process |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101303136B1 (en) | Acrylic copolymer injecting materials and repairing method of concrete structure by using cementitious acrylic copolymer injecting materials | |
| CN104119853B (en) | A kind of preparation method of air foam fracturing fluid | |
| CN101633573A (en) | Water-emulsion organic silicon composited acrylic acid modified asphalt cement-base waterproof coating and preparation method thereof | |
| CN106243660A (en) | A kind of waterproof ageing-resistant resin anchoring agent | |
| CN207229079U (en) | A kind of high-power ultrasonic oil formation treatment system | |
| CN101265800A (en) | Oil layer wax-condensing type oil reservoir mining method | |
| CN101240702B (en) | Oil layer coagulating type oil reservoir mining method | |
| JPH10513512A (en) | Compositions and methods for stabilizing underground structures | |
| CN108084881B (en) | Non-cured rubber asphalt waterproof coating for wet ground and preparation method thereof | |
| CN104099074A (en) | Volume fracturing reconstruction crack plugging agent and water plugging construction method | |
| CN108329891A (en) | A kind of waterproof roll adhesive and preparation method thereof | |
| CN104371524A (en) | Heat-insulation fireproof water-based paint and preparation method thereof | |
| CN108384527B (en) | Mud cake cleaning fluid for deepwater synthetic base drilling fluid and application thereof | |
| CN105038593B (en) | A kind of aqueous uncured rubber-asphalt coating and preparation method thereof | |
| CN101240701B (en) | Non-strong water-sensitive special oil reservoir heating power oil extraction method | |
| CN105273507A (en) | Reactive waterproof coating | |
| CN105860625A (en) | Phastgel plugging agent | |
| CN102442805B (en) | On-site molded waterproof and heat-insulating material and construction method thereof | |
| CN105110688A (en) | Novel tile sticking mortar admixture and environment-friendly cement | |
| CN105199693B (en) | A kind of oil base gel leak stopping slurry | |
| Zhao et al. | Application status and research progress of CO2 fracturing fluid in petroleum engineering and its enlightenment to China: A mini-review | |
| CN101210174B (en) | Nano oil displacement agent for thermodynamic oil extraction process | |
| CN109505575B (en) | Combustible plugging method for water flooding fire flooding oil reservoir | |
| CN106189157A (en) | A kind of fire-resistant waterproof resin anchoring agent | |
| CN106367001A (en) | Resin adhesive with high waterproofness and high durability |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161221 |
|
| RJ01 | Rejection of invention patent application after publication |