CN106367001A - Resin adhesive with high waterproofness and high durability - Google Patents
Resin adhesive with high waterproofness and high durability Download PDFInfo
- Publication number
- CN106367001A CN106367001A CN201610747831.4A CN201610747831A CN106367001A CN 106367001 A CN106367001 A CN 106367001A CN 201610747831 A CN201610747831 A CN 201610747831A CN 106367001 A CN106367001 A CN 106367001A
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- resin adhesive
- modified pitch
- good endurance
- npe
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a resin adhesive with high waterproofness and high durability. The resin adhesive is prepared from the following raw materials in parts by weight: 40 to 90 parts of unsaturated resin 189, 5 to 15 parts of modified asphalt, 1 to 8 parts of natural gas-based slot black, 2 to 4 parts of cotton flocks, 5 to 15 parts of glass fibers, 5 to 15 parts of mica powder, 1 to 8 parts of hollow microspheres, 5 to 12 parts of titanium dioxide powder, 2 to 6 parts of calcined clay, 5 to 15 parts of organic bentonite, 2 to 7 parts of wollastonite powder, 2 to 10 parts of 1,1-di(tert-butylperoxy)cyclohexane, 5 to 15 parts of microcrystalline wax, 1 to 6 parts of hydroxyethyl methylcellulose, 2 to 8 parts of fumed silica and 50 to 120 parts of water. The resin adhesive provided by the invention is extremely high in waterproofness and high in corrosion resistance and durability.
Description
Technical field
The present invention relates to resin adhesive technical field, more particularly, to a kind of waterproof good endurance resin adhesive.
Background technology
Resin adhesive is with unsaturated-resin as bonding agent, and using agstone etc. as reinforcing material, it is suitable to be equipped with
Promote initiator system, the resin-bonded mastic of production can obtain high intensity and fast solidification effect.In technical field of electronic encapsulation
The application of resin adhesive widely, but current resin adhesive waterproof, anti-corrosion and endurance quality also cannot meet demand,
In urgent need to be improved.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of waterproof good endurance resin adhesive, prevents
Aqueouss are fabulous, anti-corrosion, excellent durability.
A kind of waterproof good endurance resin adhesive proposed by the present invention, its raw material includes by weight: 189 unsaturated trees
40～90 parts of fat, 5～15 parts of modified pitch, 1～8 part of natural gas-based channel black, 2～4 parts of flocking, 5～15 parts of glass fibre, mica powder
5～15 parts, 1～8 part of hollow microsphere, 5～12 parts of titanium dioxide, 2～6 parts of calcinated argil, 5～15 parts of organobentonite, wollastonite
2～7 parts of powder, cyclohexanone peroxide dibutyl ester pastes 2～10 parts, 5～15 parts of microcrystalline wax, 1～6 part of hydroxyethylmethyl-cellulose,
2～8 parts of aerosil, 50～120 parts of water.
Preferably, the weight ratio of 189 unsaturated-resins, modified pitch, cyclohexanone peroxide dibutyl ester paste is for 50～80:8
～12:4～8.
Preferably, the weight of modified pitch, microcrystalline wax, natural gas-based channel black, flocking, glass fibre, mica powder, hollow microsphere
Amount ratio is 8～12:6～10:3～7:2.5～3.5:6～10:10～12:3～5.
Preferably, modified pitch, calcinated argil, organobentonite, wollastonite in powder weight than for 8～12:3～5:8～
12:4～6.
Preferably, modified pitch adopts following technique preparation: Colophonium, octadecyl trimethyl ammonium chloride, nonyl phenol are gathered
After oxygen vinyl Ether, polyvinyl alcohol, water mix, colloid mill grinds and obtains prefabricated material；By s-B-S block altogether
Polymers, toluene mix and blend, add hexadecyltrimethylammonium chloride, NPE, polyvinyl alcohol, methylol fine
Dimension plain sodium stirring, adds prefabricated material, cumyl peroxide, organobentonite stirring to obtain modified pitch.
Preferably, modified pitch adopts following technique preparation: Colophonium, octadecyl trimethyl ammonium chloride, nonyl phenol are gathered
After oxygen vinyl Ether, polyvinyl alcohol, water mix, colloid mill grinds 20～50min, obtains prefabricated material；By styrene-butadiene-benzene
Ethylene block copolymer, toluene mix and blend 20～50min, whipping temp is 50～70 DEG C, adds cetyl trimethyl chlorine
Change ammonium, NPE, polyvinyl alcohol, Carboxymethyl cellulose sodium stirring 15～45min, whipping temp is 60～80
DEG C, add prefabricated material, cumyl peroxide, organobentonite to stir 5～15min, obtain modified pitch.
Preferably, modified pitch adopts following technique preparation: by weight by 20～50 parts of Colophoniumes, 1～2 part of octadecyl
After trimethyl ammonium chloride, 1～2 part of NPE, 2～5 parts of polyvinyl alcohol, 1～5 part of water mix, colloid mill grinds
20～50min, obtains prefabricated material；By 5～15 parts of styrene butadiene styrene block copolymer (SBS), 30～60 parts of toluene mixing
Stirring 20～50min, whipping temp is 50～70 DEG C, adds 1～2 part of hexadecyltrimethylammonium chloride, 0.4～0.9 part of nonyl
Base phenol polyethenoxy ether, 0.1～0.6 part of polyvinyl alcohol, 1～5 part of Carboxymethyl cellulose sodium stir 15～45min, whipping temp
For 60～80 DEG C, add prefabricated material, 1～2 part of cumyl peroxide, 5～15 parts of organobentonites to stir 5～15min, obtain
Modified pitch.
The present invention carries out mating reaction using 189 unsaturated-resins, modified pitch and cyclohexanone peroxide dibutyl ester paste, resists
Compressive Strength is high, and cohesive force is extremely strong, and has excellent waterproof, anti-corrosion and endurance quality；In modified pitch, Colophonium is through ten
Eight alkyl trimethyl ammonium chlorides, NPE, after polyvinyl alcohol pretreatment, and through cetyl trimethyl chlorination
S-B-S block after ammonium, NPE, polyvinyl alcohol, Carboxymethyl cellulose sodium are processed is common
Polymers acts on, in the tentatively modified swelling network-like structure in styrene butadiene styrene block copolymer (SBS) of Colophonium
Portion, forms inierpeneirating network structure, and crosslinked under cumyl peroxide with organobentonite, makes the water proofing property pole of the present invention
Good, anti-corrosion, excellent durability；Modified pitch and microcrystalline wax synergism, with natural gas-based channel black, flocking, glass fibre, cloud
Between female powder, hollow microsphere, intersolubility is good, and bond strength is high, makes the density of the present invention and mechanical strength high, waterproof and anti-corrosive properties
Can further enhance；And modified pitch and titanium dioxide, calcinated argil, organobentonite, wollastonite in powder mating reaction, can be to gap
Effectively filled, waterproof, seepage control permeability can be fabulous, and low cost.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of waterproof good endurance resin adhesive proposed by the present invention, its raw material includes by weight: 189 unsaturated trees
40 parts of fat, 15 parts of modified pitch, 1 part of natural gas-based channel black, 4 parts of flocking, 5 parts of glass fibre, 15 parts of mica powder, 1 part of hollow microsphere,
12 parts of titanium dioxide, 2 parts of calcinated argil, 15 parts of organobentonite, 2 parts of wollastonite in powder, cyclohexanone peroxide dibutyl ester pastes 10 parts, micro-
5 parts of spar wax, 6 parts of hydroxyethylmethyl-cellulose, 2 parts of aerosil, 120 parts of water.
Embodiment 2
A kind of waterproof good endurance resin adhesive proposed by the present invention, its raw material includes by weight: 189 unsaturated trees
90 parts of fat, 5 parts of modified pitch, 8 parts of natural gas-based channel black, 2 parts of flocking, 15 parts of glass fibre, 5 parts of mica powder, 8 parts of hollow microsphere,
5 parts of titanium dioxide, 6 parts of calcinated argil, 5 parts of organobentonite, 7 parts of wollastonite in powder, cyclohexanone peroxide dibutyl ester pastes 2 parts, crystallite
15 parts of paraffin, 1 part of hydroxyethylmethyl-cellulose, 8 parts of aerosil, 50 parts of water.
Modified pitch adopts following technique preparation: by Colophonium, octadecyl trimethyl ammonium chloride, Nonyl pheno
After ether, polyvinyl alcohol, water mix, colloid mill grinds and obtains prefabricated material；By styrene butadiene styrene block copolymer (SBS), first
Benzene mix and blend, adds hexadecyltrimethylammonium chloride, NPE, polyvinyl alcohol, Carboxymethyl cellulose sodium
Stirring, adds prefabricated material, cumyl peroxide, organobentonite stirring to obtain modified pitch.
Embodiment 3
A kind of waterproof good endurance resin adhesive proposed by the present invention, its raw material includes by weight: 189 unsaturated trees
50 parts of fat, 12 parts of modified pitch, 3 parts of natural gas-based channel black, 3.5 parts of flocking, 6 parts of glass fibre, 12 parts of mica powder, hollow microsphere 3
Part, 10 parts of titanium dioxide, 3 parts of calcinated argil, 12 parts of organobentonite, 4 parts of wollastonite in powder, cyclohexanone peroxide dibutyl ester pastes 8 parts,
6 parts of microcrystalline wax, 4 parts of hydroxyethylmethyl-cellulose, 4 parts of aerosil, 100 parts of water.
Modified pitch adopts following technique preparation: by Colophonium, octadecyl trimethyl ammonium chloride, Nonyl pheno
After ether, polyvinyl alcohol, water mix, colloid mill grinds 35min, obtains prefabricated material；By s-B-S block altogether
Polymers, toluene mix and blend 35min, whipping temp is 60 DEG C, adds hexadecyltrimethylammonium chloride, Nonyl pheno
Ether, polyvinyl alcohol, Carboxymethyl cellulose sodium stirring 30min, whipping temp be 70 DEG C, add prefabricated material, cumyl peroxide,
Organobentonite stirs 10min, obtains modified pitch.
Embodiment 4
A kind of waterproof good endurance resin adhesive proposed by the present invention, its raw material includes by weight: 189 unsaturated trees
80 parts of fat, 8 parts of modified pitch, 7 parts of natural gas-based channel black, 2.5 parts of flocking, 10 parts of glass fibre, 10 parts of mica powder, hollow microsphere 5
Part, 8 parts of titanium dioxide, 5 parts of calcinated argil, 8 parts of organobentonite, 6 parts of wollastonite in powder, cyclohexanone peroxide dibutyl ester pastes 4 parts, micro-
10 parts of spar wax, 2 parts of hydroxyethylmethyl-cellulose, 6 parts of aerosil, 80 parts of water.
Modified pitch adopts the preparation of following technique: by weight by 20 parts of Colophoniumes, 2 parts of octadecyl trimethyl ammonium chloride, 1
After part NPE, 5 parts of polyvinyl alcohol, 1 part of water mix, colloid mill grinds 50min, obtains prefabricated material；By 5 parts of benzene
Ethylene-butadiene-styrene block copolymer, 60 parts of toluene mix and blend 20min, whipping temp is 70 DEG C, adds 1 part 16
Alkyl trimethyl ammonium chloride, 0.9 part of NPE, 0.1 part of polyvinyl alcohol, 5 parts of Carboxymethyl cellulose sodium stirrings
15min, whipping temp is 80 DEG C, adds prefabricated material, 1 part of cumyl peroxide, 15 parts of organobentonites to stir 5min, obtains
Modified pitch.
Embodiment 5
A kind of waterproof good endurance resin adhesive proposed by the present invention, its raw material includes by weight: 189 unsaturated trees
60 parts of fat, 10 parts of modified pitch, 5 parts of natural gas-based channel black, 3 parts of flocking, 8 parts of glass fibre, 11 parts of mica powder, 4 parts of hollow microsphere,
9 parts of titanium dioxide, 4 parts of calcinated argil, 10 parts of organobentonite, 5 parts of wollastonite in powder, cyclohexanone peroxide dibutyl ester pastes 6 parts, crystallite
8 parts of paraffin, 3 parts of hydroxyethylmethyl-cellulose, 5 parts of aerosil, 90 parts of water.
Modified pitch adopts the preparation of following technique: by weight by 50 parts of Colophoniumes, 1 part of octadecyl trimethyl ammonium chloride, 2
After part NPE, 2 parts of polyvinyl alcohol, 5 parts of water mix, colloid mill grinds 20min, obtains prefabricated material；By 15 parts
Styrene butadiene styrene block copolymer (SBS), 30 parts of toluene mix and blend 50min, whipping temp is 50 DEG C, adds 2 part ten
Six alkyl trimethyl ammonium chlorides, 0.4 part of NPE, 0.6 part of polyvinyl alcohol, 1 part of Carboxymethyl cellulose sodium stirring
45min, whipping temp is 60 DEG C, adds prefabricated material, 2 parts of cumyl peroxides, 5 parts of organobentonites to stir 15min, obtains
Modified pitch.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (7)
1. a kind of waterproof good endurance resin adhesive is it is characterised in that its raw material includes by weight: 189 unsaturated-resins
40～90 parts, 5～15 parts of modified pitch, 1～8 part of natural gas-based channel black, 2～4 parts of flocking, 5～15 parts of glass fibre, mica powder 5
～15 parts, 1～8 part of hollow microsphere, 5～12 parts of titanium dioxide, 2～6 parts of calcinated argil, 5～15 parts of organobentonite, wollastonite in powder
2～7 parts, cyclohexanone peroxide dibutyl ester pastes 2～10 parts, 5～15 parts of microcrystalline wax, 1～6 part of hydroxyethylmethyl-cellulose, gas
2～8 parts of aerosil, 50～120 parts of water.
2. according to claim 1 waterproof good endurance resin adhesive it is characterised in that 189 unsaturated-resins, modified drip
Blue or green, cyclohexanone peroxide dibutyl ester paste weight ratio is for 50～80:8～12:4～8.
3. waterproof good endurance resin adhesive according to claim 1 or claim 2 is it is characterised in that modified pitch, microlite
Wax, natural gas-based channel black, flocking, glass fibre, mica powder, hollow microsphere weight than for 8～12:6～10:3～7:2.5～
3.5:6～10:10～12:3～5.
4. according to any one of claim 1-3 waterproof good endurance resin adhesive it is characterised in that modified pitch, forging
The weight ratio burning potter's clay, organobentonite, wollastonite in powder is for 8～12:3～5:8～12:4～6.
5. according to any one of claim 1-4 waterproof good endurance resin adhesive it is characterised in that modified pitch adopt
Following technique preparation: after Colophonium, octadecyl trimethyl ammonium chloride, NPE, polyvinyl alcohol, water mixing,
Colloid mill grinds and obtains prefabricated material；By styrene butadiene styrene block copolymer (SBS), toluene mix and blend, add hexadecane
Base trimethyl ammonium chloride, NPE, polyvinyl alcohol, Carboxymethyl cellulose sodium stirring, add prefabricated material, peroxidating
Diisopropylbenzene (DIPB), organobentonite stirring obtain modified pitch.
6. according to any one of claim 1-5 waterproof good endurance resin adhesive it is characterised in that modified pitch adopt
Following technique preparation: after Colophonium, octadecyl trimethyl ammonium chloride, NPE, polyvinyl alcohol, water mixing,
Colloid mill grinds 20～50min, obtains prefabricated material；By styrene butadiene styrene block copolymer (SBS), toluene mix and blend
20～50min, whipping temp is 50～70 DEG C, adds hexadecyltrimethylammonium chloride, NPE, polyethylene
Alcohol, Carboxymethyl cellulose sodium stir 15～45min, whipping temp be 60～80 DEG C, add prefabricated material, cumyl peroxide,
Organobentonite stirs 5～15min, obtains modified pitch.
7. according to any one of claim 1-6 waterproof good endurance resin adhesive it is characterised in that modified pitch adopt
Following technique preparation: by weight 20～50 parts of Colophoniumes, 1～2 part of octadecyl trimethyl ammonium chloride, 1～2 part of nonyl phenol are gathered
After oxygen vinyl Ether, 2～5 parts of polyvinyl alcohol, 1～5 part of water mix, colloid mill grinds 20～50min, obtains prefabricated material；By 5～15
Part styrene butadiene styrene block copolymer (SBS), 30～60 parts of toluene mix and blend 20～50min, whipping temp is 50～
70 DEG C, add 1～2 part of hexadecyltrimethylammonium chloride, 0.4～0.9 part of NPE, 0.1～0.6 part of poly- second
Enol, 1～5 part of Carboxymethyl cellulose sodium stir 15～45min, and whipping temp is 60～80 DEG C, adds prefabricated material, 1～2 part of mistake
Oxidation diisopropylbenzene (DIPB), 5～15 parts of organobentonites stir 5～15min, obtain modified pitch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610747831.4A CN106367001A (en) | 2016-08-27 | 2016-08-27 | Resin adhesive with high waterproofness and high durability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610747831.4A CN106367001A (en) | 2016-08-27 | 2016-08-27 | Resin adhesive with high waterproofness and high durability |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106367001A true CN106367001A (en) | 2017-02-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610747831.4A Pending CN106367001A (en) | 2016-08-27 | 2016-08-27 | Resin adhesive with high waterproofness and high durability |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106367001A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107524064A (en) * | 2017-10-13 | 2017-12-29 | 重庆众誉材工科技有限公司 | Multifunction road structure |
| CN107587400A (en) * | 2017-10-13 | 2018-01-16 | 重庆众誉材工科技有限公司 | High abrasion colour road surface structure |
| CN108558272A (en) * | 2018-05-24 | 2018-09-21 | 浙江绣山园林建设有限公司 | A kind of regenerated type road cold-repairing material |
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| CN101100553A (en) * | 2007-08-15 | 2008-01-09 | 戴建华 | Bitumen compositions and preparation method thereof |
| CN101679048A (en) * | 2007-05-31 | 2010-03-24 | 赢创德固赛有限责任公司 | Tackiness agent and sealant systems |
| CN103497729A (en) * | 2013-09-13 | 2014-01-08 | 河南省高速公路实业开发有限公司道路材料中心 | Road sealant for use at normal temperature and preparation method thereof |
| CN105505261A (en) * | 2015-12-16 | 2016-04-20 | 无锡吉进环保科技有限公司 | Novel environment-friendly adhesive |
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| CN101679048A (en) * | 2007-05-31 | 2010-03-24 | 赢创德固赛有限责任公司 | Tackiness agent and sealant systems |
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| CN103497729A (en) * | 2013-09-13 | 2014-01-08 | 河南省高速公路实业开发有限公司道路材料中心 | Road sealant for use at normal temperature and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107524064A (en) * | 2017-10-13 | 2017-12-29 | 重庆众誉材工科技有限公司 | Multifunction road structure |
| CN107587400A (en) * | 2017-10-13 | 2018-01-16 | 重庆众誉材工科技有限公司 | High abrasion colour road surface structure |
| CN107587400B (en) * | 2017-10-13 | 2023-07-04 | 重庆海聚道路材料有限公司 | High wear-resistant color pavement structure |
| CN107524064B (en) * | 2017-10-13 | 2024-01-12 | 义乌市江夏市政工程有限公司 | Multifunctional pavement structure |
| CN108558272A (en) * | 2018-05-24 | 2018-09-21 | 浙江绣山园林建设有限公司 | A kind of regenerated type road cold-repairing material |
| CN108558272B (en) * | 2018-05-24 | 2020-10-09 | 浙江绣山园林建设有限公司 | Regenerative road cold-patch material |
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Application publication date: 20170201 |