CN105505261A - Novel environment-friendly adhesive - Google Patents
Novel environment-friendly adhesive Download PDFInfo
- Publication number
- CN105505261A CN105505261A CN201510952463.2A CN201510952463A CN105505261A CN 105505261 A CN105505261 A CN 105505261A CN 201510952463 A CN201510952463 A CN 201510952463A CN 105505261 A CN105505261 A CN 105505261A
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- China
- Prior art keywords
- parts
- resin
- novel environment
- ziram
- environment friendly
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to a novel environment-friendly adhesive. The novel environment-friendly adhesive is prepared from, by weight, 6-10 parts of epoxy resin, 6-10 parts of unsaturated polyester resin, 3-6 parts of calcium carbonate, 3-9 parts of argil, 3-8 parts of 2-methylaziridine, 3-7 parts of organic peroxide, 4-8 parts of zinc dimethyldithiocarbamate, 1-2 parts of asphalt, 3-5 parts of trimethoxypropylsilane, 5-10 parts of tackifying resin, 15-25 parts of vinyl acetate emulsion, 2-5 parts of extending oil, 4-8 parts of zinc dimethyldithiocarbamate, 3-7 parts of waterborne rosin-modified resin, 2-5 parts of octadecanol, 4-10 parts of acrylic acid, 2-8 parts of melamine and 10-20 parts of paraffin. The novel environment-friendly adhesive does not harm the human health in the use process and can be used for a long term; besides, the adhesive prepared through the method is high in adhesion strength and good in water resistance.
Description
Technical field
The present invention relates to a kind of novel environment friendly tackiness agent.
Background technology
Due to population growth and Economic development, the series of problems affecting resource quality produced the excessive exploitation of resource and unreasonable development, these problems have directly threatened the existence of we and descendants.
At present, the tackiness agent of China is mainly main production raw material with formaldehyde, i.e. urea-formaldehyde resin adhesive, Phenol aldehyde resin and melamine-formaldehyde resin adhesive, its output account for that whole wood-based panel industry sticks with glue agent more than 90%, wherein, urea-formaldehyde resin adhesive due to low cost of manufacture, raw material be easy to get, bonding strength is high, color and luster close to plurality of advantages such as timber, and is subject to the favor of most of artificial board enterprise.But existing sizing agent is very large on the impact of environment, the injury of the formaldehyde simultaneously discharged to human body is larger, people suck for a long time and may cause disease, cause irremediable loss, the one that the sizing agent therefore finding a kind of low toxic and environment-friendly has become people in the urgent need to.
Summary of the invention
The object of the invention is to: for the above-mentioned technical problem existed in prior art, provide a kind of low toxicity low evil, high efficiency, low cost, novel environment friendly tackiness agent applied widely and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of environment-friendly adhesive, configured to form by following ratio of weight and number and comprise: epoxy resin 6 ~ 10 parts, 6 ~ 10 parts, unsaturated polyester paint, 3 ~ 6 parts, calcium carbonate, 3 ~ 9 parts, potter's clay, 2-methylaziridine 3 ~ 8 parts, organo-peroxide 3 ~ 7 parts, ziram 4 ~ 8 parts, pitch 1 ~ 2 part, propyl trimethoxy silicane 3 ~ 5 parts, tackifying resin 5 ~ 10 parts, acetate emulsion 15 ~ 25 parts, extending oil 2 ~ 5 parts, ziram 4 ~ 8 parts, water-based modified rosin resin 3 ~ 7 parts, octadecanol 2 ~ 5 parts, 4 ~ 10 parts, vinylformic acid, trimeric cyanamide 2 ~ 8 parts, 10 ~ 20 parts, paraffin, 5 ~ 10 parts, formic acid, dioctyl pyrophosphate 2 ~ 5 parts.
Further, also comprise Walocel MT 20.000PV 2 ~ 6 parts, zinc dibutyl dithiocarbamate 1 ~ 3 part, 1 ~ 5 part, anti-aging agent, furfuryl alcohol 7 ~ 10 parts, stearic acid 4 ~ 8 parts, ethanol 2 ~ 5 parts, polyoxyethylene glycol 4 ~ 8 parts, tackifier 1 ~ 2 part, vulcanizing agent 2 ~ 4 parts, vinyl acetate copolymer resin 10 ~ 20 parts.
Further, described epoxy resin 8 parts, 8 parts, unsaturated polyester paint, 5 parts, calcium carbonate, 6 parts, potter's clay, 2-methylaziridine 6 parts, organo-peroxide 5 parts, ziram 5 parts, pitch 1.5 parts, propyl trimethoxy silicane 4 parts, tackifying resin 7 parts, acetate emulsion 20 parts, extending oil 3 parts, ziram 5 parts, water-based modified rosin resin 5 parts, 7 parts, octadecanol 3 parts of vinylformic acid, trimeric cyanamide 3 parts, 15 parts, paraffin, 6 parts, formic acid, dioctyl pyrophosphate 3 parts.
Further, described Walocel MT 20.000PV 4 parts, zinc dibutyl dithiocarbamate 2 parts, 4 parts, anti-aging agent, furfuryl alcohol 8 parts, stearic acid 6 parts, ethanol 3 parts, polyoxyethylene glycol 5 parts, tackifier 1 ~ 2 part, vulcanizing agent 3 parts, vinyl acetate copolymer resin 14 parts.
In sum, owing to have employed technique scheme, the invention has the beneficial effects as follows: the present invention can not produce injury to the health of human body in the process used, be a kind of can the environment-protective adhesive of life-time service.And the tackiness agent prepared by this method has that bonding strength is higher, water tolerance is better, thermotolerance is splendid, solidification value is lower and the more excellent feature of corrosionproof protection effect, belong to environmentally friendly tackiness agent.Decrease when the present invention uses a large amount of gas defence making equipment drop into, thus reduce produce cost, ensure workman and user healthy, also there is excellent adhering, snappiness, photostabilization.
Embodiment
All features disclosed in this specification sheets, or the step in disclosed all methods or process, except mutually exclusive feature and/or step, all can combine by any way.
Arbitrary feature disclosed in this specification sheets (comprising any accessory claim and summary), unless specifically stated otherwise, all can be replaced by other equivalences or the alternative features with similar object.That is, unless specifically stated otherwise, each feature is an example in a series of equivalence or similar characteristics.
A kind of environment-friendly adhesive, configured to form by following ratio of weight and number and comprise: epoxy resin 6 ~ 10 parts, 6 ~ 10 parts, unsaturated polyester paint, 3 ~ 6 parts, calcium carbonate, 3 ~ 9 parts, potter's clay, 2-methylaziridine 3 ~ 8 parts, organo-peroxide 3 ~ 7 parts, ziram 4 ~ 8 parts, pitch 1 ~ 2 part, propyl trimethoxy silicane 3 ~ 5 parts, tackifying resin 5 ~ 10 parts, acetate emulsion 15 ~ 25 parts, extending oil 2 ~ 5 parts, ziram 4 ~ 8 parts, water-based modified rosin resin 3 ~ 7 parts, octadecanol 2 ~ 5 parts, 4 ~ 10 parts, vinylformic acid, trimeric cyanamide 2 ~ 8 parts, 10 ~ 20 parts, paraffin, 5 ~ 10 parts, formic acid, dioctyl pyrophosphate 2 ~ 5 parts.
Further, also comprise Walocel MT 20.000PV 2 ~ 6 parts, zinc dibutyl dithiocarbamate 1 ~ 3 part, 1 ~ 5 part, anti-aging agent, furfuryl alcohol 7 ~ 10 parts, stearic acid 4 ~ 8 parts, ethanol 2 ~ 5 parts, polyoxyethylene glycol 4 ~ 8 parts, tackifier 1 ~ 2 part, vulcanizing agent 2 ~ 4 parts, vinyl acetate copolymer resin 10 ~ 20 parts.
Further, described epoxy resin 8 parts, 8 parts, unsaturated polyester paint, 5 parts, calcium carbonate, 6 parts, potter's clay, 2-methylaziridine 6 parts, organo-peroxide 5 parts, ziram 5 parts, pitch 1.5 parts, propyl trimethoxy silicane 4 parts, tackifying resin 7 parts, acetate emulsion 20 parts, extending oil 3 parts, ziram 5 parts, water-based modified rosin resin 5 parts, octadecanol 3 parts, 7 parts, vinylformic acid, trimeric cyanamide 3 parts, 15 parts, paraffin, 6 parts, formic acid, dioctyl pyrophosphate 3 parts.
Further, described Walocel MT 20.000PV 4 parts, zinc dibutyl dithiocarbamate 2 parts, 4 parts, anti-aging agent, furfuryl alcohol 8 parts, stearic acid 6 parts, ethanol 3 parts, polyoxyethylene glycol 5 parts, tackifier 1 ~ 2 part, vulcanizing agent 3 parts, vinyl acetate copolymer resin 14 parts.
A preparation method for environment-friendly adhesive, its concrete steps are as follows:
(1) by epoxy resin 6 ~ 10 parts, 6 ~ 10 parts, unsaturated polyester paint, 3 ~ 6 parts, calcium carbonate, 3 ~ 9 parts, potter's clay, 2-methylaziridine 3 ~ 8 parts, organo-peroxide 3 ~ 7 parts, ziram 4 ~ 8 parts, pitch 1 ~ 2 part, heats to 95 DEG C of dissolvings after propyl trimethoxy silicane 3 ~ 5 parts mixing, fully, insulation is after 1-2 hour, is cooled to 60 DEG C;
(2) in the mixture in step (1), tackifying resin 5 ~ 10 parts is added again, acetate emulsion 15 ~ 25 parts, fully be uniformly mixed, then add extending oil 2 ~ 5 parts, after ziram 4 ~ 8 parts mixing, be warming up to 95 DEG C.
(3) in the mixture in step (2), add water-based modified rosin resin 3 ~ 7 parts again, octadecanol 2 ~ 5 parts, 4 ~ 10 parts, vinylformic acid, 10 ~ 20 parts, paraffin, dioctyl pyrophosphate 2 ~ 5 parts, react 8 hours and be cooled to 40 DEG C
(4) add in the mixture in step (3) again after trimeric cyanamide 2 ~ 8 parts stirs 30 minutes to 40 minutes with 5 ~ 10 parts, formic acid and namely obtain this environment-friendly adhesive.
Further, described step (4) also adds Walocel MT 20.000PV 2 ~ 6 parts, zinc dibutyl dithiocarbamate 1 ~ 3 part, 1 ~ 5 part, anti-aging agent, furfuryl alcohol 7 ~ 10 parts, stearic acid 4 ~ 8 parts, ethanol 2 ~ 5 parts, polyoxyethylene glycol 4 ~ 8 parts, tackifier 1 ~ 2 part, vulcanizing agent 2 ~ 4 parts, vinyl acetate copolymer resin 10 ~ 20 parts.
Above-described specific embodiment, further describes object of the present invention, technical scheme and beneficial effect, and institute it should be understood that and the foregoing is only specific embodiments of the invention, is not limited to the present invention.The present invention expands to any new feature of disclosing in this manual or any combination newly, and the step of the arbitrary new method disclosed or process or any combination newly.
Claims (4)
1. a novel environment friendly tackiness agent, it is characterized in that: formed by following ratio of weight and number configuration and comprise: epoxy resin 6 ~ 10 parts, 6 ~ 10 parts, unsaturated polyester paint, 3 ~ 6 parts, calcium carbonate, 3 ~ 9 parts, potter's clay, 2-methylaziridine 3 ~ 8 parts, organo-peroxide 3 ~ 7 parts, ziram 4 ~ 8 parts, pitch 1 ~ 2 part, propyl trimethoxy silicane 3 ~ 5 parts, tackifying resin 5 ~ 10 parts, acetate emulsion 15 ~ 25 parts, extending oil 2 ~ 5 parts, ziram 4 ~ 8 parts, water-based modified rosin resin 3 ~ 7 parts, octadecanol 2 ~ 5 parts, 4 ~ 10 parts, vinylformic acid, trimeric cyanamide 2 ~ 8 parts, 10 ~ 20 parts, paraffin, 5 ~ 10 parts, formic acid, dioctyl pyrophosphate 2 ~ 5 parts.
2. novel environment friendly tackiness agent according to claim 1, it is characterized in that, also comprise Walocel MT 20.000PV 2 ~ 6 parts, zinc dibutyl dithiocarbamate 1 ~ 3 part, 1 ~ 5 part, anti-aging agent, furfuryl alcohol 7 ~ 10 parts, stearic acid 4 ~ 8 parts, ethanol 2 ~ 5 parts, polyoxyethylene glycol 4 ~ 8 parts, tackifier 1 ~ 2 part, vulcanizing agent 2 ~ 4 parts, vinyl acetate copolymer resin 10 ~ 20 parts.
3. novel environment friendly tackiness agent according to claim 1, it is characterized in that, described epoxy resin 8 parts, 8 parts, unsaturated polyester paint, 5 parts, calcium carbonate, 6 parts, potter's clay, 2-methylaziridine 6 parts, organo-peroxide 5 parts, ziram 5 parts, pitch 1.5 parts, propyl trimethoxy silicane 4 parts, tackifying resin 7 parts, acetate emulsion 20 parts, extending oil 3 parts, ziram 5 parts, water-based modified rosin resin 5 parts, octadecanol 3 parts, 7 parts, vinylformic acid, trimeric cyanamide 3 parts, 15 parts, paraffin, 6 parts, formic acid, dioctyl pyrophosphate 3 parts.
4. novel environment friendly tackiness agent according to claim 2, it is characterized in that, described Walocel MT 20.000PV 4 parts, zinc dibutyl dithiocarbamate 2 parts, 4 parts, anti-aging agent, furfuryl alcohol 8 parts, stearic acid 6 parts, ethanol 3 parts, polyoxyethylene glycol 5 parts, tackifier 1 ~ 2 part, vulcanizing agent 3 parts, vinyl acetate copolymer resin 14 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510952463.2A CN105505261A (en) | 2015-12-16 | 2015-12-16 | Novel environment-friendly adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510952463.2A CN105505261A (en) | 2015-12-16 | 2015-12-16 | Novel environment-friendly adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105505261A true CN105505261A (en) | 2016-04-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510952463.2A Pending CN105505261A (en) | 2015-12-16 | 2015-12-16 | Novel environment-friendly adhesive |
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| Country | Link |
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| CN (1) | CN105505261A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106147679A (en) * | 2016-07-14 | 2016-11-23 | 陆锦莹 | A kind of wood-based plate water resistant, high temperature resistant epoxy resin adhesive and preparation method thereof |
| CN106367001A (en) * | 2016-08-27 | 2017-02-01 | 安徽天瞳智能科技有限公司 | Resin adhesive with high waterproofness and high durability |
| CN106833440A (en) * | 2017-02-23 | 2017-06-13 | 郭钦 | A kind of strong high temperature resistant type chemical glue formula of cementability and its preparation technology |
| CN107629409A (en) * | 2017-09-25 | 2018-01-26 | 广西众昌树脂有限公司 | High-temperature resisting liquid resin |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050288437A1 (en) * | 2004-06-28 | 2005-12-29 | Tesa Aktiengesellschaft | Heat-activable adhesive tape for bonding electronic components and conductor tracks |
| CN103965796A (en) * | 2013-09-04 | 2014-08-06 | 杨学荣 | Formaldehyde-free wood adhesive film |
| CN104371621A (en) * | 2014-10-30 | 2015-02-25 | 田琳琳 | Low-toxicity environment-friendly adhesive |
-
2015
- 2015-12-16 CN CN201510952463.2A patent/CN105505261A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050288437A1 (en) * | 2004-06-28 | 2005-12-29 | Tesa Aktiengesellschaft | Heat-activable adhesive tape for bonding electronic components and conductor tracks |
| CN103965796A (en) * | 2013-09-04 | 2014-08-06 | 杨学荣 | Formaldehyde-free wood adhesive film |
| CN104371621A (en) * | 2014-10-30 | 2015-02-25 | 田琳琳 | Low-toxicity environment-friendly adhesive |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106147679A (en) * | 2016-07-14 | 2016-11-23 | 陆锦莹 | A kind of wood-based plate water resistant, high temperature resistant epoxy resin adhesive and preparation method thereof |
| CN106367001A (en) * | 2016-08-27 | 2017-02-01 | 安徽天瞳智能科技有限公司 | Resin adhesive with high waterproofness and high durability |
| CN106833440A (en) * | 2017-02-23 | 2017-06-13 | 郭钦 | A kind of strong high temperature resistant type chemical glue formula of cementability and its preparation technology |
| CN107629409A (en) * | 2017-09-25 | 2018-01-26 | 广西众昌树脂有限公司 | High-temperature resisting liquid resin |
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Application publication date: 20160420 |