CN106280350A - A kind of good toughness long resin in service life Anchor Agent - Google Patents
A kind of good toughness long resin in service life Anchor Agent Download PDFInfo
- Publication number
- CN106280350A CN106280350A CN201610642244.9A CN201610642244A CN106280350A CN 106280350 A CN106280350 A CN 106280350A CN 201610642244 A CN201610642244 A CN 201610642244A CN 106280350 A CN106280350 A CN 106280350A
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- parts
- coal ash
- service life
- good toughness
- anchor agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses a kind of good toughness long resin in service life Anchor Agent, including major ingredient and curing system, major ingredient is 10:0.5 2.5 with the weight ratio of curing system；Major ingredient includes by weight: bisphenol A-type unsaturated polyester (UP) 100 parts, modified coal ash 15 25 parts, cobaltous linoleate 12 parts, dimethyl-p-toluidine 37 parts, silica flour 25 45 parts, aerosil 35 parts, 2 hydroxyl 4 methoxy benzophenones 0.4 0.8 parts, aphthenic acids ketone 1.5 2.5 parts, diphenylamines 0.3 0.7 parts, dimethyl phthalate 1 1.6 parts, 1.5 2.5 parts of antioxidant；Curing system includes by weight: diethylene glycol 25 45 parts, 0.5 0.8 parts of potassium permanganate, disproportionated rosin 1.5 2.5 parts, medical stone powder 25 45 parts, benzoyl peroxide 25 55 parts, carboxymethyl cellulose 10 20 parts, 70 130 parts of water.
Description
Technical field
The present invention relates to Anchor Agent technical field, particularly relate to a kind of good toughness long resin in service life Anchor Agent.
Background technology
Resin anchoring agent is applicable to mine, underground engineering and side slope, bolt-spary supports, mine vertical shaft equipment installation, building structure
Part connects and reinforcing, equipment Foundations anchoring etc..Resin anchoring agent is overall along with the development of anchoring support and the innovation of construction equipment
Trend is to Heat stability is good, and storage period is long, and good waterproof performance develops, the region of some complex geologic conditions, particularly underground simultaneously
The direction that the oriented major diameter of engineering, Hydraulic and Hydro-Power Engineering, big anchor are deep, be easy to Shi Hanzhang is developed, and wants in some engineering construction
Asking resin anchoring agent to be also required to have extremely strong toughness, existing resin anchoring agent is not met by these demands.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of good toughness long resin in service life anchoring
Agent, thermally-stabilised good, storage period is long, and toughness, water resistance are good, and service life is long.
A kind of good toughness long resin in service life Anchor Agent that the present invention proposes, including major ingredient and curing system, major ingredient with
The weight ratio of curing system is 10:0.5-2.5；Major ingredient includes by weight: bisphenol A-type unsaturated polyester (UP) 100 parts, modified fine coal
Ash 15-25 part, cobaltous linoleate 1-2 part, dimethyl-p-toluidine 3-7 part, silica flour 25-45 part, aerosil 3-5 part,
ESCALOL 567 0.4-0.8 part, aphthenic acids ketone 1.5-2.5 part, diphenylamines 0.3-0.7 part, phthalic acid
Dimethyl ester 1-1.6 part, antioxidant 1.5-2.5 part；Curing system includes by weight: diethylene glycol 25-45 part, potassium permanganate 0.5-
0.8 part, disproportionated rosin 1.5-2.5 part, medical stone powder 25-45 part, benzoyl peroxide 25-55 part, carboxymethyl cellulose 10-20
Part, water 70-130 part.
Preferably, major ingredient is 10:1-2 with the weight ratio of curing system.
Preferably, bisphenol A-type unsaturated polyester (UP), modified coal ash, cobaltous linoleate, the weight ratio of dimethyl-p-toluidine are
100:18-22:1.3-1.7:4-6.
Preferably, ESCALOL 567, aphthenic acids ketone, diphenylamines, the weight of dimethyl phthalate
Ratio is 0.5-0.7:1.7-2.3:0.4-0.6:1.2-1.4.
Preferably, modified coal ash uses following technique to prepare: by octamethylcy-clotetrasiloxane, γ-diethylenetriamine third
Ylmethyl dimethoxysilane, water, dehydrated alcohol mix and blend, heat up, and adds Tetramethylammonium hydroxide stirring, adds flyash
Stirring, filters, and grinds, and dries, and cooling is pulverized and obtained modified coal ash.
Preferably, modified coal ash uses following technique to prepare: by octamethylcy-clotetrasiloxane, γ-diethylenetriamine third
Ylmethyl dimethoxysilane, water, dehydrated alcohol mix and blend 15-35min, be warming up to 80-90 DEG C, adds tetramethyl hydroxide
Ammonium stirring 10-30min, adds flyash stirring 25-65min, filters, and grinds 25-55min, dries 0.8-for 110-120 DEG C
1.6h, cooling, pulverize and obtain modified coal ash.
Preferably, modified coal ash uses following technique to prepare: by weight by 8-12 part octamethylcy-clotetrasiloxane, 2-
3 parts of γ-diethylenetriamine hydroxypropyl methyl dimethoxysilane, 30-60 part water, 10-20 part dehydrated alcohol mix and blend 15-
35min, is warming up to 80-90 DEG C, adds 0.5-1 part Tetramethylammonium hydroxide stirring 10-30min, adds 25-35 part flyash and stir
Mix 25-65min, filter, grind 25-55min, dry 0.8-1.6h, cooling, pulverize and obtain modified coal ash for 110-120 DEG C.
The present invention use bisphenol A-type unsaturated polyester (UP) under dimethyl-p-toluidine, cobaltous linoleate effect with benzoyl peroxide
Formyl solidification polymerization, makes the present invention thermally-stabilised good, and storage period is long, and cured strength is high, adds modified coal ash and enters
Row cooperates, and improves the water resistance of the present invention, significantly extends service life.In modified coal ash, amido silicon oil with
In the process of lapping of flyash, flyash surface produces the newest active group, abundant with the amino group in amido silicon oil
After contact, forming one layer of hydrophobic layer on flyash top layer, not only water resistance is fabulous, and both carry out synergism, makes institute
Obtain the resistance to oxidation of modified coal ash, weatherability, thermostability, crushing resistance performance the most excellent；Modified coal ash and aphthenic acids ketone,
ESCALOL 567, dimethyl phthalate, diphenylamines, potassium permanganate, disproportionated rosin mating reaction, phase
Between Hu, miscible characteristic is excellent, and not only heat stability further enhances, and makes the good toughness of the present invention, not easily broken after shock,
And the silica flour added, medical stone powder not only can reduce cost, improve mechanical performance and the stability of the present invention simultaneously.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of good toughness long resin in service life Anchor Agent that the present invention proposes, including major ingredient and curing system, major ingredient with
The weight ratio of curing system is 10:0.5；Major ingredient includes by weight: bisphenol A-type unsaturated polyester (UP) 100 parts, modified coal ash 25
Part, cobaltous linoleate 1 part, dimethyl-p-toluidine 7 parts, silica flour 25 parts, aerosil 5 parts, 2-hydroxyl-4-methoxyl group two
Benzophenone 0.4 part, aphthenic acids ketone 2.5 parts, diphenylamines 0.3 part, dimethyl phthalate 1.6 parts, 1.5 parts of antioxidant；Solidification
System includes by weight: diethylene glycol 45 parts, 0.5 part of potassium permanganate, disproportionated rosin 2.5 parts, medical stone powder 25 parts, benzoyl peroxide
Formyl 55 parts, carboxymethyl cellulose 10 parts, 130 parts of water.
Embodiment 2
A kind of good toughness long resin in service life Anchor Agent that the present invention proposes, including major ingredient and curing system, major ingredient with
The weight ratio of curing system is 10:2.5；Major ingredient includes by weight: bisphenol A-type unsaturated polyester (UP) 100 parts, modified coal ash 15
Part, cobaltous linoleate 2 parts, dimethyl-p-toluidine 3 parts, silica flour 45 parts, aerosil 3 parts, 2-hydroxyl-4-methoxyl group two
Benzophenone 0.8 part, aphthenic acids ketone 1.5 parts, diphenylamines 0.7 part, dimethyl phthalate 1 part, 2.5 parts of antioxidant；Firming body
System includes by weight: diethylene glycol 25 parts, 0.8 part of potassium permanganate, disproportionated rosin 1.5 parts, medical stone powder 45 parts, benzoyl peroxide first
Acyl 25 parts, carboxymethyl cellulose 20 parts, 70 parts of water.
Modified coal ash uses following technique to prepare: by weight by 8 parts of octamethylcy-clotetrasiloxanes, 3 parts of γ-divinyls
Triamine hydroxypropyl methyl dimethoxysilane, 30 parts of water, 20 parts of dehydrated alcohol mix and blend 15min, be warming up to 90 DEG C, adds 0.5
Part Tetramethylammonium hydroxide stirring 30min, adds 25 parts of flyash stirring 65min, filters, grind 25min, 120 DEG C of drying
0.8h, cooling, pulverize and obtain modified coal ash.
Embodiment 3
A kind of good toughness long resin in service life Anchor Agent that the present invention proposes, including major ingredient and curing system, major ingredient with
The weight ratio of curing system is 10:1；Major ingredient includes by weight: bisphenol A-type unsaturated polyester (UP) 100 parts, modified coal ash 22
Part, cobaltous linoleate 1.3 parts, dimethyl-p-toluidine 6 parts, silica flour 30 parts, aerosil 4.5 parts, 2-hydroxyl-4-methoxy
Base benzophenone 0.5 part, aphthenic acids ketone 2.3 parts, diphenylamines 0.4 part, dimethyl phthalate 1.4 parts, 1.8 parts of antioxidant；
Curing system includes by weight: diethylene glycol 40 parts, 0.6 part of potassium permanganate, disproportionated rosin 2.2 parts, medical stone powder 30 parts, peroxide
Change benzoyl 50 parts, carboxymethyl cellulose 12 parts, 120 parts of water.
Modified coal ash uses following technique to prepare: by weight by 12 parts of octamethylcy-clotetrasiloxanes, 2 parts of γ-diethyls
Alkene triamine hydroxypropyl methyl dimethoxysilane, 60 parts of water, 10 parts of dehydrated alcohol mix and blend 35min, be warming up to 80 DEG C, adds 1
Part Tetramethylammonium hydroxide stirring 10min, adds 35 parts of flyash stirring 25min, filters, grind 55min, 110 DEG C of drying
1.6h, cooling, pulverize and obtain modified coal ash.
Embodiment 4
A kind of good toughness long resin in service life Anchor Agent that the present invention proposes, including major ingredient and curing system, major ingredient with
The weight ratio of curing system is 10:2；Major ingredient includes by weight: bisphenol A-type unsaturated polyester (UP) 100 parts, modified coal ash 18
Part, cobaltous linoleate 1.7 parts, dimethyl-p-toluidine 4 parts, silica flour 40 parts, aerosil 3.5 parts, 2-hydroxyl-4-methoxy
Base benzophenone 0.7 part, aphthenic acids ketone 1.7 parts, diphenylamines 0.6 part, dimethyl phthalate 1.2 parts, 2.2 parts of antioxidant；
Curing system includes by weight: diethylene glycol 30 parts, 0.7 part of potassium permanganate, disproportionated rosin 1.8 parts, medical stone powder 40 parts, peroxide
Change benzoyl 30 parts, carboxymethyl cellulose 18 parts, 80 parts of water.
Modified coal ash uses following technique to prepare: by octamethylcy-clotetrasiloxane, γ-diethylenetriamine hydroxypropyl methyl two
Methoxy silane, water, dehydrated alcohol mix and blend 25min, be warming up to 85 DEG C, adds Tetramethylammonium hydroxide stirring 20min, adds
Enter flyash stirring 45min, filter, grind 40min, dry 1.2h, cooling, pulverize and obtain modified coal ash for 115 DEG C.
Embodiment 5
A kind of good toughness long resin in service life Anchor Agent that the present invention proposes, including major ingredient and curing system, major ingredient with
The weight ratio of curing system is 10:1.5；Major ingredient includes by weight: bisphenol A-type unsaturated polyester (UP) 100 parts, modified coal ash 20
Part, cobaltous linoleate 1.5 parts, dimethyl-p-toluidine 5 parts, silica flour 35 parts, aerosil 4 parts, 2-hydroxyl-4-methoxyl group
Benzophenone 0.6 part, aphthenic acids ketone 2 parts, diphenylamines 0.5 part, dimethyl phthalate 1.3 parts, 2 parts of antioxidant；Firming body
System includes by weight: diethylene glycol 35 parts, 0.65 part of potassium permanganate, disproportionated rosin 2 parts, medical stone powder 35 parts, benzoyl peroxide first
Acyl 40 parts, carboxymethyl cellulose 15 parts, 100 parts of water.
Modified coal ash uses following technique to prepare: by octamethylcy-clotetrasiloxane, γ-diethylenetriamine hydroxypropyl methyl two
Methoxy silane, water, dehydrated alcohol mix and blend, heat up, and adds Tetramethylammonium hydroxide stirring, adds flyash stirring, mistake
Filter, grinds, and dries, and cooling is pulverized and obtained modified coal ash.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. good toughness long resin in a service life Anchor Agent, it is characterised in that include major ingredient and curing system, major ingredient and solidification
The weight ratio of system is 10:0.5-2.5；
Major ingredient includes by weight: bisphenol A-type unsaturated polyester (UP) 100 parts, modified coal ash 15-25 part, cobaltous linoleate 1-2 part,
Dimethyl-p-toluidine 3-7 part, silica flour 25-45 part, aerosil 3-5 part, ESCALOL 567
0.4-0.8 part, aphthenic acids ketone 1.5-2.5 part, diphenylamines 0.3-0.7 part, dimethyl phthalate 1-1.6 part, antioxidant
1.5-2.5 part；
Curing system includes by weight: diethylene glycol 25-45 part, potassium permanganate 0.5-0.8 part, disproportionated rosin 1.5-2.5 part, wheat
Meal stone powder 25-45 part, benzoyl peroxide 25-55 part, carboxymethyl cellulose 10-20 part, water 70-130 part.
Good toughness long resin in service life Anchor Agent the most according to claim 1, it is characterised in that major ingredient and curing system
Weight ratio is 10:1-2.
Good toughness long resin in service life Anchor Agent the most according to claim 1 or claim 2, it is characterised in that bisphenol A-type is unsaturated
Polyester, modified coal ash, cobaltous linoleate, the weight ratio of dimethyl-p-toluidine are 100:18-22:1.3-1.7:4-6.
4. according to good toughness long resin in service life Anchor Agent described in any one of claim 1-3, it is characterised in that 2-hydroxyl-
4-methoxy benzophenone, aphthenic acids ketone, diphenylamines, the weight ratio of dimethyl phthalate are 0.5-0.7:1.7-2.3:
0.4-0.6:1.2-1.4.
5. according to good toughness long resin in service life Anchor Agent described in any one of claim 1-4, it is characterised in that modified fine coal
Ash uses following technique to prepare: by octamethylcy-clotetrasiloxane, γ-diethylenetriamine hydroxypropyl methyl dimethoxysilane, water, nothing
Water-ethanol mix and blend, heats up, and adds Tetramethylammonium hydroxide stirring, adds flyash stirring, filters, grind, dries, cold
But, pulverizing obtains modified coal ash.
6. according to good toughness long resin in service life Anchor Agent described in any one of claim 1-5, it is characterised in that modified fine coal
Ash uses following technique to prepare: by octamethylcy-clotetrasiloxane, γ-diethylenetriamine hydroxypropyl methyl dimethoxysilane, water, nothing
Water-ethanol mix and blend 15-35min, is warming up to 80-90 DEG C, adds Tetramethylammonium hydroxide stirring 10-30min, adds fine coal
Ash stirring 25-65min, filters, and grinds 25-55min, dries 0.8-1.6h, cooling for 110-120 DEG C, pulverize and obtain modified fine coal
Ash.
7. according to good toughness long resin in service life Anchor Agent described in any one of claim 1-6, it is characterised in that modified fine coal
Ash uses following technique to prepare: by weight by 8-12 part octamethylcy-clotetrasiloxane, 2-3 part γ-diethylenetriamine propyl group first
Base dimethoxysilane, 30-60 part water, 10-20 part dehydrated alcohol mix and blend 15-35min, be warming up to 80-90 DEG C, adds
0.5-1 part Tetramethylammonium hydroxide stirring 10-30min, adds 25-35 part flyash stirring 25-65min, filters, grind 25-
Dry 0.8-1.6h, cooling, pulverize and obtain modified coal ash for 55min, 110-120 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610642244.9A CN106280350A (en) | 2016-08-08 | 2016-08-08 | A kind of good toughness long resin in service life Anchor Agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610642244.9A CN106280350A (en) | 2016-08-08 | 2016-08-08 | A kind of good toughness long resin in service life Anchor Agent |
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| CN106280350A true CN106280350A (en) | 2017-01-04 |
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| CN201610642244.9A Pending CN106280350A (en) | 2016-08-08 | 2016-08-08 | A kind of good toughness long resin in service life Anchor Agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868283A (en) * | 2017-11-30 | 2018-04-03 | 安徽坤大化学锚固有限公司 | A kind of high low-temperature resistance type resin anchoring agent and its preparation technology |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1876713A (en) * | 2006-06-30 | 2006-12-13 | 王厚东 | Flame-retarded resin anchoring agent |
| CN1876714A (en) * | 2006-06-30 | 2006-12-13 | 王厚东 | Antistatic resin anchoring agent |
| CN101508540A (en) * | 2009-04-07 | 2009-08-19 | 晋城宏圣科威矿用材料有限公司 | Resin mastic cement for anchorage agent and anchorage agent thereof |
-
2016
- 2016-08-08 CN CN201610642244.9A patent/CN106280350A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1876713A (en) * | 2006-06-30 | 2006-12-13 | 王厚东 | Flame-retarded resin anchoring agent |
| CN1876714A (en) * | 2006-06-30 | 2006-12-13 | 王厚东 | Antistatic resin anchoring agent |
| CN101508540A (en) * | 2009-04-07 | 2009-08-19 | 晋城宏圣科威矿用材料有限公司 | Resin mastic cement for anchorage agent and anchorage agent thereof |
Non-Patent Citations (2)
| Title |
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| 郑重远，黄乃炯: "《树脂锚杆及锚固剂》", 30 April 1983, 煤炭工业出版社 * |
| 黄发荣，焦扬声: "《不饱和聚酯树脂》", 30 March 2001, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868283A (en) * | 2017-11-30 | 2018-04-03 | 安徽坤大化学锚固有限公司 | A kind of high low-temperature resistance type resin anchoring agent and its preparation technology |
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Application publication date: 20170104 |