CN106281179A - A kind of waterproof high bond strength resin adhesive - Google Patents

A kind of waterproof high bond strength resin adhesive Download PDF

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Publication number
CN106281179A
CN106281179A CN201610748272.9A CN201610748272A CN106281179A CN 106281179 A CN106281179 A CN 106281179A CN 201610748272 A CN201610748272 A CN 201610748272A CN 106281179 A CN106281179 A CN 106281179A
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CN
China
Prior art keywords
parts
red oil
turkey red
bond strength
resin adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610748272.9A
Other languages
Chinese (zh)
Inventor
吴家猛
吴刚
陈铖
丁维
李伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI SKY EYE INTELLIGENT TECHNOLOGY Co Ltd
Original Assignee
ANHUI SKY EYE INTELLIGENT TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI SKY EYE INTELLIGENT TECHNOLOGY Co Ltd filed Critical ANHUI SKY EYE INTELLIGENT TECHNOLOGY Co Ltd
Priority to CN201610748272.9A priority Critical patent/CN106281179A/en
Publication of CN106281179A publication Critical patent/CN106281179A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of waterproof high bond strength resin adhesive, the weight ratio including resin-bonded mastic and firming agent, resin-bonded mastic and firming agent is 1:0.1～0.3；Resin-bonded mastic includes by weight: 188 unsaturated polyester resins 50～80 parts, dimethylaniline 3～7 parts, mica powder 4～12 parts, clay 3～6 parts, glass microballoon 8～16 parts, nano silicon 25～35 parts, attapulgite 25～45 parts, flake asbestos 10～20 parts, white carbon black 10～20 parts, modified turkey red oil 2～6 parts；Firming agent includes by weight: ground calcium carbonate 5～20 parts, benzoyl peroxide 10～20 parts, magnesium hydroxide 25～45 parts, sodium lignin sulfonate 3～7 parts, water 35～45 parts.The waterproof high bond strength resin adhesive that the present invention proposes, the most waterproof outstanding with mechanical performance, and also toughness is fabulous, and adhesion strength is high, the most with low cost.

Description

A kind of waterproof high bond strength resin adhesive
Technical field
The present invention relates to field of adhesive technology, particularly relate to a kind of waterproof high bond strength resin adhesive.
Background technology
Resin adhesive is with unsaturated-resin as bonding agent, using agstone etc. as reinforcing material, is equipped with suitably Promoting initiator system, the resin-bonded mastic of production can obtain high intensity and fast solidification effect.In technical field of electronic encapsulation Widely, but at present waterproof, the ageing-resistant and mechanical performance of resin adhesive also can not meet and needs in the application of resin adhesive Ask.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of waterproof high bond strength resin adhesive, The most waterproof outstanding with mechanical performance, and toughness is fabulous, and adhesion strength is high, the most with low cost.
The one waterproof high bond strength resin adhesive that the present invention proposes, including resin-bonded mastic and firming agent, resin glue The weight ratio of mud and firming agent is 1:0.1～0.3；Resin-bonded mastic includes by weight: 188 unsaturated polyester resins 50～80 Part, dimethylaniline 3～7 parts, mica powder 4～12 parts, clay 3～6 parts, glass microballoon 8～16 parts, nano silicon 25～ 35 parts, attapulgite 25～45 parts, flake asbestos 10～20 parts, white carbon black 10～20 parts, modified turkey red oil 2～6 parts；Firming agent is by weight Amount part includes: ground calcium carbonate 5～20 parts, benzoyl peroxide 10～20 parts, magnesium hydroxide 25～45 parts, sodium lignin sulfonate 3～7 parts, water 35～45 parts.
Preferably, the weight ratio of resin-bonded mastic and firming agent is 1:0.15～0.25.
Preferably, 188 unsaturated polyester resins, dimethylaniline, mica powder, the weight ratio of modified turkey red oil be 60～ 70:4～6:6～10:3～5.
Preferably, clay, glass microballoon, nano silicon, attapulgite, flake asbestos, white carbon black, the weight of modified turkey red oil Amount ratio is 4～5:10～14:28～32:30～40:13～15:16～18:3～5.
Preferably, modified turkey red oil uses following technique to prepare: by polymethyl methacrylate, POLYPROPYLENE GLYCOL, turkey red oil Mix homogeneously, adds cumyl peroxide stirring, sends in low-temperature plasma generator and process, take out, add nano-silica SiClx, ethylhydroxyethylcellulose, ethanol mix and blend obtain modified turkey red oil.
Preferably, modified turkey red oil uses following technique to prepare: by polymethyl methacrylate, POLYPROPYLENE GLYCOL, turkey red oil Mix homogeneously, adds cumyl peroxide stirring 25～55min, and whipping temp is 45～55 DEG C, sends into low-temperature plasma and sends out Raw device processes 60～110min, takes out, add nano silicon, ethylhydroxyethylcellulose, ethanol mix and blend 25～ 55min, whipping temp is 45～55 DEG C, obtains modified turkey red oil.
Preferably, modified turkey red oil uses following technique to prepare: by weight by 4～12 parts of polymethyl methacrylates, 3 ～10 parts of POLYPROPYLENE GLYCOLs, 25～45 parts of turkey red oil mix homogeneously, add 2～4 parts of cumyl peroxide stirrings 25～55min, Whipping temp is 45～55 DEG C, sends into and processes 60～110min in low-temperature plasma generator, takes out, add 10～20 parts of nanometers Silicon dioxide, 25～45 parts of ethylhydroxyethylcelluloses, 15～35 parts of ethanol mix and blends 25～55min, whipping temp is 45 ～55 DEG C, obtain modified turkey red oil.
The present invention uses the collaborative solidification polymerization of 188 unsaturated polyester resins, benzoyl peroxide, sodium lignin sulfonate, makes The present invention not only adhesion strength is high, and after solidifying, hardness is fabulous with toughness, and physical and mechanical properties is excellent；At modified turkey red oil In, polymethyl methacrylate, POLYPROPYLENE GLYCOL, under cumyl peroxide effect, use low-temperature plasma to hand over after processing Connection, with turkey red oil and the nano silicon of follow-up addition, ethylhydroxyethylcellulose mating reaction, not only has good dividing Dissipate property, and waterproof, ageing-resistant performance is excellent；188 unsaturated polyester resins and modified turkey red oil mating reaction, not only with peroxide Change benzoyl, the mutual degree of scatter of sodium lignin sulfonate high, and make the toughness of the present invention fabulous, waterproof and ageing-resistant performance Excellent；And modified turkey red oil can effectively promote mica powder, white carbon black, clay, nano silicon, flake asbestos, glass microballoon, concavo-convex Between rod soil miscible, the most waterproof further enhance with mechanical performance, and can effectively reduce cost.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
The one waterproof high bond strength resin adhesive that the present invention proposes, including resin-bonded mastic and firming agent, resin glue The weight ratio of mud and firming agent is 1:0.1；Resin-bonded mastic includes by weight: 188 unsaturated polyester resins 80 parts, dimethyl benzene Amine 3 parts, mica powder 12 parts, clay 3 parts, glass microballoon 16 parts, nano silicon 25 parts, attapulgite 45 parts, flake asbestos 10 Part, white carbon black 20 parts, modified 2 parts of turkey red oil；Firming agent includes by weight: ground calcium carbonate 20 parts, benzoyl peroxide 10 parts, 45 parts of magnesium hydroxide, sodium lignin sulfonate 3 parts, 45 parts of water.
Embodiment 2
The one waterproof high bond strength resin adhesive that the present invention proposes, including resin-bonded mastic and firming agent, resin glue The weight ratio of mud and firming agent is 1:0.3；Resin-bonded mastic includes by weight: 188 unsaturated polyester resins 50 parts, dimethyl benzene Amine 7 parts, mica powder 4 parts, clay 6 parts, glass microballoon 8 parts, nano silicon 35 parts, attapulgite 25 parts, flake asbestos 20 parts, White carbon black 10 parts, modified 6 parts of turkey red oil；Firming agent includes by weight: ground calcium carbonate 5 parts, benzoyl peroxide 20 parts, hydrogen-oxygen Change 25 parts of magnesium, sodium lignin sulfonate 7 parts, 35 parts of water.
Modified turkey red oil uses following technique to prepare: by weight by 4 parts of polymethyl methacrylates, 10 parts of polypropylene Alcohol, 25 parts of turkey red oil mix homogeneously, add 4 parts of cumyl peroxide stirring 25min, and whipping temp is 55 DEG C, sends into low temperature Plasma generator processes 60min, takes out, add 20 parts of nano silicons, 25 parts of ethylhydroxyethylcelluloses, 35 parts of second Alcohol mix and blend 25min, whipping temp is 55 DEG C, obtains modified turkey red oil.
Embodiment 3
The one waterproof high bond strength resin adhesive that the present invention proposes, including resin-bonded mastic and firming agent, resin glue The weight ratio of mud and firming agent is 1:0.2；Resin-bonded mastic includes by weight: 188 unsaturated polyester resins 65 parts, dimethyl benzene Amine 5 parts, mica powder 8 parts, clay 4.5 parts, glass microballoon 12 parts, nano silicon 30 parts, attapulgite 35 parts, flake asbestos 14 Part, white carbon black 17 parts, modified 4 parts of turkey red oil；Firming agent includes by weight: ground calcium carbonate 12 parts, benzoyl peroxide 15 parts, 35 parts of magnesium hydroxide, sodium lignin sulfonate 5 parts, 40 parts of water.
Modified turkey red oil uses following technique to prepare: by weight by 12 parts of polymethyl methacrylates, 3 parts of polypropylene Alcohol, 45 parts of turkey red oil mix homogeneously, add 2 parts of cumyl peroxide stirring 55min, and whipping temp is 45 DEG C, sends into low temperature Plasma generator processes 110min, takes out, add 10 parts of nano silicons, 45 parts of ethylhydroxyethylcelluloses, 15 parts Ethanol mix and blend 55min, whipping temp is 45 DEG C, obtains modified turkey red oil.
Embodiment 4
The one waterproof high bond strength resin adhesive that the present invention proposes, including resin-bonded mastic and firming agent, resin glue The weight ratio of mud and firming agent is 1:0.15；Resin-bonded mastic includes by weight: 188 unsaturated polyester resins 70 parts, dimethyl Aniline 4 parts, mica powder 10 parts, clay 4 parts, glass microballoon 14 parts, nano silicon 28 parts, attapulgite 40 parts, flake asbestos 13 parts, white carbon black 18 parts, modified 3 parts of turkey red oil；Firming agent includes by weight: ground calcium carbonate 15 parts, benzoyl peroxide 14 Part, 41 parts of magnesium hydroxide, sodium lignin sulfonate 4 parts, 42 parts of water.
Modified turkey red oil uses following technique to prepare: by polymethyl methacrylate, POLYPROPYLENE GLYCOL, turkey red oil mixing all Even, add cumyl peroxide stirring 40min, whipping temp is 50 DEG C, sends in low-temperature plasma generator and processes 80min, takes out, and adds nano silicon, ethylhydroxyethylcellulose, ethanol mix and blend 40min, and whipping temp is 50 DEG C, obtain modified turkey red oil.
Embodiment 5
The one waterproof high bond strength resin adhesive that the present invention proposes, including resin-bonded mastic and firming agent, resin glue The weight ratio of mud and firming agent is 1:0.25；Resin-bonded mastic includes by weight: 188 unsaturated polyester resins 60 parts, dimethyl Aniline 6 parts, mica powder 6 parts, clay 5 parts, glass microballoon 10 parts, nano silicon 32 parts, attapulgite 30 parts, flake asbestos 15 Part, white carbon black 16 parts, modified 5 parts of turkey red oil；Firming agent includes by weight: ground calcium carbonate 10 parts, benzoyl peroxide 16 parts, 30 parts of magnesium hydroxide, sodium lignin sulfonate 6 parts, 38 parts of water.
Modified turkey red oil uses following technique to prepare: by polymethyl methacrylate, POLYPROPYLENE GLYCOL, turkey red oil mixing all Even, add cumyl peroxide stirring, send in low-temperature plasma generator and process, take out, add nano silicon, second Ethylhydroxyethylcellulose, ethanol mix and blend obtain modified turkey red oil.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (7)

1. a waterproof high bond strength resin adhesive, it is characterised in that include resin-bonded mastic and firming agent, resin-bonded mastic and The weight ratio of firming agent is 1:0.1～0.3；
Resin-bonded mastic includes by weight: 188 unsaturated polyester resins 50～80 parts, dimethylaniline 3～7 parts, mica powder 4～ 12 parts, clay 3～6 parts, glass microballoon 8～16 parts, nano silicon 25～35 parts, attapulgite 25～45 parts, flake asbestos 10～20 parts, white carbon black 10～20 parts, modified turkey red oil 2～6 parts；
Firming agent includes by weight: ground calcium carbonate 5～20 parts, benzoyl peroxide 10～20 parts, magnesium hydroxide 25～45 Part, sodium lignin sulfonate 3～7 parts, water 35～45 parts.
The most waterproof high bond strength resin adhesive, it is characterised in that resin-bonded mastic and firming agent Weight ratio is 1:0.15～0.25.
Waterproof high bond strength resin adhesive the most according to claim 1 or claim 2, it is characterised in that 188 unsaturated polyester (UP) trees Fat, dimethylaniline, mica powder, the weight ratio of modified turkey red oil are 60～70:4～6:6～10:3～5.
4. according to high bond strength resin adhesive waterproof described in any one of claim 1-3, it is characterised in that clay, glass Microballon, nano silicon, attapulgite, flake asbestos, white carbon black, the weight ratio of modified turkey red oil be 4～5:10～14:28～ 32:30～40:13～15:16～18:3～5.
5. according to high bond strength resin adhesive waterproof described in any one of claim 1-4, it is characterised in that modified turkey red oil Use following technique to prepare: by polymethyl methacrylate, POLYPROPYLENE GLYCOL, turkey red oil mix homogeneously, add peroxidating diisopropyl Benzene stirs, and sends in low-temperature plasma generator and processes, and takes out, and adds nano silicon, ethylhydroxyethylcellulose, ethanol Mix and blend obtains modified turkey red oil.
6. according to high bond strength resin adhesive waterproof described in any one of claim 1-5, it is characterised in that modified turkey red oil Use following technique to prepare: by polymethyl methacrylate, POLYPROPYLENE GLYCOL, turkey red oil mix homogeneously, add peroxidating diisopropyl Benzene stirring 25～55min, whipping temp is 45～55 DEG C, sends into and processes 60～110min in low-temperature plasma generator, takes out, Adding nano silicon, ethylhydroxyethylcellulose, ethanol mix and blend 25～55min, whipping temp is 45～55 DEG C, To modified turkey red oil.
7. according to high bond strength resin adhesive waterproof described in any one of claim 1-6, it is characterised in that modified turkey red oil Use following technique to prepare: by weight by 4～12 parts of polymethyl methacrylates, 3～10 parts of POLYPROPYLENE GLYCOLs, 25～45 parts too Ancient oil mix homogeneously, adds 2～4 parts of cumyl peroxide stirrings 25～55min, and whipping temp is 45～55 DEG C, sends into low Temperature plasma generator processes 60～110min, takes out, add 10～20 parts of nano silicons, 25～45 parts of ethyl hydroxyl second Base cellulose, 15～35 parts of ethanol mix and blends 25～55min, whipping temp is 45～55 DEG C, obtains modified turkey red oil.
CN201610748272.9A 2016-08-27 2016-08-27 A kind of waterproof high bond strength resin adhesive Pending CN106281179A (en)

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CN201610748272.9A CN106281179A (en) 2016-08-27 2016-08-27 A kind of waterproof high bond strength resin adhesive

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107043610A (en) * 2017-01-20 2017-08-15 长安大学 A kind of bridge deck water-proof tack coat material and preparation method thereof
CN109135862A (en) * 2018-07-09 2019-01-04 安徽大地节能科技有限公司 A kind of biomass fuel binder and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101508540A (en) * 2009-04-07 2009-08-19 晋城宏圣科威矿用材料有限公司 Resin mastic cement for anchorage agent and anchorage agent thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101508540A (en) * 2009-04-07 2009-08-19 晋城宏圣科威矿用材料有限公司 Resin mastic cement for anchorage agent and anchorage agent thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107043610A (en) * 2017-01-20 2017-08-15 长安大学 A kind of bridge deck water-proof tack coat material and preparation method thereof
CN109135862A (en) * 2018-07-09 2019-01-04 安徽大地节能科技有限公司 A kind of biomass fuel binder and preparation method thereof

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Application publication date: 20170104