CN100341812C - Wall and floor tile and its making method - Google Patents
Wall and floor tile and its making method Download PDFInfo
- Publication number
- CN100341812C CN100341812C CNB2004100278668A CN200410027866A CN100341812C CN 100341812 C CN100341812 C CN 100341812C CN B2004100278668 A CNB2004100278668 A CN B2004100278668A CN 200410027866 A CN200410027866 A CN 200410027866A CN 100341812 C CN100341812 C CN 100341812C
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- China
- Prior art keywords
- floor tile
- quartz
- base substrate
- wall
- wall floor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000000758 substrate Substances 0.000 claims abstract description 60
- 239000010453 quartz Substances 0.000 claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 25
- 239000000843 powder Substances 0.000 claims description 24
- 239000004927 clay Substances 0.000 claims description 19
- 239000011734 sodium Substances 0.000 claims description 19
- 238000001354 calcination Methods 0.000 claims description 17
- 230000004907 flux Effects 0.000 claims description 16
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 14
- 239000011707 mineral Substances 0.000 claims description 14
- 235000010755 mineral Nutrition 0.000 claims description 14
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 14
- 235000017550 sodium carbonate Nutrition 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 8
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 7
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 238000003825 pressing Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 238000003854 Surface Print Methods 0.000 claims description 3
- 238000000748 compression moulding Methods 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- -1 vitriol Chemical compound 0.000 claims description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000010304 firing Methods 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 12
- 230000005540 biological transmission Effects 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 239000013078 crystal Substances 0.000 abstract description 5
- 230000003373 anti-fouling effect Effects 0.000 abstract 2
- 239000002734 clay mineral Substances 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000035807 sensation Effects 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 229910052570 clay Inorganic materials 0.000 description 16
- 238000000498 ball milling Methods 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 9
- 235000019832 sodium triphosphate Nutrition 0.000 description 8
- 229910004298 SiO 2 Inorganic materials 0.000 description 7
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 6
- 238000005245 sintering Methods 0.000 description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 5
- 238000013467 fragmentation Methods 0.000 description 5
- 238000006062 fragmentation reaction Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 4
- 238000003701 mechanical milling Methods 0.000 description 4
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 4
- 238000001694 spray drying Methods 0.000 description 4
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 4
- 229910052845 zircon Inorganic materials 0.000 description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 239000011449 brick Substances 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 238000005336 cracking Methods 0.000 description 2
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical class [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 229910021647 smectite Inorganic materials 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 241000370738 Chlorion Species 0.000 description 1
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 229940078494 nickel acetate Drugs 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
Landscapes
- Finishing Walls (AREA)
Abstract
The present invention discloses a wall and floor tile. The wall and floor tile has the raw materials of weight percent of 65 to 90% of quartz, 5 to 30% of fusing agent and 5 to 30% of clay mineral substance. The wall and floor tile uses the quartz as a principal raw material; the fusing agent and the quartz are mixed and calcined before the base substrates are burnt to eliminate or weaken stress brought about by volume expansion generated by the crystal form conversion of the quartz in a burning process on the base substrates; therefore, a large amount of quartz can be led in the base substrates, and the content of Al2O3 is reduced to increase the whiteness, the antifouling property and the decorative effect of products. The present invention also discloses a preparation method for the wall and floor tile; the quartz and the fusing agent are mixed and calcined at 800 DEG C to 1600 DEG C for 0.2 to 48 hours; then, quartz calcined objects and the clay mineral substances are mixed, and the mixture is manufactured into the wall and floor tile by a conventional method. When the preparation method of the present invention is used, burnt base substrates can not crack or deform; the manufactured wall and floor tile has the characteristics of high whiteness, good light transmission, strong jadestone sensation, zero radioactivity, strong antifouling property and favorable appearance decorating effect.
Description
Technical field
The present invention relates to a kind of ceramic, relate in particular to a kind of wall floor tile and manufacture method thereof.
Background technology
Existing wall floor tile is raw materials such as feldspar, pottery stone, porcelain stone, porcelain sand, potter's clay, china clay, talcum, zircon sand, quartz and clay class mineral plastic materials such as (as kaolinite class mineral, smectite type mineral (as wilkinite), illite class mineral) are mixed according to a certain percentage and levigate, powder process, shaping, drying, to burn till.Its common base substrate chemical ingredients is: SiO
263～75%, Al
2O
315～23%, CaO+MgO=0～3%, K
2O+Na
2O+Li
2O=4.0～10%, Fe
2O
3+ TiO
2=0～3%, ZrO
2=0～10%.Existing wall floor tile exists following defective: one, owing to Al in its chemical ingredients
2O
3Higher, formed glassy phase crystallization ability is stronger in the base substrate sintering process, and it is relatively poor that base substrate burns till the back light transmission, thereby poor, the beautiful texture of wall floor tile light transmission that makes is relatively poor, exterior decorative effect is undesirable.Two, because Al
2O
3The content height, in the base substrate sintering process higher, the diffusibility of formed glassy phase viscosity a little less than, the glassy phase of viscosity higher is difficult to infiltrate and be filled in the hole of base substrate inside, still have higher water-intake rate after base substrate burns till, thereby the didirtresistance of base substrate is relatively poor.Three, for common wall floor tile, because common selected raw material Fe
2O
3+ TiO
2Content is higher, and the base substrate whiteness is not high.Therefore, for improving the base substrate whiteness and reducing Al
2O
3Content, prior art generally, the one, introduce a certain amount of quartz, but quartzy add-on can not too high (generally less than 35%), otherwise the volumetric expansion that brings owing to quartzy moment crystal conversion when burning till, be easy to make the very big stress of the inner generation of base substrate, cause the cracking and the distortion of base substrate.The 2nd, in base substrate, introduce the zircon sand (powder) of a certain amount of (2～10%), but because zircon sand (powder) has radioactivity, thereby prepared wall floor tile also has radioactivity.Simultaneously because the introducing of zircon sand (powder) has also reduced the light transmission of wall floor tile, beautiful texture.
Summary of the invention
The object of the present invention is to provide that a kind of whiteness height, good, the beautiful texture of light transmission are strong, "dead", didirtresistance and exterior decorative effect be good, the wall floor tile of the not easy to crack and distortion of base substrate, and the manufacture method of this wall floor tile.
Purpose of the present invention is achieved by the following technical programs:
A kind of wall floor tile provided by the invention, its raw material consists of quartzy 65-90%, flux 5-30% and clay class mineral 5-30% by weight percentage; Described flux is the one or more combination of the fluorochemical of the muriate of oxide compound, metal of carbonate, vitriol, nitrate, phosphoric acid, phosphoric acid salt, boric acid, borate, silicate, silicofluoride, metal or metal.Preferred version is: its raw material consists of by weight percentage: quartzy 70-82%, flux 8-11% and clay class mineral 9-22%.
Wall floor tile of the present invention is to be main raw material with the quartz, described flux is used for before base substrate burns till and quartzy mixed calcining, the stress that brings to base substrate to eliminate or to weaken volumetric expansion that crystal conversion quartzy in the sintering process produces, so can introduce a large amount of quartz in the base substrate.Generally coloring element content is lower in the quartz, so the increase of quartz content can make the whiteness of base substrate be significantly improved in the base substrate.In addition, because the increase of quartz content, formed glassy phase crystallization ability weakens in the base substrate sintering process, becomes glass power to strengthen, and the light transmission of base substrate and beautiful texture are obviously strengthened, and decorative effect is able to obvious improvement.In addition, because Al in the selected raw material of wall floor tile of the present invention
2O
3Content is lower, thereby can reduce formed glassy phase viscosity in the base substrate sintering process, and can improve its diffusibility.More low viscous glassy phase more easily infiltrates and is filled in the hole of base substrate inside, reduced base substrate and burnt the back water-intake rate, thereby the didirtresistance of base substrate is better.Simultaneously, owing to Al in its chemical constitution
2O
3Lower, in the base substrate sintering process formed glassy phase crystallization ability a little less than, it is better that base substrate burns till the back light transmission, thereby good, the beautiful texture of wall floor tile light transmission that makes is strong, exterior decorative effect is better.
Preferred flux of the present invention component by weight percentage is yellow soda ash 16%～47%, Sodium Silicofluoride 16～47%, lime carbonate 23～53%, talcum powder 7～25%, barium carbonate 7～19%.Perhaps preferred flux is yellow soda ash.
The preparation method of wall floor tile of the present invention comprises the following steps:
(1) quartz and flux are mixed be incorporated in 800 ℃～1600 ℃ calcinings down, calcination time is 0.2～48 hour, obtains quartzy calcined material;
(3) the base substrate mixture is made the wall floor tile according to ordinary method.
Quartzy mixes with flux and through calcining, metal ion, fluorion, chlorion contacts with quartzy in the flux, under the high temperature with quartz in silicon ion fight for oxygen, siloxane bond is ruptured, formation silicate or silicate glass.Therefore destroy quartzy crystalline structure, eliminated or reduced the volumetric expansion of quartzy crystal conversion generation.Generally, if quartz does not mix with flux and through calcining, and directly join in the base substrate of wall floor tile, after base substrate burns till, be easy to the volumetric expansion that crystal conversion produced because of quartz and cause the sintered compact cracking or crack.The purpose that adds plastic materials such as clay class mineral such as kaolinite class mineral, smectite type mineral (as wilkinite), illite class mineral is in order to improve the forming property of base substrate, to increase the associativity of base substrate and the green strength that improves base substrate.If do not add or add less plastic raw materials such as clay class mineral in the base substrate, base substrate will be difficult to be shaped (especially dry powder press forming).
In the wall body brick preparation method's of the present invention step (3), can be undertaken by following measure: the base substrate mixture is levigate and make moisture 4.5%～12.0% powder, the fineness of powder is that 10000-hole sieve tails over 0～4%, after this powder pressing forming and drying, put into kiln and fire under 1150 ℃～1350 ℃, the firing time is 0.3～12 hour.
In order to improve the decorative effect of brick body, also can after compression moulding of base substrate mixture and drying, contain the paste or the soluble powder of soluble salt solution at its surface printing earlier, and spray water or penetration-assisting agent, and then put into kiln and fire, polish after burning till.
The present invention has following beneficial effect:
(1) the wall floor tile that makes of the present invention has that whiteness height, good, the beautiful texture of light transmission are strong, "dead", didirtresistance reaches the good characteristics of exterior decorative effect by force.
(2) can introduce a large amount of quartz in the base substrate, and ftracture after being unlikely to make base substrate to burn till or crack.
The present invention is described in further detail below in conjunction with embodiment.
Embodiment
Embodiment one:
1. the constitutive material of present embodiment wall floor tile
Quartzy (SiO
2〉=99.0%) 67%
Soda ash (Na
2CO
3〉=99.0%) 4%
Sodium Silicofluoride 4%
Lime carbonate 2.2%
Talcum powder 0.8%
Clay 22%
2. the manufacture method of this wall floor tile
(1) quartz in the above-mentioned constitutive material and soda ash, Sodium Silicofluoride, lime carbonate and talcum powder are mixed, in 800 ℃ of calcinings, calcination time is 0.2 hour, obtains quartzy calcined material.
(2) with mixing with clay during above-mentioned raw materials is formed after the quartzy calcined material fragmentation, obtain the base substrate mixture.
(3) the base substrate mixture is carried out ball milling, be incorporated as the water, 0.1% carboxymethyl cellulose of base substrate mixture weight 50% and 0.3% tripoly phosphate sodium STPP in the mechanical milling process to improve the ball milling effect.Then with the mud after the ball milling, make moisture 4.5%～8.5% powder with spray-drying tower, the fineness of powder is that 10000-hole sieve tails over 0～4%, with this powder pressing forming and after drying under 150 ℃ of temperature, put into kiln and under 1150 ℃ of temperature, burnt till 0.3 hour, at last sintered compact is polished.
Embodiment two:
1. the constitutive material of present embodiment wall floor tile
Quartzy (SiO
2〉=99.0%) 68%
Soda ash (Na
2CO
3〉=99.0%) 1.6%
Sodium Silicofluoride 2.4%
Lime carbonate 3.3%
Talcum powder 0.8%
Barium carbonate 1.9%
Clay 22%
2. the manufacture method of this wall floor tile
(1) quartz in the above-mentioned constitutive material and soda ash, Sodium Silicofluoride, lime carbonate, barium carbonate, talcum powder are mixed, in 1100 ℃ of temperature lower calcinations, calcination time is 24 hours, obtains quartzy calcined material.
(2) with mixing with clay during above-mentioned raw materials is formed after the quartzy calcined material fragmentation, obtain the base substrate mixture.
Be with embodiment one manufacture method difference: in step (3) after compression moulding of base substrate mixture and the drying, earlier ooze fancy glaze (as in 10% nickel acetate solution what its surface printing contained soluble salt solution, add 2.6% carboxymethyl cellulose and 5% ethylene glycol etc., form body of paste after the thickening), and then put into kiln, burn till under 1195 ℃ of temperature, the time is 3 hours, at last sintered compact is polished.
Embodiment three:
1. the constitutive material of present embodiment wall floor tile
Quartzy (SiO
2〉=99.0%) 73%
Soda ash (Na
2CO
3〉=99.0%) 2%
Sodium Silicofluoride 2%
Calcium phosphate 2%
Talcum powder 2%
Clay 19%
2. the manufacture method of this wall floor tile
(1) quartz in the above-mentioned constitutive material and soda ash, Sodium Silicofluoride, lime carbonate and talcum powder are mixed, in 1350 ℃ of calcinings, calcination time is 28 hours.Obtain quartzy calcined material.
(2) with mixing with clay during above-mentioned raw materials is formed after the quartzy calcined material fragmentation, obtain the base substrate mixture.
(3) the base substrate mixture is carried out ball milling, be incorporated as the water, 0.1% carboxymethyl cellulose of base substrate mixture weight 50% and 0.3% tripoly phosphate sodium STPP in the mechanical milling process to improve the ball milling effect.With the mud after the ball milling, make moisture 5%～10% powder with spray-drying tower then, the fineness of powder is that 10000-hole sieve tails over 0～4%, with this powder pressing forming and after drying under 100 ℃ of temperature, puts into kiln and burns till 6 hours under 1280 ℃ of temperature.At last sintered compact is polished.
Embodiment four:
1. the constitutive material of present embodiment wall floor tile
Quartzy (SiO
2〉=99.0%) 85%
Soda ash (Na
2CO
3〉=99.0%) 6%
Clay 8%
Wilkinite 1%
2. the manufacture method of this wall floor tile
(1) quartz in the above-mentioned constitutive material and soda ash are mixed, in 1500 ℃ of calcinings, calcination time is 36 hours.Obtain quartzy calcined material.
(2) with mixing with clay, wilkinite during above-mentioned raw materials is formed after the quartzy calcined material fragmentation, obtain the base substrate mixture.
(3) the base substrate mixture is carried out ball milling, be incorporated as the water, 0.5% carboxymethyl cellulose of base substrate mixture weight 50% and 0.6% tripoly phosphate sodium STPP in the mechanical milling process to improve the ball milling effect.With the mud after the ball milling, make moisture 6～8% powder then,, put into kiln and under 1330 ℃ of temperature, burnt till 8 hours, at last sintered compact is polished with this powder pressing forming and after drying under 180 ℃ of temperature with spray-drying tower.
Embodiment five:
1. the constitutive material of embodiment wall floor tile
Quartzy (SiO
2〉=99.0%) 87%
Soda ash (Na
2CO
3〉=99.0%) 5%
Clay 7%
Wilkinite 1%
2. the manufacture method of this wall floor tile
(1) quartz in the above-mentioned constitutive material and soda ash are mixed, in 1600 ℃ of calcinings, calcination time is 48 hours, obtains quartzy calcined material.
(2) with mixing with clay and wilkinite during above-mentioned raw materials is formed after the quartzy calcined material fragmentation, obtain the base substrate mixture.
(3) the base substrate mixture is carried out ball milling, be incorporated as the water, 0.3% carboxymethyl cellulose of base substrate mixture weight 50% and 0.4% tripoly phosphate sodium STPP in the mechanical milling process to improve the ball milling effect.Then with the mud after the ball milling, make moisture 6～9% powder with spray-drying tower, the fineness of powder is that 10000-hole sieve tails over 0～4%, with this powder pressing forming and after drying under 200 ℃ of temperature, put into kiln and under 1350 ℃ of temperature, burnt till 12 hours, at last sintered compact is polished.
The chemical ingredients scope of wall body brick of the present invention is:
SiO
2＝75％～95％
Al
2O
3＝3～12％
Fe
2O
3+TiO
2+Co
2O
3+Ni
2O
3+Cr
2O
3+V
2O
5+CuO+MnO
2+CeO
2＝0～2％
Li
2O+Na
2O+K
2O+Rb
2O+MgO+CaO+BaO+ZnO+BeO+
SrO+B
2O
3+P
2O
5+PbO+Bi
2O
3+SnO
2+ZrO
2+La
2O
3＝2～15％
As
2O
3+Sb
2O
3＝0～2％
F+Cl+Br+S+C＝0～6％
Surplus 0～1%.
Claims (7)
1, a kind of wall floor tile, its raw material consists of quartzy 65-90%, flux 5-30% and clay class mineral 5-30% by weight percentage; Described flux is the one or more combination of the fluorochemical of the muriate of oxide compound, metal of carbonate, vitriol, nitrate, phosphoric acid, phosphoric acid salt, boric acid, borate, silicate, silicofluoride, metal or metal.
2, wall floor tile according to claim 1, its raw material consists of by weight percentage: quartzy 70-82%, flux 8-11% and clay class mineral 9-22%.
3, wall floor tile according to claim 1 and 2, described flux component by weight percentage are yellow soda ash 16%～47%, Sodium Silicofluoride 16～47%, lime carbonate 23～53%, talcum powder 7～25%, barium carbonate 7～19%.
4, wall floor tile according to claim 1 and 2, described flux is yellow soda ash.
5, the preparation method of the described wall floor tile of claim 1 comprises the following steps:
(1) quartz and flux are mixed be incorporated in 800 ℃～1600 ℃ calcinings down, calcination time is 0.2～48 hour, obtains quartzy calcined material;
(2) quartzy calcined material is mixed with clay class mineral, obtain the base substrate mixture;
(3) the base substrate mixture is made the wall floor tile according to ordinary method.
6, preparation method according to claim 5, in the described step (3) that the base substrate mixture is levigate and make moisture 4.5%～12.0% powder, the fineness of powder is that 10000-hole sieve tails over 0～4%, after this powder pressing forming and drying, put into kiln and fire under 1150 ℃～1350 ℃, the firing time is 0.3～12 hour.
7, preparation method according to claim 6, after compression moulding of base substrate mixture and the drying, contain the paste or the soluble powder of soluble salt solution at its surface printing earlier, and spray water or penetration-assisting agent in the described step (3), and then put into kiln and fire, polish after burning till.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB2004100278668A CN100341812C (en) | 2004-07-02 | 2004-07-02 | Wall and floor tile and its making method |
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| CNB2004100278668A CN100341812C (en) | 2004-07-02 | 2004-07-02 | Wall and floor tile and its making method |
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| CN1594180A CN1594180A (en) | 2005-03-16 |
| CN100341812C true CN100341812C (en) | 2007-10-10 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103011767A (en) * | 2012-12-25 | 2013-04-03 | 青岛科技大学 | Sanitary ceramic body |
| CN103058630A (en) * | 2012-12-25 | 2013-04-24 | 青岛科技大学 | Construction ceramic body |
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| CN1031069A (en) * | 1987-07-31 | 1989-02-15 | 南京市住宅建设公司 | Light porous face-decorative material |
| US4866015A (en) * | 1987-02-17 | 1989-09-12 | Dr. C. Otto Feuerfest Gmbh | Silica brick and process for producing same |
| JPH0733276B2 (en) * | 1990-12-24 | 1995-04-12 | 日本植生株式会社 | Freezing prevention building material |
| CN1163238A (en) * | 1997-04-03 | 1997-10-29 | 沈瑞生 | Artificial jade paving tile |
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| CN1486954A (en) * | 2003-04-17 | 2004-04-07 | 杨铁军 | Pottery curb stone and floor tile |
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- 2004-07-02 CN CNB2004100278668A patent/CN100341812C/en not_active Expired - Fee Related
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| US4866015A (en) * | 1987-02-17 | 1989-09-12 | Dr. C. Otto Feuerfest Gmbh | Silica brick and process for producing same |
| CN1031069A (en) * | 1987-07-31 | 1989-02-15 | 南京市住宅建设公司 | Light porous face-decorative material |
| JPH0733276B2 (en) * | 1990-12-24 | 1995-04-12 | 日本植生株式会社 | Freezing prevention building material |
| CN1163238A (en) * | 1997-04-03 | 1997-10-29 | 沈瑞生 | Artificial jade paving tile |
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