CL2021002705A1 - Proceso de bucle químico para la producción de hidrógeno - Google Patents

Proceso de bucle químico para la producción de hidrógeno

Info

Publication number
CL2021002705A1
CL2021002705A1 CL2021002705A CL2021002705A CL2021002705A1 CL 2021002705 A1 CL2021002705 A1 CL 2021002705A1 CL 2021002705 A CL2021002705 A CL 2021002705A CL 2021002705 A CL2021002705 A CL 2021002705A CL 2021002705 A1 CL2021002705 A1 CL 2021002705A1
Authority
CL
Chile
Prior art keywords
reaction zone
oxygen carrier
solid oxygen
fed
solid
Prior art date
Application number
CL2021002705A
Other languages
English (en)
Inventor
Kok-Seng Lim
Trevor Deon Hadley
Doki Yamaguchi
Liangguang Tang
José Orellana
Original Assignee
Commw Scient Ind Res Org
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AU2019901354A external-priority patent/AU2019901354A0/en
Application filed by Commw Scient Ind Res Org filed Critical Commw Scient Ind Res Org
Publication of CL2021002705A1 publication Critical patent/CL2021002705A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/061—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of metal oxides with water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B01J8/1827—Feeding of the fluidising gas the fluidising gas being a reactant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/28—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles
    • C01B3/30—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles using the fluidised bed technique
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/50—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00752—Feeding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00938—Flow distribution elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B5/00—Water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Un proceso de bucle químico para la producción de hidrógeno y la coproducción de dióxido de carbono que comprende: un primer bucle redox que comprende: alimentar un primer portador sólido de oxígeno a una primera zona de reacción (R1) en la que también se alimenta un primer combustible carbonoso, que reacciona con el primer portador sólido de oxígeno alimentado en su estado de oxidación máximo (forma totalmente oxidada), lo que conduce a la formación de los productos de combustión dióxido de carbono y agua y el portador sólido de oxígeno en un estado de oxidación inferior (forma reducida); y alimentar el primer portador sólido de oxígeno en forma reducida a una segunda zona de reacción (R2) en la que también se alimenta aire, obteniendo, a partir de la oxidación del primer portador sólido de oxígeno, calor y el portador sólido de oxígeno en forma totalmente oxidada para ser reciclado a la primera zona de reacción (R1); y un segundo bucle redox que comprende: alimentar un segundo portador sólido de oxígeno a una tercera zona de reacción (R3) en la que también se alimenta un segundo combustible carbonoso, que reacciona con el segundo portador sólido de oxígeno alimentado en su estado de oxidación intermedio (forma oxidada), lo que conduce a la formación de los productos de combustión dióxido de carbono y agua y el portador sólido de oxígeno en un estado de oxidación inferior (forma reducida); y alimentar el segundo portador sólido de oxígeno en forma reducida a una cuarta zona de reacción (R4) en la que también se alimenta vapor, que reacciona con la forma reducida del portador sólido de oxígeno, produciendo hidrógeno y el portador sólido de oxígeno en un estado oxidante intermedio (forma oxidada) que se reciclará a la tercera zona de reacción (R3) y/o a la primera zona de reacción (R1), en donde la primera zona de reacción (R1) y la tercera zona de reacción (R3) están interconectadas permitiendo la transferencia de al menos una porción del primer portador sólido de oxígeno desde la primera zona de reacción (R1) a la tercera zona de reacción (R3)
CL2021002705A 2019-04-18 2021-10-15 Proceso de bucle químico para la producción de hidrógeno CL2021002705A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AU2019901354A AU2019901354A0 (en) 2019-04-18 Chemical looping process for the production of hydrogen

Publications (1)

Publication Number Publication Date
CL2021002705A1 true CL2021002705A1 (es) 2022-05-27

Family

ID=72836730

Family Applications (1)

Application Number Title Priority Date Filing Date
CL2021002705A CL2021002705A1 (es) 2019-04-18 2021-10-15 Proceso de bucle químico para la producción de hidrógeno

Country Status (8)

Country Link
US (1) US20220194787A1 (es)
EP (1) EP3956260A4 (es)
JP (1) JP2022529349A (es)
KR (1) KR20210154830A (es)
CN (1) CN113825721A (es)
AU (1) AU2020259801A1 (es)
CL (1) CL2021002705A1 (es)
WO (1) WO2020210865A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020033500A1 (en) 2018-08-09 2020-02-13 Ohio State Innovation Foundation Systems, methods and materials for hydrogen sulfide conversion
CA3129146A1 (en) 2019-04-09 2020-10-15 Liang-Shih Fan Alkene generation using metal sulfide particles
CN115349067A (zh) * 2020-02-14 2022-11-15 俄亥俄州立创新基金会 具有至少两种粒子类型的化学链系统
CN112744785B (zh) * 2020-12-31 2023-11-10 西北大学 一种原位利用二氧化碳联产合成气和氢气的化学链耦合工艺
US11752480B2 (en) * 2021-02-04 2023-09-12 Babcock & Wilcox Company Apparatus for enclosing a chemical looping process
WO2024059619A2 (en) * 2022-09-13 2024-03-21 Ohio State Innovation Foundation Redox looping systems, methods and techniques for the production of hydrogen and carbon dioxide products
AT526550A1 (de) * 2022-10-06 2024-04-15 Chi En Huang Verfahren zur kontinuierlichen Produktion von Wasserstoff, Kohlenstoffdioxid und Stickstoff

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT505526B1 (de) * 2007-08-14 2010-09-15 Univ Wien Tech Wirbelschichtreaktorsystem
CN101746721B (zh) * 2009-08-12 2012-04-18 东南大学 一种基于铁或铁氧化物制氢并分离co2的方法及装置
CA2754948A1 (en) * 2010-10-13 2012-04-13 Song Sit Chemical looping combustion
WO2012155054A1 (en) * 2011-05-11 2012-11-15 The Ohio State University Systems for converting fuel
CN104401938B (zh) * 2014-10-31 2016-04-20 东南大学 富含甲烷气体制备h2/co比例可调的合成气的装置和方法
US9902615B2 (en) * 2015-07-14 2018-02-27 The Babcock & Wilcox Company Syngas production via cyclic reduction and oxidation of metal oxides
US9890949B2 (en) * 2015-09-10 2018-02-13 Institute of Nuclear Energy Research, Atomic Energy Council, Executive Yuan, R.O.C. Hydrocarbon fuel reactor for separating and purifying carbon dioxide

Also Published As

Publication number Publication date
WO2020210865A1 (en) 2020-10-22
CN113825721A (zh) 2021-12-21
US20220194787A1 (en) 2022-06-23
KR20210154830A (ko) 2021-12-21
EP3956260A4 (en) 2023-01-11
AU2020259801A1 (en) 2021-11-04
EP3956260A1 (en) 2022-02-23
JP2022529349A (ja) 2022-06-21

Similar Documents

Publication Publication Date Title
CL2021002705A1 (es) Proceso de bucle químico para la producción de hidrógeno
RU2008135988A (ru) Способ получения акролеина
EP1580162A3 (en) Process for the production of hydrogen and the co-production of carbon dioxide
NO20006618L (no) Prosess for produksjon av elektrisk energi, damp og karbondioksid fra et hydrokarbonråstoff
GR1001615B (el) Μέ?οδος αεριοποίησης στερεών καυσίμων χαμηλού ?ερμικού περιεχομένου με ωφέλιμη αξιοποίηση στην παραγωγή ηλεκτρικής ενέργειας χωρίς δημιουργία ρύπανσης περιβάλλοντος.
AR073939A1 (es) Proceso para producir monomero de estireno sobre la base de la deshidrogenacion oxidativa de etilbenceno usando co2 como un oxidante suave
IN2014MN01474A (es)
ATE357062T1 (de) Prozess zur herstellung von elektrizität und kohlendioxid
RU2012120045A (ru) Способ получения фенола из кумола
BR112020001492A2 (pt) método para aumentar a eficiência de uma usina de gás de síntese de amônia
BR8503388A (pt) Processo para a producao de uma mistura de gases contendo hidrogenio e monoxido de carbono
ES2643081T3 (es) Procedimiento de producción de un producto orgánico a partir de una carga de materia carbonada que utiliza una gasificación seguida de una fermentación del gas de síntesis
MY154030A (en) Process to prepare a hydrogen rich gas mixture
WO2009154512A2 (ru) Способ получения синтез-газа и устройство для его осуществления
RU2013130857A (ru) Способ металлургической газификации твердого топлива
RU2012137276A (ru) Способ и система для подачи тепловой энергии в систему термообработки из газификации сухого углеродсодержащего сырья с последующим окислением и установка, эксплуатирующая такую систему
RU2015104766A (ru) Способ получения водорода из биомассы
ES2547465B1 (es) Procedimiento de calcinación con producción de co2 puro mediantecombustión usando transportadores de o2
KR20110060339A (ko) 다단식 석탄가스화기
RU2012102318A (ru) Способ получения гидроксида натрия из жидких отходов производства волокнистой массы
RU2379230C2 (ru) Способ получения водорода паро-углекислотной конверсией природного газа
KR20140055596A (ko) 순산소연소와 촉매전환 공정을 연계한 융합형 이산화탄소 전환 시스템
ES2703803T3 (es) Procedimiento de generación de una mezcla de gases que contiene monóxido de carbono e hidrógeno en proporciones sustancialmente iguales
CN101942345A (zh) 煤气生产装置和方法
RU2008113761A (ru) Способ преобразования энергии с регенерацией энергоносителей в циклическом процессе (барчана)