CL2020000910A1 - Una resina de polietileno para moldeo rotacional que tienen una densidad de aproximadamente 0,950 g/cc y buena rigidez. (divisional solicitud 201801507) - Google Patents

Una resina de polietileno para moldeo rotacional que tienen una densidad de aproximadamente 0,950 g/cc y buena rigidez. (divisional solicitud 201801507)

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Publication number
CL2020000910A1
CL2020000910A1 CL2020000910A CL2020000910A CL2020000910A1 CL 2020000910 A1 CL2020000910 A1 CL 2020000910A1 CL 2020000910 A CL2020000910 A CL 2020000910A CL 2020000910 A CL2020000910 A CL 2020000910A CL 2020000910 A1 CL2020000910 A1 CL 2020000910A1
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CL
Chile
Prior art keywords
molecular weight
average molecular
density
component
weight
Prior art date
Application number
CL2020000910A
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English (en)
Inventor
Celine Bellehumeur
Mark Hoidas
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Nova Chem Int Sa
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Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Publication of CL2020000910A1 publication Critical patent/CL2020000910A1/es

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/04Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/01High molecular weight, e.g. >800,000 Da.
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/07High density, i.e. > 0.95 g/cm3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/10Short chain branches
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/13Environmental stress cracking resistance
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Moulding By Coating Moulds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

UNA RESINA DE POLIETILENO, QUE COMPRENDE DE 0,6 A 1 % EN PESO DE 1-OCTENO Y EL RESTO ES ETILENO, QUE TIENE UNA DENSIDAD ENTRE 0,948 Y 0,953 KG/M3, UN ÍNDICE DE FUSIÓN ENTRE 0,0010 Y 0,0015 KG/10 MINUTOS; UN ÍNDICE DE FUSIÓN DETERMINADO DE ACUERDO CON LA NORMA ASTM1238 BAJO UNA CARGA DE 21,6 KG A UNA TEMPERATURA DE 190ºC (I21) ENTRE 0,032 Y 0,055 KG/10 MINUTOS; UN PESO MOLECULAR PROMEDIO PONDERADO (MW) ENTRE 90.000 Y 130.000; UN PESO MOLECULAR PROMEDIO EN NÚMERO (MN) DETERMINADO MEDIANTE CROMATOGRAFÍA DE PERMEACIÓN EN GEL (GPC) ENTRE 20.000 Y 40.000; UN PESO MOLECULAR PROMEDIO Z (MZ) ENTRE 240.000 Y 360.000; UN MW/MN ENTRE 2,9 Y 4; UN MZ/MW ENTRE 2,9 Y 3,2; Y QUE TIENE UN CBDI (50) ENTRE 80 Y 95, EN DONDE LA DISTRIBUCIÓN DE PESO MOLECULAR DETERMINADA MEDIANTE GPC DE DICHO POLÍMERO SE DECONVOLUCIONA EN TRES COMPONENTES QUE COMPRENDEN: ENTRE 20 Y 40 % EN PESO DE UN PRIMER COMPONENTE QUE TIENE UN PESO MOLECULAR PROMEDIO PONDERADO CALCULADO (MW) QUE ES ENTRE 170.000 Y 265.000; UN PESO MOLECULAR PROMEDIO EN NÚMERO CALCULADO (MN) ENTRE 90.000 Y 140.000; UN PESO MOLECULAR PROMEDIO Z 390.000 Y 520.000 Y UNA DENSIDAD ESTIMADA ENTRE 0,921 Y 0,930 KG/M3; ENTRE 40 Y 70 % EN PESO DE UN SEGUNDO COMPONENTE QUE TIENE UN PESO MOLECULAR PROMEDIO PONDERADO CALCULADO (MW) QUE ES ENTRE 20.000 Y 57.000; UN PESO MOLECULAR PROMEDIO EN NÚMERO CALCULADO (MN) ENTRE 10.000 Y 27.000; UN PESO MOLECULAR PROMEDIO Z ENTRE 30.000 Y 72.000 Y UNA DENSIDAD ESTIMADA ENTRE 0,948 Y 0,953 KG/M3, CON LA CONDICIÓN DE QUE LA DIFERENCIA DE DENSIDAD ENTRE EL COMPONENTE DOS Y EL COMPONENTE UNO SEA MENOR QUE 0,030 KG/M3.
CL2020000910A 2015-12-08 2020-04-03 Una resina de polietileno para moldeo rotacional que tienen una densidad de aproximadamente 0,950 g/cc y buena rigidez. (divisional solicitud 201801507) CL2020000910A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA2914166A CA2914166C (en) 2015-12-08 2015-12-08 High density rotomolding resin

Publications (1)

Publication Number Publication Date
CL2020000910A1 true CL2020000910A1 (es) 2020-08-21

Family

ID=57406287

Family Applications (2)

Application Number Title Priority Date Filing Date
CL2018001507A CL2018001507A1 (es) 2015-12-08 2018-06-06 Resina de alta densidad para moldeo rotacional
CL2020000910A CL2020000910A1 (es) 2015-12-08 2020-04-03 Una resina de polietileno para moldeo rotacional que tienen una densidad de aproximadamente 0,950 g/cc y buena rigidez. (divisional solicitud 201801507)

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CL2018001507A CL2018001507A1 (es) 2015-12-08 2018-06-06 Resina de alta densidad para moldeo rotacional

Country Status (15)

Country Link
US (2) US9982077B2 (es)
EP (2) EP3489266B1 (es)
JP (1) JP6892860B2 (es)
KR (1) KR102634165B1 (es)
CN (1) CN108290980B (es)
AU (1) AU2016366721A1 (es)
BR (2) BR122022000892B1 (es)
CA (1) CA2914166C (es)
CL (2) CL2018001507A1 (es)
ES (1) ES2905551T3 (es)
MX (1) MX2018006214A (es)
PE (1) PE20181033A1 (es)
SG (1) SG11201804180XA (es)
TW (1) TWI621651B (es)
WO (1) WO2017098359A1 (es)

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BR112020011394A2 (pt) 2017-12-26 2020-11-24 Dow Global Technologies Llc composição polimérica, e, artigo
SG11202005775UA (en) * 2017-12-26 2020-07-29 Dow Global Technologies Llc Compositions with multimodal ethylene-based polymers having improved toughness at low temperatures
US11680119B2 (en) 2017-12-26 2023-06-20 Dow Global Technologies Llc Process for the production of multimodal ethylene-based polymers
CN111655744B (zh) * 2017-12-26 2023-04-28 陶氏环球技术有限责任公司 韧性改善的多峰型乙烯类聚合物组合物
US11555084B2 (en) 2017-12-26 2023-01-17 Dow Global Technologies Llc Multimodal ethylene-based polymer processing systems and methods
EP3732215B8 (en) 2017-12-26 2022-04-27 Dow Global Technologies LLC Dual reactor solution process for the production of multimodal ethylene-based polymer
CA3011030A1 (en) * 2018-07-11 2020-01-11 Nova Chemicals Corporation Polyethylene composition and film having retained dart impact
CA3011038A1 (en) * 2018-07-11 2020-01-11 Nova Chemicals Corporation Polyethylene composition and film having a good permeability, stiffness and sealability
CA3011031A1 (en) * 2018-07-11 2020-01-11 Nova Chemicals Corporation Polyethylene composition and film having outstanding properties
AR119038A1 (es) * 2019-06-11 2021-11-17 Dow Global Technologies Llc Tapas o cierres moldeados por inyección y métodos de estos
US20220017663A1 (en) 2019-09-27 2022-01-20 Lg Chem, Ltd. Polyethylene and Its Chlorinated Polyethylene
CA3158392A1 (en) * 2019-11-01 2021-05-06 Nova Chemicals Corporation Linear high-density polyethylene with high toughness and high escr
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EP4308361A1 (en) * 2021-03-19 2024-01-24 Nova Chemicals (International) S.A. High density polyethylene composition

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Also Published As

Publication number Publication date
CA2914166A1 (en) 2017-06-08
WO2017098359A1 (en) 2017-06-15
CL2018001507A1 (es) 2018-08-24
AU2016366721A1 (en) 2018-06-21
EP3489266C0 (en) 2024-03-27
US20180230255A1 (en) 2018-08-16
BR112018011675A2 (pt) 2018-11-27
CN108290980A (zh) 2018-07-17
TW201730260A (zh) 2017-09-01
BR122022000892B1 (pt) 2022-12-27
KR102634165B1 (ko) 2024-02-06
JP2018536748A (ja) 2018-12-13
PE20181033A1 (es) 2018-06-27
BR112018011675B1 (pt) 2022-05-03
CN108290980B (zh) 2021-03-26
EP3387026A1 (en) 2018-10-17
US20170158789A1 (en) 2017-06-08
ES2905551T3 (es) 2022-04-11
CA2914166C (en) 2022-07-26
TWI621651B (zh) 2018-04-21
JP6892860B2 (ja) 2021-06-23
US9982077B2 (en) 2018-05-29
MX2018006214A (es) 2018-08-01
EP3489266A1 (en) 2019-05-29
EP3387026B1 (en) 2021-12-29
SG11201804180XA (en) 2018-06-28
US10189924B2 (en) 2019-01-29
KR20180090800A (ko) 2018-08-13
EP3489266B1 (en) 2024-03-27

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