CH661934A5 - COMBUSTION-IMPROVING ADDITIVE COMPOSITION FOR CLEANING HEATING DEVICES, FIREPLACES, SMOKE EXTRACTIONS AND HEAT GENERATORS. - Google Patents
COMBUSTION-IMPROVING ADDITIVE COMPOSITION FOR CLEANING HEATING DEVICES, FIREPLACES, SMOKE EXTRACTIONS AND HEAT GENERATORS. Download PDFInfo
- Publication number
- CH661934A5 CH661934A5 CH4570/84A CH457084A CH661934A5 CH 661934 A5 CH661934 A5 CH 661934A5 CH 4570/84 A CH4570/84 A CH 4570/84A CH 457084 A CH457084 A CH 457084A CH 661934 A5 CH661934 A5 CH 661934A5
- Authority
- CH
- Switzerland
- Prior art keywords
- weight
- parts
- oxide
- additives
- ammonium
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 25
- 239000000654 additive Substances 0.000 title claims description 20
- 238000010438 heat treatment Methods 0.000 title claims description 14
- 230000000996 additive effect Effects 0.000 title claims description 12
- 238000004140 cleaning Methods 0.000 title claims description 9
- 239000000779 smoke Substances 0.000 title claims 2
- 238000000605 extraction Methods 0.000 title 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 16
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 12
- 239000000446 fuel Substances 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 8
- 239000000292 calcium oxide Substances 0.000 claims description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 235000019359 magnesium stearate Nutrition 0.000 claims description 6
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 4
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 4
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 claims description 4
- 239000001099 ammonium carbonate Substances 0.000 claims description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 4
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 229930192627 Naphthoquinone Natural products 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 claims description 2
- 150000002680 magnesium Chemical class 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 150000002791 naphthoquinones Chemical class 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000002816 fuel additive Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- KYCIUIVANPKXLW-UHFFFAOYSA-N dimethyl-(2-phenoxyethyl)-(thiophen-2-ylmethyl)azanium Chemical compound C=1C=CSC=1C[N+](C)(C)CCOC1=CC=CC=C1 KYCIUIVANPKXLW-UHFFFAOYSA-N 0.000 claims 1
- 206010022000 influenza Diseases 0.000 claims 1
- 108090000623 proteins and genes Proteins 0.000 claims 1
- 239000011833 salt mixture Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910001868 water Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000010297 mechanical methods and process Methods 0.000 description 2
- 230000005226 mechanical processes and functions Effects 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011089 mechanical engineering Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- FJQLIWTWAFYOMG-UHFFFAOYSA-N sulfur dioxide;sulfur trioxide Chemical compound O=S=O.O=S(=O)=O FJQLIWTWAFYOMG-UHFFFAOYSA-N 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Incineration Of Waste (AREA)
- Developing Agents For Electrophotography (AREA)
- Detergent Compositions (AREA)
Description
Die Erfindung betrifft eine verbrennungsverbessernde zur Verbesserung der Verbrennung von Anthracit oder Ma- The invention relates to a combustion-improving to improve the combustion of anthracite or Ma
Zusatzstoffkomposition zur Reinigung von Heizvorrichtun- gerkohle in einer Menge von 0,16% angewandt: NaCl 60%, Additive composition used to clean heating coal in an amount of 0.16%: NaCl 60%,
gen, Kaminen, Rauchzügen und Wärmeregeneratoren. CaO 4%, NH4C128%, S 4%, sowie 2% zulässige Verunrei- chimneys, chimneys and heat regenerators. CaO 4%, NH4C128%, S 4%, and 2% permissible impurities
Es ist bekannt, dass die Verwendung von festen Brenn- 30nigung und etwas Wasser. Bei der Anwendung dieses Zu- It is known that the use of solid burning and some water. When applying this
stoffen in den Vordergrund getreten ist; daneben werden na- satzstoffes könnten die Russbildung und die Verschmutzung türlich die verschiedenen Erdölderivate weiterhin als Brenn- der Luft vermindert werden. Die HU-PS 166 853 beschreibt stoffe verwendet werden. eine Reinigungsmittelkomposition zur Reinigung der Feuer- substances has come to the fore; In addition, soot formation and pollution, of course, the various petroleum derivatives could continue to be reduced as combustion air. The HU-PS 166 853 describes substances to be used. a detergent composition for cleaning the fire
Es ist auch bekannt, dass alle, nicht gasförmigen Brenn- seite der Heizvorrichtungen. Hier wird eine Komposition stoffe sich während der Heizung zu Asche, zu Kohlendioxyd,35 folgender Zusammensetzung angewandt: Ammoniumsulfat It is also known that all the non-gaseous burning side of the heaters. Here a composition is used during the heating to ash, to carbon dioxide, 35 of the following composition: ammonium sulfate
Kohlenmonoxyd, Wasser, Schwefeldioxyd und Stickstoff- oder Ammoniumbisulfat 37 bis 57%, Natriumchlorid 42 bis monoxyd umsetzen. Der Aschengehalt der Brennstoffe be- 62%, Graphitpulver 0,5 bis 2% und gegebenenfalls 0,5 bis trägt 0,01% (destillierter Brennstoff) bis 40% (Braunkohle 0,1% Emulgiermittel. React carbon monoxide, water, sulfur dioxide and nitrogen or ammonium bisulfate 37 to 57%, sodium chloride 42 to monoxide. The ash content of the fuels is 62%, graphite powder 0.5 to 2% and possibly 0.5 to 0.01% (distilled fuel) to 40% (lignite 0.1% emulsifier).
schwacher Qualität). Die Asche kann im Falle der Verwen- Laut der DE-PS 2 501 503 kann der Schwefel der schwe- poor quality). The ash can be used in the case of use. According to DE-PS 2 501 503, the sulfur can
dung von sowohl Heizöl als auch Kohle solche Elemente 40felhaltigen Brennstoffe mit Dolomit bzw. kalksteinhaltigen enthalten, die Probleme verursachen. Solche sind z.B. das Stoffen teilweise gebunden werden. Formation of both heating oil and coal contain fuels with dolomite or limestone containing fuels that cause problems. Such are e.g. the fabrics are partially bound.
Natrium, Kalium, Nickel, Eisen, Vanadium, Silizium und Wie es aus dem oben Beschriebenen hervorgeht, konnte Sodium, potassium, nickel, iron, vanadium, silicon and, as can be seen from the above, could
Schwefel. Während der Heizung bilden diese Elemente ein eine bestimmte Komposition bei den bekannten Lösungen Sulfur. During heating, these elements form a certain composition in the known solutions
Eutektikum mit niedrigem Schmelzpunkt, welches nach vom Brennstoff abhängig verwendet werden oder die Kom- Eutectic with a low melting point, which can be used depending on the fuel or the com-
Schmelzung und darauffolgender Erstarrung ausserordent- 45 position war nur zur Reinigung von bestimmten Teilen, z.B. lieh schwer entfernbare Ablagerungen auf den verschiedenen von Feuerseiten der Heizvorrichtungen geeignet. Aufgrund Teilen der Heizvorrichtungen, sowie in den zweiten und drit- unserer Versuche sind die zur Zeit bekannten Kompositio- Melting and subsequent solidification was exceptional 45 position only for cleaning certain parts, e.g. borrowed hard-to-remove deposits on the various fire sides of the heaters. Due to parts of the heating devices, as well as in the second and third attempts, the currently known compositions are
ten Zügen, in den Rauchzügen und auch in den Kaminen nen zur Beseitigung oder Verminderung der Umsetzungsre- trains, in the chimneys and also in the chimneys to remove or reduce the implementation regulations
bildet. Die Bildung der Ablagerungen wird durch die Teil- aktion Schwefeldioxyd-Schwefeltrioxyd nicht geeignet, forms. The formation of the deposits is not suitable due to the partial action sulfur dioxide-sulfur trioxide,
chengrösse, den Schmelzpunkt der Schlacke, den Trägheits- 50 Ziel der Erfindung ist, eine solche Komposition auszuar- size, the melting point of the slag, the inertia. The aim of the invention is to develop such a composition.
stoss und die molekulare Diffusion bestimmt. Die Ablage- beiten, durch deren Anwendung die Ablagerungen ohne rangen an der Feuerseite vermindern wesentlich den Wir- Rücksicht auf den Brennstoff bei Heizvorrichtungen, Kami-kungsgrad des Kessels, erhöhen den Kostenaufwand der spe- nen, Rauchzügen, Wärmeregeneratoren wirksam entfernt zifischen Dampfherstellung und die Emission von umweit- werden können. collision and determines the molecular diffusion. The filing work, through the use of which the deposits without wrinkles on the fire side significantly reduce the consideration of the fuel in heating devices, degree of combing of the boiler, increase the cost of the spares, chimneys, heat regenerators, effectively remove specific steam production and Emission of can be removed.
verschmutzenden Stoffen; zugleich bedeuten sie eine Unfall- 55 Die erfindungsgemässe Komposition besteht darin, dass gefahr, und sie schaffen die Bedingungen für die bei hohen sie 15 bis 20 Gew.-teile Ammoniumderivat-Komponente, polluting substances; at the same time they mean an accident. 55 The composition according to the invention consists in the fact that there is danger and they create the conditions for the 15 to 20 parts by weight of ammonium derivative component
und niedrigen Temperaturen auftretende Korrosion. Die und zwar Ammoniumcarbamat und Ammoniumbicarbonat, and low temperature corrosion. The namely ammonium carbamate and ammonium bicarbonate,
Fachliteratur der Feuerungstechnik hält die Bildung der er- 5 bis 40 Gew.-teile Magnesiumderivat-Komponente, und wähnten Ablagerungen eindeutig für ungünstig und be- zwar Magnesiumoxyd und Magnesiumcarbonat, 5 bis 30 Technical literature on furnace technology considers the formation of the 5 to 40 parts by weight of magnesium derivative component and clearly think deposits are unfavorable, namely magnesium oxide and magnesium carbonate, 5 to 30
schreibt zur Entfernung der Ablagerungen bzw. zur Verhin- ^Gew.-teile Natriumchlorid, 0 bis 30 Gew.-teile Ammonium- writes to remove the deposits or to prevent ^ parts by weight of sodium chloride, 0 to 30 parts by weight of ammonium
derang deren Bildung verschiedene mechanische Verfahren, sulfat, 1 bis 5 Gew.-teile a-Naphtochinon, 0,1 bis 1 Gew.-teil sowie Zusatzstoffe. Die bekannten Lösungen können in drei Kupfernaphtenat, 0,1 bis 1 Gew.-teil Magnesiumstearat, 4 depending on their formation, various mechanical processes, sulfate, 1 to 5 parts by weight of a-naphthoquinone, 0.1 to 1 part by weight and additives. The known solutions can be in three copper naphtenate, 0.1 to 1 part by weight of magnesium stearate, 4
Gruppen aufgeteilt werden, und zwar: bis 9 Gew.-teile Metalloxyd-Komponente, und zwar Alumi- Groups are divided, namely: up to 9 parts by weight of metal oxide component, namely aluminum
1) Mechanische Verfahren, z.B. Verwendung von Draht- niumoxyd und Eisen(III)-oxyd, sowie 0 bis 6,5 Gew.-teile Si-scheiben oder Drahtbürsten, Kratzen, Meissein, Ausklopfen 6sliziumdioxyd und Calciumoxyd enthält. 1) Mechanical processes, e.g. Use of wire oxide and iron (III) oxide, as well as 0 to 6.5 parts by weight of Si disks or wire brushes, scratching, chipping, knocking out silicon dioxide and calcium oxide.
mit Dampf oder Wasser. Laut den Versuchserfahrungen übt die Komposition ihre with steam or water. According to the experimental experience, the composition practices its
2) Reinigung mit Chemikalien, deren Prinzip es ist, dass Wirkung am besten aus, wenn die gesamte Menge von a-auf die zu reinigenden Oberflächen der Heizvorrichtungen Naphtochinon, Kupfernaphtenat und Magnesiumstearat 2) Cleaning with chemicals, the principle of which is that it works best when the total amount of a-on the surfaces of the heaters to be cleaned is naphthoquinone, copper naphtenate and magnesium stearate
3 3rd
661 934 661 934
mindestens 3 Gew.-teile, höchstens 6 Gew.- teile, die gesamte Menge von Aluminiumoxyd, Eisen(III)-oxyd, Siliziumdioxyd und Calciumoxyd mindestens 9 Gew.-teile und die gesamte Menge von Natriumchlorid und Ammoniumsulfat mindestens 30 Gew.-teile beträgt. at least 3 parts by weight, at most 6 parts by weight, the total amount of aluminum oxide, ferric oxide, silicon dioxide and calcium oxide at least 9 parts by weight and the total amount of sodium chloride and ammonium sulfate at least 30 parts by weight is.
Was den Wirkungsmechanismus des Zusatzstoffes anbelangt, haben wir festgestellt, dass die erfindungsgemässe Komposition durch die Wirkung von a-Naphtochinon, welches die Sublimation fördert, schnell gasförmig wird und auch zu den weiteren Teilen der Heizvorrichtungen, zu den Wärmeregeneratoren und den Kaminen gelangt. Hier kommt sie infolge molekularer Diffusion und Adsorption zwischen der Wand der Heizvorrichtung und den Ablagerungen, danach entwickelt sie Kohlendioxyd. Durch die Wirkung des sich entwickelnden Gases scheiden sich die Ablagerungen von der Metalloberfläche ab. As far as the mechanism of action of the additive is concerned, we have found that the composition according to the invention quickly becomes gaseous due to the action of a-naphthoquinone, which promotes sublimation, and also reaches the other parts of the heating devices, the heat regenerators and the chimneys. Here it comes as a result of molecular diffusion and adsorption between the wall of the heater and the deposits, after which it develops carbon dioxide. Due to the effect of the evolving gas, the deposits separate from the metal surface.
Die Reinigung der Wärmeregeneratoren und Kamine war mit den bisher bekannten Zusatzstoffen nicht erreichbar. Die erfindungsgemässe Komposition bedeutet also einen wesentlichen Fortschritt gegenüber den bekannten Zusatzstoffen. The cleaning of the heat regenerators and chimneys was not achievable with the additives known up to now. The composition according to the invention thus means a significant advance over the known additives.
Die erfindungsgemässe Komposition vermindert die Umsetzung so2-so3 nicht nur viel wesentlicher als die bekannten Zusatzstoffe, sondern beseitigt sie fast, indem das während der Verbrennung entstandene S03 reduziert und durch Erhöhung des Schmelzpunktes der Schlacke eine trockene, undichte Schlacke erhalten wird. Die erfindungsgemässe Komposition tritt ausserdem mit den Schwefeloxyden direkt in Reaktion. Während der Reaktion entstehen Komplexe, die keine Ablagerungen und keine Korrosion verursachen; so wird die bei hohen Temperaturen auftretende Korrosion eliminiert. Es wurde gefunden, dass die erfindungsgemässe Komposition gleisam wie ein negativer Katalysator in der Umsetzungsreaktion S02-S03 funktioniert. Wie es bekannt ist, vermindert sich die Temperatur des Abgases in den Wärmeregeneratoren der Heizvorrichtungen unter den Säuretaupunkt, was die Bildung der schwefligen Säure auf den Metalloberflächen fördert und so erfolgt die bei niedrigen Temperaturen auftretende Korrosion. Diese filmförmige schweflige Säure kann Säurerussablagerungen verursachen, was schliesslich zu Betriebsunterbrechung und Energieverlusten führen kann. Zur Verhinderung der bei niedrigen Temperaturen auftretenden Korrosion wurden maschinenbautechnische Lösungen angewandt, doch sind diese nicht wirtschaftlich, da bei der Verwendung dieser Lösungen immer Wärmeenergie besitzende Gase in die Luft austreten, d.h. ein Energieverlust erfolgt. The composition according to the invention not only significantly reduces the conversion of so2-so3 than the known additives, but almost eliminates it by reducing the SO3 formed during the combustion and by obtaining the melting point of the slag a dry, leaky slag is obtained. The composition according to the invention also reacts directly with the sulfur oxides. Complexes develop during the reaction, which do not cause deposits or corrosion; this eliminates the corrosion occurring at high temperatures. It was found that the composition according to the invention functions as a negative catalyst in the reaction S02-S03. As is known, the temperature of the exhaust gas in the heat regenerators of the heaters drops below the acid dew point, which promotes the formation of sulfurous acid on the metal surfaces and so the corrosion occurs at low temperatures. This film-like sulfurous acid can cause deposits of acid soot, which can ultimately lead to business interruptions and energy losses. Mechanical engineering solutions have been used to prevent corrosion occurring at low temperatures, but these are not economical since gases containing heat energy always escape into the air when using these solutions, i.e. there is a loss of energy.
Die erfindungsgemässe Zusatzstoffkomposition vermindert den nötigen Luftüberschuss infolge ihrer verbrennungs-verbessernden katalytischen Wirkung, und so vermindert sie auch die Strömungsgeschwindigkeit des Abgases. Infolge der kleineren Strömungsgeschwindigkeit wird auch die Zahl der The additive composition according to the invention reduces the necessary excess air due to its combustion-improving catalytic effect, and thus also reduces the flow velocity of the exhaust gas. As a result of the smaller flow velocity, the number of
Trägheitsstösse geringer sein, und dies vermindert die Bildung von Ablagerungen. Die erfindungsgemässe Komposition verhindert die Bildung von S03 und neutralisiert die schwefelige Säure völlig auf den Teilen mit niedrigen Tempe-5raturen der Wärmeregeneratoren. Die Verschmutzung kann dadurch eliminiert werden, dass die Metalloberfläche nicht klebrig wird. Dies kann dadurch erreicht werden, dass die Zusatzstoffkomposition den Taupunkt der schwefligen Säure unter der Betriebstemperatur hält. So kann die Heizvor-îorichtung mit minimaler austretender Abgastemperatur und Kamintemperatur funktionieren und gleichzeitig eine maximale Energiemenge ausnutzen. Inertia shocks are less, and this reduces the formation of deposits. The composition according to the invention prevents the formation of SO 3 and completely neutralizes the sulphurous acid on the parts with low temperatures of the heat regenerators. Soiling can be eliminated by not making the metal surface sticky. This can be achieved in that the additive composition keeps the dew point of the sulfurous acid below the operating temperature. In this way, the heating device can function with a minimal exhaust gas temperature and chimney temperature and at the same time utilize a maximum amount of energy.
Während der Versuche haben wir gefunden, dass durch Anwendung von 0,5 kg erfindungsgemässer Komposition 15 pro 1000 kg Brennstoff schon gute Ergebnisse erhalten werden können. Aufgrund der Prüfungen braucht man zweckmässig 0,5 bis 0,8 kg verbrennungsverbessernde Zusatzstoffkomposition pro 1000 kg Brennstoff, abhängig von der Qualität der Brennstoffe. During the tests we found that good results can already be obtained by using 0.5 kg of composition 15 according to the invention per 1000 kg of fuel. Based on the tests, it is advisable to use 0.5 to 0.8 kg of combustion-improving additive composition per 1000 kg of fuel, depending on the quality of the fuels.
20 Die erfindungsgemässe Komposition wird durch die folgenden Beispiele näher erläutert, ohne die Erfindung darauf einzuschränken. The composition according to the invention is explained in more detail by the following examples, without restricting the invention thereto.
Beispiel 1 example 1
Beispiel 2 Example 2
a-Naphtochinon a-naphthoquinone
5 Gew.-teil 5 parts by weight
1 Gew.-teil 1 part by weight
Kupfernaphtenat Copper naphtenate
0,5 Gew.-teil 0.5 part by weight
1 Gew.-teil 1 part by weight
Magnesiumstearat Magnesium stearate
0,5 Gew.-teil 0.5 part by weight
1 Gew.-teil 1 part by weight
A1203 A1203
6 Gew.-teil 6 parts by weight
4 Gew.-teil 4 parts by weight
Fe203 Fe203
Si02 Si02
3,5 Gew.-teil 3.5 parts by weight
6,5 Gew.-teil 6.5 parts by weight
CaO CaO
Ammoniumbicarbonat Ammonium bicarbonate
15 Gew.-teil 15 parts by weight
20 Gew.-teil 20 parts by weight
Ammoniumcarbamat Ammonium carbamate
MgO MgO
30 Gew.-Teil 30 parts by weight
40 Gew.-teil 40 parts by weight
MgC03 MgC03
NaCl NaCl
20 Gew.-teil 20 parts by weight
30 Gew.-teil 30 parts by weight
Ammoniumsulfat Ammonium sulfate
20 Gew.-teil 20 parts by weight
- -
Beispiel 3 Example 3
Beispiel 4 Example 4
a-Naphtochinon a-naphthoquinone
2,8 Gew.-teil 2.8 parts by weight
3 Gew.-teil 3 parts by weight
Kupfernaphtenat Copper naphtenate
0,1 Gew.-teil 0.1 part by weight
1 Gew.-teil 1 part by weight
Magnesiumstearat Magnesium stearate
0,1 Gew.-teil 0.1 part by weight
1 Gew.-teil ai2o3 1 part by weight of ai2o3
9 Gew.-teil 9 parts by weight
8 Gew.-teil 8 parts by weight
Fe203 Fe203
Si02 Si02
- -
4,5 Gew.-teil 4.5 parts by weight
CaO CaO
Ammoniumbicarbonat Ammonium bicarbonate
18 Gew.-teil 18 parts by weight
17,5 Gew.-tei 17.5 parts by weight
Ammoniumcarbamat Ammonium carbamate
MgO MgO
17 Gew.-teil 17 parts by weight
5 Gew.-teil 5 parts by weight
1 MgC03 1 MgC03
NaCl NaCl
5 Gew.-teil 5 parts by weight
30 Gew.-teil 30 parts by weight
Ammoniumsulfat Ammonium sulfate
30 Gew.-teil 30 parts by weight
25 Gew.-teil 25 parts by weight
C C.
Claims (3)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU833326A HU188491B (en) | 1983-09-26 | 1983-09-26 | Additive composition for the improvement of combustion in fuels |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH661934A5 true CH661934A5 (en) | 1987-08-31 |
Family
ID=10963589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH4570/84A CH661934A5 (en) | 1983-09-26 | 1984-09-24 | COMBUSTION-IMPROVING ADDITIVE COMPOSITION FOR CLEANING HEATING DEVICES, FIREPLACES, SMOKE EXTRACTIONS AND HEAT GENERATORS. |
Country Status (8)
| Country | Link |
|---|---|
| AT (1) | AT387030B (en) |
| BG (1) | BG48696A3 (en) |
| CH (1) | CH661934A5 (en) |
| DD (1) | DD224613A5 (en) |
| DE (1) | DE3429584A1 (en) |
| HU (1) | HU188491B (en) |
| PL (1) | PL141989B1 (en) |
| RO (1) | RO90387A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107974325A (en) * | 2017-12-07 | 2018-05-01 | 河北千捷润化工科技有限公司 | Power plant's economical and environmental-protective combustion improver and preparation method thereof |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3530277A1 (en) * | 1985-08-24 | 1987-02-26 | Hoelter Heinz | Simultaneous SO2 and NOx separation preferably in fluidized-bed combustion plants |
| DE3530276A1 (en) * | 1985-08-24 | 1987-02-26 | Hoelter Heinz | Environment-friendly fuel |
| HU200361B (en) * | 1987-12-28 | 1990-05-28 | Gyoergy Vamos | Composition and process for reducing slagging of boiler furnaces and sulfur emission |
| FR2749855B1 (en) * | 1996-10-10 | 1998-10-30 | Eurexim | SOLID FUEL AGENT FOR DESTRUCTION OF SOOT AND TARS, MANUFACTURING METHOD THEREOF AND USE THEREOF |
| GB0207876D0 (en) | 2002-04-05 | 2002-05-15 | British Nuclear Fuels Plc | Removal of blockages from pipework |
| US7276094B2 (en) | 2003-11-25 | 2007-10-02 | Ethyl Petroleum Additives, Inc. | Mixed metal catalyst additive and method for use in hydrocarbonaceous fuel combustion system |
| KR101844936B1 (en) | 2011-01-14 | 2018-04-03 | 인바이런멘탈 에너지 서비시즈, 인크. | Process for operating a furnace with a bituminous coal and method for reducing slag formation therewith |
| KR101440758B1 (en) * | 2014-08-07 | 2014-09-17 | 차예주 | Nature-friendly solid fuel producting method using food waste |
| CN106190430A (en) * | 2016-08-24 | 2016-12-07 | 郴州回康科技有限责任公司 | A kind of desulphurization denitration combustion adjuvant and the application in fire coal thereof |
| CN111594853A (en) * | 2020-04-30 | 2020-08-28 | 山东清博生态材料综合利用有限公司 | Coke inhibitor for hazardous waste incineration kiln |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2044640A1 (en) * | 1969-05-08 | 1971-02-26 | Comerzan Octavian | Combustion additive salts for fuels |
| JPS4622740Y1 (en) * | 1969-06-11 | 1971-08-06 | ||
| JPS5322505A (en) * | 1976-08-14 | 1978-03-02 | Tsuneto Yokoyama | Method of making auxiliary fuel added to mineral oil especially heavy oil |
| SU667579A1 (en) * | 1976-11-10 | 1979-06-15 | Предприятие П/Я А-7553 | Multifunctional additive to diesel fuels |
-
1983
- 1983-09-26 HU HU833326A patent/HU188491B/en not_active IP Right Cessation
-
1984
- 1984-08-10 DE DE19843429584 patent/DE3429584A1/en not_active Withdrawn
- 1984-08-23 AT AT0269884A patent/AT387030B/en not_active IP Right Cessation
- 1984-09-24 CH CH4570/84A patent/CH661934A5/en not_active IP Right Cessation
- 1984-09-24 DD DD84267558A patent/DD224613A5/en not_active IP Right Cessation
- 1984-09-25 RO RO84115801A patent/RO90387A/en unknown
- 1984-09-25 PL PL1984249738A patent/PL141989B1/en unknown
- 1984-09-25 BG BG066969A patent/BG48696A3/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107974325A (en) * | 2017-12-07 | 2018-05-01 | 河北千捷润化工科技有限公司 | Power plant's economical and environmental-protective combustion improver and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| RO90387A (en) | 1986-10-30 |
| BG48696A3 (en) | 1991-04-15 |
| HU188491B (en) | 1986-04-28 |
| PL249738A1 (en) | 1985-06-04 |
| AT387030B (en) | 1988-11-25 |
| ATA269884A (en) | 1988-04-15 |
| DE3429584A1 (en) | 1985-04-11 |
| PL141989B1 (en) | 1987-09-30 |
| DD224613A5 (en) | 1985-07-10 |
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