KR101440758B1 - Nature-friendly solid fuel producting method using food waste - Google Patents

Nature-friendly solid fuel producting method using food waste Download PDF

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KR101440758B1
KR101440758B1 KR1020140101637A KR20140101637A KR101440758B1 KR 101440758 B1 KR101440758 B1 KR 101440758B1 KR 1020140101637 A KR1020140101637 A KR 1020140101637A KR 20140101637 A KR20140101637 A KR 20140101637A KR 101440758 B1 KR101440758 B1 KR 101440758B1
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solid fuel
fuel
kgf
food material
mixture
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KR1020140101637A
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Korean (ko)
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차예주
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차예주
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Priority to PCT/KR2015/000182 priority patent/WO2016021787A1/en
Priority to CN201510024236.3A priority patent/CN105368519B/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/445Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24Mixing, stirring of fuel components
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/30Pressing, compressing or compacting
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/32Molding or moulds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

The present invention relates to a method for manufacturing eco-friendly solid fuel, the method including: stirring a waste food material mixed together with chaff, oak sawdust, corn stalk, rice straw, barley, wheat stalk, peanut shells and coconut shells; putting the stirred waste food material in a compressor and pressuring the stirred waste food material with a pressure of 90 to 100 tons; putting the pressured waste food material in a heating pot to heat the waste food material at 400 to 600°C for 20 hours; removing moisture and gas from the heated waste food material to form a primary molded charcoal; putting silica, sodium chloride, starch and water into the primary molded charcoal and stirring the mixture to form a fuel mixture; pressuring the fuel mixture by using a compressor with a pressure of 90 to 100 tons to form the fuel mixture into the shape of solid fuel; and drying the solid fuel at room temperature for a certain period of time and completing the manufacturing of the eco-friendly solid fuel having a strength of 180 kgf to 250 kgf before combustion, wherein the strength of ash after combustion of the solid fuel is greater than 60 kgf. The waste food material is characterized by being mixed with 90% of chaff, 2.4% of oak sawdust, 2% of corn stalk, 1.2% of a rice straw, 1.2% of barley, 1.1% of wheat stalk, 1.1% of peanut shells and 1% of coconut shells, and the fuel mixture is formed by mixing 300 to 400 g of silica, 200 to 300 g of sodium chloride, 10 to 15 g of starch and 100 to 250 g of distilled water to the primary molded charcoal.

Description

폐식자재를 이용한 친환경 고체연료 제조방법 및 이에 의해 제조된 친환경 고체연료{NATURE-FRIENDLY SOLID FUEL PRODUCTING METHOD USING FOOD WASTE}BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing an environmentally friendly solid fuel using waste materials,

본 발명은 친환경 고체연료 제조방법 및 이에 의해 제조된 친환경 고체연료에 관한 것으로서, 보다 자세히는 버려지는 폐식자재를 이용해 유해물질을 생성하지 않는 친환경 고체연료를 제조하는 제조방법 및 이에 의해 제조된 친환경 고체연료에 관한 것이다. The present invention relates to a process for producing an environmentally friendly solid fuel and an environmentally friendly solid fuel produced thereby. More particularly, the present invention relates to a process for producing an environmentally friendly solid fuel which does not generate harmful substances by using abandoned waste materials, Fuel.

최근 기름값의 폭등에 따라 난방연료로 연탄의 사용이 다시 증가하고 있다. 또한, 음식점들에서도 연탄에 구운 음식의 수요가 증가함에 따라 연탄 사용이 증가하고 있다. Recently, the use of briquettes as heating fuel has been increasing again due to the surge in oil prices. In addition, the demand for briquetted food in restaurants has increased, and the use of briquettes is increasing.

연탄은 공개특허 제1984-0003280호에 개시된 "연탄 제조방법"에 의해 제조된다. 통상 연탄은 화석연료인 석탄을 이용해 제조되므로, 연탄을 연소할 경우 유해성분이 발생된다. The briquettes are manufactured by "briquette production method" disclosed in Japanese Patent Laid-Open No. 1984-0003280. Normally, briquettes are produced using coal, which is a fossil fuel, so when burning briquette, harmful substances are generated.

도 1은 연탄의 연소시 발생되는 유해성분의 분석결과를 나타낸 도표이다. 도표에 도시된 바와 같이 연탄은 납, 카드뮴, 구리, 크롬, 비소 및 수은 등의 유해성분이 공정규격 보다는 낮으나 상당한 양이 배출된다. 특히, 일산화탄소와 이산화탄소가 대량으로 발생되며 대기를 오염시키고, 카드뮴과 비소와 같은 발암물질을 발생시켜 인체에 유해한 영향을 준다. BRIEF DESCRIPTION OF DRAWINGS FIG. 1 is a chart showing the analysis result of harmful components generated when burning briquettes. FIG. As shown in the chart, briquettes have a lower level of harmful components such as lead, cadmium, copper, chromium, arsenic, and mercury, but a significant amount is emitted. In particular, carbon monoxide and carbon dioxide are generated in large quantities, pollute the atmosphere, and produce carcinogenic substances such as cadmium and arsenic, which have harmful effects on the human body.

또한, 연탄의 연소후 잔류하는 연탄재가 공기 중으로 비산하며 토양오염을 비롯한 자연을 훼손하게 된다. 이에 연탄재를 별도로 처리하기 위한 처리비용도 별도로 발생되는 문제가 있다.
In addition, briquette residue remaining after the burning of briquettes is scattered into the air and damages the nature including soil pollution. There is a problem in that a treatment cost for separately treating the briquette material is generated separately.

본 발명의 목적은 상술한 문제를 해결하기 위한 것으로, 화석연료가 아닌 폐식자재를 이용하여 인체와 자연에 무해한 친환경적인 고체연료 제조방법과 이에 의해 제조된 고체연료를 제공하는 것이다. An object of the present invention is to provide an environmentally friendly solid fuel production method which is harmless to the human body and nature by using waste materials that are not fossil fuels, and a solid fuel produced thereby.

본 발명의 다른 목적은 연소후 잔류하는 재가 일정 강도 이상을 갖도록 고형화하여 공기중으로 미세먼지가 비산되는 것을 방지할 수 있는 친화경 고체연료 제조방법과 이에 의해 제조된 친화경 고체연료를 제공하는 것이다. Another object of the present invention is to provide an affinity light solid fuel production method capable of preventing fine dust from being scattered into the air by solidifying the ash remaining after combustion to have a certain strength or more, and to provide an affinity light solid fuel produced thereby.

본 발명의 또 다른 목적은 연소시 충분한 발열량을 제공하여 화석연료를 대체할 수 있는 친환경 고체연료 제조방법과 이에 의해 제조된 친환경 고체연료를 제공하는 것이다. Another object of the present invention is to provide an environmentally friendly solid fuel manufacturing method capable of replacing fossil fuels by providing a sufficient calorific value during combustion and to provide an environmentally friendly solid fuel produced thereby.

본 발명의 상기 목적과 여러 가지 장점은 이 기술분야에 숙련된 사람들에 의해 본 발명의 바람직한 실시예로부터 더욱 명확하게 될 것이다.
The above objects and various advantages of the present invention will become more apparent from the preferred embodiments of the present invention by those skilled in the art.

본 발명의 목적은 친환경 고체연료 제조방법에 의해 달성될 수 있다. 본 발명의 친환경 고체연료 제조방법은, 왕겨, 참나무 톱밥, 옥수수대, 볏집, 보리대, 밀대, 땅콩껍질, 야자껍질을 혼합한 폐식자재를 함께 교반하는 단계와; 교반된 상기 폐식자재를 압축기에 넣고 90~100ton의 압력으로 가압하는 단계와; 가압된 상기 폐식자재를 가열솥에 투입하고, 400~600℃ 온도에서 20시간 가열하는 단계와; 가열된 폐식자재로부터 수분과 가스를 제거하여 1차 성형숯으로 형성하는 단계와; 상기 1차 성형숯에 실리카, 염화나트륨, 전분, 물을 넣고 교반하여 연료혼합물을 형성하는 단계와; 상기 연료혼합물을 압축기를 이용해 90~100ton의 압력으로 가압하며 고체연료의 형상으로 성형하는 단계와; 고체연료를 상온에서 일정시간 건조하여 연소전에 180kgf~250kgf의 강도를 가지며, 연소후의 재의 강도가 60kgf 이상인 친환경 고체연료를 완성하는 단계를 포함하며, 상기 폐식자재는 왕겨 90%, 참나무톱밥 2.4%, 옥수수대 2%, 볏집 1.2%, 보리대 1.2%, 밀대 1.1%, 땅콩껍질 1.1%, 야자껍질 1%로 혼합되며, 상기 연료혼합물은 상기 1차 성형숯 1kg에 실리카 300g~400g, 염화나트륨 200~300g, 전분 10g~15g, 정류수 100g~250g을 혼합하여 형성되는 것을 특징으로 한다. The object of the present invention can be achieved by a method of manufacturing an environmentally friendly solid fuel. The method for producing an environmentally friendly solid fuel according to the present invention includes the steps of stirring a rice meal, an oak sawdust, a cornstalk, a rice straw, a barley stand, a stick, a peanut shell, Placing the agitated waste material in a compressor and pressurizing the waste material at a pressure of 90 to 100 tons; Feeding the pressurized waste material into a heating pot and heating the mixture at a temperature of 400 to 600 DEG C for 20 hours; Removing moisture and gas from the heated waste foodstuff to form a primary molded charcoal; Adding silica, sodium chloride, starch, and water to the primary shaped charcoal and stirring to form a fuel mixture; Compressing the fuel mixture at a pressure of 90 to 100 tons using a compressor and shaping the fuel mixture into a shape of a solid fuel; Comprising the step of drying the solid fuel at a room temperature for a certain period of time to complete an eco-friendly solid fuel having a strength of 180 kgf to 250 kgf before the combustion and a strength of the ash after the burning of 60 kgf or more, wherein the waste material comprises 90% The fuel mixture is mixed with 1 kg of the primary shaped charcoal in an amount of 300 to 400 g of silica, 200 to 200 g of sodium chloride, 1 to 2 g of corn, 1.2% of corn, 1.2% of barley, 1.1% 300 g of starch, 10 g to 15 g of starch and 100 g to 250 g of purified water.

본 발명의 목적은 상술한 친한경 고체연료 제조방법에 의해 제조된 친환경 고체연료에 의해 달성될 수도 있다.
The object of the present invention may also be achieved by an environmentally friendly solid fuel produced by the above-described method of manufacturing a light-weight solid fuel.

본 발명의 친환경 고체연료 제조방법에 의해 제조된 친환경 고체연료는 버려지는 폐식재료를 이용한 신재생 에너지이다. 또한, 친환경 고체연료의 연소시에 일산화탄소 및 이산화탄소를 비롯한 유해성분 발생량이 종래 연탄에 비해 현저히 줄어든다. 특히, 카드뮴과 비소와 같은 발암물질은 생성하지 않는다. 이에 따라 대기오염을 비롯한 자연훼손을 최소화할 수 있다. The eco-friendly solid fuel produced by the method of the present invention is renewable energy using waste materials. In addition, when the environmentally friendly solid fuel is burned, the amount of harmful components such as carbon monoxide and carbon dioxide is significantly reduced as compared with the conventional briquettes. In particular, it does not produce carcinogens such as cadmium and arsenic. Accordingly, natural damage including air pollution can be minimized.

한편, 기존 화석연료로 형성되는 종래 연탄에 비교할 때 본 발명의 친환경 고체연료는 4800kcal 이상의 충분한 열량을 발생시켜 대체연료로서의 역할을 충분히 할 수 있다. 또한, 기존연탄 1장이 3.6kg인데 반해 본 발명의 친환경 고체연료는 1.5kg으로 무게가 가벼워 운반이 용이하고 사용이 편리하다.
On the other hand, compared with conventional briquettes formed of conventional fossil fuels, the eco-friendly solid fuel of the present invention generates a sufficient amount of heat of 4800 kcal or more and can sufficiently serve as an alternative fuel. In addition, the conventional briquettes have a weight of 3.6 kg, whereas the eco-friendly solid fuel of the present invention has a weight of 1.5 kg, which is easy to carry and convenient to use.

도 1은 종래 연탄의 유해성분 분석결과를 도시한 도표,
도 2는 본 발명의 친환경 고체연료 제조과정을 도시한 흐름도,
도 3은 본 발명의 친환경 고체연료 제조과정에 의해 제조된 친환경 고체연료를 도시한 예시도,
도 4는 본 발명의 친환경 고체연료의 서로 다른 연료혼합 비율에 따른 재의 강도를 실험한 실험그래프,
도 5는 본 발명의 친환경 고체연료와 종래 연탄의 연소시 발생되는 일산화탄소와 이산화탄소의 발생량을 측정한 실험결과,
도 6은 본 발명의 친환경 고체연료의 연소시 발생되는 유해성분 분석결과를 도시한 도표이다.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a graph showing the analysis results of harmful components of conventional briquettes,
FIG. 2 is a flow chart showing a process for producing an environmentally friendly solid fuel of the present invention,
FIG. 3 is an illustration showing an environmentally friendly solid fuel produced by the process of manufacturing an environmentally friendly solid fuel of the present invention,
FIG. 4 is an experimental graph illustrating the strength of ash of the green solid fuel according to different fuel mixing ratios of the present invention,
FIG. 5 is a graph showing the results of measurement of the amount of carbon monoxide and carbon dioxide generated during the combustion of the environmentally friendly solid fuel of the present invention and conventional briquettes,
FIG. 6 is a chart showing analysis results of harmful components generated when the environmentally friendly solid fuel is burned according to the present invention. FIG.

본 발명을 충분히 이해하기 위해서 본 발명의 바람직한 실시예를 첨부 도면을 참조하여 설명한다. 본 발명의 실시예는 여러 가지 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상세히 설명하는 실시예로 한정되는 것으로 해석되어서는 안 된다. 본 실시예는 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해서 제공되어지는 것이다. 따라서 도면에서의 요소의 형상 등은 보다 명확한 설명을 강조하기 위해서 과장되어 표현될 수 있다. 각 도면에서 동일한 부재는 동일한 참조부호로 도시한 경우가 있음을 유의하여야 한다. 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 공지 기능 및 구성에 대한 상세한 기술은 생략된다.
For a better understanding of the present invention, a preferred embodiment of the present invention will be described with reference to the accompanying drawings. The embodiments of the present invention may be modified into various forms, and the scope of the present invention should not be construed as being limited to the embodiments described in detail below. The present embodiments are provided to enable those skilled in the art to more fully understand the present invention. Therefore, the shapes and the like of the elements in the drawings can be exaggeratedly expressed to emphasize a clearer description. It should be noted that in the drawings, the same members are denoted by the same reference numerals. Detailed descriptions of well-known functions and constructions which may be unnecessarily obscured by the gist of the present invention are omitted.

도 2는 본 발명의 친환경 고체연료 제조과정을 도시한 흐름도이고, 도 3은 본 발명의 친환경 고체연료 제조과정에 의해 제조된 친환경 고체연료(100)를 도시한 예시도이다. FIG. 2 is a flow chart illustrating a process for manufacturing an environmentally friendly solid fuel according to the present invention, and FIG. 3 is an exemplary diagram illustrating an environmentally friendly solid fuel 100 manufactured by the process of manufacturing an environmentally friendly solid fuel of the present invention.

도시된 바와 같이 본 발명에 따른 친환경 고체연료(100)는 외관 형상은 종래 연탄과 동일하도록 형성된다. 이에 의해 본 발명의 친환경 고체연료(100)는 종래 연탄을 사용하던 난로나 화덕 등에 사용될 수 있다. 친환경 고체연료(100)는 연료본체(110) 표면에 연소시 발생되는 열량과 연소시간을 고려하여 10~25개의 구멍(120)이 형성될 수 있다.
As shown in the drawing, the environmentally friendly solid fuel 100 according to the present invention is formed so that its external shape is the same as that of conventional briquettes. Accordingly, the environmentally friendly solid fuel 100 of the present invention can be used in a fireplace or an oven where conventional briquettes are used. 10 to 25 holes 120 may be formed on the surface of the fuel body 110 in consideration of the amount of heat generated during combustion and the combustion time.

친환경 고체연료(100)는 왕겨, 참나무 톱밥, 옥수수대, 볏집, 밀대, 땅콩껍질, 야자껍질로 이루어진 폐식자재를 이용해 제조된다. 폐식자재는 사람이 음식물을 먹은 후 버려지는 것이다. 버려진 폐식자재를 이용해 본 발명의 친환경 고체연료(100)를 형성하므로 친환경적이고 위생적이며 무독무해하고 화력은 강해질 수 있다. The environmentally friendly solid fuel 100 is manufactured using a waste food material consisting of rice hull, oak sawdust, corn stand, rice straw, stick, peanut shell, and palm shell. The abolished materials are those that are consumed after a person eats food. Friendly eutectic solid fuel 100 according to the present invention by using abandoned waste materials, and thus can be environmentally friendly, sanitary, non-toxic and firepower.

왕겨는 벼의 껍질을 의미하는 것으로, 벼를 도정할 때 버려지는 부산물이다. 참나무 톱밥은 참나무 목재를 켜거나 자를 때에 나무에서 쓸려 나오는 가루를 의미하는 것으로, 목재를 재단할 때 버려지는 부산물이다. 옥수수대는 옥수수 껍질이고, 밀대는 밀의 껍질이다. 땅콩껍질과 야자껍질은 각각 땅콩과 야자의 껍질이다. Rice horses are the bark of rice, a by-product of rice paddy. Oakwood sawdust refers to powder that is washed away from the tree when oak wood is turned on or cut. It is a by-product that is discarded when cutting wood. The corn stand is a corn husk, and a wheat is a shell of wheat. Peanut shells and palm shells are peanuts and palm shells, respectively.

왕겨, 참나무 톱밥, 옥수수대, 볏집, 밀대, 땅콩껍질, 야자껍질은 가공과정에서 버려지는 부산물이지만, 성분의 대부분은 연소시 다량의 열량을 방출할 수 있는 섬유질로 이루어진다. Rice hulls, oak sawdust, corn stalks, cornstalks, sticks, peanut hulls, and coconut shells are by-products that are discarded during processing, but most of the ingredients consist of fibers that can release a large amount of heat when burned.

여기서, 폐식자재를 형성하는 각 부산물들은 일정한 비율로 혼합된다. 즉, 전체 폐식자재의 무게에 대해 대해 왕겨 90%, 참나무톱밥 2.4%, 옥수수대 2%, 볏집 1.2% , 보리대 1.2%, 밀대 1.1%, 땅콩껍질 1.1%, 야자껍질 1%로 혼합된다. 이러한 혼합비율은 연소시 종래 연탄에 비해 높은 열량을 방출하기 위해 최적화된 값이다.
Here, the byproducts forming the waste material are mixed at a constant ratio. That is, about 90% of the total waste materials are mixed with 90% of rice hull, 2.4% of oak sawdust, 2% of corn, 1.2% of rice husk, 1.2% of barley, 1.1% of stick, 1.1% of peanut husk and 1% of palm husk. This blend ratio is optimized for burning, which is higher than conventional briquettes.

친환경 고체연료(100)의 제조를 위해 도 2에 도시된 바와 같이 상술한 혼합비율에 따라 폐식자재를 함께 교반하여 잘 혼합한다(S110). 여기서, 각 폐식자재는 교반하면서 잘게 분쇄될 수 있다. For the production of the environmentally friendly solid fuel 100, the waste materials are stirred together according to the mixing ratio as shown in FIG. 2 and mixed well (S110). Here, each of the waste materials can be finely pulverized while stirring.

서로 잘 혼합된 폐식자재를 압축기에 넣고 가압한다(S120). 여기서, 폐식자재 1kg에 대해 압축기는 90~100ton의 압력을 가한다. 가압과정을 거치면서 폐식자재에 포함되어 있는 수분이 외부로 배출되게 된다. The waste materials mixed well are put into the compressor and pressurized (S120). Here, the compressor applies 90 to 100 tons of pressure to 1 kg of waste materials. And the moisture contained in the waste food material is discharged to the outside through the pressurizing process.

가압된 폐식자재는 가열솥에 투입된 후, 섭씨 400~600도의 온도에서 20시간 동안 가열된다(S130). 그리고, 가열된 폐식자재를 냉풍건조기를 이용해 교반, 압축 및 가열의 과정에서 발생한 수분 및 가스를 제거한다(S140). 수분 및 가스의 제거가 완료되면, 폐식자재가 탄화된 1차 성형숯이 형성된다. The pressurized waste food material is put into a heating pot and heated at a temperature of 400 to 600 degrees Celsius for 20 hours (S130). Then, water and gas generated in the process of stirring, compressing, and heating the hot rolled food material are removed using a cold air dryer (S140). When the removal of moisture and gas is completed, a primary molded char is formed in which the waste material is carbonized.

1차 성형숯에 실리카, 염화나트륨, 전분, 물을 넣고 교반하여 연료혼합물을 형성한다(S150). 여기서, 실리카는 녹는점이 1200℃ 이상으로, 녹으면서 주변의 물질을 잡아당겨 주는 역할을 한다. 염화나트륨은 실리카의 녹는점을 현저히 낮춰주는 역할을 한다. 전분과 물은 1차 성형숯을 뭉쳐주는 역할을 한다. Silica, sodium chloride, starch and water are added to the primary shaped charcoal and stirred to form a fuel mixture (S150). Here, the silica has a melting point of 1200 ° C or higher and serves to pull around the material while melting. Sodium chloride plays a role in lowering the melting point of silica significantly. Starch and water act as the primary charcoal.

실리카가 1200℃ 이하에서는 녹지 않으므로 고체연료(100)의 재의 강도가 현저히 떨어져 연탄재의 기준강도인 60kgf 이하가 된다. 이에 염화나트륨을 함께 섞어주면 실리카의 녹는점을 600℃까지 낮추어 고체연료(100)의 재의 강도를 60kgf 이상으로 형성할 수 있다. 여기서, 실리카는 연소시 화학반응을 일으키지 않는다. Since the silica does not dissolve at a temperature of 1200 DEG C or less, the strength of the ash of the solid fuel 100 is remarkably reduced and becomes 60 kgf or less, which is the reference strength of the briquette. If the sodium chloride is mixed together, the melting point of the silica can be lowered to 600 ° C, and the strength of the ash of the solid fuel 100 can be formed to be 60 kgf or more. Here, silica does not cause a chemical reaction upon combustion.

여기서, 1차 성형숯 1kg에 대해 실리카는 300~400g, 염화나트륨은 200~300g, 전분 10~15g, 물 100~150g을 혼합하는 것이 바람직하다. Here, it is preferable to mix 300 to 400 g of silica, 200 to 300 g of sodium chloride, 10 to 15 g of starch and 100 to 150 g of water per 1 kg of the primary shaped charcoal.

도 4의 (a)는 1차 성형숯이 서로 다른 혼합비율로 실리카, 염화나트륨, 전분, 물이 혼합되어 제조된 친환경 고체연료(100)를 연소시킨 후 남은 재의 강도를 실험한 그래프이다. 도 4의 (b)는 각 실험 차수에 대응하는 실리카, 염화나트륨, 전분, 물의 혼합량을 도시한 도표이다. 4 (a) is a graph showing the strength of the remaining material after burning the environmentally friendly solid fuel 100 produced by mixing silica, sodium chloride, starch, and water at different mixing ratios of the primary molded charcoal. 4 (b) is a chart showing the amount of silica, sodium chloride, starch, and water mixed corresponding to each experimental order.

여기서, 연료가 연소 후 남은 재의 강도가 60kgf 이상이어야 미세먼지가 날리지 않는다. Here, if the strength of the material remaining after the combustion of the fuel is 60 kgf or more, fine dust will not be blown.

1차 시험연료는 1차 성형숯 1kg에 실리카 100g, 염화나트륨 50g, 전분 5g, 물 50g을 혼합한 것이다. 2차 시험연료는 실리카 200g, 염화나트륨 100g, 전분 7g, 물 70g을 혼합한 것이다. 3차 시험연료는 실리카 300g, 염화나트륨 200g, 전분 10g, 물 100g을 혼합한 것이다. 4차 시험연료는 실리카 400g, 염화나트륨 300g, 전분 15g, 물 150g을 혼합한 것이다. The first test fuel is a mixture of 100 g of silica, 50 g of sodium chloride, 5 g of starch and 50 g of water in 1 kg of the primary molded charcoal. The secondary test fuel is a mixture of 200 g of silica, 100 g of sodium chloride, 7 g of starch and 70 g of water. The third test fuel is a mixture of 300 g of silica, 200 g of sodium chloride, 10 g of starch and 100 g of water. The fourth test fuel is a mixture of 400 g of silica, 300 g of sodium chloride, 15 g of starch and 150 g of water.

도 4의 (a)에 도시된 바와 같이 1차 시험연료는 재의 강도가 30kgf, 2차 시험연료는 재의 강도가 60kgf, 3차 시험연료는 90kgf, 4차 시험연료는 재의 강도가 100kgf에 근접한 것을 알 수 있다. As shown in FIG. 4 (a), the strength of the primary test fuel is 30 kgf, the strength of the secondary test fuel is 60 kgf, the test fuel of the third test is 90 kgf, and the strength of the fourth test fuel is close to 100 kgf Able to know.

이에 따라 재의 강도를 60kgf 이상을 유지하기 위해 실리카는 300~400g, 염화나트륨은 200~300g, 전분 10~15g, 물 100~150g을 혼합하는 것이 바람직하다.
Accordingly, it is preferable to mix 300 to 400 g of silica, 200 to 300 g of sodium chloride, 10 to 15 g of starch, and 100 to 150 g of water to maintain the strength of the ash of 60 kgf or more.

연료혼합물이 혼합되면, 연료혼합물을 압축기에 넣고 가압하여 연탄의 형상으로 성형한다(S160). 연료혼합물은 연탄의 형상의 틀에 투입되고, 압축기를 이용해 90~100ton의 압력을 가하여 성형한다. 이렇게 형성된 연료혼합물을 상온(25℃, 습도 30% 이하)에서 6시간~12시간 건조시켜 고체연료로 완성한다. When the fuel mixture is mixed, the fuel mixture is put into a compressor and pressurized to form a shape of briquettes (S160). The fuel mixture is injected into the mold of the briquetting shape and is molded by applying a pressure of 90 to 100 tons using a compressor. The fuel mixture thus formed is dried at room temperature (25 ° C, humidity 30% or less) for 6 hours to 12 hours to complete a solid fuel.

이렇게 건조가 완료된 고체연료는 180~250kgf의 강도를 가지며, 연소후 재의 강도도 60kgf 이상을 갖게 된다. 고체연료의 강도가 180kgf 이상이 되어야 한꺼번에 연소되지 않고 연소시간을 지연시킬 수 있다. 반면, 고체연료의 강도가 250kgf 이상이면 연소자체가 원활히 되지 않는다. The solid fuel thus dried has a strength of 180 to 250 kgf and the strength of the ash after combustion is 60 kgf or more. If the strength of the solid fuel is 180 kgf or more, the combustion time can be delayed without burning all at once. On the other hand, if the strength of the solid fuel is 250 kgf or more, the combustion itself is not smooth.

도 5는 종래 연탄과 본 발명의 친환경 고체연료의 연소시 발생되는 이산화탄소(CO2)와 일산화탄소(CO)의 량을 측정한 실험 결과이다. 종래 연탄의 착화 후 30분에 측정한 이산화탄소의 배출량을 932.5이고 일산화탄소의 배출량은 91.71이다. 이에 반해 본 발명의 친환경 고체연료의 연소시 발생되는 이산화탄소의 배출량은 417.3으로 종래 연탄에 비해 절반 이상 낮은 수치이다. 또한, 본 발명의 친환경 고체연료의 연소시 발생되는 일산화탄소의 배출량도 10.68로 종래 연탄에 비해 1/9이하로 낮아진 수치이다. FIG. 5 is a graph showing the results of an experiment in which the amount of carbon dioxide (CO 2 ) and carbon monoxide (CO) generated during combustion of the conventional briquettes and the environmentally friendly solid fuel of the present invention are measured. The emission of carbon dioxide measured at 30 minutes after ignition of conventional briquettes is 932.5 and the emission amount of carbon monoxide is 91.71. On the other hand, the emission amount of carbon dioxide generated in the combustion of the environmentally friendly solid fuel of the present invention is 417.3, which is more than half that of the conventional briquettes. In addition, the amount of carbon monoxide emitted during burning of the environmentally friendly solid fuel of the present invention is also 10.68, which is lower than 1/9 of the conventional briquettes.

도 6은 본 발명의 친환경 고체연료의 연소시 발생되는 유해성분을 분석한 결과이다. 도 1의 종래 연탄의 연소시 발생되는 유해성분과 비교해보면, 현저한 차이를 나타낸다. 납의 발생량은 연탄이 26.62ppm인데 반해 고체연료가 1.55이고, 카드뮴과 비소는 검출이 되지 않았다. 또한, 구리, 크롬, 수은도 종래 연탄에 비해 현저히 낮은 수치로 발생되는 것을 알 수 있다.
FIG. 6 is a result of analyzing harmful components generated when the environmentally friendly solid fuel is burned according to the present invention. Compared with the harmful substances generated in the combustion of the conventional briquettes of Fig. 1, they show a remarkable difference. The amount of lead generated was 26.62 ppm of briquettes, 1.55 of solid fuel, and no cadmium and arsenic were detected. It can also be seen that copper, chromium, and mercury are generated at significantly lower values than conventional briquettes.

이상에서 살펴본 바와 같이 본 발명의 친환경 고체연료 제조방법에 의해 제조된 친환경 고체연료는 버려지는 폐식재료를 이용한 신재생 에너지이다. 또한, 친환경 고체연료의 연소시에 일산화탄소 및 이산화탄소를 비롯한 유해성분 발생량이 종래 연탄에 비해 현저히 줄어든다. 특히, 카드뮴과 비소와 같은 발암물질은 생성하지 않는다. 이에 따라 대기오염을 비롯한 자연훼손을 최소화할 수 있다. As described above, the eco-friendly solid fuel produced by the method of manufacturing the environmentally friendly solid fuel of the present invention is renewable energy using the waste material. In addition, when the environmentally friendly solid fuel is burned, the amount of harmful components such as carbon monoxide and carbon dioxide is significantly reduced as compared with the conventional briquettes. In particular, it does not produce carcinogens such as cadmium and arsenic. Accordingly, natural damage including air pollution can be minimized.

한편, 기존 화석연료로 형성되는 종래 연탄에 비교할 때 본 발명의 친환경 고체연료는 5000kcal/kg 이상의 충분한 열량을 발생시켜 대체연료로서의 역할을 충분히 할 수 있다. 또한, 기존연탄 1장이 3.6kg인데 반해 본 발명의 친환경 고체연료는 1.7kg으로 무게가 가벼워 운반이 용이하고 사용이 편리하다.
On the other hand, compared with conventional briquettes formed of conventional fossil fuels, the environmentally-friendly solid fuel of the present invention generates sufficient heat of 5000 kcal / kg or more, and thus can sufficiently serve as an alternative fuel. In addition, the existing briquettes have a weight of 3.6 kg, whereas the environmentally friendly solid fuel of the present invention has a weight of 1.7 kg, which is easy to carry and convenient to use.

이상에서 설명된 본 발명의 친환경 고체연료 제조방법 및 이에 의해 제조된 친환경 고체연료의 실시예는 예시적인 것에 불과하며, 본 발명이 속한 기술분야의 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 타 실시예가 가능하다는 점을 잘 알 수 있을 것이다. 그러므로 본 발명은 상기의 상세한 설명에서 언급되는 형태로만 한정되는 것은 아님을 잘 이해할 수 있을 것이다. 따라서 본 발명의 진정한 기술적 보호 범위는 첨부된 특허청구범위의 기술적 사상에 의해 정해져야 할 것이다. 또한, 본 발명은 첨부된 청구범위에 의해 정의되는 본 발명의 정신과 그 범위 내에 있는 모든 변형물과 균등물 및 대체물을 포함하는 것으로 이해되어야 한다.
The method of manufacturing the environmentally friendly solid fuel of the present invention described above and the embodiment of the environmentally friendly solid fuel produced thereby are merely illustrative and those skilled in the art will appreciate that various modifications, It will be appreciated that other embodiments are possible. Therefore, it is to be understood that the present invention is not limited to the above-described embodiments. Accordingly, the true scope of the present invention should be determined by the technical idea of the appended claims. It is also to be understood that the invention includes all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.

100 : 고체연료 110 : 연료본체
120 : 구멍
100: solid fuel 110: fuel body
120: hole

Claims (2)

왕겨, 참나무 톱밥, 옥수수대, 볏집, 보리대, 밀대, 땅콩껍질, 야자껍질을 혼합한 폐식자재를 함께 교반하는 단계와;
교반된 상기 폐식자재를 압축기에 넣고 90~100ton의 압력으로 가압하는 단계와;
가압된 상기 폐식자재를 가열솥에 투입하고, 400~600℃ 온도에서 20시간 가열하는 단계와;
가열된 폐식자재로부터 수분과 가스를 제거하여 1차 성형숯으로 형성하는 단계와;
상기 1차 성형숯에 실리카, 염화나트륨, 전분, 물을 넣고 교반하여 연료혼합물을 형성하는 단계와;
상기 연료혼합물을 압축기를 이용해 90~100ton의 압력으로 가압하며 고체연료의 형상으로 성형하는 단계와;
고체연료를 상온에서 일정시간 건조하여 연소전에 180kgf~250kgf의 강도를 가지며, 연소후의 재의 강도가 60kgf 이상인 친환경 고체연료를 완성하는 단계를 포함하며,
상기 폐식자재는 왕겨 90%, 참나무톱밥 2.4%, 옥수수대 2%, 볏집 1.2%, 보리대 1.2%, 밀대 1.1%, 땅콩껍질 1.1%, 야자껍질 1%로 혼합되며,
상기 연료혼합물은 상기 1차 성형숯 1kg에 실리카 300g~400g, 염화나트륨 200~300g, 전분 10g~15g, 정류수 100g~250g을 혼합하여 형성되는 것을 특징으로 하는 친환경 고체연료 제조방법.
Agitating a waste food material comprising a mixture of rice hulls, oak sawdust, cornstarch, rice straw, barley stand, wheat bran, peanut shell, and coconut shell;
Placing the agitated waste material in a compressor and pressurizing the waste material at a pressure of 90 to 100 tons;
Feeding the pressurized waste material into a heating pot and heating the mixture at a temperature of 400 to 600 DEG C for 20 hours;
Removing moisture and gas from the heated waste foodstuff to form a primary molded charcoal;
Adding silica, sodium chloride, starch, and water to the primary shaped charcoal and stirring to form a fuel mixture;
Compressing the fuel mixture at a pressure of 90 to 100 tons using a compressor and shaping the fuel mixture into a shape of a solid fuel;
Drying the solid fuel at room temperature for a certain period of time to complete an eco-friendly solid fuel having a strength of 180 kgf to 250 kgf before combustion and a strength of the ash after combustion of 60 kgf or more,
The waste materials were mixed with 90% of rice hull, 2.4% of oak sawdust, 2% of corn, 1.2% of rice husk, 1.2% of barley, 1.1% of stick, 1.1% of peanut husk and 1%
Wherein the fuel mixture is formed by mixing 300 g to 400 g of silica, 200 to 300 g of sodium chloride, 10 g to 15 g of starch, and 100 g to 250 g of rectified water to 1 kg of the primary molded charcoal.
제1항의 친환경 고체연료 제조방법에 의해 제조된 친환경 고체연료. An environmentally friendly solid fuel produced by the method of claim 1.
KR1020140101637A 2014-08-07 2014-08-07 Nature-friendly solid fuel producting method using food waste KR101440758B1 (en)

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