CH620933A5 - Catalyst for the polymerisation of alpha-olefins, process for its preparation, and its use - Google Patents
Catalyst for the polymerisation of alpha-olefins, process for its preparation, and its use Download PDFInfo
- Publication number
- CH620933A5 CH620933A5 CH719375A CH719375A CH620933A5 CH 620933 A5 CH620933 A5 CH 620933A5 CH 719375 A CH719375 A CH 719375A CH 719375 A CH719375 A CH 719375A CH 620933 A5 CH620933 A5 CH 620933A5
- Authority
- CH
- Switzerland
- Prior art keywords
- compound
- polymerization
- catalyst
- alpha
- olefins
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 16
- 239000004711 α-olefin Substances 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title claims description 12
- 238000002360 preparation method Methods 0.000 title description 4
- 239000000463 material Substances 0.000 claims abstract description 20
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 11
- 229910001868 water Inorganic materials 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 150000002681 magnesium compounds Chemical class 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005977 Ethylene Substances 0.000 claims abstract description 5
- 239000008135 aqueous vehicle Substances 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims abstract description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 229910052739 hydrogen Chemical group 0.000 claims abstract description 3
- 239000001257 hydrogen Chemical group 0.000 claims abstract description 3
- 125000003118 aryl group Chemical group 0.000 claims abstract 2
- 229910052736 halogen Inorganic materials 0.000 claims abstract 2
- 125000005843 halogen group Chemical group 0.000 claims abstract 2
- 238000006116 polymerization reaction Methods 0.000 claims description 27
- 239000011777 magnesium Substances 0.000 claims description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 229910052681 coesite Inorganic materials 0.000 claims description 15
- 229910052906 cristobalite Inorganic materials 0.000 claims description 15
- 229910052682 stishovite Inorganic materials 0.000 claims description 15
- 229910052905 tridymite Inorganic materials 0.000 claims description 15
- -1 aluminum compound Chemical class 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims 2
- 241000772991 Aira Species 0.000 claims 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims 1
- 235000019341 magnesium sulphate Nutrition 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 abstract description 4
- 101100058670 Aeromonas hydrophila subsp. hydrophila (strain ATCC 7966 / DSM 30187 / BCRC 13018 / CCUG 14551 / JCM 1027 / KCTC 2358 / NCIMB 9240 / NCTC 8049) bsr gene Proteins 0.000 abstract 1
- 150000001399 aluminium compounds Chemical class 0.000 abstract 1
- 239000010936 titanium Substances 0.000 description 25
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- 229910003074 TiCl4 Inorganic materials 0.000 description 8
- 229910001629 magnesium chloride Inorganic materials 0.000 description 8
- 238000011282 treatment Methods 0.000 description 7
- 230000002045 lasting effect Effects 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- 239000011148 porous material Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- NUMXHEUHHRTBQT-AATRIKPKSA-N 2,4-dimethoxy-1-[(e)-2-nitroethenyl]benzene Chemical compound COC1=CC=C(\C=C\[N+]([O-])=O)C(OC)=C1 NUMXHEUHHRTBQT-AATRIKPKSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT23899/74A IT1014991B (it) | 1974-06-12 | 1974-06-12 | Catalizzatore per la polimerizza zione di alfa olefine metodo per la sua preparazione e processo di polimerizzazione impiegante detto catalizzatore |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH620933A5 true CH620933A5 (en) | 1980-12-31 |
Family
ID=11210741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH719375A CH620933A5 (en) | 1974-06-12 | 1975-06-04 | Catalyst for the polymerisation of alpha-olefins, process for its preparation, and its use |
Country Status (19)
| Country | Link |
|---|---|
| JP (1) | JPS5111881A (en:Method) |
| BE (1) | BE830112A (en:Method) |
| CA (1) | CA1069876A (en:Method) |
| CH (1) | CH620933A5 (en:Method) |
| CS (1) | CS189708B2 (en:Method) |
| DD (1) | DD119796A5 (en:Method) |
| DE (1) | DE2526352A1 (en:Method) |
| DK (1) | DK264375A (en:Method) |
| FR (1) | FR2274631A1 (en:Method) |
| GB (1) | GB1504417A (en:Method) |
| HU (2) | HU173924B (en:Method) |
| IL (1) | IL47461A (en:Method) |
| IT (1) | IT1014991B (en:Method) |
| LU (1) | LU72708A1 (en:Method) |
| NL (1) | NL7507036A (en:Method) |
| NO (1) | NO148851C (en:Method) |
| SE (1) | SE7506765L (en:Method) |
| YU (1) | YU142775A (en:Method) |
| ZA (1) | ZA753470B (en:Method) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0389173A3 (en) * | 1989-03-20 | 1992-01-29 | Neste Oy | Procedure for producing polymerising catalyst component, a polymerisation component, and use of the same |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS591284B2 (ja) * | 1975-06-24 | 1984-01-11 | 日石三菱株式会社 | ポリオレフインノ セイゾウホウホウ |
| DE2721194C2 (de) * | 1977-05-11 | 1983-09-08 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Herstellen von Homo- und Copolymerisaten von C↓2↓- bis C↓6↓-α-Monoolefinen |
| DE2721094A1 (de) * | 1977-05-11 | 1978-11-23 | Basf Ag | Verfahren zum herstellen einer uebergangsmetall-katalysatorkomponente fuer ziegler-katalysatorsysteme |
| DE2721058C2 (de) * | 1977-05-11 | 1983-08-25 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Herstellen von Homo- und Copolymerisaten von C↓2↓- bis C↓6↓-α-Monoolefinen |
| CA1219996A (en) * | 1982-11-10 | 1987-03-31 | Kazuo Matsuura | Process for preparing polyolefins |
| DE3823934C2 (de) * | 1987-07-31 | 2002-01-03 | Petroleo Brasileiro Sa | Verfahren zur Herstellung eines Ethylenpolymerisationskatalysators und Ethylenpolymerisationsverfahren |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5040434B2 (en:Method) * | 1971-12-14 | 1975-12-24 | ||
| JPS5248911B2 (en:Method) * | 1974-05-13 | 1977-12-13 |
-
1974
- 1974-06-12 IT IT23899/74A patent/IT1014991B/it active
-
1975
- 1975-05-28 ZA ZA00753470A patent/ZA753470B/xx unknown
- 1975-05-29 CS CS753788A patent/CS189708B2/cs unknown
- 1975-06-03 YU YU01427/75A patent/YU142775A/xx unknown
- 1975-06-04 CH CH719375A patent/CH620933A5/it not_active IP Right Cessation
- 1975-06-05 FR FR7517605A patent/FR2274631A1/fr active Granted
- 1975-06-10 LU LU72708A patent/LU72708A1/xx unknown
- 1975-06-11 BE BE157227A patent/BE830112A/xx not_active IP Right Cessation
- 1975-06-11 CA CA229,053A patent/CA1069876A/en not_active Expired
- 1975-06-11 HU HU75SA3063A patent/HU173924B/hu unknown
- 1975-06-11 DK DK264375A patent/DK264375A/da not_active Application Discontinuation
- 1975-06-11 IL IL47461A patent/IL47461A/xx unknown
- 1975-06-11 NO NO752082A patent/NO148851C/no unknown
- 1975-06-11 HU HU75SA00002800A patent/HU172079B/hu unknown
- 1975-06-12 SE SE7506765A patent/SE7506765L/xx unknown
- 1975-06-12 DE DE19752526352 patent/DE2526352A1/de active Pending
- 1975-06-12 JP JP50070244A patent/JPS5111881A/ja active Granted
- 1975-06-12 DD DD186600A patent/DD119796A5/xx unknown
- 1975-06-12 NL NL7507036A patent/NL7507036A/xx unknown
- 1975-06-12 GB GB2528175A patent/GB1504417A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0389173A3 (en) * | 1989-03-20 | 1992-01-29 | Neste Oy | Procedure for producing polymerising catalyst component, a polymerisation component, and use of the same |
Also Published As
| Publication number | Publication date |
|---|---|
| NO752082L (en:Method) | 1975-12-15 |
| HU172079B (hu) | 1978-05-28 |
| DK264375A (da) | 1975-12-13 |
| AU8170775A (en) | 1976-12-02 |
| DD119796A5 (en:Method) | 1976-05-12 |
| NO148851C (no) | 1984-01-04 |
| LU72708A1 (en:Method) | 1975-10-08 |
| IT1014991B (it) | 1977-04-30 |
| SE7506765L (sv) | 1975-12-15 |
| DE2526352A1 (de) | 1975-12-18 |
| NO148851B (no) | 1983-09-19 |
| JPS5111881A (en) | 1976-01-30 |
| CA1069876A (en) | 1980-01-15 |
| YU142775A (en) | 1982-02-28 |
| ZA753470B (en) | 1976-05-26 |
| BE830112A (fr) | 1975-10-01 |
| GB1504417A (en) | 1978-03-22 |
| IL47461A (en) | 1979-03-12 |
| IL47461A0 (en) | 1975-08-31 |
| FR2274631B1 (en:Method) | 1980-04-25 |
| FR2274631A1 (fr) | 1976-01-09 |
| NL7507036A (nl) | 1975-12-16 |
| CS189708B2 (en) | 1979-04-30 |
| JPS5615644B2 (en:Method) | 1981-04-11 |
| HU173924B (hu) | 1979-09-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased | ||
| PL | Patent ceased |