CH513785A - Process for the preparation of new bis-stilbene compounds - Google Patents

Process for the preparation of new bis-stilbene compounds

Info

Publication number
CH513785A
CH513785A CH1380667A CH1380667A CH513785A CH 513785 A CH513785 A CH 513785A CH 1380667 A CH1380667 A CH 1380667A CH 1380667 A CH1380667 A CH 1380667A CH 513785 A CH513785 A CH 513785A
Authority
CH
Switzerland
Prior art keywords
preparation
stilbene compounds
new bis
bis
new
Prior art date
Application number
CH1380667A
Other languages
German (de)
Inventor
Kurt Dr Weber
Peter Dr Liechti
Rudolf Dr Meyer Hans
Emil Dr Siegrist Adolf
Original Assignee
Ciba Geigy Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Priority to CH700070A priority Critical patent/CH566420B5/en
Priority to CH1380667A priority patent/CH513785A/en
Priority to CH700170A priority patent/CH532106A/en
Priority to CH1251168A priority patent/CH554821A/en
Priority to SE11552/68A priority patent/SE367399B/xx
Priority to DE1793482A priority patent/DE1793482C3/en
Priority to NO3765/68A priority patent/NO131456C/no
Priority to DE1794386A priority patent/DE1794386C3/en
Priority to IL30776A priority patent/IL30776A/en
Priority to IE1160/68A priority patent/IE32388B1/en
Priority to YU2263/68A priority patent/YU35093B/en
Priority to FI682768A priority patent/FI50238C/en
Priority to GB46376/68A priority patent/GB1247934A/en
Priority to SU1272695A priority patent/SU391781A3/ru
Priority to CS6816A priority patent/CS174763B2/cs
Priority to SU1805029A priority patent/SU476748A3/en
Priority to CS5622A priority patent/CS174800B2/en
Priority to RORUA57857*8A priority patent/RO55806A/ro
Priority to NL686814089A priority patent/NL145531B/en
Priority to AT361770A priority patent/AT299171B/en
Priority to BE721754D priority patent/BE721754A/xx
Priority to AT960968A priority patent/AT288306B/en
Priority to ES358737A priority patent/ES358737A1/en
Priority to DK475168AA priority patent/DK139845B/en
Priority to PL1968129326A priority patent/PL79354B1/en
Priority to MX13106868A priority patent/MX143265A/en
Priority to BR202828/68A priority patent/BR6802828D0/en
Priority to FR1583595D priority patent/FR1583595A/fr
Priority to CH479169A priority patent/CH554848A/en
Priority to DE2012779A priority patent/DE2012779C3/en
Priority to FR7010578A priority patent/FR2044704A6/fr
Priority to BE748017D priority patent/BE748017R/en
Priority to NL7004439A priority patent/NL7004439A/xx
Priority to GB04984/70A priority patent/GB1298577A/en
Priority to ES378656A priority patent/ES378656A1/en
Priority to JP133771A priority patent/JPS54929B1/ja
Publication of CH513785A publication Critical patent/CH513785A/en
Priority to US05/509,768 priority patent/US3984399A/en
Priority to HK530/76*UA priority patent/HK53076A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182—Radicals derived from carboxylic acids
    • C07D295/192—Radicals derived from carboxylic acids from aromatic carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/324—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a phosphorus atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2635—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving a phosphorus compound, e.g. Wittig synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/32—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by introduction of halogenated alkyl groups into ring compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/24—Halogenated aromatic hydrocarbons with unsaturated side chains
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/29—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/39—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing halogen atoms bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/63—Esters of sulfonic acids
    • C07C309/72—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/73—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/78—Halides of sulfonic acids
    • C07C309/86—Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/78—Halides of sulfonic acids
    • C07C309/86—Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/87—Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/15—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C311/16—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/15—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C311/16—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom
    • C07C311/17—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom to an acyclic carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/02—Sulfinic acids; Derivatives thereof
    • C07C313/04—Sulfinic acids; Esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/14—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/44—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reduction and hydrolysis of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/546—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings polycyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/55—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/30—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings
    • C07C57/42—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings having unsaturation outside the rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/64—Acyl halides
    • C07C57/72—Acyl halides containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/66—Polycyclic acids with unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
    • C07D295/26—Sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
    • C—CHEMISTRY; METALLURGY
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
    • C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/3241—Esters of arylalkanephosphinic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4056—Esters of arylalkanephosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/535—Organo-phosphoranes
    • C07F9/5352—Phosphoranes containing the structure P=C-
    • C—CHEMISTRY; METALLURGY
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    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C—CHEMISTRY; METALLURGY
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    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5456—Arylalkanephosphonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/14—Styryl dyes
    • C09B23/141—Bis styryl dyes containing two radicals C6H5-CH=CH-
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/14—Styryl dyes
    • C09B23/148—Stilbene dyes containing the moiety -C6H5-CH=CH-C6H5
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Paper (AREA)
CH1380667A 1967-10-03 1967-10-03 Process for the preparation of new bis-stilbene compounds CH513785A (en)

Priority Applications (38)

Application Number Priority Date Filing Date Title
CH700070A CH566420B5 (en) 1967-10-03 1967-10-03 Bis-stilbene compds for use as optical brighteners
CH1380667A CH513785A (en) 1967-10-03 1967-10-03 Process for the preparation of new bis-stilbene compounds
CH700170A CH532106A (en) 1967-10-03 1967-10-03 Bis-stilbene compds for use as optical brighteners
CH1251168A CH554821A (en) 1967-10-03 1968-08-20 Prepg. fluorescent bis-stilbene cpds. - for use as optical brighteners for organic materials
SE11552/68A SE367399B (en) 1967-10-03 1968-08-28
DE1793482A DE1793482C3 (en) 1967-10-03 1968-09-24 New bis-stilbene compounds and processes for their preparation
NO3765/68A NO131456C (en) 1967-10-03 1968-09-24
DE1794386A DE1794386C3 (en) 1967-10-03 1968-09-24 Use of bis-stilbene compounds as optical brightening agents
IL30776A IL30776A (en) 1967-10-03 1968-09-27 Bis-stilbene compounds,their manufacture and optical bright eners containing them
IE1160/68A IE32388B1 (en) 1967-10-03 1968-09-27 Bis-stilbene compounds,their manufacture and use
YU2263/68A YU35093B (en) 1967-10-03 1968-09-30 Process for preparing bis-stilbene compounds
FI682768A FI50238C (en) 1967-10-03 1968-09-30 Symmetrical bis-stilbene compounds useful as optical brighteners.
GB46376/68A GB1247934A (en) 1967-10-03 1968-09-30 Bis-stilbene compounds, their manufacture and use
SU1272695A SU391781A3 (en) 1967-10-03 1968-10-01
CS6816A CS174763B2 (en) 1967-10-03 1968-10-01
SU1805029A SU476748A3 (en) 1967-10-03 1968-10-01 The method of obtaining bis-stilbene compounds
CS5622A CS174800B2 (en) 1967-10-03 1968-10-01 Process for preparing bis-stilbene compounds
AT361770A AT299171B (en) 1967-10-03 1968-10-02 Process for the preparation of new bis-stilbene compounds
NL686814089A NL145531B (en) 1967-10-03 1968-10-02 PROCESS FOR THE PREPARATION OF BIS-STILLBONE COMPOUNDS, PROCESS FOR OPTICAL BLEACHING OF ORGANIC MATERIALS, AND PROCESS FOR PREPARING SOAP AND DETERGENTS UNDER THE APPLICATION OF THESE BIS-STILLBONE COMPOUNDS, OR MERELY ORGANIZED STILL BLEACHING MATERIALS.
RORUA57857*8A RO55806A (en) 1967-10-03 1968-10-02
BE721754D BE721754A (en) 1967-10-03 1968-10-02
AT960968A AT288306B (en) 1967-10-03 1968-10-02 Optical brighteners
ES358737A ES358737A1 (en) 1967-10-03 1968-10-02 Procedure for preparing bis-estilben compounds. (Machine-translation by Google Translate, not legally binding)
DK475168AA DK139845B (en) 1967-10-03 1968-10-02 Bis-stilbene compounds for use as optical clarifiers.
PL1968129326A PL79354B1 (en) 1967-10-03 1968-10-02 Bis-stilbene compounds, their manufacture and use[gb1247934a]
MX13106868A MX143265A (en) 1967-10-03 1968-10-02 PROCEDURE FOR PREPARING BIS-STYLBENE COMPOUNDS
BR202828/68A BR6802828D0 (en) 1967-10-03 1968-10-03 PROCESS FOR THE MANUFACTURE OF BISSTYLBENE COMPOUNDS AND OPTICAL REVIVAL PROCESS BASED ON THESE
FR1583595D FR1583595A (en) 1967-10-03 1968-10-20
CH479169A CH554848A (en) 1967-10-03 1969-03-27 PROCESS FOR PRODUCING NEW STILBENE DERIVATIVES.
DE2012779A DE2012779C3 (en) 1967-10-03 1970-03-18 Stilbene derivatives
FR7010578A FR2044704A6 (en) 1967-10-03 1970-03-24
BE748017D BE748017R (en) 1967-10-03 1970-03-26 NEW BIS-STILBENE COMPOUNDS, THEIR PREPARATION PROCESS AND THEIR
NL7004439A NL7004439A (en) 1967-10-03 1970-03-26
GB04984/70A GB1298577A (en) 1967-10-03 1970-03-26 New stilbene derivatives
ES378656A ES378656A1 (en) 1967-10-03 1970-04-16 Procedure for the optical clarification of organic materials. (Machine-translation by Google Translate, not legally binding)
JP133771A JPS54929B1 (en) 1967-10-03 1971-01-20
US05/509,768 US3984399A (en) 1967-10-03 1974-09-27 Bis-stilbene compounds
HK530/76*UA HK53076A (en) 1967-10-03 1976-08-26 Bis-stilbene compounds, their manufacture and use

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH1380667A CH513785A (en) 1967-10-03 1967-10-03 Process for the preparation of new bis-stilbene compounds

Publications (1)

Publication Number Publication Date
CH513785A true CH513785A (en) 1971-10-15

Family

ID=4395511

Family Applications (4)

Application Number Title Priority Date Filing Date
CH700070A CH566420B5 (en) 1967-10-03 1967-10-03 Bis-stilbene compds for use as optical brighteners
CH1380667A CH513785A (en) 1967-10-03 1967-10-03 Process for the preparation of new bis-stilbene compounds
CH700170A CH532106A (en) 1967-10-03 1967-10-03 Bis-stilbene compds for use as optical brighteners
CH1251168A CH554821A (en) 1967-10-03 1968-08-20 Prepg. fluorescent bis-stilbene cpds. - for use as optical brighteners for organic materials

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CH700070A CH566420B5 (en) 1967-10-03 1967-10-03 Bis-stilbene compds for use as optical brighteners

Family Applications After (2)

Application Number Title Priority Date Filing Date
CH700170A CH532106A (en) 1967-10-03 1967-10-03 Bis-stilbene compds for use as optical brighteners
CH1251168A CH554821A (en) 1967-10-03 1968-08-20 Prepg. fluorescent bis-stilbene cpds. - for use as optical brighteners for organic materials

Country Status (22)

Country Link
JP (1) JPS54929B1 (en)
AT (2) AT288306B (en)
BE (1) BE721754A (en)
BR (1) BR6802828D0 (en)
CH (4) CH566420B5 (en)
CS (2) CS174763B2 (en)
DE (1) DE1793482C3 (en)
DK (1) DK139845B (en)
ES (2) ES358737A1 (en)
FI (1) FI50238C (en)
FR (1) FR1583595A (en)
GB (1) GB1247934A (en)
HK (1) HK53076A (en)
IE (1) IE32388B1 (en)
IL (1) IL30776A (en)
NL (1) NL145531B (en)
NO (1) NO131456C (en)
PL (1) PL79354B1 (en)
RO (1) RO55806A (en)
SE (1) SE367399B (en)
SU (2) SU476748A3 (en)
YU (1) YU35093B (en)

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* Cited by examiner, † Cited by third party
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CH540233A (en) * 1969-06-05 1973-08-15 Ciba Geigy Ag Process for the preparation of new di-styrylbenzene derivatives
US3880841A (en) * 1971-03-18 1975-04-29 Sandoz Ltd Triazolyl ethenyl phenylene derivatives
CH1917171A4 (en) * 1971-12-30 1975-04-30
FR2168210A2 (en) * 1972-01-20 1973-08-31 Ciba Geigy Ag Bis-stilbene cpds - as optical brighteners
DE2326467B2 (en) * 1972-06-01 1979-02-22 Colgate-Palmolive Co., New York, N.Y. (V.St.A.) Liquid heavy duty detergent
CH569043A5 (en) * 1973-01-23 1975-11-14 Ciba Geigy Ag
CH630215B (en) * 1976-07-09 Ciba Geigy Ag LIGHTENING AGENTS AND THEIR USE FOR LIGHTENING TEXTILES.
ZA802159B (en) * 1979-04-11 1981-04-29 Ciba Geigy Ag Distyrylbenzenes
ZA802160B (en) * 1979-04-11 1981-04-29 Ciba Geigy Ag Distyrylbiphenyls
US4339393A (en) * 1979-04-11 1982-07-13 Ciba-Geigy Corporation Distyrylbiphenyls
EP0054511B1 (en) * 1980-12-12 1987-05-13 Ciba-Geigy Ag 4-styryl-4'-vinylbifenyls, methods for their preparation and their use as optical whiteners
US4925595A (en) * 1987-07-03 1990-05-15 Ciba-Geigy Corporation Liquid detergent compositions containing disulfonated fluorescent whitening agents: di-styryl-biphenyl or di-styryl-benzene derivatives
DE58903875D1 (en) * 1988-10-13 1993-04-29 Ciba Geigy Ag DISTYRYLBIPHENYL COMPOUNDS.
DE4019309A1 (en) * 1990-06-16 1991-12-19 Bayer Ag NEW LIGHT-POLARIZING FILMS OR FILMS AND DYES FOR THEIR PRODUCTION
MY109837A (en) * 1992-06-30 1997-08-30 Ciba Specialty Chemicals Holding Inc Hydrates of the disodium salt or dipotassium salt of 4, 4''-bis (2-sulfostyryl)bipheny]
TW229199B (en) * 1992-09-03 1994-09-01 Ciba Geigy
GB2277749B (en) * 1993-05-08 1996-12-04 Ciba Geigy Ag Fluorescent whitening of paper
US6168776B1 (en) * 1994-07-19 2001-01-02 University Of Pittsburgh Alkyl, alkenyl and alkynyl Chrysamine G derivatives for the antemortem diagnosis of Alzheimer's disease and in vivo imaging and prevention of amyloid deposition
GB9422280D0 (en) * 1994-11-04 1994-12-21 Ciba Geigy Ag Fluorescent whitening agent formulation
GB9718353D0 (en) * 1997-08-30 1997-11-05 Ciba Geigy Ag Sulphonated distyryl - Biphenyl compounds
ID25593A (en) 1998-03-19 2000-10-19 Ciba Sc Holding Ag THE PROCESS OF MAKING SULFONATED DISTRIL-BEFENIL COMPOUNDS
KR100274871B1 (en) * 1998-11-12 2000-12-15 김순택 Photoluminescence compound and display device adopting photoluminescence compound as color-developing substance
DE10334046A1 (en) * 2003-07-25 2005-02-10 Clariant Gmbh Process for the preparation of granulated acyloxybenzenesulfonates or acyloxybenzenecarboxylic acids and their salts
GB0405193D0 (en) * 2004-03-08 2004-04-21 Medical Res Council Compounds
BR112012029133A2 (en) 2010-05-18 2016-09-13 Milliken & Co optical brighteners and compositions comprising the same
BR112012029188B1 (en) * 2010-05-18 2020-12-08 Milliken & Company optical whitening compounds and compositions comprising the same
CN109912465B (en) * 2019-04-17 2021-08-24 沈阳新纪化学有限公司 Synthesis method of distyrylbiphenyl fluorescent whitening agent with bluish tone
US11292957B2 (en) 2020-01-21 2022-04-05 King Fahd University Of Petroleum And Minerals Gemini surfactants containing an arylene linker for clay swelling inhibition
CN114230509A (en) * 2021-04-19 2022-03-25 闽都创新实验室 Stilbene derivative containing fluorine substituted biphenyl and preparation method and application thereof
JP2023056635A (en) * 2021-10-08 2023-04-20 セイコーエプソン株式会社 Binding material and method for manufacturing molded body

Also Published As

Publication number Publication date
YU35093B (en) 1980-09-25
AT299171B (en) 1972-06-12
NO131456C (en) 1975-06-11
SU391781A3 (en) 1973-07-25
NO131456B (en) 1975-02-24
BR6802828D0 (en) 1973-04-17
SU476748A3 (en) 1975-07-05
ES378656A1 (en) 1973-02-01
ES358737A1 (en) 1970-10-16
HK53076A (en) 1976-09-03
RO55806A (en) 1974-01-03
DK139845C (en) 1979-10-08
DK139845B (en) 1979-04-30
CH700070A4 (en) 1975-01-31
FI50238C (en) 1976-01-12
CH566420B5 (en) 1975-09-15
JPS54929B1 (en) 1979-01-18
IE32388L (en) 1969-04-03
IL30776A (en) 1974-06-30
FR1583595A (en) 1969-11-14
FI50238B (en) 1975-09-30
NL6814089A (en) 1969-04-09
IE32388B1 (en) 1973-07-11
GB1247934A (en) 1971-09-29
DE1793482A1 (en) 1972-03-09
PL79354B1 (en) 1975-06-30
CH532106A (en) 1972-12-31
YU226368A (en) 1980-03-15
BE721754A (en) 1969-04-02
DE1793482C3 (en) 1975-09-25
NL145531B (en) 1975-04-15
CS174763B2 (en) 1977-04-29
IL30776A0 (en) 1968-11-27
CH554821A (en) 1974-10-15
DE1793482B2 (en) 1975-02-20
AT288306B (en) 1971-02-25
SE367399B (en) 1974-05-27
CS174800B2 (en) 1977-04-29

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