CH387400A - Root-resistant or root-repellent bituminous sealant and sealing compound - Google Patents

Root-resistant or root-repellent bituminous sealant and sealing compound

Info

Publication number
CH387400A
CH387400A CH196260A CH196260A CH387400A CH 387400 A CH387400 A CH 387400A CH 196260 A CH196260 A CH 196260A CH 196260 A CH196260 A CH 196260A CH 387400 A CH387400 A CH 387400A
Authority
CH
Switzerland
Prior art keywords
root
potting compound
seal
compound according
herbicides
Prior art date
Application number
CH196260A
Other languages
German (de)
Inventor
Otto Dr Pauli
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DEF26326A priority Critical patent/DE1089103B/en
Priority to DEF26325A priority patent/DE1108833B/en
Priority to FR1213672D priority patent/FR1213672A/en
Priority to FR799528A priority patent/FR1229420A/en
Priority to NL241701A priority patent/NL241701A/xx
Priority to GB25907/59A priority patent/GB916489A/en
Application filed by Bayer Ag filed Critical Bayer Ag
Priority to CH196260A priority patent/CH387400A/en
Publication of CH387400A publication Critical patent/CH387400A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • C08K5/105Esters; Ether-esters of monocarboxylic acids with phenols
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16JPISTONS; CYLINDERS; SEALINGS
    • F16J15/00Sealings
    • F16J15/16Sealings between relatively-moving surfaces
    • F16J15/18Sealings between relatively-moving surfaces with stuffing-boxes for elastic or plastic packings
    • F16J15/20Packing materials therefor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L13/00Non-disconnectible pipe-joints, e.g. soldered, adhesive or caulked joints
    • F16L13/10Adhesive or cemented joints
    • F16L13/11Adhesive or cemented joints using materials which fill the space between parts of a joint before hardening
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L58/00Protection of pipes or pipe fittings against corrosion or incrustation
    • F16L58/02Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L58/00Protection of pipes or pipe fittings against corrosion or incrustation
    • F16L58/02Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
    • F16L58/04Coatings characterised by the materials used
    • F16L58/12Coatings characterised by the materials used by tar or bitumen

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Toxicology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

       

  Wurzelfeste bzw. wurzelabweisende     bitumenhaltige    Dichtung und     Vergussmasse       Die     Wurzelspitzen    von gewissen Pflanzen, die  sich in der Nähe von z.     JB.    unterirdisch verlegten  Wasserleitungen befinden, streben     bekanntlich    mit  verwunderlicher Zielsicherheit und     Beharrlichkeit          dorthin,    wo sie Wasser wittern, und     überwinden     hierbei     mit        erstaunlicher        Kraft        Hindernisse    aller Art.

    Selbst durch wasserdichte     Muffenverbindungen    schaf  fen sie sich Zugang zum Wasser. Leichter     gelingt     ihnen das bei     mit    den     üblichen        Vergussmassen    abge  dichteten Rohrverbindungen, obwohl diese     Verguss-          massen    aus Bitumen und Füllstoffen,. wie     Kaolin,          Talkum,    Asbest,     Sand,    Stein- und Quarzmehl und  dergleichen, bestehen.  



       Man.    ist daher schon seit langem bemüht, solche  Dichtungen     wurzelfest    zu machen. Dies war bisher  jedoch nur mit beschränktem Erfolg möglich.  



  Es wurde nun gefunden, dass bituminöse Dich  tungen und     Vergussmassen    der erwähnten Art einen  guten Schutz gegen das     Einwachsen    von     Wurzeln.     bieten, das heisst, dass sie     wurzelfest    bzw.

   sogar weit  gehend wurzelabweisend sind, wenn sie mit Bitumen  und Asphaltmassen     verträgliche,    in Wasser     nicht     merklich lösliche, schwerflüchtige     Herbizide,    wie       Schwermetallsalze    von     Polychlorphenolen,    insbeson  dere von     Pentachlorphenol,

      oder     Veresterungs-          produkte    solcher     Phenole    mit höheren     Carbonsäuren     oder mehrbasischen Säuren sowie die     Verbindungen     von mehrwertigen Metallen mit     Polychlorphenolen     einerseits und höheren     Carbonsäuren    anderseits,  ferner Herbizide, wie     2,4-Dichlorphenoxyessigsäure,          2,4,5-Trichlorphenoxyessigsäure    und     a-Naphthyl-          essigsäure    sowie deren Salze, Ester und     Amide,

       ferner     Phenyl-N-isopropylcarbaminat    und     p-Chlor-          phenyldimethylharnstoff,    enthalten.  



  Geeignete Verbindungen im Sinne dieser Erfin  dung sind z. B.    Zink- bzw.     Kupferpentachlorphenolat,          Pentachlorphenyl-laurinsäureester,          Bis-pentachlorphenylcarbonat,          Pentachlorphenylisooctylcarbonat,          Pentachlorphenyl-zink-naphthenat,          2,4-Dichlorphenoxyessigsäurebutylester,          2,4,5-Trichlorphenoxyessigsäurebutylglykolester,          2,4,5-Trichlorphenoxyessigsäure-N-methylamid     und       2,4-Dichlorphenoxyessigsäureamid.       Die genannten Herbizide haben eine über  raschend starke Wirkung,

   so     dass        ein    guter Schutz  im     allgemeinen    schon mit geringen Mengen erzielt  wird.     In    manchen     Fällen    genügen schon Zusätze  zwischen etwa 0,1 und etwa     0,30/a,    jedoch können  auch grössere Mengen, so z. B. bis zu etwa 5     0/a,     der     erwähnten    Herbizide den     Vergussmassen    zuge  setzt     werden.     



  Der Zusatz der     genannten        Stoffe    zu solchen     Ver-          gussmassen    bewirkt überraschenderweise, dass die       Wurzeln    der     Pflanzen,    insbesondere Baum- und       Strauchwurzeln,    in der Regel schon bevor sie mit  den Wirkstoff enthaltenden Massen in engere Be  rührung kommen, ihre Wachstumsrichtung in eini  gem Abstand von den Massen umkehren, ohne dass  sie und damit die     Pflanzen    erkranken oder abster  ben.

   Sollten     dennoch        einzelne    Wurzelspitzen bis       zur    Oberfläche der     Vergussmassen    oder in dieselben  eindringen, so sterben sie schon in den obern  Schichten der Massen ab.  



  Die     Dichtungen    und     Vergussmassen    gemäss der       Erfindung    können für die verschiedensten Zwecke  verwendet werden, so ausser bei den bereits erwähn  ten unterirdisch verlegten Wasserleitungen auch bei  Leitungen     beliebiger    Art oder bei mit dem Erd  reich in Berührung stehenden oder in die Erde ein-      gelassenem Mauerwerk, bei Strassenbelägen und der  gleichen.  



  <I>Beispiel 1</I>       Vergussmassen        mit    2,5      /u        Zinkpentachlorphenolat     sind gegen das Einwachsen von Wurzeln voll wirk  sam und verlieren auch bei wiederholtem Erhitzen  praktisch nicht an Wirksamkeit.  



  <I>Beispiel 2</I>  Eine     Asphalt-Dichtungsmasse    mit     0,60/a    Zusatz  an     2,4-Dichlorphenoxyessigsäurebutylester    ist gegen       Wurzeleinwachsen    voll wirksam.  



  <I>Beispiel 3</I>  Bituminöse Dichtungsmassen mit einem Gehalt  von     0,7 /a        an        2,4,5-Trichlorphenoxyessigsäurebutyl-          glykolester    sind gegen das Einwachsen von Wurzeln  <B>a</B>  schützt, auch wenn die Massen vorher mehrfach  auf 160-180  C erhitzt     wurden.  



  Root-resistant or root-repellent bituminous sealant and potting compound. The root tips of certain plants that are near z. JB. underground water pipes are known to strive with astonishing accuracy and perseverance where they smell water, and overcome obstacles of all kinds with astonishing power.

    They even gain access to the water through watertight socket connections. This is easier for them to do with pipe connections sealed with the usual potting compounds, although these potting compounds are made from bitumen and fillers. such as kaolin, talc, asbestos, sand, rock and quartz flour and the like.



       Man. has therefore tried for a long time to make such seals root-proof. However, this has so far only been possible with limited success.



  It has now been found that bituminous seals and casting compounds of the type mentioned provide good protection against the ingrowth of roots. offer, that means that they are root-proof or

   are even largely root-repellent if they are compatible with bitumen and asphalt compounds, not noticeably soluble in water, low-volatility herbicides, such as heavy metal salts of polychlorophenols, in particular of pentachlorophenol,

      or esterification products of such phenols with higher carboxylic acids or polybasic acids as well as the compounds of polyvalent metals with polychlorophenols on the one hand and higher carboxylic acids on the other hand, also herbicides such as 2,4-dichlorophenoxyacetic acid, 2,4,5-trichlorophenoxyacetic acid and a-naphthylacetic acid as well their salts, esters and amides,

       also contain phenyl-N-isopropylcarbaminate and p-chlorophenyldimethylurea.



  Suitable compounds for the purposes of this inven tion are, for. B. zinc or copper pentachlorophenolate, pentachlorophenyl lauric acid ester, bis-pentachlorophenyl carbonate, pentachlorophenyl isooctyl carbonate, pentachlorophenyl zinc naphthenate, 2,4-dichlorophenoxyacetate, 2,4,5-trichlorophenoxyacetate, 2,4,5-trichlorophenoxyacetate butylglycol ester, 2,4,5-trichlorophenoxyacetate and trichloro-2,4-phenoxyacetamido-butylglycol ester, 2,4,5-phenoxyacetate 2,4-dichlorophenoxyacetic acid amide. The herbicides mentioned have a surprisingly powerful effect,

   so that good protection is generally achieved even with small amounts. In some cases, additions between about 0.1 and about 0.30 / a are sufficient, but larger amounts can also be used, e.g. B. up to about 5 0 / a, the herbicides mentioned are added to the casting compounds.



  The addition of the substances mentioned to such potting compounds surprisingly has the effect that the roots of the plants, in particular tree and bush roots, usually before they come into closer contact with the compounds containing the active substance, their direction of growth at some distance from the Reversing masses without them and thus the plants becoming sick or dying.

   Should individual root tips nevertheless penetrate to the surface of the casting compound or into the same, then they will die in the upper layers of the compound.



  The seals and potting compounds according to the invention can be used for a wide variety of purposes, except in the case of the already mentioned underground water pipes and pipes of any kind or in the case of masonry that is in contact with the earth or sunk into the earth, in the case of road surfaces and the same.



  <I> Example 1 </I> casting compounds with 2.5 / u zinc pentachlorophenolate are fully effective against the ingrowth of roots and practically do not lose their effectiveness even with repeated heating.



  <I> Example 2 </I> An asphalt sealing compound with 0.60 / a addition of butyl 2,4-dichlorophenoxyacetate is fully effective against root ingrowth.



  <I> Example 3 </I> Bituminous sealing compounds with a content of 0.7 / a of 2,4,5-trichlorophenoxyacetic acid butyl glycol ester are protected against the ingrowth of roots <B> a </B>, even if the compounds were previously heated to 160-180 C several times.


    

Claims (1)

PATENTANSPRUCH I Wurzelfeste bzw. wurzelabweisende, bitumen- haltige Dichtung und Vergussmasse, gekennzeichnet durch einen Gehalt an mit Bitumen- und Asphalt massen verträglichen, in Wasser nicht merklich lösli chen, schwerflüchtigen Herbiziden. UNTERANSPRÜCHE 1. Dichtung und Vergussmasse gemäss Patent anspruch 1, dadurch gekennzeichnet, dass sie als Herbizide Schwermetallsalze von Polychlorphenolen enthalten. 2. PATENT CLAIM I Root-resistant or root-repellent, bitumen-containing sealant and potting compound, characterized by a content of low-volatility herbicides that are compatible with bitumen and asphalt compounds and not noticeably soluble in water. SUBSTANTIAL CLAIMS 1. Seal and potting compound according to patent claim 1, characterized in that they contain heavy metal salts of polychlorophenols as herbicides. 2. Dichtung und Vergussmasse gemäss Patent anspruch I, dadurch gekennzeichnet, dass sie als Herbizide Veresterungsprodukte von Polychlor- phenolen mit höheren Carbonsäuren oder mehr basischen Säuren enthalten. 3. Dichtung und Vergussmasse gemäss Patent anspruch 1, dadurch gekennzeichnet, dass sie als Herbizide Verbindungen von mehrwertigen Metallen mit Polychlorphenolen einerseits und höheren Car- bonsäuren anderseits enthalten. 4. Seal and potting compound according to patent claim I, characterized in that they contain esterification products of polychlorophenols with higher carboxylic acids or more basic acids as herbicides. 3. Seal and potting compound according to claim 1, characterized in that they contain, as herbicides, compounds of polyvalent metals with polychlorophenols on the one hand and higher carboxylic acids on the other. 4th Dichtung und Vergussmasse gemäss Patent anspruch I, dadurch gekennzeichnet, dass sie als Herbizide im Kern halogenierte Phenoxyessigsäuren, deren wasserunlösliche Salze, Ester oder Amide ent halten. 5. Dichtung und Vergussmasse gemäss Patent anspruch 1, dadurch gekennzeichnet, dass sie als Herbizid Phenyl - N - isopropylcarbaminat oder p-Chlorphenyldimethylharnstoff enthalten. Seal and potting compound according to patent claim I, characterized in that they contain halogenated phenoxyacetic acids, their water-insoluble salts, esters or amides as herbicides. 5. Seal and potting compound according to claim 1, characterized in that they contain phenyl - N - isopropylcarbaminate or p-chlorophenyldimethylurea as the herbicide. PATENTANSPRUCH 1f Verwendung der Dichtung und Vergussmasse gemäss Patentanspruch 1 für unterirdisch verlegte Wasserleitungen. PATENT CLAIM 1f Use of the seal and potting compound according to claim 1 for water pipes laid underground.
CH196260A 1958-08-05 1960-02-22 Root-resistant or root-repellent bituminous sealant and sealing compound CH387400A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DEF26326A DE1089103B (en) 1958-08-05 1958-08-05 Root-repellent seals and potting compounds for water pipes, especially sewer pipes
DEF26325A DE1108833B (en) 1958-08-05 1958-08-05 Root-resistant or root-repellent sealing and casting compounds for underground water pipes
FR1213672D FR1213672A (en) 1958-08-05 1958-09-30 Root-repelling caulks and coverings for water pipes, especially wastewater
FR799528A FR1229420A (en) 1958-08-05 1959-07-07 Root-resistant or root-repellent seals and flooding compounds for water pipes laid under the ground
NL241701A NL241701A (en) 1958-08-05 1959-07-27
GB25907/59A GB916489A (en) 1958-08-05 1959-07-28 Root-resistant and root-repellent packing and sealing compounds for underground water pipes
CH196260A CH387400A (en) 1958-08-05 1960-02-22 Root-resistant or root-repellent bituminous sealant and sealing compound

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEF26326A DE1089103B (en) 1958-08-05 1958-08-05 Root-repellent seals and potting compounds for water pipes, especially sewer pipes
DEF26325A DE1108833B (en) 1958-08-05 1958-08-05 Root-resistant or root-repellent sealing and casting compounds for underground water pipes
CH196260A CH387400A (en) 1958-08-05 1960-02-22 Root-resistant or root-repellent bituminous sealant and sealing compound

Publications (1)

Publication Number Publication Date
CH387400A true CH387400A (en) 1965-01-31

Family

ID=27173372

Family Applications (1)

Application Number Title Priority Date Filing Date
CH196260A CH387400A (en) 1958-08-05 1960-02-22 Root-resistant or root-repellent bituminous sealant and sealing compound

Country Status (5)

Country Link
CH (1) CH387400A (en)
DE (2) DE1108833B (en)
FR (2) FR1213672A (en)
GB (1) GB916489A (en)
NL (1) NL241701A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202015105377U1 (en) * 2015-10-12 2017-01-13 Rehau Ag + Co pipe arrangement

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1196115B (en) * 1961-07-27 1965-07-01 Bayer Ag Non-root building materials, in particular sealing and insulating compounds based on bituminous binders
DE4329419A1 (en) * 1993-09-01 1995-03-02 Bayer Ag Root penetration inhibitors
DE4337844A1 (en) * 1993-11-05 1995-05-11 Bayer Ag Root penetration inhibitors
DE19500123A1 (en) * 1995-01-04 1996-07-11 Bayer Ag Root penetration inhibitors

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2623830A (en) * 1948-05-03 1952-12-30 Aronberg Lester Pipe joint sealing compound
US2519780A (en) * 1949-08-11 1950-08-22 Monsanto Chemicals Herbicidal formulations

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202015105377U1 (en) * 2015-10-12 2017-01-13 Rehau Ag + Co pipe arrangement
EP3156708A1 (en) * 2015-10-12 2017-04-19 REHAU AG + Co Tubing assembly

Also Published As

Publication number Publication date
DE1089103B (en) 1960-09-15
NL241701A (en) 1964-02-05
GB916489A (en) 1963-01-23
FR1229420A (en) 1960-09-07
DE1108833B (en) 1961-06-15
FR1213672A (en) 1960-04-04

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