CH261281A - Process for the production of a new dye of the anthraquinone series. - Google Patents
Process for the production of a new dye of the anthraquinone series.Info
- Publication number
- CH261281A CH261281A CH261281DA CH261281A CH 261281 A CH261281 A CH 261281A CH 261281D A CH261281D A CH 261281DA CH 261281 A CH261281 A CH 261281A
- Authority
- CH
- Switzerland
- Prior art keywords
- production
- anthraquinone series
- new dye
- dye
- anthraquinone
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/22—Dyes with unsubstituted amino groups
- C09B1/24—Dyes with unsubstituted amino groups sulfonated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
Zusatzpatent zum Hauptpatent Nr. 253955. Verfahren zur Herstellung eines neuen Farbstoffes der Anthrachinonreihe. Das vorliegende Patent betrifft ein Ver fahren zur Herstellung eines neuen Farb stoffes der Anthrachinonreihe und ist da durch gekennzeichnet, dass man 1-Amino-4- brom-8-ehloranthrachinon-2-sulfonsäure mit p- Toluolsulfamid kondensiert und das Konden sationsprodukt hernach verseift.
<I>Beispiel:</I> 28 Gewichtsteile 1-amino-4-brom-8-chlor- anthrachinon-2-sulfonsaures Natrium werden mit 14,4 Gewichtsteilen p-Toluolsulfamid, 6,4 Gewichtsteilen Natriumbicarbonat, 0,4 Ge wichtsteilen Kupferbronze und 0,2 Gewichts teilen Kupferchlorür in 350 Teilen Wasser unter Rühren während 2 Stunden auf 40 bis 45 C erhitzt.
Nach erfolgter Kondensation wird das Reaktionsprodukt auf übliche Weise aufgear beitet und durch Digerieren in konzentrierter Schwefelsäure bei gewöhnlicher oder erhöhter Temperatur verseift. Durch Ausladen in Wasser gewinnt man die 1,4-Diamino-8-chlor- anthrachinon-2-sulfonsäure.
Der Farbstoff löst sich in konzentrierter Schwefelsäure mit hellgelber Farbe, die beim Zusatz von wenig Paraformaldehyd in Blau umschlägt. Er färbt tierische Fasern, z. B. Wolle, Seide, und künstliche Fasern wie Nylon in rotstichig violetten Tönen von guten Echtheiten.
Additional patent to main patent No. 253955. Process for the production of a new dye of the anthraquinone series. The present patent relates to a process for the production of a new dye of the anthraquinone series and is characterized by the fact that 1-amino-4-bromo-8-ehloranthraquinone-2-sulfonic acid is condensed with p-toluenesulfamide and the condensation product is saponified afterwards.
<I> Example: </I> 28 parts by weight of 1-amino-4-bromo-8-chloro-anthraquinone-2-sulfonic acid sodium are mixed with 14.4 parts by weight of p-toluenesulfamide, 6.4 parts by weight of sodium bicarbonate, 0.4 parts by weight Copper bronze and 0.2 parts by weight of copper chloride in 350 parts of water heated to 40 to 45 ° C. for 2 hours with stirring.
After condensation has taken place, the reaction product is worked up in the usual way and saponified by digestion in concentrated sulfuric acid at normal or elevated temperature. The 1,4-diamino-8-chloro-anthraquinone-2-sulfonic acid is obtained by unloading into water.
The dye dissolves in concentrated sulfuric acid with a light yellow color, which turns blue when a little paraformaldehyde is added. It dyes animal fibers, e.g. B. wool, silk, and artificial fibers such as nylon in reddish purple shades of good fastness properties.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH261281T | 1946-10-10 | ||
CH253955T | 1948-04-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH261281A true CH261281A (en) | 1949-04-30 |
Family
ID=25729814
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH261281D CH261281A (en) | 1946-10-10 | 1946-10-10 | Process for the production of a new dye of the anthraquinone series. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH261281A (en) |
-
1946
- 1946-10-10 CH CH261281D patent/CH261281A/en unknown
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