CH232279A - Process for the preparation of a water-soluble, higher molecular weight acyl biguanide. - Google Patents

Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.

Info

Publication number
CH232279A
CH232279A CH232279DA CH232279A CH 232279 A CH232279 A CH 232279A CH 232279D A CH232279D A CH 232279DA CH 232279 A CH232279 A CH 232279A
Authority
CH
Switzerland
Prior art keywords
water
soluble
biguanide
preparation
molecular weight
Prior art date
Application number
Other languages
German (de)
Inventor
Ag J R Geigy
Original Assignee
Ag J R Geigy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ag J R Geigy filed Critical Ag J R Geigy
Publication of CH232279A publication Critical patent/CH232279A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
    • C07C279/20—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylguanidines
    • C07C279/24—Y being a hetero atom
    • C07C279/26—X and Y being nitrogen atoms, i.e. biguanides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/13—Fugitive dyeing or stripping dyes
    • D06P5/138—Fugitive dyeing or stripping dyes fugitive dyeing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)

Description

  

  Verfahren zur Darstellung eines     wasserlöslichen,        höhenmolekularen        Acylbiguanids.            Gegenstand    des     vorliegenden    Zusatz  patentes ist ein Verfahren zur Darstellung  eines wasserlöslichen, höhenmolekularen     Acyl-          biguanids,    welches dadurch     gekennzeichnet     ist,

   dass     Lauroylcyanguanidin    mit     Triäthyl-          entetramin    zum     Lauroyltriaminotriäthylen-          biguanid    kondensiert und dieses in das     Salz     der     Essigsäure    übergeführt wird. Das neue  Produkt ist in Wasser klar löslich und findet  Verwendung als     Textilhilfsmittel    oder zur  Herstellung von solchen.  



  <I>Beispiel:</I>  70 Teile     Lauroylcyanguanidin    werden  durch Erhitzen mit 38 Teilen     Triäthylen-          tetramin    (18     Stunden,    140-150 ) in     Lauroyl-          triaminotriäthylenbiguanid    übergeführt. Die  entstehende, hellgelbe, halbfeste Masse ist  an der Luft     zerfliesslich;    sie löst sich neutral    mit starker     Opaleszenz,    sauer jedoch voll  ständig klar in heissem Wasser.  



  42,6 Teile dieser Verbindung werden mit  6 Teilen Essigsäure vermischt und zur Trockne  eingedampft. Das     klar    wasserlösliche Acetat  eignet sich zum     Wasserechtmachen    von       Direktfärbungen.  



  Process for the preparation of a water-soluble, high molecular weight acyl biguanide. The subject of the present additional patent is a method for the preparation of a water-soluble, high molecular weight acyl biguanide, which is characterized by

   that lauroylcyanguanidine condenses with triethylenetetramine to give lauroyltriaminotriäthylen- biguanid and this is converted into the salt of acetic acid. The new product is clearly soluble in water and is used as a textile auxiliary or for the production of such.



  <I> Example: </I> 70 parts of lauroylcyanguanidine are converted into lauroyltriaminotriethylene biguanide by heating with 38 parts of triethylenetetramine (18 hours, 140-150). The resulting, light yellow, semi-solid mass dissolves in the air; it dissolves neutrally with strong opalescence, but acidic but completely clear in hot water.



  42.6 parts of this compound are mixed with 6 parts of acetic acid and evaporated to dryness. The clear water-soluble acetate is suitable for making direct dyeings waterfast.

Claims (1)

PATENTANSPRUCH: Verfahren zur Darstellung eines wasser- löslichen, höhenmolekularen Acylbiguanids, dadurch gekennzeichnet, PATENT CLAIM: Process for the preparation of a water-soluble, high molecular weight acyl biguanide, characterized in dass Lauroylcyan- guanidin mit Triäthylentetramin zum Lauroyl- triaminotriäthylenbiguanid kondensiert und dieses in das Salz der Essigsäure übergeführt wird. Das neue Produkt ist in Wasser klar löslich und findet Verwendung als Textil- hilfsmittel oder zur Herstellung von solchen. that lauroylcyanguanidine condenses with triethylenetetramine to form lauroyltriaminotriäthylenbiguanid and this is converted into the salt of acetic acid. The new product is clearly soluble in water and is used as a textile aid or for the production of such.
CH232279D 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide. CH232279A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH225155T 1939-12-21
CH232822T 1940-04-11

Publications (1)

Publication Number Publication Date
CH232279A true CH232279A (en) 1944-05-15

Family

ID=34137166

Family Applications (13)

Application Number Title Priority Date Filing Date
CH232284D CH232284A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232280D CH232280A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232285D CH232285A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232281D CH232281A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232282D CH232282A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH225155D CH225155A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232278D CH232278A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232277D CH232277A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232283D CH232283A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232279D CH232279A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232822D CH232822A (en) 1939-12-21 1940-04-11 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH235189D CH235189A (en) 1939-12-21 1940-04-11 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH235190D CH235190A (en) 1939-12-21 1940-04-11 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.

Family Applications Before (9)

Application Number Title Priority Date Filing Date
CH232284D CH232284A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232280D CH232280A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232285D CH232285A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232281D CH232281A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232282D CH232282A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH225155D CH225155A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232278D CH232278A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232277D CH232277A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH232283D CH232283A (en) 1939-12-21 1939-12-21 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.

Family Applications After (3)

Application Number Title Priority Date Filing Date
CH232822D CH232822A (en) 1939-12-21 1940-04-11 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH235189D CH235189A (en) 1939-12-21 1940-04-11 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.
CH235190D CH235190A (en) 1939-12-21 1940-04-11 Process for the preparation of a water-soluble, higher molecular weight acyl biguanide.

Country Status (3)

Country Link
AT (2) AT163430B (en)
CH (13) CH232284A (en)
GB (1) GB546027A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2431644A (en) * 1943-01-15 1947-11-25 American Cyanamid Co Preparation of guanides
US2446421A (en) * 1944-11-03 1948-08-03 Ici Ltd Manufacture of arylbiguanide hydrochlorides
US2479498A (en) * 1946-08-08 1949-08-16 American Cyanamid Co Preparation of 1,2-disubstituted-3-cyanoguanidines
US2622075A (en) * 1946-12-03 1952-12-16 Sandoz Ltd Polyamine-cyanamide resins
DE1049587B (en) * 1955-03-21 1959-01-29 Rohm & Haas Company, Philadelphia, Pa. (V. St. A.) Process for the production of polymers and copolymers

Also Published As

Publication number Publication date
AT165059B (en) 1950-01-10
CH232277A (en) 1944-05-15
AT163430B (en) 1949-07-11
CH232822A (en) 1944-06-15
CH232285A (en) 1944-05-15
CH235190A (en) 1944-11-15
CH232280A (en) 1944-05-15
CH232281A (en) 1944-05-15
GB546027A (en) 1942-06-24
CH225155A (en) 1943-01-15
CH232282A (en) 1944-05-15
CH232278A (en) 1944-05-15
CH235189A (en) 1944-11-15
CH232283A (en) 1944-05-15
CH232284A (en) 1944-05-15

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