CH206919A - Process for the production of a vat dye. - Google Patents

Process for the production of a vat dye.

Info

Publication number
CH206919A
CH206919A CH206919DA CH206919A CH 206919 A CH206919 A CH 206919A CH 206919D A CH206919D A CH 206919DA CH 206919 A CH206919 A CH 206919A
Authority
CH
Switzerland
Prior art keywords
production
vat dye
dye
vat
amino
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellsc Farbenindustrie
Original Assignee
Ig Farbenindustrie Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ig Farbenindustrie Ag filed Critical Ig Farbenindustrie Ag
Publication of CH206919A publication Critical patent/CH206919A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B43/00—Preparation of azo dyes from other azo compounds
    • C09B43/32—Preparation of azo dyes from other azo compounds by reacting carboxylic or sulfonic groups, or derivatives thereof, with amines; by reacting keto-groups with amines
    • C09B43/36—Preparation of azo dyes from other azo compounds by reacting carboxylic or sulfonic groups, or derivatives thereof, with amines; by reacting keto-groups with amines with amino-anthracene or amino-anthraquinone dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

  Zusatzpatent zum     Hauptpatent    Nr. 200369.    Verfahren zur Herstellung eines     Küpenfarbstoffes.            Vorliegendes    Patent bezieht sich auf ein  Verfahren zur Herstellung eines Küpenfarb-    Stoffes, dadurch     gekennzeichnet,        dass    man  ein     Dicarbonsäuredichlorid    der Formel:  
EMI0001.0007     
    mit     1-Amino-5-benzoylaminoanthrachinon    im       Molekularverhältnis    1 : 2 kondensiert.  



  Der So erhaltene Farbstoff löst sich in       konzentrierter    Schwefelsäure mit braun  oranger Farbe und färbt Baumwolle aus vio  letter     Hüpe    in     rotstichig-gelben    Tönen von  hervorragenden     Echtheitseigenschaften.       <I>Beispiel:

  </I>    Durch Kondensation von     4,4'-Diamino-          benzophenon    mit 2 Molekülen     4-Nitrosoben-          zoesäure-methylester,    anschliessende     Versei-          fung    und Umsetzung mit     Phosphorpenta-          chlorid    erhält man ein     Dicarbonsäuredichlo-          rid    der Formel:  
EMI0001.0024     
    das aus Chlorbenzol in fleischfarbenen Na  deln vom Schmelzpunkt 242' C kristallisiert.

      51 Teile dieser Verbindung werden bei  etwa<B>160'</B> C langsam     unter    Rühren in     eine         Lösung von 69 Teilen     1-Amino-5-benzo5#1-          aminoanthrachinon    in etwa 700 Teilen       o-Diclilorbenzol    eingetragen. Nach etwa zwei  stündigem Rühren bei etwa     '-)00'C    lässt man  auf<B>IM'</B> C erkalten, saugt das gebildete       Kondensationsprodukt    ab und trocknet es.



  Additional patent to main patent no. 200369. Process for the production of a vat dye. The present patent relates to a process for the production of a vat dye, characterized in that a dicarboxylic acid dichloride of the formula:
EMI0001.0007
    condensed with 1-amino-5-benzoylaminoanthraquinone in a molecular ratio of 1: 2.



  The dye obtained in this way dissolves in concentrated sulfuric acid with a brownish-orange color and dyes cotton from vio letter Hüpe in reddish-yellow shades with excellent fastness properties. <I> example:

  </I> The condensation of 4,4'-diamino benzophenone with 2 molecules of methyl 4-nitrosobenzoate, subsequent saponification and reaction with phosphorus pentachloride gives a dicarboxylic acid dichloride of the formula:
EMI0001.0024
    which crystallizes from chlorobenzene in flesh-colored needles with a melting point of 242 ° C.

      51 parts of this compound are slowly introduced into a solution of 69 parts of 1-amino-5-benzo5 # 1-aminoanthraquinone in about 700 parts of o-diclilobenzene at about 160.degree. C. with stirring. After stirring for about two hours at about '-) 00'C, the mixture is left to cool to <B> IM' </B> C, the condensation product formed is filtered off with suction and dried.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines Küpen- farbstoffes, dadurch gekennzeichnet, dass man ein Dicarbonsäuredichlorid der Formel: EMI0002.0009 mit 1-Amino-5-benzovlaminoantliraehinon im Holekularverhältnis 1. : J kondensiert. Der so erhaltene Farbstoff löst sieh in konzentrierter Schwefelsäure mit braun oranger Farbe und färbt. Baumwolle aus vio- letter Küpe in rotstichig-gelben Tönen von hervorragenden Eehtheitseigenseha.ften. PATENT CLAIM: Process for the production of a vat dye, characterized in that a dicarboxylic acid dichloride of the formula: EMI0002.0009 with 1-amino-5-benzovlaminoantliraehinon in the molecular ratio 1.: J condensed. The dye thus obtained dissolves in concentrated sulfuric acid with a brown-orange color and stains. Cotton from violet vat in reddish-yellow tones with excellent integrity properties.
CH206919D 1937-03-25 1938-03-21 Process for the production of a vat dye. CH206919A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE206919X 1937-03-25
CH200369T 1938-03-21

Publications (1)

Publication Number Publication Date
CH206919A true CH206919A (en) 1939-08-31

Family

ID=25723485

Family Applications (1)

Application Number Title Priority Date Filing Date
CH206919D CH206919A (en) 1937-03-25 1938-03-21 Process for the production of a vat dye.

Country Status (1)

Country Link
CH (1) CH206919A (en)

Similar Documents

Publication Publication Date Title
CH206919A (en) Process for the production of a vat dye.
CH206918A (en) Process for the production of a vat dye.
CH204132A (en) Process for the production of a vat dye.
DE609119C (en) Process for the production of Kuepen dyes
CH204135A (en) Process for the production of a vat dye.
CH204136A (en) Process for the production of a vat dye.
CH204133A (en) Process for the production of a vat dye.
CH163280A (en) Process for the production of a new vat dye.
CH184785A (en) Process for the production of a vat dye.
CH224548A (en) Process for the preparation of a new dye of the anthraquinone series.
CH204134A (en) Process for the production of a vat dye.
CH266027A (en) Process for the production of a vat dye.
CH184193A (en) Process for the production of an asymmetrical vat dye of the thioindigo series.
CH128993A (en) Process for the production of a new condensation product of the benzanthrone series.
CH178427A (en) Process for the production of a vat dye.
CH205423A (en) Process for the preparation of a dye of the 2-naphthalene-2&#39;-indolindigo series.
CH204127A (en) Process for the production of a vat dye.
CH204125A (en) Process for the production of a vat dye.
CH200539A (en) Process for the production of a vat dye.
CH204126A (en) Process for the production of a vat dye.
CH197771A (en) Process for the preparation of a vat dye.
CH178425A (en) Process for the production of a vat dye.
CH224878A (en) Process for the preparation of a new, water-soluble dye of the anthraquinone series.
CH276922A (en) Process for the production of a vat dye.
CH165052A (en) Process for the production of a new vat dye.