CH205817A - Process for the production of a new, metal-containing stain dye. - Google Patents

Process for the production of a new, metal-containing stain dye.

Info

Publication number
CH205817A
CH205817A CH205817DA CH205817A CH 205817 A CH205817 A CH 205817A CH 205817D A CH205817D A CH 205817DA CH 205817 A CH205817 A CH 205817A
Authority
CH
Switzerland
Prior art keywords
acid
new
amino
chromium
dye
Prior art date
Application number
Other languages
German (de)
Inventor
A-G Durand Huguenin
Original Assignee
Durand & Huguenin Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Durand & Huguenin Ag filed Critical Durand & Huguenin Ag
Publication of CH205817A publication Critical patent/CH205817A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B33/00—Disazo and polyazo dyes of the types A->K<-B, A->B->K<-C, or the like, prepared by diazotising and coupling
    • C09B33/18—Trisazo or higher polyazo dyes
    • C09B33/22—Trisazo dyes of the type A->B->K<-C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00—Complex metal compounds of azo dyes
    • C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
    • C09B45/24—Disazo or polyazo compounds
    • C09B45/26—Disazo or polyazo compounds containing chromium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Description

  

      Zusatzpatent    zum Hauptpatent Nr. 202856.    Verfahren zur Herstellung eines neuen, metallhaltigen     Beizenfarbstoffes.       Es wurde gefunden, dass man einen neuen,       chromhaltigen        Beizenfarbstoff    erhält, wenn  man ein     Molekül        2-Amino-5-oxynaphthalin-          7-sulfonsäure    zuerst in schwach saurem Me  dium mit     einem    Molekül     diazotierter        3-          Amino-4'-oxy-1.        :.'        1'-azobenzol-:

  3,'-carbonsäure-          4-sulfonsäure    und nachher in schwach alkali  schem Medium mit einem Molekül     :diazotier-          ter        2-Amino:-l-oxybenzol-:6-carbonsäure-4-sul-          fonsäure    kuppelt     und    den erhaltenen     Trisazo-          farbstoff    mit einer chromabgebenden Sub  stanz behandelt.  



  <I>Beispiel:</I>       33,7        Teile        3--Amino-4'-oxy-1.:1'-azaben-          zol-d'-carbons@äure-4-sulfon,säure    werden nach  dem aus der schweizerischen Patentschrift  Nr.     1750:2i9        bekannten    Verfahren     diazotiert     und in essigsaurer Lösung mit<B>23,9</B> Teilen       2-Amino-5-oxynaphthalin-7-sulfons:äure    ge  kuppelt.

   Der erhaltene     Disazofarbsto:ff    wird  in alkalischer Lösung mit der     Diazoverbin-          dung    aus     2:3,.3    Teilen     2.-Amino-1.-:oxy-benzo:l-          6-carbonsäure-4-aulfonsäure    gekuppelt.

   Nach    beendeter Kupplung wird der erhaltene     Tris-          azofarbsto:ff        ausgesalzen,        abg        enutscht,    in  2000     Teilen    kochendem Wasser gelöst und  die Lösung unter     Zusatz    einer     Chromaoetat-          lösung    entsprechend     3:0,4    Teilen     Cr20,    wäh  rend 1.5     Stunden    unter     Rückfluss    gekocht.

   Die       neue    Chromverbindung wird durch Eindamp  fen der     Lösung    in     fester    Form gewonnen.  



  Der neue, chromhaltige Farbstoff bildet,  wenn getrocknet,     ein.    dunkelbraunes Pulver,  löst     sieb,        in.        Wasser    mit brauner, in konzen  trierter     .Schwefelsäure    mit gelbbrauner Farbe  und liefert im Chromdruck auf Baumwolle,       Kunstseide    aus regenerierter Zellulose oder  auf Naturseide tiefe, dunkle     Brauntöne,    die  sich durch gute     Echtheiten        auszeichnen.  



      Additional patent to main patent no. 202856. Process for the production of a new, metal-containing stain dye. It has been found that a new, chromium-containing mordant dye is obtained if a molecule of 2-amino-5-oxynaphthalene-7-sulfonic acid is first in weakly acidic medium with a molecule of diazotized 3-amino-4'-oxy-1. :. ' 1'-azobenzene-:

  3, '- carboxylic acid-4-sulphonic acid and then in a weakly alkaline medium with a molecule: diazotized 2-amino: -l-oxybenzene: 6-carboxylic acid-4-sulphonic acid and the resulting trisazo dye with treated with a chromium-releasing substance.



  <I> Example: </I> 33.7 parts of 3 - amino-4'-oxy-1.: 1'-azaben- zol-d'-carbons @ acid-4-sulfone, acid are after the Swiss Patent No. 1750: 2i9 known processes and diazotized in acetic acid solution with 23.9 parts of 2-amino-5-oxynaphthalene-7-sulfone: acid.

   The disazo dye obtained is coupled in an alkaline solution with the diazo compound of 2: 3, .3 parts of 2.-amino-1 .-: oxy-benzo: 1-6-carboxylic acid-4-sulfonic acid.

   After the coupling is complete, the tris azo dye obtained is salted out, suction filtered, dissolved in 2000 parts of boiling water and the solution is refluxed for 1.5 hours with the addition of a chromo acetate solution corresponding to 3: 0.4 parts of Cr20.

   The new chromium compound is obtained in solid form by evaporating the solution.



  The new chromium-containing dye forms when dried. Dark brown powder, dissolves in water with brown, concentrated sulfuric acid with yellow-brown color and, with chrome printing on cotton, artificial silk made from regenerated cellulose or natural silk, produces deep, dark brown tones that are characterized by good fastness properties.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines neuen, chromhaltigen Beizenfarbstoffes, dadurch ge- kennzeichnet, :dass man ein Molekül 2-Amino- 5 - oxynaphthalin - 7 - isulfonsäure zuerst in schwach saurem Medium mit einem Molekül dianotierter 3-Amino-4'-oxy-1 :1'-azobenzol- 3'-carbonsä.ure-4-: PATENT CLAIM: A process for the production of a new, chromium-containing mordant dye, characterized in that: a molecule of 2-amino-5-oxynaphthalene-7-isulphonic acid is first mixed with a molecule of dianotized 3-amino-4'-oxy- 1: 1'-azobenzene-3'-carboxylic acid-4-: sulfons-äure und nachher in schwach alkalischem Medium mit einem Molekül diazotiexter 2-Amino 1-oxy-benzol- 6-carbo:nsäure-4-sulfonsäure kuppelt und den erhaltenen Trisazofarbstoff mit einer chrom abgebenden Substanz behandelt. sulfonic acid and then in a weakly alkaline medium with a molecule of diazotized 2-amino 1-oxy-benzene-6-carbonic acid-4-sulfonic acid and the resulting trisazo dye is treated with a chromium-releasing substance. Der neue, chromhaltige Farbstoff bildet, wenn getrocknet, ein dunkelbraunes Pulver, löst sich in Wasser mit brauner, in konzen trierter Schwefelsäure mit gelbbrauner Farbe und liefert im Chromdruck. a.uf Baumwolle. Kunstseide, aus regenerierter Zellulose oder auf 'Naturseide tiefe, dunl:l#, Brauntöne, die sich durch gute Echtheiten auszeichnen. The new, chromium-containing dye forms a dark brown powder when dried, dissolves in water with brown, in concentrated sulfuric acid with a yellow-brown color and delivers in chrome printing. a.on cotton. Artificial silk, made from regenerated cellulose or on natural silk deep, dark: l #, brown tones that are characterized by good fastness properties.
CH205817D 1936-05-28 1937-05-20 Process for the production of a new, metal-containing stain dye. CH205817A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE205817X 1936-05-28
CH202856T 1937-05-20

Publications (1)

Publication Number Publication Date
CH205817A true CH205817A (en) 1939-06-30

Family

ID=25723864

Family Applications (1)

Application Number Title Priority Date Filing Date
CH205817D CH205817A (en) 1936-05-28 1937-05-20 Process for the production of a new, metal-containing stain dye.

Country Status (1)

Country Link
CH (1) CH205817A (en)

Similar Documents

Publication Publication Date Title
CH205817A (en) Process for the production of a new, metal-containing stain dye.
CH205815A (en) Process for the production of a new, metal-containing stain dye.
CH205812A (en) Process for the production of a new, metal-containing stain dye.
CH205814A (en) Process for the production of a new, metal-containing stain dye.
CH205813A (en) Process for the production of a new, metal-containing stain dye.
CH205816A (en) Process for the production of a new, metal-containing stain dye.
CH205818A (en) Process for the production of a new, metal-containing stain dye.
CH115470A (en) Process for the production of a chromium-containing dye.
CH249550A (en) Process for the preparation of a polyazo dye.
CH200250A (en) Process for the preparation of a new chromable disazo dye.
CH119888A (en) Process for the production of a new dye.
CH119886A (en) Process for the production of a new dye.
CH167053A (en) Process for the production of a metal-containing dye.
CH212990A (en) Process for the preparation of a hexakisazo dye.
CH251797A (en) Process for the preparation of a polyazo dye.
CH189037A (en) Process for the preparation of a water-soluble monoazo dye.
CH200999A (en) Process for the preparation of an azo dye.
CH203950A (en) Process for the preparation of an azo dye.
CH212999A (en) Process for the preparation of a hexakisazo dye.
CH133383A (en) Process for the production of a new azo dye.
CH105144A (en) Process for the production of a chromium-containing dye.
CH117270A (en) Process for the production of a new dye.
CH117996A (en) Process for the production of a new dye.
CH289588A (en) Process for the preparation of a polyazo dye.
CH238336A (en) Process for the preparation of a new disazo dye.