CH205771A - Process for the preparation of a condensation product which can be used for pest control. - Google Patents
Process for the preparation of a condensation product which can be used for pest control.Info
- Publication number
- CH205771A CH205771A CH205771DA CH205771A CH 205771 A CH205771 A CH 205771A CH 205771D A CH205771D A CH 205771DA CH 205771 A CH205771 A CH 205771A
- Authority
- CH
- Switzerland
- Prior art keywords
- condensation product
- preparation
- mol
- pest control
- benzaldehyde
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Darstellung eines zur Schädlingsbekämpfung verwendbaren Kondensationsproduktes. Es wurde gefunden, dass das wasserlös liche, licht- und walkechte, beständige Ben- zyl-3,4-dichlorphenylmercaptal der Benzal- dehyd-o-sulfonsäure erhalten werden kann,
wenn man in steter Gegenwart von sauren Kondensationsmitteln 1 Mol Benzaldehyd-o- sulfonsäure mit einem Mol Benzylmercaptan und die entstandene Hydrolsulfonsäure mit 1 Mol 3,4-Dichlorthiophenol behandelt. Die neue Verbindung ist zur Verwendung als Schäd lingsbekämpfungsmittel, insbesondere zum Im munisieren gegen Kleidermotten geeignet. Das neue Kondensationsprodukt stellt nach dem Trocknen und Mahlen ein helles Pulver dar, das in Wasser gut löslich ist und schwer lösliche Blei- und Eisensalze bildet.
<I>Beispiel:</I> i/jo Mol Benzaldehyd-o-sulfonsäure wird in 100 Teilen Eisessig gelöst und bei<B>0'</B> C mit 12,4 Teilen Benzylmercaptan (1/1o Mol) ver setzt, worauf das Gemisch 12 Stunden bei Raumtemperatur sich selbst überlassen wird. Dann wird mit 17,9 Teilen 3,4-Dichlorthio- phenol (1/1o Mol) versetzt und unter Eisküh lung mit Salzsäuregas gesättigt.
Nach 6stün- digem Stehen wird in 1000 Teile Wasser ein gerührt, die Lösung kalt mit Natronlauge kongoneutral gestellt und ausgeäthert. Der Äther wird mit conc. Natronlauge zweimal gewaschen, getrocknet und abdestilliert. De'r Rückstand wird im Vakuum bei 80-90 o C getrocknet und gemahlen. Das Benzyl-3,4- dichlorphenylmercaptal der Benzaldehyd-o- sulfonsäure ist in Wasser leicht löslich und bildet schwerlösliche Blei- und Eisensalze.
Process for the preparation of a condensation product which can be used for pest control. It has been found that the water-soluble, lightfast and masticatory, stable benzyl-3,4-dichlorophenyl mercaptal of benzaldehyde-o-sulfonic acid can be obtained,
if, in the constant presence of acidic condensing agents, 1 mole of benzaldehyde-o-sulfonic acid is treated with one mole of benzyl mercaptan and the hydrolsulfonic acid formed is treated with 1 mole of 3,4-dichlorothiophenol. The new compound is suitable for use as a pesticide, especially for immunizing against clothes moths. After drying and grinding, the new condensation product is a light-colored powder that is readily soluble in water and forms poorly soluble lead and iron salts.
<I> Example: </I> 1/1 mole of benzaldehyde-o-sulfonic acid is dissolved in 100 parts of glacial acetic acid and added at <B> 0 '</B> C with 12.4 parts of benzyl mercaptan (1/10 mol) and the mixture is left to stand for 12 hours at room temperature. Then 17.9 parts of 3,4-dichlorothiophenol (1/10 mol) are added and the mixture is saturated with hydrochloric acid gas while cooling with ice.
After standing for 6 hours, the mixture is stirred into 1000 parts of water, and the solution is rendered Congo-neutral with cold sodium hydroxide solution and extracted with ether. The ether becomes with conc. Sodium hydroxide solution washed twice, dried and distilled off. De'r residue is dried in vacuo at 80-90 o C and ground. The benzyl-3,4-dichlorophenyl mercaptal of benzaldehyde-o-sulfonic acid is easily soluble in water and forms poorly soluble lead and iron salts.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH205771T | 1938-03-26 | ||
CH193611T | 1939-03-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH205771A true CH205771A (en) | 1939-06-30 |
Family
ID=25722528
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH205771D CH205771A (en) | 1938-03-26 | 1938-03-26 | Process for the preparation of a condensation product which can be used for pest control. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH205771A (en) |
-
1938
- 1938-03-26 CH CH205771D patent/CH205771A/en unknown
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