CH163003A - Process for the production of a wetting, dispersing, emulsifying and washing agent. - Google Patents
Process for the production of a wetting, dispersing, emulsifying and washing agent.Info
- Publication number
- CH163003A CH163003A CH163003DA CH163003A CH 163003 A CH163003 A CH 163003A CH 163003D A CH163003D A CH 163003DA CH 163003 A CH163003 A CH 163003A
- Authority
- CH
- Switzerland
- Prior art keywords
- product
- wetting
- dispersing
- emulsifying
- production
- Prior art date
Links
- 238000009736 wetting Methods 0.000 title claims description 5
- 230000001804 emulsifying effect Effects 0.000 title claims description 3
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 238000000034 method Methods 0.000 title claims description 3
- 238000005406 washing Methods 0.000 title claims 2
- 239000000047 product Substances 0.000 claims description 8
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000012265 solid product Substances 0.000 claims description 2
- 238000006277 sulfonation reaction Methods 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/10—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfur dioxide and halogen or by reaction with sulfuryl halides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Description
Verfahren zur Herstellung eines Netz-, Dispergier-; Emulgier- und ll'aschmittels. Es wurde gefunden, dass man zu einem neuen, wertvollen Netz-, Dispergier-. Emul- gier- und Waschmittel gelangen kann, wenn man Laurinalkohol mit Sulfurylchlorid ver estert und hierauf das entstandene Produkt mit dem neutralisierten Sulfierungsprodukt von Phenol unter Zusatz von säurebindenden Mitteln zur Reaktion bringt.
Das entstandene feste Produkt ist in Wasser klar löslich und zeichnet sich durch vorzügliche, von einem solchen Textilhilfs- produkt heute geforderte Gesamtechtheiten aus. <I>Beispiel:</I> Zu 186 Teilen Laurinalkohol tropft man bei 20 bis<B>30'</B> 150 Teile Sulfurylchlorid, rührt langsam während 24 Stunden bei die ser Temperatur und bläst dann einen lang samen Luftstrom durch, um das überschüs sige Sulfurylchlorid zu entfernen.
Das Reak tionsprodukt wird nun einem trockenen Ge misch von 200 Teilen .des neutralisierten Sulfierungsproduktes von Phenol, mit 180 Teilen Diäthylanilin beigegeben, wobei Er wärmung eintritt. Unter Rühren wird die Temperatur auf 90 gesteigert und, sobald eine Probe nach Entfernen .des Diäthylani- lins wasserlöslich ist, der Gefässinhalt vorn Diäthylanilin befreit und nach Lösen in Wasser der neue Körper ausgeschieden.
An Stelle von Diäthylanilin kann in .das Reak tionsgemisch Sodalösung zugetropft werden, und zwar so, dass rotes Lackmuspapier stets schwach blau anzeigt. Das abgeschiedene Produkt ist in Wasser leicht und klar lös lieh und zeigt vorzügliche Netzfähigkeit, sowie ein ausgezeichnetes Wollwaschver- mögen. Die Echtheiten gegen Mineralsäuren, hartes Wasser, Magnesiumsalze, Kochsalz und Alkalien sind bemerkenswerte.
Process for the production of a wetting, dispersing; Emulsifying and ash agents. It was found that a new, valuable wetting, dispersing. Emulsifiers and detergents can be obtained if lauric alcohol is esterified with sulphuryl chloride and the resulting product is then reacted with the neutralized sulphonation product of phenol with the addition of acid-binding agents.
The resulting solid product is clearly soluble in water and is characterized by the excellent overall fastness that is required of such a textile auxiliary product today. <I> Example: </I> 150 parts of sulfuryl chloride are added dropwise to 186 parts of lauric alcohol at 20 to <B> 30 '</B>, the mixture is slowly stirred for 24 hours at this temperature and then a slow stream of air is blown through remove the excess sulfuryl chloride.
The reaction product is then added to a dry mixture of 200 parts of the neutralized sulfonation product of phenol with 180 parts of diethylaniline, with heating occurring. The temperature is increased to 90 with stirring and, as soon as a sample is water-soluble after removal of the diethyl aniline, the contents of the vessel are freed from diethyl aniline and the new body is excreted after dissolving in water.
Instead of diethylaniline, soda solution can be added dropwise to the reaction mixture in such a way that red litmus paper always shows a weak blue. The deposited product is easily and clearly soluble in water and shows excellent wetting properties and excellent wool washability. The fastness properties to mineral acids, hard water, magnesium salts, common salt and alkalis are remarkable.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH163003T | 1932-09-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH163003A true CH163003A (en) | 1933-07-31 |
Family
ID=4416113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH163003D CH163003A (en) | 1932-09-10 | 1932-09-03 | Process for the production of a wetting, dispersing, emulsifying and washing agent. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH163003A (en) |
-
1932
- 1932-09-03 CH CH163003D patent/CH163003A/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CH163003A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| CH167030A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| CH167031A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| CH167028A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| CH163001A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| AT138252B (en) | Process for the preparation of ester-like wetting agents, foaming agents and dispersants. | |
| DE670097C (en) | Process for the production of pellets from protein substances and / or protein breakdown products | |
| CH167025A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| DE927929C (en) | Process for the production of peptide-like protein degradation products | |
| CH167027A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| CH167026A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| DE627054C (en) | Process for the production of haloaminoalkylsulfonic acid esters or sulfonic acids | |
| CH256763A (en) | Process for the production of a new half-ester. | |
| DE582380C (en) | Process for the production of condensation products of aromatic sulfonic acids with capillary-active properties | |
| CH167029A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| CH163005A (en) | Process for the preparation of a new sulfonic acid. | |
| CH162732A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| CH165386A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| CH164730A (en) | Process for the preparation of a new sulfonic acid. | |
| CH204118A (en) | Process for the production of a valuable substance which is active in the boil capillary. | |
| CH172369A (en) | Process for the preparation of a nitrogen-containing condensation product. | |
| CH159664A (en) | Process for the preparation of a water-soluble derivative of the terpene series. | |
| CH233100A (en) | Process for the production of a tanning agent. | |
| CH165394A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. | |
| CH163002A (en) | Process for the production of a wetting, dispersing, emulsifying and washing agent. |