CH124946A - Process for producing a soluble mercury compound. - Google Patents
Process for producing a soluble mercury compound.Info
- Publication number
- CH124946A CH124946A CH124946DA CH124946A CH 124946 A CH124946 A CH 124946A CH 124946D A CH124946D A CH 124946DA CH 124946 A CH124946 A CH 124946A
- Authority
- CH
- Switzerland
- Prior art keywords
- sep
- producing
- mercury compound
- soluble mercury
- soluble
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 5
- 229940100892 mercury compound Drugs 0.000 title claims description 4
- 150000002731 mercury compounds Chemical class 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 208000035473 Communicable disease Diseases 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 4
- 229910000474 mercury oxide Inorganic materials 0.000 description 4
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 229910052787 antimony Inorganic materials 0.000 description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- GQTHXQVZAKGYGN-UHFFFAOYSA-N 2,4-dihydroxybenzene-1,3-disulfonic acid Chemical compound OC1=CC=C(S(O)(=O)=O)C(O)=C1S(O)(=O)=O GQTHXQVZAKGYGN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- -1 resorcinol disulphonic acid potassium Chemical compound 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
- C07F3/103—Mercury compounds without C-Mercury linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
Verfahren zur Herstellung einer löslichen Quecksilberverbindung. Im Hauptpatent ist ein Verfahren be schrieben, nach dem man eine Komplexver bindung von Antimon mit Pyrogalloldisulfo- säure erhält. Verbindungen dieser Art unter scheiden sich von gewöhnlichen Salzen des Antimons dadurch, dass sie eine Reihe von Reaktionen dieser Salze nicht haben. Sie enthalten nämlich das Antimon in festerer, sog enannter Komplexverbindung. Diese Stoff e sind als Heilmittel verwendbar, da in ihnen infolge der festeren Bindung des Anti mons die schädliche Wirkung gegenüber dei Heilwirkung zurückgedrängt ist.
Es wurde nun gefunden, dass die glei chen Verhältnisse obwalten, wenn " man resorcindisulfosaures Kalium mit Quecksilber oxyd umsetzt.
Die Ausführung des Verfahrens erfolgt am besten in der Weise, dass man resorcindi- sulfosaures Kalium mit der erforderlichen Menge der Quecksilberverbindung in wässe riger Lösung, gegebenenfalls unter Erwär men umsetzt. <I>Beispiel:</I> 36 gr resorcindisulfosaures Kalium wer den in 360 gr Wasser gelöst und mit einer Aufschlämmung von 15 gr Quecksilberoxyd versetzt. Unter Rühren und Erwärmen auf dem Wasserbade löst sich das Quecksilberoxyd auf. Die Lösung wird, wenn nötig, filtriert und zur Trockne gedampft.
Auch kann man die Lösung nach dem Einengen mit Alkohol behandeln und die Quecksilberkomplexver- bindungen des resorcindisulfo-sauren Kaliums dadurch zur Fällung bringen.
Das Produkt stellt ein gelbliches Pulver dar, das sich in der Kälte allmählich, schnel ler beim Erwärmen in Nasser löst. Aus der .Lösung fällt Alkali kein Quecksilberoxyd. Es dient als Mittel gegen Infektionskrank heiten.
Process for producing a soluble mercury compound. The main patent describes a process according to which a complex compound of antimony with pyrogallol disulfonic acid is obtained. Compounds of this type differ from ordinary salts of antimony in that they do not have a number of reactions of these salts. They contain the antimony in a more solid, so-called complex compound. These substances can be used as remedies, since in them, due to the stronger binding of the anti-mons, the harmful effects are suppressed compared to the healing effects.
It has now been found that the same conditions prevail when "resorcinol disulphonate potassium is reacted with mercury oxide.
The method is best carried out in such a way that resorcinol disulphonate is reacted with the required amount of the mercury compound in an aqueous solution, optionally with heating. <I> Example: </I> 36 grams of resorcinol disulphonic acid potassium are dissolved in 360 grams of water and mixed with a slurry of 15 grams of mercury oxide. The mercury oxide dissolves by stirring and heating on the water bath. The solution is filtered, if necessary, and evaporated to dryness.
The solution can also be treated with alcohol after it has been concentrated and the mercury complex compounds of the resorcinol disulfo-acidic potassium precipitate.
The product is a yellowish powder that dissolves gradually in the cold, faster when heated in water. Alkali and no mercury oxide fall out of the solution. It is used as a remedy against infectious diseases.
Claims (1)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH123233T | 1926-01-29 | ||
| CH125392T | 1926-01-29 | ||
| CH124946T | 1926-01-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH124946A true CH124946A (en) | 1928-03-16 |
Family
ID=27176800
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH124946D CH124946A (en) | 1926-01-29 | 1926-01-29 | Process for producing a soluble mercury compound. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH124946A (en) |
-
1926
- 1926-01-29 CH CH124946D patent/CH124946A/en unknown
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