CH125391A - Process for the preparation of a soluble vanadyl compound. - Google Patents
Process for the preparation of a soluble vanadyl compound.Info
- Publication number
- CH125391A CH125391A CH125391DA CH125391A CH 125391 A CH125391 A CH 125391A CH 125391D A CH125391D A CH 125391DA CH 125391 A CH125391 A CH 125391A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- soluble
- vanadyl compound
- compound
- vanadyl
- Prior art date
Links
- -1 vanadyl compound Chemical class 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 208000035473 Communicable disease Diseases 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- OQMUXQPCUBYTEB-UHFFFAOYSA-N benzene-1,2-diol;sodium Chemical compound [Na].OC1=CC=CC=C1O OQMUXQPCUBYTEB-UHFFFAOYSA-N 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- CJAZCKUGLFWINJ-UHFFFAOYSA-N 3,4-dihydroxybenzene-1,2-disulfonic acid Chemical compound OC1=CC=C(S(O)(=O)=O)C(S(O)(=O)=O)=C1O CJAZCKUGLFWINJ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/005—Compounds of elements of Group 5 of the Periodic Table without metal-carbon linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
Verfahren zur Herstellung einer löslichen Tanadylverbindung. Im Hauptpatent ist ein Verfahren be schrieben, nach dem man eine Komplexver bindung von Antimon mit Pyroga.lloldisulfo- säure erhält. Verbindungen dieser Art unter scheiden sich von gewöhnlichen Salzen des Antimons dadurch, dass sie eine Reihe von Reaktionen dieser Salze nicht haben. Sie ent halten nämlich das Antimon in festerer so- :;enannter Komplexverbindung. Diese Stoffe sind als Heilmittel verwendbar, da in ihnen infolge der festeren Bindung des Antimons die schädliche Wirkung gegenüber der Heil wirkung zurückgedrängt ist.
Es wurde gefunden, dass die gleichen Ver hältnisse obwalten, wenn man brenzkatechin- disulfosa.ures Natrium mit Vanadylhydroxyd umsetzt.
Die Ausführung des Verfahrens erfolgt am besten in der Weise, dass man brenz- ka.techindisulfosaures Natrium mit der er forderlichen Menge der Vanadylverbindung in wässeriger Lösung, gegebenenfalls -unter Erwärmen umsetzt.
<I>Beispiel:</I> 21 gr brenzkatechindisulfosaures Natrium werden in Wasser gelöst und Vanadylhydro- xyd (aus 7 gr Ammoniumvanadat durch Re duzieren gewonnen) darin aufgelöst. Man fügt verdünnte Natronlauge zu der tiefdunk len Lösung bis zum Eintreten der neutralen Reaktion zu, filtriert dann und 'fällt durch Eingiessen in Alkohol aus. Man erhält ein tief dunkelblaues, in Wasser leicht lösliches Pulver, das als Mittel gegen Infektionskrank heiten dient.
Process for the preparation of a soluble tanadyl compound. The main patent describes a process according to which a complex compound of antimony with Pyroga.lloldisulfonic acid is obtained. Compounds of this type differ from ordinary salts of antimony in that they do not have a number of reactions of these salts. This is because they contain the antimony in a more solid so-called complex compound. These substances can be used as remedies, as in them, due to the stronger bond of the antimony, the harmful effect is suppressed compared to the healing effect.
It has been found that the same conditions prevail when catechol disulfosa.ures sodium is reacted with vanadyl hydroxide.
The process is best carried out in such a way that sodium brenzka.techindisulfosaures sodium is reacted with the required amount of the vanadyl compound in aqueous solution, if necessary with heating.
<I> Example: </I> 21 grams of pyrocatechol disulphonic acid are dissolved in water and vanadyl hydroxide (obtained from 7 grams of ammonium vanadate by reducing) is dissolved in it. Dilute sodium hydroxide solution is added to the deeply dark solution until the neutral reaction occurs, then filtered and precipitated by pouring into alcohol. A deep dark blue powder which is readily soluble in water and which is used as an agent against infectious diseases is obtained.
Claims (1)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH125391T | 1926-01-29 | ||
| CH123233T | 1926-01-29 | ||
| CH125392T | 1926-01-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH125391A true CH125391A (en) | 1928-04-16 |
Family
ID=27176814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH125391D CH125391A (en) | 1926-01-29 | 1926-01-29 | Process for the preparation of a soluble vanadyl compound. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH125391A (en) |
-
1926
- 1926-01-29 CH CH125391D patent/CH125391A/en unknown
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