CH125394A - Process for the preparation of a soluble vanadium compound. - Google Patents
Process for the preparation of a soluble vanadium compound.Info
- Publication number
- CH125394A CH125394A CH125394DA CH125394A CH 125394 A CH125394 A CH 125394A CH 125394D A CH125394D A CH 125394DA CH 125394 A CH125394 A CH 125394A
- Authority
- CH
- Switzerland
- Prior art keywords
- vanadium compound
- preparation
- soluble vanadium
- pyrogallol
- soluble
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 5
- 150000003682 vanadium compounds Chemical class 0.000 title claims description 4
- 238000002360 preparation method Methods 0.000 title description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims description 6
- 229940079877 pyrogallol Drugs 0.000 claims description 3
- -1 vanadyl hydroxide Chemical compound 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 208000035473 Communicable disease Diseases 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- RALRVIPTUXSBPO-UHFFFAOYSA-N 4-[4-chloro-3-(trifluoromethyl)phenyl]piperidin-4-ol Chemical compound C=1C=C(Cl)C(C(F)(F)F)=CC=1C1(O)CCNCC1 RALRVIPTUXSBPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/005—Compounds of elements of Group 5 of the Periodic Table without metal-carbon linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Description
Verfahren zur Herstellung einer löslichen Vanadinverbindung. Im Hauptpatent ist ein Verfahren be schrieben, nach dem man eine Komplex verbindung von Antimon mit Pyrogallol.di- sulfosäure erhält. Verbindungen dieser Art unterscheiden sich von gewöhnlichen Salzen des Antimons dadurch, dass sie eine Reihe von Reaktionen dieser Salze nicht haben. Sie enthalten nämlich das Antimon in fe sterer sogenannter Komplexverbindung. Diese Stoffe sind als Heilmittel verwendbar, da in ihnen infolge der festeren Bindung des Antimons die schädliche Wirkung gegenüber der Heilwirkung zurückgedrängt ist.
Es wurde nun gefunden, dass die gleichen Verhältnisse obwalten, wenn man pyroga.llol- disulfosaures Natrium mit Vanadylhydroxyd umsetzt.
Die Ausführung des Verfahrens erfolgt ;im besten: in der Weise, dass man pyrogallol- disulfosaures Natrium mit der erforderlichen @le@. < ,@e der Vanadinverbindung in wässeriger Lö.,ung gegebenenfalls unter Erwärmen um setzt. , <I>Beispiel:</I> 20 gr pyrogalloldisulfosaures Natrium werden in Wasser gelöst und Vanadylhy- droxyd (aus 7 gr Ammoniumvanadat durch Reduzieren gewonnen) darin aufgelöst.
Man fügt verdünnte Natronlauge bis zur neu tralen Reaktion hinzu, filtriert dann und fällt durch Eingiessen in Methylalkohol aus. Nach dem Absaugen und Trocknen erhält man ein tiefdunkelblaues Pulver, das sich leicht in Wasser löst. Das erhaltene Produkt dient als Mittel gegen Infektionskrankheiten.
Process for the preparation of a soluble vanadium compound. The main patent describes a process by which a complex compound of antimony with Pyrogallol.disulfonic acid is obtained. Compounds of this type differ from ordinary salts of antimony in that they do not have a number of reactions of these salts. This is because they contain the antimony in a so-called complex compound. These substances can be used as remedies, because in them, due to the stronger binding of the antimony, the harmful effects are suppressed compared to the healing effects.
It has now been found that the same conditions prevail when pyroga.llol-disulphonate sodium is reacted with vanadyl hydroxide.
The procedure is carried out, ideally: in such a way that pyrogallol-disulfosauresodium with the required @ le @. <, @ e of the vanadium compound in an aqueous solution., and optionally with heating. , <I> Example: </I> 20 grams of pyrogallol disulfonic acid are dissolved in water and vanadyl hydroxide (obtained from 7 grams of ammonium vanadate by reducing) is dissolved in it.
Dilute sodium hydroxide solution is added until the reaction is neutral, then filtered and precipitated by pouring into methyl alcohol. After suctioning off and drying, a deep dark blue powder is obtained that dissolves easily in water. The product obtained is used as an agent against infectious diseases.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH123233T | 1926-01-29 | ||
| CH125394T | 1926-01-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH125394A true CH125394A (en) | 1928-04-16 |
Family
ID=25710062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH125394D CH125394A (en) | 1926-01-29 | 1926-01-29 | Process for the preparation of a soluble vanadium compound. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH125394A (en) |
-
1926
- 1926-01-29 CH CH125394D patent/CH125394A/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CH125394A (en) | Process for the preparation of a soluble vanadium compound. | |
| CH125391A (en) | Process for the preparation of a soluble vanadyl compound. | |
| CH125381A (en) | Process for the preparation of a soluble vanadyl compound. | |
| CH125386A (en) | Process for the preparation of a soluble vanadium compound. | |
| CH124939A (en) | Process for producing a soluble copper compound. | |
| CH155688A (en) | Process for the preparation of a water-soluble antimony salt. | |
| CH124947A (en) | Process for producing a soluble copper compound. | |
| CH124948A (en) | Process for producing a soluble manganese compound. | |
| AT106981B (en) | Process for the production of acid-free, pure, resinous condensation products from phenols and aldehydes. | |
| CH124949A (en) | Process for the production of a soluble cadmium compound. | |
| AT126152B (en) | Process for the production of physiologically active copper-arsenic compounds. | |
| CH125379A (en) | Process for the preparation of a soluble tin compound. | |
| CH125382A (en) | Process for producing a soluble copper compound. | |
| CH125378A (en) | Process for the production of a soluble cadmium compound. | |
| CH125377A (en) | Process for producing a soluble arsenic compound. | |
| DE411051C (en) | Process for the preparation of derivatives of 2-phenylquinoline-4-carboxylic acid | |
| CH125389A (en) | Process for the preparation of a soluble tin compound. | |
| DE442039C (en) | Process for the preparation of alkali-alkaline earth double salts of aromatic halosulfonamides | |
| CH125390A (en) | Process for the production of a soluble chromium compound. | |
| CH205160A (en) | Method for producing a capillary-active connection. | |
| DE436517C (en) | Process for the preparation of vanadium compounds of the quinoline series which are insoluble or sparingly soluble in water | |
| DE234054C (en) | ||
| CH125393A (en) | Process for the preparation of a soluble tin compound. | |
| CH124946A (en) | Process for producing a soluble mercury compound. | |
| CH125388A (en) | Process for the production of a soluble cadmium compound. |