CA3115366C - Alliage resistant a la chaleur antioxydation et procede de preparation - Google Patents

Alliage resistant a la chaleur antioxydation et procede de preparation Download PDF

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Publication number
CA3115366C
CA3115366C CA3115366A CA3115366A CA3115366C CA 3115366 C CA3115366 C CA 3115366C CA 3115366 A CA3115366 A CA 3115366A CA 3115366 A CA3115366 A CA 3115366A CA 3115366 C CA3115366 C CA 3115366C
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Prior art keywords
alloy
oxidation
present disclosure
resistant
temperature
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CA3115366A1 (fr
Inventor
Heli LUO
Xinglei WANG
Shangping LI
Zhaoxiong GU
Jiantao Wang
Lijuan WEI
Fajie YIN
Zhenhua Wang
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QINGDAO NPA INDUSTRY Co Ltd
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QINGDAO NPA INDUSTRY Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/023—Alloys based on nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/053—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 30% but less than 40%
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/02—Pretreatment of the material to be coated
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/10—Oxidising
    • C23C8/12—Oxidising using elemental oxygen or ozone
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/10—Oxidising
    • C23C8/12—Oxidising using elemental oxygen or ozone
    • C23C8/14—Oxidising of ferrous surfaces
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/80—After-treatment

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

La présente invention concerne le domaine technique des alliages, et concerne un alliage résistant à la chaleur antioxydation et un procédé de préparation, qui résolvent le problème des alliages existants ayant une ténacité faible lorsque la teneur en oxygène, en soufre et en azote dans les alliages est élevée, la proportion d'un film de Al2O3 dans un film d'oxyde d'une surface d'alliage est faible, et la teneur en aluminium est élevée. L'alliage résistant à la chaleur antioxydation de la présente invention comprend, selon un pourcentage en masse : Al: 2,5 % à 6 %, Cr : 24 % à 30 %, C : 0,3 % à 0,55 %, Ni : 30 % à 50 %, W : 2 % à 8 %, Ti : 0,01 % à 0,2 %, Zr : 0,01 % à 0,2 %, Hf : 0,01 % à 0,4 %, Y : 0,01 % à 0,2 %, V : 0,01 % à 0,2 %, N < 0,05 %, O < 0,003 %, S < 0,003 %, Si < 0,5 %, et le reste est Fe et des impuretés inévitables, Ti et V constituant l'une de celles-ci. Le procédé de préparation de l'alliage résistant à la chaleur antioxydation comprend : la fusion de matériaux d'éléments non actifs ? raffinage ? ajout d'un mélange de terres rares ? ajout de scories ? alliage des éléments actifs. La température de grade antioxydation complète de l'alliage résistant à la chaleur antioxydation de la présente invention atteint 1200 °C, de façon à mettre en uvre le service stable de l'alliage au-dessous de 1200 °C pendant une longue durée.
CA3115366A 2018-11-08 2019-09-12 Alliage resistant a la chaleur antioxydation et procede de preparation Active CA3115366C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201811324651.0A CN109112327B (zh) 2018-11-08 2018-11-08 一种抗氧化耐热合金及制备方法
CN201811324651.0 2018-11-08
PCT/CN2019/105531 WO2020093783A1 (fr) 2018-11-08 2019-09-12 Alliage résistant à la chaleur antioxydation et procédé de préparation

Publications (2)

Publication Number Publication Date
CA3115366A1 CA3115366A1 (fr) 2020-05-14
CA3115366C true CA3115366C (fr) 2023-12-12

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ID=64853651

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CA3115366A Active CA3115366C (fr) 2018-11-08 2019-09-12 Alliage resistant a la chaleur antioxydation et procede de preparation

Country Status (16)

Country Link
US (2) US12270095B2 (fr)
JP (1) JP7084551B2 (fr)
KR (1) KR102556685B1 (fr)
CN (1) CN109112327B (fr)
CA (1) CA3115366C (fr)
DK (1) DK3650560T3 (fr)
ES (1) ES2891575T3 (fr)
IL (1) IL283000B2 (fr)
MX (1) MX2021005478A (fr)
MY (1) MY204842A (fr)
RU (1) RU2760223C1 (fr)
SA (1) SA119410180B1 (fr)
SG (1) SG11202012154WA (fr)
UA (1) UA128118C2 (fr)
WO (1) WO2020093783A1 (fr)
ZA (1) ZA202102705B (fr)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109112327B (zh) * 2018-11-08 2019-09-03 青岛新力通工业有限责任公司 一种抗氧化耐热合金及制备方法
CN112024870A (zh) * 2020-07-30 2020-12-04 西安欧中材料科技有限公司 一种3d打印用smtgh3230球形粉末及其制备方法和应用
CN112553504B (zh) * 2020-11-23 2021-12-14 中国华能集团有限公司 一种高抗氧化性能的析出强化型镍钴基合金及其制备方法
CN112853155A (zh) * 2021-01-08 2021-05-28 烟台玛努尔高温合金有限公司 具有优异高温耐腐蚀性和抗蠕变性的高铝奥氏体合金
CN113234961B (zh) * 2021-03-05 2022-04-26 北京钢研高纳科技股份有限公司 一种耐1100℃高温抗氧化燃烧室合金及其制备方法
CN113278968B (zh) * 2021-06-24 2022-06-14 南昌大学 一种抗高温氧化的Al、Si复合添加改性镍基高温合金涂层及其制备方法
CN114107803A (zh) * 2021-10-22 2022-03-01 中国科学院金属研究所 一种电站流化床风帽用高温耐磨cnre稀土耐热钢及其制备方法
CN115433853B (zh) * 2022-09-13 2023-08-01 中国联合重型燃气轮机技术有限公司 一种抗氧化、抗裂纹镍基高温合金及其制备方法和应用
CN115533064A (zh) * 2022-09-30 2022-12-30 深圳市钢昱碳晶科技有限公司 压铸或挤压铸造铝合金材料的制造方法
CN115595469A (zh) * 2022-10-18 2023-01-13 深圳市钢昱碳晶科技有限公司（Cn） 铝合金熔体精炼时接触熔体的器具材料及其制造方法
CN116334473A (zh) * 2023-03-16 2023-06-27 长沙金铎机械有限公司 过共晶耐热高铬铸铁导板及其制造方法
CN117026084B (zh) * 2023-08-22 2024-11-05 青岛新力通工业有限责任公司 一种耐热合金及其制备方法
CN120843893B (zh) * 2025-07-16 2026-03-31 青岛新力通工业有限责任公司 一种综合性能优异的含铝耐热合金及其制备方法
CN120624894B (zh) * 2025-08-12 2025-11-07 铸新科技(苏州)有限责任公司 一种耐高温的奥氏体耐热铸造合金材料及其应用方法

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Also Published As

Publication number Publication date
ES2891575T3 (es) 2022-01-28
CA3115366A1 (fr) 2020-05-14
SG11202012154WA (en) 2021-01-28
CN109112327A (zh) 2019-01-01
RU2760223C1 (ru) 2021-11-23
US20250243574A1 (en) 2025-07-31
KR102556685B1 (ko) 2023-07-18
UA128118C2 (uk) 2024-04-10
MY204842A (en) 2024-09-18
BR112021008637A2 (pt) 2021-08-10
KR20200126001A (ko) 2020-11-05
JP2021526593A (ja) 2021-10-07
ZA202102705B (en) 2022-08-31
IL283000B2 (en) 2024-12-01
IL283000B1 (en) 2024-08-01
JP7084551B2 (ja) 2022-06-14
US20220018005A1 (en) 2022-01-20
DK3650560T3 (da) 2021-09-20
CN109112327B (zh) 2019-09-03
WO2020093783A1 (fr) 2020-05-14
MX2021005478A (es) 2021-06-18
IL283000A (en) 2021-06-30
SA119410180B1 (ar) 2022-07-20
US12270095B2 (en) 2025-04-08

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