CA3115366C - Alliage resistant a la chaleur antioxydation et procede de preparation - Google Patents
Alliage resistant a la chaleur antioxydation et procede de preparation Download PDFInfo
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- CA3115366C CA3115366C CA3115366A CA3115366A CA3115366C CA 3115366 C CA3115366 C CA 3115366C CA 3115366 A CA3115366 A CA 3115366A CA 3115366 A CA3115366 A CA 3115366A CA 3115366 C CA3115366 C CA 3115366C
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- alloy
- oxidation
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- 239000000956 alloy Substances 0.000 title claims abstract description 245
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 241
- 238000002360 preparation method Methods 0.000 title abstract description 25
- 230000003064 anti-oxidating effect Effects 0.000 title abstract description 7
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 26
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 21
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 20
- 239000002893 slag Substances 0.000 claims abstract description 17
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 14
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 13
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 12
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 8
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 131
- 230000003647 oxidation Effects 0.000 claims description 123
- 239000010959 steel Substances 0.000 claims description 71
- 229910000831 Steel Inorganic materials 0.000 claims description 70
- 238000005266 casting Methods 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 30
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 22
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 5
- 238000010079 rubber tapping Methods 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- 241000180579 Arca Species 0.000 claims 1
- -1 titaniurn Chemical compound 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 31
- 229910052782 aluminium Inorganic materials 0.000 abstract description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 18
- 229910052719 titanium Inorganic materials 0.000 abstract description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 16
- 238000007670 refining Methods 0.000 abstract description 12
- 238000003723 Smelting Methods 0.000 abstract description 11
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 11
- 229910052760 oxygen Inorganic materials 0.000 abstract description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 10
- 239000001301 oxygen Substances 0.000 abstract description 10
- 229910052720 vanadium Inorganic materials 0.000 abstract description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011593 sulfur Substances 0.000 abstract description 7
- 229910052593 corundum Inorganic materials 0.000 abstract description 5
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract description 5
- 229910052759 nickel Inorganic materials 0.000 abstract description 4
- 229910052804 chromium Inorganic materials 0.000 abstract description 3
- 229910052721 tungsten Inorganic materials 0.000 abstract description 3
- 238000005275 alloying Methods 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 28
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 22
- 239000010936 titanium Substances 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 17
- 229940024548 aluminum oxide Drugs 0.000 description 16
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 16
- 239000000203 mixture Substances 0.000 description 15
- 239000011651 chromium Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
- 239000011159 matrix material Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- 229910052786 argon Inorganic materials 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 238000006477 desulfuration reaction Methods 0.000 description 8
- 230000023556 desulfurization Effects 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
- 238000005336 cracking Methods 0.000 description 7
- 150000001247 metal acetylides Chemical class 0.000 description 7
- 238000009750 centrifugal casting Methods 0.000 description 6
- 150000004767 nitrides Chemical class 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- 238000005728 strengthening Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000002411 adverse Effects 0.000 description 4
- QDOXWKRWXJOMAK-UHFFFAOYSA-N chromium(III) oxide Inorganic materials O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 4
- 230000003749 cleanliness Effects 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 150000003568 thioethers Chemical class 0.000 description 4
- 229910001566 austenite Inorganic materials 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910000601 superalloy Inorganic materials 0.000 description 3
- 238000010301 surface-oxidation reaction Methods 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 229910000604 Ferrochrome Inorganic materials 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910000714 At alloy Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005235 decoking Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000005495 investment casting Methods 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/023—Alloys based on nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/053—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 30% but less than 40%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/02—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/10—Oxidising
- C23C8/12—Oxidising using elemental oxygen or ozone
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/10—Oxidising
- C23C8/12—Oxidising using elemental oxygen or ozone
- C23C8/14—Oxidising of ferrous surfaces
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/80—After-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Heat Treatment Of Steel (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
La présente invention concerne le domaine technique des alliages, et concerne un alliage résistant à la chaleur antioxydation et un procédé de préparation, qui résolvent le problème des alliages existants ayant une ténacité faible lorsque la teneur en oxygène, en soufre et en azote dans les alliages est élevée, la proportion d'un film de Al2O3 dans un film d'oxyde d'une surface d'alliage est faible, et la teneur en aluminium est élevée. L'alliage résistant à la chaleur antioxydation de la présente invention comprend, selon un pourcentage en masse : Al: 2,5 % à 6 %, Cr : 24 % à 30 %, C : 0,3 % à 0,55 %, Ni : 30 % à 50 %, W : 2 % à 8 %, Ti : 0,01 % à 0,2 %, Zr : 0,01 % à 0,2 %, Hf : 0,01 % à 0,4 %, Y : 0,01 % à 0,2 %, V : 0,01 % à 0,2 %, N < 0,05 %, O < 0,003 %, S < 0,003 %, Si < 0,5 %, et le reste est Fe et des impuretés inévitables, Ti et V constituant l'une de celles-ci. Le procédé de préparation de l'alliage résistant à la chaleur antioxydation comprend : la fusion de matériaux d'éléments non actifs ? raffinage ? ajout d'un mélange de terres rares ? ajout de scories ? alliage des éléments actifs. La température de grade antioxydation complète de l'alliage résistant à la chaleur antioxydation de la présente invention atteint 1200 °C, de façon à mettre en uvre le service stable de l'alliage au-dessous de 1200 °C pendant une longue durée.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811324651.0 | 2018-11-08 | ||
| CN201811324651.0A CN109112327B (zh) | 2018-11-08 | 2018-11-08 | 一种抗氧化耐热合金及制备方法 |
| PCT/CN2019/105531 WO2020093783A1 (fr) | 2018-11-08 | 2019-09-12 | Alliage résistant à la chaleur antioxydation et procédé de préparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3115366A1 CA3115366A1 (fr) | 2020-05-14 |
| CA3115366C true CA3115366C (fr) | 2023-12-12 |
Family
ID=64853651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3115366A Active CA3115366C (fr) | 2018-11-08 | 2019-09-12 | Alliage resistant a la chaleur antioxydation et procede de preparation |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US12270095B2 (fr) |
| JP (1) | JP7084551B2 (fr) |
| KR (1) | KR102556685B1 (fr) |
| CN (1) | CN109112327B (fr) |
| CA (1) | CA3115366C (fr) |
| DK (1) | DK3650560T3 (fr) |
| ES (1) | ES2891575T3 (fr) |
| IL (1) | IL283000B2 (fr) |
| MX (1) | MX2021005478A (fr) |
| MY (1) | MY204842A (fr) |
| RU (1) | RU2760223C1 (fr) |
| SA (1) | SA119410180B1 (fr) |
| SG (1) | SG11202012154WA (fr) |
| UA (1) | UA128118C2 (fr) |
| WO (1) | WO2020093783A1 (fr) |
| ZA (1) | ZA202102705B (fr) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109112327B (zh) | 2018-11-08 | 2019-09-03 | 青岛新力通工业有限责任公司 | 一种抗氧化耐热合金及制备方法 |
| CN112024870A (zh) * | 2020-07-30 | 2020-12-04 | 西安欧中材料科技有限公司 | 一种3d打印用smtgh3230球形粉末及其制备方法和应用 |
| CN112553504B (zh) * | 2020-11-23 | 2021-12-14 | 中国华能集团有限公司 | 一种高抗氧化性能的析出强化型镍钴基合金及其制备方法 |
| CN112853155A (zh) * | 2021-01-08 | 2021-05-28 | 烟台玛努尔高温合金有限公司 | 具有优异高温耐腐蚀性和抗蠕变性的高铝奥氏体合金 |
| CN113234961B (zh) * | 2021-03-05 | 2022-04-26 | 北京钢研高纳科技股份有限公司 | 一种耐1100℃高温抗氧化燃烧室合金及其制备方法 |
| CN113278968B (zh) * | 2021-06-24 | 2022-06-14 | 南昌大学 | 一种抗高温氧化的Al、Si复合添加改性镍基高温合金涂层及其制备方法 |
| CN114107803A (zh) * | 2021-10-22 | 2022-03-01 | 中国科学院金属研究所 | 一种电站流化床风帽用高温耐磨cnre稀土耐热钢及其制备方法 |
| CN115433853B (zh) * | 2022-09-13 | 2023-08-01 | 中国联合重型燃气轮机技术有限公司 | 一种抗氧化、抗裂纹镍基高温合金及其制备方法和应用 |
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| CN116334473A (zh) * | 2023-03-16 | 2023-06-27 | 长沙金铎机械有限公司 | 过共晶耐热高铬铸铁导板及其制造方法 |
| CN117026084B (zh) * | 2023-08-22 | 2024-11-05 | 青岛新力通工业有限责任公司 | 一种耐热合金及其制备方法 |
| CN120843893A (zh) * | 2025-07-16 | 2025-10-28 | 青岛新力通工业有限责任公司 | 一种综合性能优异的含铝耐热合金及其制备方法 |
| CN120624894B (zh) * | 2025-08-12 | 2025-11-07 | 铸新科技(苏州)有限责任公司 | 一种耐高温的奥氏体耐热铸造合金材料及其应用方法 |
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| SU1713962A1 (ru) | 1989-12-27 | 1992-02-23 | Центральный научно-исследовательский институт черной металлургии им.И.П.Бардина | Порошковый сплав на основе никел |
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| DE102012004488A1 (de) * | 2011-06-21 | 2012-12-27 | Thyssenkrupp Vdm Gmbh | Hitzebeständige Eisen-Chrom-Aluminium-Legierung mit geringer Chromverdampfungsrate und erhöhter Warmfestigkeit |
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| CN109112327B (zh) * | 2018-11-08 | 2019-09-03 | 青岛新力通工业有限责任公司 | 一种抗氧化耐热合金及制备方法 |
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| KR102556685B1 (ko) | 2023-07-18 |
| IL283000A (en) | 2021-06-30 |
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| MY204842A (en) | 2024-09-18 |
| IL283000B2 (en) | 2024-12-01 |
| JP7084551B2 (ja) | 2022-06-14 |
| RU2760223C1 (ru) | 2021-11-23 |
| CN109112327B (zh) | 2019-09-03 |
| MX2021005478A (es) | 2021-06-18 |
| US20220018005A1 (en) | 2022-01-20 |
| SG11202012154WA (en) | 2021-01-28 |
| US20250243574A1 (en) | 2025-07-31 |
| SA119410180B1 (ar) | 2022-07-20 |
| US12270095B2 (en) | 2025-04-08 |
| WO2020093783A1 (fr) | 2020-05-14 |
| ES2891575T3 (es) | 2022-01-28 |
| IL283000B1 (en) | 2024-08-01 |
| JP2021526593A (ja) | 2021-10-07 |
| BR112021008637A2 (pt) | 2021-08-10 |
| CN109112327A (zh) | 2019-01-01 |
| KR20200126001A (ko) | 2020-11-05 |
| UA128118C2 (uk) | 2024-04-10 |
| ZA202102705B (en) | 2022-08-31 |
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