CA3039380C - Procede de separation de particules contenant des sels de metaux alcalins a partir d'hydrocarbures liquides - Google Patents

Procede de separation de particules contenant des sels de metaux alcalins a partir d'hydrocarbures liquides Download PDF

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Publication number
CA3039380C
CA3039380C CA3039380A CA3039380A CA3039380C CA 3039380 C CA3039380 C CA 3039380C CA 3039380 A CA3039380 A CA 3039380A CA 3039380 A CA3039380 A CA 3039380A CA 3039380 C CA3039380 C CA 3039380C
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Canada
Prior art keywords
alkali metal
mixture
sulfur
liquid hydrocarbon
liquid
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Active
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CA3039380A
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English (en)
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CA3039380A1 (fr
Inventor
Michael Zenaitis
Jeff Killpack
Mykola MAKOWSKY
John Howard Gordon
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Enlighten Innovations Inc
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Enlighten Innovations Inc
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Filing date
Publication date
Priority claimed from US15/446,299 external-priority patent/US20170253816A1/en
Application filed by Enlighten Innovations Inc filed Critical Enlighten Innovations Inc
Publication of CA3039380A1 publication Critical patent/CA3039380A1/fr
Application granted granted Critical
Publication of CA3039380C publication Critical patent/CA3039380C/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/02—Non-metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/04—Metals, or metals deposited on a carrier
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Peptides Or Proteins (AREA)

Abstract

La présente invention concerne un procédé comprenant le chauffage d'un premier mélange de soufre élémentaire et de particules comprenant un sulfure de métal alcalin dans un hydrocarbure liquide jusqu'à une température d'au moins 150 °C, afin de fournir un mélange traité au soufre comprenant des particules agglomérées ; et la séparation des particules agglomérées du mélange traité au soufre pour fournir un hydrocarbure liquide désulfurisé et des solides séparés. Ce procédé peut être utilisé en tant que partie d'une suite de procédés de désulfurisation d'hydrocarbures liquides contaminés par des composés organosoufrés et d'autres contaminants à base d'hétéroatomes. La présente technologie concerne en outre des procédés de conversion de solides riches en carbone (par exemple, du coke de pétrole) en carburants.
CA3039380A 2016-10-04 2017-10-04 Procede de separation de particules contenant des sels de metaux alcalins a partir d'hydrocarbures liquides Active CA3039380C (fr)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201662404119P 2016-10-04 2016-10-04
US62/404,119 2016-10-04
US15/446,299 US20170253816A1 (en) 2016-03-03 2017-03-01 Method for recovering alkali metal from hydrocarbon feedstocks treated with alkali metal
US15/446,299 2017-03-01
US201762513871P 2017-06-01 2017-06-01
US62/513,871 2017-06-01
PCT/US2017/055213 WO2018067753A1 (fr) 2016-10-04 2017-10-04 Procédé de séparation de particules contenant des sels de métaux alcalins à partir d'hydrocarbures liquides

Publications (2)

Publication Number Publication Date
CA3039380A1 CA3039380A1 (fr) 2018-04-12
CA3039380C true CA3039380C (fr) 2023-02-28

Family

ID=61831294

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3039380A Active CA3039380C (fr) 2016-10-04 2017-10-04 Procede de separation de particules contenant des sels de metaux alcalins a partir d'hydrocarbures liquides

Country Status (8)

Country Link
EP (1) EP3523396B1 (fr)
JP (1) JP6817656B2 (fr)
KR (1) KR102211995B1 (fr)
CN (1) CN109890944B (fr)
CA (1) CA3039380C (fr)
ES (1) ES2836679T3 (fr)
SG (1) SG11201902990UA (fr)
WO (1) WO2018067753A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20230193144A1 (en) * 2020-05-19 2023-06-22 Enlighten Innovations Inc. Purification and conversion processes for asphaltene-containing feedstocks
CA3183922A1 (fr) * 2020-05-19 2021-11-25 Enlighten Innovations Inc. Procedes permettant d'ameliorer les performances d'une conversion d'huile en aval
TW202216971A (zh) * 2020-10-19 2022-05-01 大陸商中國石油化工科技開發有限公司 一種生產燃料油的方法和系統及其應用以及燃料油及其應用
WO2023042175A1 (fr) * 2021-09-17 2023-03-23 Enlighten Innovations Inc. Compositions et procédés de fabrication de fibres de carbone à partir d'asphaltènes

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1300816A (en) * 1915-09-11 1919-04-15 Standard Oil Co Process of desulfurizing petroleum-oils.
US3791966A (en) * 1972-05-24 1974-02-12 Exxon Research Engineering Co Alkali metal desulfurization process for petroleum oil stocks
US3849297A (en) * 1972-06-08 1974-11-19 Exxon Research Engineering Co Process for removing metals from petroleum residua
US3904511A (en) * 1973-10-05 1975-09-09 Mobil Oil Corp Process for eliminating unstable hydrogen from lubricating oil stock
US6210564B1 (en) * 1996-06-04 2001-04-03 Exxon Research And Engineering Company Process for desulfurization of petroleum feeds utilizing sodium metal
WO2009070593A1 (fr) * 2007-11-27 2009-06-04 Ceramatec, Inc. Procédé pour récupérer des métaux alcalins et du soufre à partir de sulfures et de polysulfures de métaux alcalins
US9475998B2 (en) * 2008-10-09 2016-10-25 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
EP2496669B1 (fr) 2009-11-02 2017-12-20 Field Upgrading Limited Valorisation de charges d'huiles de pétrole à l'aide de métaux alcalins et d'hydrocarbures
US20160053185A1 (en) * 2009-11-02 2016-02-25 Field Upgrading Limited Process to separate alkali metal salts from alkali metal reacted hydrocarbons
US9688920B2 (en) * 2009-11-02 2017-06-27 Field Upgrading Limited Process to separate alkali metal salts from alkali metal reacted hydrocarbons
DE102011013470A1 (de) * 2010-07-26 2012-01-26 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren und Mittel zur Entfernung von Metallen aus hochsiedenden Kohlenwasserstofffraktionen
KR102090358B1 (ko) * 2013-04-15 2020-03-17 필드 업그레이딩 리미티드 알칼리금속과 반응시킨 탄화수소들로부터 알칼리금속염들을 분리하는 방법

Also Published As

Publication number Publication date
EP3523396A1 (fr) 2019-08-14
CN109890944A (zh) 2019-06-14
JP2019536883A (ja) 2019-12-19
KR102211995B1 (ko) 2021-02-05
CN109890944B (zh) 2020-07-03
ES2836679T3 (es) 2021-06-28
WO2018067753A1 (fr) 2018-04-12
SG11201902990UA (en) 2019-05-30
EP3523396B1 (fr) 2020-11-25
JP6817656B2 (ja) 2021-01-20
KR20190058616A (ko) 2019-05-29
CA3039380A1 (fr) 2018-04-12

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