CA3004324C - Process and system for making cyclopentadiene and/or dicyclopentadiene - Google Patents

Process and system for making cyclopentadiene and/or dicyclopentadiene Download PDF

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Publication number
CA3004324C
CA3004324C CA3004324A CA3004324A CA3004324C CA 3004324 C CA3004324 C CA 3004324C CA 3004324 A CA3004324 A CA 3004324A CA 3004324 A CA3004324 A CA 3004324A CA 3004324 C CA3004324 C CA 3004324C
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Canada
Prior art keywords
stream
reactor
wash oil
rich
cpd
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CA3004324A
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English (en)
French (fr)
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CA3004324A1 (en
Inventor
Larry L. Iaccino
Kevin C.P. Leung
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ExxonMobil Chemical Patents Inc
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ExxonMobil Chemical Patents Inc
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Publication of CA3004324A1 publication Critical patent/CA3004324A1/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44Noble metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50Diels-Alder conversion
    • C07C2/52Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/10Purification; Separation; Use of additives by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44Noble metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/06Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00Systems containing at least three condensed rings
    • C07C2603/56Ring systems containing bridged rings
    • C07C2603/58Ring systems containing bridged rings containing three rings
    • C07C2603/60Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
    • C07C2603/66Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings
    • C07C2603/68Dicyclopentadienes; Hydrogenated dicyclopentadienes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA3004324A 2015-11-04 2016-10-07 Process and system for making cyclopentadiene and/or dicyclopentadiene Active CA3004324C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201562250692P 2015-11-04 2015-11-04
US62/250,692 2015-11-04
EP16153728.7 2016-02-02
EP16153728 2016-02-02
PCT/US2016/056038 WO2017078902A1 (en) 2015-11-04 2016-10-07 Process and system for making cyclopentadiene and/or dicyclopentadiene

Publications (2)

Publication Number Publication Date
CA3004324A1 CA3004324A1 (en) 2017-05-11
CA3004324C true CA3004324C (en) 2020-04-28

Family

ID=55304868

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3004324A Active CA3004324C (en) 2015-11-04 2016-10-07 Process and system for making cyclopentadiene and/or dicyclopentadiene

Country Status (5)

Country Link
EP (1) EP3371132A4 (de)
JP (1) JP6549321B2 (de)
CN (1) CN108349833A (de)
CA (1) CA3004324C (de)
WO (1) WO2017078902A1 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116802264A (zh) * 2020-12-28 2023-09-22 沙特基础工业全球技术公司 用于制备洗油的系统和方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2438400A (en) * 1945-11-24 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
US2438401A (en) * 1946-02-26 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
US2438404A (en) * 1948-01-20 1948-03-23 Sun Oil Co Treatment of hydrocarbons
US4140587A (en) * 1969-07-18 1979-02-20 Snamprogetti, S.P.A. Process for the separation of diolefins from mixtures containing the same
BE754878A (fr) * 1969-08-16 1971-02-15 Erdoelchemie Gmbh Procede de separation du cyclopentadiene de fractions en c5
DE2535809A1 (de) * 1974-08-13 1976-03-04 Shell Int Research Verfahren zur herstellung von cyclischen c tief 5-kohlenwasserstoffen
JPH0739354B2 (ja) * 1985-07-08 1995-05-01 日本ゼオン株式会社 高純度ジシクロペンタジエンの製造方法
DE3887990T2 (de) * 1987-11-17 1994-06-01 Mobil Oil Corp Dehydrogenierungskatalysator und dessen verwendung.
JPH03501942A (ja) * 1987-11-17 1991-05-09 モービル オイル コーポレーシヨン 脱水素及び脱水素環化触媒、その合成及び用途
US4886926A (en) * 1988-06-24 1989-12-12 Mobil Oil Corporation Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials
DK0940381T3 (da) * 1998-03-05 2004-03-15 Bp Koeln Gmbh Fremgangsmåde til fremstilling af cyclopentan og/eller cyclopenten
JP2001247490A (ja) * 2000-03-03 2001-09-11 Nippon Petrochem Co Ltd ジシクロペンタジエンの製造方法
RU2186051C1 (ru) * 2000-10-30 2002-07-27 Центр по разработке эластомеров Казанского государственного технологического университета Способ получения дициклопентадиена из c5-фракции пиролиза углеводородов
US6958426B2 (en) * 2001-09-29 2005-10-25 China Petroleum & Chemical Corporation Process for separating C5 cuts obtained from a petroleum cracking process
CN101450885B (zh) * 2007-12-07 2012-08-29 中国石油化工股份有限公司 一段萃取精馏分离碳五馏分的方法
RU2463284C1 (ru) * 2011-05-04 2012-10-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технологический университет" Способ получения дициклопентадиена
CN102951985A (zh) * 2011-08-17 2013-03-06 中国石油化工股份有限公司 分离碳五馏分并制取环戊二烯的方法
AR101431A1 (es) * 2013-06-05 2016-12-21 Gtc Technology Us Llc Proceso y aparatos para separar di-olefinas c₅ de naftas de pirólisis

Also Published As

Publication number Publication date
EP3371132A4 (de) 2018-10-17
WO2017078902A1 (en) 2017-05-11
JP6549321B2 (ja) 2019-07-24
CA3004324A1 (en) 2017-05-11
CN108349833A (zh) 2018-07-31
EP3371132A1 (de) 2018-09-12
JP2018535971A (ja) 2018-12-06
WO2017078902A8 (en) 2017-09-08

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