CA2986772C - Hydrogen production via sorbent enhanced reforming with atmospheric calcination - Google Patents

Hydrogen production via sorbent enhanced reforming with atmospheric calcination Download PDF

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Publication number
CA2986772C
CA2986772C CA2986772A CA2986772A CA2986772C CA 2986772 C CA2986772 C CA 2986772C CA 2986772 A CA2986772 A CA 2986772A CA 2986772 A CA2986772 A CA 2986772A CA 2986772 C CA2986772 C CA 2986772C
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CA
Canada
Prior art keywords
sorbent
hydrogen gas
carbon dioxide
calciner
enhanced reformer
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CA2986772A
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English (en)
French (fr)
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CA2986772A1 (en
Inventor
Jeffrey MAYS
Sreenivasan RAVISHANKAR
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GTI Energy
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Gas Technology Institute
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/28—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles, e.g. fluidised bed technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/0425—In-situ adsorption process during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Gas Separation By Absorption (AREA)
CA2986772A 2015-05-28 2016-05-27 Hydrogen production via sorbent enhanced reforming with atmospheric calcination Active CA2986772C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562167871P 2015-05-28 2015-05-28
US62/167,871 2015-05-28
PCT/US2016/034636 WO2016191678A1 (en) 2015-05-28 2016-05-27 Hydrogen production via sorbent enhanced reforming with atmospheric calcination

Publications (2)

Publication Number Publication Date
CA2986772A1 CA2986772A1 (en) 2016-12-01
CA2986772C true CA2986772C (en) 2024-03-19

Family

ID=56236060

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2986772A Active CA2986772C (en) 2015-05-28 2016-05-27 Hydrogen production via sorbent enhanced reforming with atmospheric calcination

Country Status (9)

Country Link
US (1) US10227234B2 (enExample)
EP (1) EP3303216A1 (enExample)
JP (2) JP7352330B2 (enExample)
KR (1) KR20180013990A (enExample)
CN (1) CN107635913A (enExample)
AU (1) AU2016267612B2 (enExample)
CA (1) CA2986772C (enExample)
WO (1) WO2016191678A1 (enExample)
ZA (1) ZA201708748B (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180162729A1 (en) 2015-05-28 2018-06-14 Gas Technology Institute Power generation using hydrogen fuel with economical carbon dioxide capture
WO2018148514A1 (en) * 2017-02-09 2018-08-16 Gas Technology Institute Power generation using hydrogen fuel with economical carbon dioxide capture
US20190135625A1 (en) * 2017-08-28 2019-05-09 Gas Technology Institute Staged sorbent enhanced methane reformer
CN112742169B (zh) * 2019-10-30 2023-10-10 中国石油化工股份有限公司 一种吸附工艺方法
US11535514B2 (en) * 2020-02-26 2022-12-27 Gas Technology Institute System and method for recycling pressure swing absorber off-gas
CA3227389A1 (en) 2021-08-09 2023-02-16 Arnstein NORHEIM Hydrogen production system
KR102618893B1 (ko) * 2021-12-13 2024-01-02 김지완 고온 증기를 이용한 수소 추출 장치
PL4292979T3 (pl) * 2022-06-17 2024-09-09 Zeg Power As Układ produkcji wodoru
CN115133072A (zh) * 2022-06-30 2022-09-30 哈尔滨工业大学 一种高效率低排放的高温燃料电池涡轮混合发电系统及方法

Family Cites Families (16)

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JPH0763318A (ja) * 1993-08-24 1995-03-07 Ishikawajima Harima Heavy Ind Co Ltd 加圧流動層ボイラのベッド材排出装置
JPH1130411A (ja) * 1997-07-08 1999-02-02 Nippon Steel Corp 廃棄物焼却炉
US6942719B2 (en) 2003-06-30 2005-09-13 The Boeing Company Methods and systems for pressure swing regeneration for hydrogen generation
US20050232855A1 (en) 2004-04-19 2005-10-20 Texaco Inc. Reactor with carbon dioxide fixing material
JP4939094B2 (ja) 2006-03-31 2012-05-23 三井造船株式会社 ガスハイドレートペレット製造装置
CA2860684C (en) * 2006-09-25 2015-12-01 The Ohio State University High purity, high pressure hydrogen production with in-situ co2 and sulfur capture in a single stage reactor
US8241374B2 (en) 2006-12-15 2012-08-14 Texaco Inc. Fluidized bed system for single step reforming for the production of hydrogen
JP4334577B2 (ja) 2007-03-09 2009-09-30 株式会社東芝 吸収材の再生方法
JP5004630B2 (ja) 2007-03-29 2012-08-22 三井造船株式会社 ガスハイドレート濃度の測定方法及び測定装置と、その測定方法を用いたガスハイドレート生成装置の制御方法及び制御装置
US7918906B2 (en) * 2007-05-20 2011-04-05 Pioneer Energy Inc. Compact natural gas steam reformer with linear countercurrent heat exchanger
JP5293099B2 (ja) 2007-11-14 2013-09-18 株式会社Ｉｈｉ Ｃｏ２回収ガス化方法及び装置
EP2305366B1 (en) 2009-09-16 2012-05-30 Consejo Superior de Investigaciones Científicas (CSIC) Method of capturing CO2 by means of CaO and the exothermal reduction of a solid
EP2501788A4 (en) * 2009-11-18 2013-12-04 G4 Insights Inc BY SORPTION REINFORCED METHANIZATION OF BIOMASS
CN102070125A (zh) 2011-03-03 2011-05-25 清华大学 一种吸附增强甲烷水蒸气重整制氢反应装置及方法
CN103288049B (zh) * 2013-06-18 2015-06-03 中国石油化工股份有限公司 一种流化-固定复合床反应吸附强化甲烷水蒸气重整制氢的装置及方法
CN104004532A (zh) 2014-05-29 2014-08-27 华南理工大学 一种以油页岩干馏气制氢提质的集成炼制系统及工艺

Also Published As

Publication number Publication date
WO2016191678A1 (en) 2016-12-01
US20160347611A1 (en) 2016-12-01
US10227234B2 (en) 2019-03-12
AU2016267612B2 (en) 2020-02-06
CA2986772A1 (en) 2016-12-01
ZA201708748B (en) 2018-12-19
KR20180013990A (ko) 2018-02-07
JP2018516836A (ja) 2018-06-28
EP3303216A1 (en) 2018-04-11
CN107635913A (zh) 2018-01-26
AU2016267612A1 (en) 2017-12-14
JP7352330B2 (ja) 2023-09-28
JP2023040004A (ja) 2023-03-22

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