CA2948242C - Compositions for cores used in investment casting - Google Patents

Compositions for cores used in investment casting Download PDF

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Publication number
CA2948242C
CA2948242C CA2948242A CA2948242A CA2948242C CA 2948242 C CA2948242 C CA 2948242C CA 2948242 A CA2948242 A CA 2948242A CA 2948242 A CA2948242 A CA 2948242A CA 2948242 C CA2948242 C CA 2948242C
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Canada
Prior art keywords
oxide
ceramic core
alumina
silica
core
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CA2948242A
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English (en)
French (fr)
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CA2948242A1 (en
Inventor
Xi Yang
John Thomas Leman
Anthony Yu-Chung Ku
Tao Li
John Patrick Pollinger
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General Electric Co
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General Electric Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C1/00Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/02Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by additives for special purposes, e.g. indicators, breakdown additives
    • B22C1/08Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by additives for special purposes, e.g. indicators, breakdown additives for decreasing shrinkage of the mould, e.g. for investment casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/10Cores; Manufacture or installation of cores
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C1/00Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/16Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
    • B22C1/18Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents
    • B22C1/183Sols, colloids or hydroxide gels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns
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    • C04B35/185Mullite 3Al2O3-2SiO2
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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10364189B2 (en) * 2017-05-04 2019-07-30 General Electric Company Methods for forming ceramic cores
US20190060982A1 (en) * 2017-08-29 2019-02-28 General Electric Company Carbon fibers in ceramic cores for investment casting
US10722939B2 (en) 2018-06-29 2020-07-28 Raytheon Technologies Corporation Production of multi-passage hollow casting
WO2021061556A1 (en) * 2019-09-27 2021-04-01 Corning Incorporated Extrudable ceramic precursor mixtures and methods of use
US11578002B2 (en) 2020-02-27 2023-02-14 General Electric Company Ceramic slurries with photoreactive-photostable hybrid binders
US11572313B2 (en) 2020-02-27 2023-02-07 General Electric Company Ceramic slurries with photoreactive-photostable hybrid binders
CN114853450B (zh) * 2022-05-23 2023-04-28 西北工业大学 一种光固化3d打印氧化铝基陶瓷型芯及其制备方法
CN115178708A (zh) * 2022-06-27 2022-10-14 惠州市棣华科技有限公司 一种精密铸件型壳及其制作工艺
CN115815574A (zh) * 2022-12-07 2023-03-21 中国航发动力股份有限公司 一种高温合金薄壁空心铸件的浇注方法

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3126357A (en) 1964-03-24 High temperature cement including
US2641044A (en) 1949-10-24 1953-06-09 Phillips Petroleum Co Process for manufacturing mullitecontaining refractories
US3108985A (en) 1960-11-02 1963-10-29 Dow Corning Polysiloxane polymer with a calcined volatile-free filler
US3445250A (en) 1967-02-28 1969-05-20 Nalco Chemical Co Precision metal casting molds comprising alumina coated silica and a refractory
US4093017A (en) 1975-12-29 1978-06-06 Sherwood Refractories, Inc. Cores for investment casting process
US4026344A (en) 1976-06-23 1977-05-31 General Electric Company Method for making investment casting molds for casting of superalloys
US4247333A (en) 1979-12-26 1981-01-27 General Electric Company Alumina shell molds used for investment casting in directional solidification of eutectic superalloys
US4703806A (en) * 1986-07-11 1987-11-03 Howmet Turbine Components Corporation Ceramic shell mold facecoat and core coating systems for investment casting of reactive metals
US4837187A (en) 1987-06-04 1989-06-06 Howmet Corporation Alumina-based core containing yttria
US4966225A (en) 1988-06-13 1990-10-30 Howmet Corporation Ceramic shell mold for investment casting and method of making the same
JP2663392B2 (ja) 1992-06-19 1997-10-15 工業技術院長 チタン及びその合金の鋳造用中子
US5660524A (en) 1992-07-13 1997-08-26 General Electric Company Airfoil blade having a serpentine cooling circuit and impingement cooling
US5332537A (en) 1992-12-17 1994-07-26 Pcc Airfoils, Inc. Method and binder for use in powder molding
US5409871A (en) 1993-11-02 1995-04-25 Pcc Airfoils, Inc. Ceramic material for use in casting reactive metals
US6036441A (en) 1998-11-16 2000-03-14 General Electric Company Series impingement cooled airfoil
US6168381B1 (en) 1999-06-29 2001-01-02 General Electric Company Airfoil isolated leading edge cooling
US7098275B2 (en) * 2001-06-27 2006-08-29 Inglefield Charles F Heat resistant material for molds and other articles
US6595748B2 (en) 2001-08-02 2003-07-22 General Electric Company Trichannel airfoil leading edge cooling
US20040152581A1 (en) 2003-02-03 2004-08-05 Bardes Bruce Paul Ceramic article and method of manufacture therefor
US6832889B1 (en) 2003-07-09 2004-12-21 General Electric Company Integrated bridge turbine blade
US20050006047A1 (en) 2003-07-10 2005-01-13 General Electric Company Investment casting method and cores and dies used therein
US7287573B2 (en) 2003-09-30 2007-10-30 General Electric Company Silicone binders for investment casting
US6929054B2 (en) 2003-12-19 2005-08-16 United Technologies Corporation Investment casting cores
DE102006020967A1 (de) 2006-05-05 2007-11-08 Goldschmidt Gmbh Reaktives, flüssiges Keramikbindemittel
US7610945B2 (en) * 2006-09-29 2009-11-03 General Electric Company Rare earth-based core constructions for casting refractory metal composites, and related processes
US20080135721A1 (en) 2006-12-06 2008-06-12 General Electric Company Casting compositions for manufacturing metal casting and methods of manufacturing thereof
US7487819B2 (en) 2006-12-11 2009-02-10 General Electric Company Disposable thin wall core die, methods of manufacture thereof and articles manufactured therefrom
US7798201B2 (en) 2007-08-24 2010-09-21 General Electric Company Ceramic cores for casting superalloys and refractory metal composites, and related processes
DE102007051850A1 (de) * 2007-10-30 2009-05-07 Ashland-Südchemie-Kernfest GmbH Formstoffmischung mit verbesserter Fliessfähigkeit
US8033320B2 (en) * 2008-07-25 2011-10-11 General Electric Company High emittance shell molds for directional casting
CN101372421A (zh) 2008-09-27 2009-02-25 辽宁省轻工科学研究院特铸材料有限公司 单晶浇铸用氧化钇陶瓷型芯材料及其成型制备方法
US20140182809A1 (en) 2012-12-28 2014-07-03 United Technologies Corporation Mullite-containing investment casting core
JP6098168B2 (ja) * 2013-01-09 2017-03-22 株式会社Ihi 鋳型及びその製造方法並びに鋳造品の鋳造方法
US20140238632A1 (en) 2013-02-28 2014-08-28 General Electric Company Methods for repairing ceramic cores
CA2885074A1 (en) * 2014-04-24 2015-10-24 Howmet Corporation Ceramic casting core made by additive manufacturing
US20160214165A1 (en) 2015-01-26 2016-07-28 General Electric Company Porous ceramic materials for investment casting

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