CA2915878A1 - Methods for mitigating the leaching of heavy metals from activated carbon - Google Patents
Methods for mitigating the leaching of heavy metals from activated carbon Download PDFInfo
- Publication number
- CA2915878A1 CA2915878A1 CA2915878A CA2915878A CA2915878A1 CA 2915878 A1 CA2915878 A1 CA 2915878A1 CA 2915878 A CA2915878 A CA 2915878A CA 2915878 A CA2915878 A CA 2915878A CA 2915878 A1 CA2915878 A1 CA 2915878A1
- Authority
- CA
- Canada
- Prior art keywords
- calcium
- halogen
- sorbent
- bromide
- flue gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 39
- 238000002386 leaching Methods 0.000 title claims abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 76
- 230000000116 mitigating effect Effects 0.000 title description 4
- 239000002594 sorbent Substances 0.000 claims abstract description 103
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 37
- 229910052736 halogen Inorganic materials 0.000 claims description 138
- 150000002367 halogens Chemical class 0.000 claims description 120
- 239000002243 precursor Substances 0.000 claims description 71
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 claims description 34
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 32
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 32
- 239000003546 flue gas Substances 0.000 claims description 32
- 229910001622 calcium bromide Inorganic materials 0.000 claims description 29
- 239000003463 adsorbent Substances 0.000 claims description 24
- 235000010323 ascorbic acid Nutrition 0.000 claims description 17
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 claims description 16
- 239000011668 ascorbic acid Substances 0.000 claims description 16
- 229960005070 ascorbic acid Drugs 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 claims description 15
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 12
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 12
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 10
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 claims description 10
- 229910021536 Zeolite Inorganic materials 0.000 claims description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
- 239000010457 zeolite Substances 0.000 claims description 9
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 8
- 239000001110 calcium chloride Substances 0.000 claims description 8
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 8
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 8
- RWSXRVCMGQZWBV-WDSKDSINSA-N glutathione Chemical class OC(=O)[C@@H](N)CCC(=O)N[C@@H](CS)C(=O)NCC(O)=O RWSXRVCMGQZWBV-WDSKDSINSA-N 0.000 claims description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 8
- 229940107700 pyruvic acid Drugs 0.000 claims description 8
- QAIPRVGONGVQAS-DUXPYHPUSA-N trans-caffeic acid Chemical compound OC(=O)\C=C\C1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-DUXPYHPUSA-N 0.000 claims description 8
- UNMYWSMUMWPJLR-UHFFFAOYSA-L Calcium iodide Chemical compound [Ca+2].[I-].[I-] UNMYWSMUMWPJLR-UHFFFAOYSA-L 0.000 claims description 6
- 229910001640 calcium iodide Inorganic materials 0.000 claims description 6
- 229940046413 calcium iodide Drugs 0.000 claims description 6
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 claims description 6
- 229910001623 magnesium bromide Inorganic materials 0.000 claims description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 6
- BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 claims description 6
- 229910001641 magnesium iodide Inorganic materials 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 claims description 5
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 claims description 5
- DKNPRRRKHAEUMW-UHFFFAOYSA-N Iodine aqueous Chemical compound [K+].I[I-]I DKNPRRRKHAEUMW-UHFFFAOYSA-N 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 235000019270 ammonium chloride Nutrition 0.000 claims description 5
- 229940107816 ammonium iodide Drugs 0.000 claims description 5
- 235000010376 calcium ascorbate Nutrition 0.000 claims description 5
- 239000011692 calcium ascorbate Substances 0.000 claims description 5
- BLORRZQTHNGFTI-ZZMNMWMASA-L calcium-L-ascorbate Chemical compound [Ca+2].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] BLORRZQTHNGFTI-ZZMNMWMASA-L 0.000 claims description 5
- XVDWMONETMNKBK-UHFFFAOYSA-N calcium;dihypobromite Chemical compound [Ca+2].Br[O-].Br[O-] XVDWMONETMNKBK-UHFFFAOYSA-N 0.000 claims description 5
- HDWFBMIXBOMTFB-UHFFFAOYSA-N calcium;dihypoiodite Chemical compound [Ca+2].I[O-].I[O-] HDWFBMIXBOMTFB-UHFFFAOYSA-N 0.000 claims description 5
- AIOKQVJVNPDJKA-ZZMNMWMASA-L magnesium;(2r)-2-[(1s)-1,2-dihydroxyethyl]-4-hydroxy-5-oxo-2h-furan-3-olate Chemical compound [Mg+2].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] AIOKQVJVNPDJKA-ZZMNMWMASA-L 0.000 claims description 5
- 235000019275 potassium ascorbate Nutrition 0.000 claims description 5
- 229940020414 potassium triiodide Drugs 0.000 claims description 5
- CONVKSGEGAVTMB-RXSVEWSESA-M potassium-L-ascorbate Chemical compound [K+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] CONVKSGEGAVTMB-RXSVEWSESA-M 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 239000000741 silica gel Substances 0.000 claims description 5
- 229910002027 silica gel Inorganic materials 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 235000010378 sodium ascorbate Nutrition 0.000 claims description 5
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 claims description 5
- 235000009518 sodium iodide Nutrition 0.000 claims description 5
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 claims description 5
- 235000019187 sodium-L-ascorbate Nutrition 0.000 claims description 5
- SMTFLSSUAHATMA-UHFFFAOYSA-K tripotassium;tribromide Chemical compound [K+].[K+].[K+].[Br-].[Br-].[Br-] SMTFLSSUAHATMA-UHFFFAOYSA-K 0.000 claims description 5
- AKROLTGTPNCGRL-UHFFFAOYSA-K tripotassium;trichloride Chemical compound [Cl-].[Cl-].[Cl-].[K+].[K+].[K+] AKROLTGTPNCGRL-UHFFFAOYSA-K 0.000 claims description 5
- ACEAELOMUCBPJP-UHFFFAOYSA-N (E)-3,4,5-trihydroxycinnamic acid Natural products OC(=O)C=CC1=CC(O)=C(O)C(O)=C1 ACEAELOMUCBPJP-UHFFFAOYSA-N 0.000 claims description 4
- KSEBMYQBYZTDHS-HWKANZROSA-M (E)-Ferulic acid Natural products COC1=CC(\C=C\C([O-])=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-M 0.000 claims description 4
- GJJVAFUKOBZPCB-ZGRPYONQSA-N (r)-3,4-dihydro-2-methyl-2-(4,8,12-trimethyl-3,7,11-tridecatrienyl)-2h-1-benzopyran-6-ol Chemical class OC1=CC=C2OC(CC/C=C(C)/CC/C=C(C)/CCC=C(C)C)(C)CCC2=C1 GJJVAFUKOBZPCB-ZGRPYONQSA-N 0.000 claims description 4
- CWVRJTMFETXNAD-FWCWNIRPSA-N 3-O-Caffeoylquinic acid Natural products O[C@H]1[C@@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-FWCWNIRPSA-N 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 4
- PZIRUHCJZBGLDY-UHFFFAOYSA-N Caffeoylquinic acid Natural products CC(CCC(=O)C(C)C1C(=O)CC2C3CC(O)C4CC(O)CCC4(C)C3CCC12C)C(=O)O PZIRUHCJZBGLDY-UHFFFAOYSA-N 0.000 claims description 4
- 108010024636 Glutathione Chemical class 0.000 claims description 4
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical class SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 claims description 4
- UBQYURCVBFRUQT-UHFFFAOYSA-N N-benzoyl-Ferrioxamine B Chemical compound CC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCN UBQYURCVBFRUQT-UHFFFAOYSA-N 0.000 claims description 4
- CWVRJTMFETXNAD-KLZCAUPSSA-N Neochlorogenin-saeure Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O CWVRJTMFETXNAD-KLZCAUPSSA-N 0.000 claims description 4
- 235000004883 caffeic acid Nutrition 0.000 claims description 4
- 229940074360 caffeic acid Drugs 0.000 claims description 4
- 150000001721 carbon Chemical class 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- 235000001368 chlorogenic acid Nutrition 0.000 claims description 4
- CWVRJTMFETXNAD-JUHZACGLSA-N chlorogenic acid Chemical compound O[C@@H]1[C@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-JUHZACGLSA-N 0.000 claims description 4
- 229940074393 chlorogenic acid Drugs 0.000 claims description 4
- FFQSDFBBSXGVKF-KHSQJDLVSA-N chlorogenic acid Natural products O[C@@H]1C[C@](O)(C[C@@H](CC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O FFQSDFBBSXGVKF-KHSQJDLVSA-N 0.000 claims description 4
- BMRSEYFENKXDIS-KLZCAUPSSA-N cis-3-O-p-coumaroylquinic acid Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)cc2)[C@@H]1O)C(=O)O BMRSEYFENKXDIS-KLZCAUPSSA-N 0.000 claims description 4
- QAIPRVGONGVQAS-UHFFFAOYSA-N cis-caffeic acid Natural products OC(=O)C=CC1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-UHFFFAOYSA-N 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Chemical class SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 claims description 4
- 235000018417 cysteine Nutrition 0.000 claims description 4
- 229960002433 cysteine Drugs 0.000 claims description 4
- 229960000958 deferoxamine Drugs 0.000 claims description 4
- KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 claims description 4
- 235000001785 ferulic acid Nutrition 0.000 claims description 4
- 229940114124 ferulic acid Drugs 0.000 claims description 4
- KSEBMYQBYZTDHS-UHFFFAOYSA-N ferulic acid Natural products COC1=CC(C=CC(O)=O)=CC=C1O KSEBMYQBYZTDHS-UHFFFAOYSA-N 0.000 claims description 4
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- 235000004515 gallic acid Nutrition 0.000 claims description 4
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- 229960003180 glutathione Drugs 0.000 claims description 4
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- 239000011732 tocopherol Substances 0.000 claims description 4
- 125000002640 tocopherol group Chemical class 0.000 claims description 4
- 235000019149 tocopherols Nutrition 0.000 claims description 4
- 229930003802 tocotrienol Natural products 0.000 claims description 4
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- QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 claims description 4
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
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- 239000000203 mixture Substances 0.000 abstract description 10
- 238000002485 combustion reaction Methods 0.000 description 58
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 47
- 229910052753 mercury Inorganic materials 0.000 description 47
- 238000002347 injection Methods 0.000 description 33
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- 239000000446 fuel Substances 0.000 description 32
- -1 for example Substances 0.000 description 30
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- 238000012360 testing method Methods 0.000 description 9
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- 241000196324 Embryophyta Species 0.000 description 8
- 229910052791 calcium Inorganic materials 0.000 description 8
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- 230000009467 reduction Effects 0.000 description 8
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 7
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- 150000001875 compounds Chemical class 0.000 description 7
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- 239000011777 magnesium Substances 0.000 description 7
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- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 5
- 239000003570 air Substances 0.000 description 5
- 239000012717 electrostatic precipitator Substances 0.000 description 5
- 239000010881 fly ash Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
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- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
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- 229910002651 NO3 Inorganic materials 0.000 description 3
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- 239000013626 chemical specie Substances 0.000 description 2
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- LCAPJKUZZYKOHT-UHFFFAOYSA-N Br.Br.Br.Br.C(O)(O)=O Chemical compound Br.Br.Br.Br.C(O)(O)=O LCAPJKUZZYKOHT-UHFFFAOYSA-N 0.000 description 1
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- 239000002803 fossil fuel Substances 0.000 description 1
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- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
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- QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 description 1
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
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- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
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- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
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- 159000000003 magnesium salts Chemical class 0.000 description 1
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- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AAJBNRZDTJPMTJ-UHFFFAOYSA-L magnesium;dinitrite Chemical compound [Mg+2].[O-]N=O.[O-]N=O AAJBNRZDTJPMTJ-UHFFFAOYSA-L 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002731 mercury compounds Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
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- RAFRTSDUWORDLA-UHFFFAOYSA-N phenyl 3-chloropropanoate Chemical compound ClCCC(=O)OC1=CC=CC=C1 RAFRTSDUWORDLA-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
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- 229910052700 potassium Inorganic materials 0.000 description 1
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- 238000012545 processing Methods 0.000 description 1
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- 238000011160 research Methods 0.000 description 1
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- 239000011669 selenium Substances 0.000 description 1
- 239000002678 semianthracite Substances 0.000 description 1
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- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- PLSARIKBYIPYPF-UHFFFAOYSA-H trimagnesium dicitrate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O PLSARIKBYIPYPF-UHFFFAOYSA-H 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
- B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/25—Coated, impregnated or composite adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/46—Materials comprising a mixture of inorganic and organic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Geochemistry & Mineralogy (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (5)
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| US201361836945P | 2013-06-19 | 2013-06-19 | |
| US61/836,945 | 2013-06-19 | ||
| US201361839962P | 2013-06-27 | 2013-06-27 | |
| US61/839,962 | 2013-06-27 | ||
| PCT/US2014/043158 WO2014205200A1 (en) | 2013-06-19 | 2014-06-19 | Methods for mitigating the leaching of heavy metals from activated carbon |
Publications (1)
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| CA2915878A1 true CA2915878A1 (en) | 2014-12-24 |
Family
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| CA2915878A Abandoned CA2915878A1 (en) | 2013-06-19 | 2014-06-19 | Methods for mitigating the leaching of heavy metals from activated carbon |
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| US (1) | US20140374655A1 (enExample) |
| EP (1) | EP3011064A4 (enExample) |
| JP (2) | JP6616928B2 (enExample) |
| KR (1) | KR20160021788A (enExample) |
| CN (1) | CN105378122A (enExample) |
| CA (1) | CA2915878A1 (enExample) |
| WO (1) | WO2014205200A1 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130330257A1 (en) | 2012-06-11 | 2013-12-12 | Calgon Carbon Corporation | Sorbents for removal of mercury |
| US11911727B2 (en) | 2012-06-15 | 2024-02-27 | Carbonxt, Inc. | Magnetic adsorbents, methods for manufacturing a magnetic adsorbent, and methods of removal of contaminants from fluid streams |
| DE102015211326A1 (de) * | 2015-06-19 | 2016-12-22 | Rwe Power Aktiengesellschaft | Verfahren zur Abscheidung von Quecksilber aus Rauchgasen von Verbrennungsanlagen |
| EA201991235A1 (ru) * | 2016-12-05 | 2020-01-16 | Юмикор | Удаление мышьяка из дымового газа |
| BR112019015829B1 (pt) | 2017-01-31 | 2024-01-23 | Calgon Carbon Corporation | Produto de folha de material sorvente, produto de folha de material sorvente laminado, recipiente adsorvente de vapor, tanque com adsorção integral de vapor e aparelho de recuperação de vapor de reabastecimento a bordo |
| CA3053282A1 (en) | 2017-02-10 | 2018-08-16 | Calgon Carbon Corporation | Sorbent and method of making |
| WO2019232391A1 (en) * | 2018-06-01 | 2019-12-05 | Carbonxt, Inc. | Magnetic adsorbents and methods of their use for removal of contaminants |
| US10874975B2 (en) * | 2018-07-11 | 2020-12-29 | S. A. Lhoist Recherche Et Developpement | Sorbent composition for an electrostatic precipitator |
| WO2020028703A2 (en) | 2018-08-01 | 2020-02-06 | Calgon Carbon Corporation | Apparatus for hydrocarbon vapor recovery |
| US11697090B2 (en) | 2018-08-02 | 2023-07-11 | Calgon Carbon Corporation | Sorbent devices |
| EP3829760A4 (en) | 2018-08-02 | 2022-04-06 | Calgon Carbon Corporation | SORPTION DEVICES |
| CN109289820B (zh) * | 2018-10-30 | 2021-03-19 | 山西新华防化装备研究院有限公司 | 吸附氰化物后活性炭的处理方法 |
| KR20210149108A (ko) | 2019-04-03 | 2021-12-08 | 칼곤 카본 코포레이션 | 퍼플루오로알킬 및 폴리플루오로알킬 수착 물질 및 사용 방법 |
| MX2022000840A (es) | 2019-07-22 | 2022-03-17 | Calgon Carbon Corp | Láminas sorbentes texturizadas, conjuntos que las contienen y moldes para su fabricación. |
| CA3150115A1 (en) | 2019-08-08 | 2021-02-11 | Calgon Carbon Corporation | Sorbent devices for air intakes |
| KR20230038260A (ko) | 2020-07-14 | 2023-03-17 | 칼곤 카본 코포레이션 | 유체로부터 pfas를 제거하기 위한 고 용적 요오드가 및 당밀가를 갖는 수착제 및 그 제조 및 사용 방법 |
| MX2023002240A (es) | 2020-08-31 | 2023-05-25 | Calgon Carbon Corp | Sorbente tratado con hierro y nitrogeno y metodo para hacer el mismo. |
| JP2023538505A (ja) | 2020-08-31 | 2023-09-08 | カルゴン カーボン コーポレーション | 銅および窒素処理された吸着剤およびその製造方法 |
| KR20230062593A (ko) | 2020-08-31 | 2023-05-09 | 칼곤 카본 코포레이션 | 구리, 철, 및 질소로 처리된 흡착제 및 이를 제조하는 방법 |
| KR102518202B1 (ko) * | 2021-02-08 | 2023-04-06 | 주식회사 에스알디글로벌 | 저농도의 반도체 폐가스 처리용 장치 |
| CN114229843A (zh) * | 2021-12-24 | 2022-03-25 | 贵州重力科技环保有限公司 | 一种废汞触媒无害化处理后的废活性炭活化再生处理方法 |
| CN114477698B (zh) * | 2022-02-11 | 2023-01-03 | 江南大学 | 一种氯化铁介导的蓝藻基生物炭在脱除烟气中零价汞中的应用 |
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| CA955035A (en) * | 1970-02-05 | 1974-09-24 | Osaka Soda Co. | Treatment process for removal of metals and treating agent therefor |
| US3833508A (en) * | 1971-04-27 | 1974-09-03 | Itt | Gas removal method and composition |
| JPS5360389A (en) * | 1976-11-11 | 1978-05-30 | Hiroshi Wake | Waste gas treatment |
| US4331639A (en) * | 1981-03-11 | 1982-05-25 | Union Oil Company Of California | Process for removing SOx and NOx compounds from gas streams |
| US5202301A (en) * | 1989-11-22 | 1993-04-13 | Calgon Carbon Corporation | Product/process/application for removal of mercury from liquid hydrocarbon |
| JPH03260170A (ja) * | 1990-01-31 | 1991-11-20 | Nippon Steel Corp | 空気清浄化繊維及び繊維製品 |
| US5322778A (en) * | 1991-10-31 | 1994-06-21 | Genencor International, Inc. | Liquefaction of granular starch slurries using an antioxidant with alpha amylase |
| US5348755A (en) * | 1992-03-04 | 1994-09-20 | Calgon Carbon Corporation | Extension of edible oil lifetime using activated carbons |
| US6186939B1 (en) * | 1993-10-07 | 2001-02-13 | Keith E. Forrester | Method for stabilizing heavy metal in a material or waste |
| JP3687014B2 (ja) * | 1996-03-13 | 2005-08-24 | 株式会社ケミカル山本 | 含クロム鉱滓の処理方法 |
| JPH1147589A (ja) * | 1997-08-07 | 1999-02-23 | Ebara Corp | 活性炭再生前処理方法 |
| WO2003085064A2 (en) * | 2002-04-04 | 2003-10-16 | Mt2, Llc | Treatment of surfaces to stabilize heavy metals |
| DE102005005818A1 (de) * | 2005-02-08 | 2006-08-17 | Grochowski, Horst, Dr. | Verfahren zum Reinigen von Abgasen eines Sinterprozesses von Erzen in der Metallerzeugung |
| CN102352274B (zh) * | 2005-03-17 | 2015-01-21 | Noxii国际有限公司 | 吸附剂组合物及使用其降低煤燃烧过程中的汞排放量的方法 |
| US8057576B1 (en) * | 2008-06-10 | 2011-11-15 | Calgon Carbon Corporation | Enhanced adsorbents and methods for mercury removal |
| US9121606B2 (en) * | 2008-02-19 | 2015-09-01 | Srivats Srinivasachar | Method of manufacturing carbon-rich product and co-products |
| JP5176839B2 (ja) * | 2008-09-30 | 2013-04-03 | 栗田工業株式会社 | 土壌またはスラグの処理方法 |
| PL2454007T3 (pl) * | 2009-07-13 | 2018-01-31 | Lhoist Rech Et Developpement Sa | Stała kompozycja mineralna, sposób jej wytwarzania i jej zastosowanie do redukcji dioksyn i metali ciężkich w gazach spalinowych |
| CA2755318C (en) * | 2009-09-28 | 2014-06-10 | Calgon Carbon Corporation | Sorbent formulation for removal of mercury from flue gas |
| RU2531303C2 (ru) * | 2010-04-07 | 2014-10-20 | Калгон Карбон Корпорейшн | Способы отделения ртути от топочного газа |
| US8496739B2 (en) * | 2010-08-30 | 2013-07-30 | Corning Incorporated | Organic antioxidant based filtration apparatus and method |
| JP5652293B2 (ja) * | 2011-03-29 | 2015-01-14 | 栗田工業株式会社 | 重金属含有固形物の処理方法 |
| EP3434353B1 (en) | 2012-11-26 | 2021-03-17 | Ecolab USA Inc. | Control of mercury emissions |
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2014
- 2014-06-19 US US14/308,926 patent/US20140374655A1/en not_active Abandoned
- 2014-06-19 JP JP2016521570A patent/JP6616928B2/ja not_active Expired - Fee Related
- 2014-06-19 EP EP14813604.7A patent/EP3011064A4/en not_active Withdrawn
- 2014-06-19 WO PCT/US2014/043158 patent/WO2014205200A1/en not_active Ceased
- 2014-06-19 KR KR1020157036027A patent/KR20160021788A/ko not_active Ceased
- 2014-06-19 CA CA2915878A patent/CA2915878A1/en not_active Abandoned
- 2014-06-19 CN CN201480034603.1A patent/CN105378122A/zh active Pending
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2019
- 2019-10-18 JP JP2019190769A patent/JP2020037107A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US20140374655A1 (en) | 2014-12-25 |
| JP2016523701A (ja) | 2016-08-12 |
| KR20160021788A (ko) | 2016-02-26 |
| WO2014205200A1 (en) | 2014-12-24 |
| EP3011064A4 (en) | 2017-03-01 |
| CN105378122A (zh) | 2016-03-02 |
| JP6616928B2 (ja) | 2019-12-04 |
| EP3011064A1 (en) | 2016-04-27 |
| JP2020037107A (ja) | 2020-03-12 |
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Legal Events
| Date | Code | Title | Description |
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| EEER | Examination request |
Effective date: 20190618 |
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| FZDE | Discontinued |
Effective date: 20220301 |