CA2889342C - Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree - Google Patents
Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree Download PDFInfo
- Publication number
- CA2889342C CA2889342C CA2889342A CA2889342A CA2889342C CA 2889342 C CA2889342 C CA 2889342C CA 2889342 A CA2889342 A CA 2889342A CA 2889342 A CA2889342 A CA 2889342A CA 2889342 C CA2889342 C CA 2889342C
- Authority
- CA
- Canada
- Prior art keywords
- manganese
- ions
- electrolytic cell
- solution
- iii
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/043—Carbon, e.g. diamond or graphene
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/22—Roughening, e.g. by etching
- C23C18/24—Roughening, e.g. by etching using acid aqueous solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/21—Manganese oxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Chemically Coating (AREA)
- Electroplating Methods And Accessories (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
L'invention concerne une cellule électrolytique et un procédé d'oxydation électrochimique d'ions de manganèse (II) vers des ions de manganèse (III) dans la cellule électrolytique. La cellule électrolytique comprend (1) une solution d'électrolyte d'ions de manganèse (II) dans une solution de 9 à 15 moles par litre d'acide sulfurique ; (2) une cathode immergée dans la solution d'électrolyte ; et (3) une anode immergée dans la solution d'électrolyte et espacée de la cathode. Divers matériaux d'anode sont décrits y compris le carbone vitreux, le carbone vitreux réticulé, et les fibres de carbone tissées.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA3056665A CA3056665A1 (fr) | 2012-11-15 | 2013-09-26 | Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/677,798 US9752241B2 (en) | 2012-01-23 | 2012-11-15 | Electrolytic generation of manganese (III) ions in strong sulfuric acid using an improved anode |
US13/677,798 | 2012-11-15 | ||
PCT/US2013/061860 WO2014077957A1 (fr) | 2012-11-15 | 2013-09-26 | Génération électrolytique d'ions de manganèse (iii) dans l'acide sulfurique fort à l'aide d'une anode améliorée |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA3056665A Division CA3056665A1 (fr) | 2012-11-15 | 2013-09-26 | Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2889342A1 CA2889342A1 (fr) | 2014-05-22 |
CA2889342C true CA2889342C (fr) | 2019-11-12 |
Family
ID=50731593
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA3056665A Abandoned CA3056665A1 (fr) | 2012-11-15 | 2013-09-26 | Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree |
CA2889342A Active CA2889342C (fr) | 2012-11-15 | 2013-09-26 | Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA3056665A Abandoned CA3056665A1 (fr) | 2012-11-15 | 2013-09-26 | Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP2920341B1 (fr) |
JP (1) | JP6060270B2 (fr) |
KR (2) | KR101950169B1 (fr) |
CN (1) | CN104838044B (fr) |
BR (1) | BR112015011123B1 (fr) |
CA (2) | CA3056665A1 (fr) |
ES (1) | ES2704672T3 (fr) |
MX (1) | MX2015006178A (fr) |
PL (1) | PL2920341T3 (fr) |
TR (1) | TR201900116T4 (fr) |
TW (1) | TWI500582B (fr) |
WO (1) | WO2014077957A1 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL2971260T3 (pl) * | 2013-03-12 | 2020-03-31 | Macdermid Acumen, Inc. | Elektrolityczne wytwarzanie jonów manganu (iii) w mocnym kwasie siarkowym |
EP3168326B2 (fr) | 2014-07-10 | 2023-09-20 | Okuno Chemical Industries Co., Ltd. | Procédé de placage de résine |
CN107078291A (zh) * | 2014-08-28 | 2017-08-18 | 英克罗恩有限公司 | 结晶过渡氧化物颗粒及制备该结晶过渡氧化物颗粒的连续方法 |
US10889905B2 (en) * | 2018-12-11 | 2021-01-12 | Rohm And Haas Electronic Materials Llc | Methods of generating manganese (III) ions in mixed aqueous acid solutions using ozone |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3065155A (en) * | 1960-09-02 | 1962-11-20 | Manganese Chemicals Corp | Electrolytic manganese dioxide process |
AT310285B (de) | 1966-02-22 | 1973-09-25 | Photocircuits Corp | Verfahren zur Herstellung eines Schichtkörpers für gedruckte Schaltungen |
US4042729A (en) | 1972-12-13 | 1977-08-16 | Kollmorgen Technologies Corporation | Process for the activation of resinous bodies for adherent metallization |
IT1159931B (it) * | 1978-10-13 | 1987-03-04 | Oronzio De Nora Impianti | Procedimento industriale per la produzione di biossido di titanio da ilmenite |
US4279705A (en) * | 1980-02-19 | 1981-07-21 | Kerr-Mcgee Corporation | Process for oxidizing a metal of variable valence by constant current electrolysis |
IT1132194B (it) * | 1980-07-15 | 1986-06-25 | Anic Spa | Processo elettrochimico per la sintesi di composti organici |
JPS58502027A (ja) * | 1981-11-23 | 1983-11-24 | バロ−ス・コ−ポレ−ション | 低デ−タ転送率の直列入出力インタ−フェイスをモニタするようにされた周辺装置 |
US4610895A (en) | 1984-02-01 | 1986-09-09 | Shipley Company Inc. | Process for metallizing plastics |
US4948630A (en) | 1984-06-07 | 1990-08-14 | Enthone, Inc. | Three step process for treating plastics with alkaline permanganate solutions |
JPS6447890A (en) * | 1987-08-13 | 1989-02-22 | Kenzo Yamaguchi | Electrolytic synthesis method |
US5213665A (en) * | 1988-02-29 | 1993-05-25 | Nippon Shokubai Kagaku Kogyo, Co., Ltd. | Process for producing 1-aminoanthraquinones |
US4936970A (en) * | 1988-11-14 | 1990-06-26 | Ebonex Technologies, Inc. | Redox reactions in an electrochemical cell including an electrode comprising Magneli phase titanium oxide |
US5160600A (en) * | 1990-03-05 | 1992-11-03 | Patel Gordhanbai N | Chromic acid free etching of polymers for electroless plating |
US5648125A (en) | 1995-11-16 | 1997-07-15 | Cane; Frank N. | Electroless plating process for the manufacture of printed circuit boards |
GB9714275D0 (en) * | 1997-07-08 | 1997-09-10 | Ciba Geigy Ag | Oxidation process |
US6780650B2 (en) | 2000-10-16 | 2004-08-24 | Ortho-Mcneil Pharmaceutical, Inc. | Ligand binding assays for vanilloid receptors |
CA2408951C (fr) * | 2002-10-18 | 2008-12-16 | Kvaerner Canada Inc. | Electrolyse assistee d'acides halogenes |
US8394289B2 (en) | 2006-04-18 | 2013-03-12 | Okuno Chemicals Industries Co., Ltd. | Composition for etching treatment of resin molded article |
US8734992B2 (en) * | 2007-02-14 | 2014-05-27 | Tosoh Corporation | Electrolytic manganese dioxide, and method for its production and its application |
PL2025708T3 (pl) * | 2007-08-10 | 2010-03-31 | Enthone | Roztwór trawiący do powierzchni tworzyw sztucznych nie zawierający chromu |
JP2010121143A (ja) * | 2008-11-17 | 2010-06-03 | Okuno Chem Ind Co Ltd | 樹脂成形体に対するエッチングの後処理剤、該後処理剤を用いる後処理方法、及び樹脂成形体に対するめっき方法 |
JP5738898B2 (ja) * | 2010-01-29 | 2015-06-24 | エバレデイ バツテリ カンパニー インコーポレーテツド | 二酸化マンガンを含む触媒電極を有する電気化学電池を製造する方法 |
US10260000B2 (en) * | 2012-01-23 | 2019-04-16 | Macdermid Acumen, Inc. | Etching of plastic using acidic solutions containing trivalent manganese |
-
2013
- 2013-09-26 MX MX2015006178A patent/MX2015006178A/es unknown
- 2013-09-26 TR TR2019/00116T patent/TR201900116T4/tr unknown
- 2013-09-26 WO PCT/US2013/061860 patent/WO2014077957A1/fr active Application Filing
- 2013-09-26 KR KR1020157015762A patent/KR101950169B1/ko active IP Right Grant
- 2013-09-26 CA CA3056665A patent/CA3056665A1/fr not_active Abandoned
- 2013-09-26 KR KR1020177008782A patent/KR20170039315A/ko not_active Application Discontinuation
- 2013-09-26 CN CN201380059513.3A patent/CN104838044B/zh active Active
- 2013-09-26 BR BR112015011123-8A patent/BR112015011123B1/pt active IP Right Grant
- 2013-09-26 PL PL13854930T patent/PL2920341T3/pl unknown
- 2013-09-26 CA CA2889342A patent/CA2889342C/fr active Active
- 2013-09-26 EP EP13854930.8A patent/EP2920341B1/fr active Active
- 2013-09-26 JP JP2015543041A patent/JP6060270B2/ja active Active
- 2013-09-26 ES ES13854930T patent/ES2704672T3/es active Active
- 2013-11-11 TW TW102140858A patent/TWI500582B/zh active
Also Published As
Publication number | Publication date |
---|---|
KR20170039315A (ko) | 2017-04-10 |
EP2920341B1 (fr) | 2018-11-14 |
KR20150082636A (ko) | 2015-07-15 |
WO2014077957A1 (fr) | 2014-05-22 |
ES2704672T3 (es) | 2019-03-19 |
TWI500582B (zh) | 2015-09-21 |
JP2016504492A (ja) | 2016-02-12 |
KR101950169B1 (ko) | 2019-02-20 |
CA2889342A1 (fr) | 2014-05-22 |
EP2920341A1 (fr) | 2015-09-23 |
BR112015011123A2 (pt) | 2017-07-11 |
EP2920341A4 (fr) | 2016-04-27 |
MX2015006178A (es) | 2015-11-06 |
JP6060270B2 (ja) | 2017-01-11 |
CN104838044B (zh) | 2017-12-05 |
TW201431793A (zh) | 2014-08-16 |
BR112015011123B1 (pt) | 2021-08-03 |
PL2920341T3 (pl) | 2019-05-31 |
TR201900116T4 (tr) | 2019-01-21 |
CN104838044A (zh) | 2015-08-12 |
CA3056665A1 (fr) | 2014-05-22 |
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US10221357B2 (en) | Etching of plastic using acidic solutions containing trivalent manganese | |
US10895016B2 (en) | Electrolytic generation of manganese (III) ions in strong sulfuric acid | |
CA2955467C (fr) | Methode de gravure d'une piece en plastique | |
CA2889342C (fr) | Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree | |
US10246788B2 (en) | Electrolytic generation of manganese (III) ions in strong sulfuric acid using an improved anode |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request |
Effective date: 20150423 |