CA2870314C - Purification of bio-based acrylic acid to crude and glacial acrylic acid - Google Patents
Purification of bio-based acrylic acid to crude and glacial acrylic acid Download PDFInfo
- Publication number
- CA2870314C CA2870314C CA2870314A CA2870314A CA2870314C CA 2870314 C CA2870314 C CA 2870314C CA 2870314 A CA2870314 A CA 2870314A CA 2870314 A CA2870314 A CA 2870314A CA 2870314 C CA2870314 C CA 2870314C
- Authority
- CA
- Canada
- Prior art keywords
- acrylic acid
- composition
- acid
- mixtures
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
- B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
- C07C51/46—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation by azeotropic distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261623054P | 2012-04-11 | 2012-04-11 | |
| US61/623,054 | 2012-04-11 | ||
| US13/760,505 US20130274518A1 (en) | 2012-04-11 | 2013-02-06 | Purification Of Bio Based Acrylic Acid To Crude And Glacial Acrylic Acid |
| US13/760,505 | 2013-02-06 | ||
| US13/838,823 | 2013-03-15 | ||
| US13/838,823 US20130274520A1 (en) | 2012-04-11 | 2013-03-15 | Purification Of Bio Based Acrylic Acid To Crude And Glacial Acrylic Acid |
| US13/835,187 US9926256B2 (en) | 2012-04-11 | 2013-03-15 | Catalytic conversion of lactic acid to acrylic acid |
| US13/835,187 | 2013-03-15 | ||
| PCT/US2013/036158 WO2013155292A2 (en) | 2012-04-11 | 2013-04-11 | Purification of bio-based acrylic acid to crude and glacial acrylic acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2870314A1 CA2870314A1 (en) | 2013-10-17 |
| CA2870314C true CA2870314C (en) | 2018-01-02 |
Family
ID=49325676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2870314A Active CA2870314C (en) | 2012-04-11 | 2013-04-11 | Purification of bio-based acrylic acid to crude and glacial acrylic acid |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US20130274520A1 (enExample) |
| EP (1) | EP2836475B1 (enExample) |
| JP (2) | JP2015517999A (enExample) |
| AU (1) | AU2013245853B2 (enExample) |
| BR (1) | BR112014025188B1 (enExample) |
| CA (1) | CA2870314C (enExample) |
| IN (1) | IN2014DN08551A (enExample) |
| MX (1) | MX380544B (enExample) |
| MY (1) | MY164790A (enExample) |
| RU (1) | RU2599640C2 (enExample) |
| SG (2) | SG10201703949YA (enExample) |
| WO (1) | WO2013155292A2 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6329257B2 (ja) * | 2013-10-16 | 2018-05-23 | ザ プロクター アンド ギャンブル カンパニー | バイオベースのアクリル酸及びその誘導体を生成するための触媒並びにその製造方法 |
| WO2016026761A1 (en) * | 2014-08-18 | 2016-02-25 | Basf Se | Process for preparing acrylic acid by dehydration of 3-hydroxypropionic acid |
| EP3012244A1 (en) | 2014-10-24 | 2016-04-27 | Sulzer Chemtech AG | Process and apparatus for purification of acrylic acid |
| EP3341121A1 (en) | 2015-08-28 | 2018-07-04 | The Procter and Gamble Company | Catalysts for the dehydration of hydroxypropionic acid and its derivatives |
| MY182384A (en) * | 2015-08-28 | 2021-01-22 | Procter & Gamble | Catalytic dehydration of hydroxypropionic acid and its derivatives |
| DE102016114555A1 (de) | 2016-08-05 | 2018-02-08 | Thyssenkrupp Ag | Prozess zur Herstellung von Acrylsäure aus einer wässrigen 3-Hydroxypropanol-Lösung |
| US9890102B1 (en) | 2016-11-03 | 2018-02-13 | The Procter & Gamble Company | Method of making acrylic acid from hydroxypropionic acid |
| US20230382842A1 (en) * | 2020-10-16 | 2023-11-30 | Lg Chem, Ltd. | Method For Vaporizing Lactic Acid, Apparatus For Vaporizing Lactic Acid, And Method For Preparing Acrylic Acid From Lactic Acid |
| KR102721330B1 (ko) * | 2020-12-03 | 2024-10-23 | 주식회사 엘지화학 | 아크릴산 제조방법 |
| FR3125064B1 (fr) | 2021-07-09 | 2024-07-12 | Snf Sa | Procédé biologique d’obtention de monomères comprenant une insaturation éthylénique par bioconversion d’un composé biosourcé comprenant au moins une fonction nitrile |
| CN122228279A (zh) | 2023-11-22 | 2026-06-16 | 株式会社日本触媒 | 源自生物原料的吸水性树脂的制造方法和所得到的吸水性树脂 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3885155A (en) | 1973-11-01 | 1975-05-20 | Stanford Research Inst | Mass spectrometric determination of carbon 14 |
| US4070178A (en) * | 1975-09-03 | 1978-01-24 | Rohm And Haas Company | Herbicidal diphenyl ethers |
| US4427884A (en) | 1982-01-25 | 1984-01-24 | The Research Foundation Of State University Of New York | Method for detecting and quantifying carbon isotopes |
| US4973841A (en) | 1990-02-02 | 1990-11-27 | Genus, Inc. | Precision ultra-sensitive trace detector for carbon-14 when it is at concentration close to that present in recent organic materials |
| US5438194A (en) | 1993-07-30 | 1995-08-01 | High Voltage Engineering Europa B.V. | Ultra-sensitive molecular identifier |
| FR2736912B1 (fr) | 1995-07-18 | 1997-08-22 | Atochem Elf Sa | Procede de purification de l'acide acrylique obtenu par oxydation catalytique du propylene |
| DE19600955A1 (de) * | 1996-01-12 | 1997-07-17 | Basf Ag | Verfahren zur Herstellung von Acrylsäure und deren Ester |
| US5661299A (en) | 1996-06-25 | 1997-08-26 | High Voltage Engineering Europa B.V. | Miniature AMS detector for ultrasensitive detection of individual carbon-14 and tritium atoms |
| DE19829477A1 (de) | 1998-07-01 | 2000-01-05 | Basf Ag | Verfahren zur Reinigung von Acrylsäure oder Methacrylsäure durch Kristallisation und Destillation |
| DE19832962A1 (de) * | 1998-07-22 | 2000-01-27 | Basf Ag | Reinigung von Acrylsäure durch Kristallisation mittels Vakuumverdampfung |
| WO2001077056A1 (de) * | 2000-04-11 | 2001-10-18 | Basf Aktiengesellschaft | Verfahren zur reinigung einer rohacrylsäureschmelze |
| BR0206396A (pt) * | 2001-01-12 | 2004-02-10 | Degussa | Processo contìnuo para preparação e purificação de ácido (met)acrìlico |
| DE10138150A1 (de) | 2001-08-03 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung wasserabsorbierender Harze |
| US20030146081A1 (en) * | 2002-01-08 | 2003-08-07 | Salvador Aldrett | Acrylic acid recovery utilizing ethyl acrylate and selected co-solvents |
| EP1732874A1 (en) * | 2004-04-02 | 2006-12-20 | Ciba Speciality Chemicals Water Treatments Limited | Preparation of acrylic acid derivatives from alpha or beta-hydroxy carboxylic acids |
| FR2897058B1 (fr) * | 2006-02-07 | 2008-04-18 | Arkema Sa | Procede de preparation d'acroleine |
| DE102006039203B4 (de) * | 2006-08-22 | 2014-06-18 | Evonik Degussa Gmbh | Verfahren zur Herstellung von durch Kristallisation gereinigter Acrylsäure aus Hydroxypropionsäure sowie Vorrichtung dazu |
| CN101589015B (zh) * | 2007-01-26 | 2013-11-13 | 巴斯夫欧洲公司 | 生产丙烯酸的方法 |
| WO2008090190A1 (de) * | 2007-01-26 | 2008-07-31 | Basf Se | Verfahren zur herstellung von acrylsäure |
| JP4822559B2 (ja) * | 2007-09-19 | 2011-11-24 | ローム アンド ハース カンパニー | （メタ）アクリル酸生成物流からのプロピオン酸の選択的減少のための改良された方法 |
| WO2009155086A2 (en) | 2008-05-30 | 2009-12-23 | E. I. Du Pont De Nemours And Company | Renewably resourced chemicals and intermediates |
| JP2010163383A (ja) * | 2009-01-14 | 2010-07-29 | Toagosei Co Ltd | アクリル酸の精製方法 |
| JP2010180171A (ja) * | 2009-02-06 | 2010-08-19 | Nippon Shokubai Co Ltd | アクリル酸の製造方法 |
| US8586787B2 (en) * | 2009-05-15 | 2013-11-19 | Nippon Shokubai Co., Ltd. | Process for producing (meth)acrylic acid |
| FR2948365B1 (fr) * | 2009-07-22 | 2011-09-09 | Arkema France | Procede de fabrication d'acide acrylique bio-ressource a partir de glycerol |
| CN102596883B (zh) * | 2009-10-29 | 2015-03-25 | 三仪股份有限公司 | 不饱和羧酸和/或其衍生物的合成方法 |
| JP2011225533A (ja) * | 2010-03-31 | 2011-11-10 | Nippon Shokubai Co Ltd | アクリル酸およびその重合体の製造方法 |
| EP2614152A4 (en) * | 2010-09-07 | 2015-04-15 | Myriant Corp | CATALYTIC DEHYDRATION OF MILKY ACID AND MILKIC ACID ESTERS |
| WO2012091114A1 (ja) * | 2010-12-28 | 2012-07-05 | 株式会社日本触媒 | アクリル酸および／またはそのエステルおよびその重合体の製法 |
| US9714208B2 (en) * | 2012-04-11 | 2017-07-25 | The Procter & Gamble Company | Catalysts conversion of hydroxypropionic acid or its derivatives to acrylic acid or its derivatives |
-
2013
- 2013-03-15 US US13/838,823 patent/US20130274520A1/en not_active Abandoned
- 2013-04-11 RU RU2014139950/04A patent/RU2599640C2/ru active
- 2013-04-11 MX MX2014012303A patent/MX380544B/es unknown
- 2013-04-11 SG SG10201703949YA patent/SG10201703949YA/en unknown
- 2013-04-11 SG SG11201406509YA patent/SG11201406509YA/en unknown
- 2013-04-11 IN IN8551DEN2014 patent/IN2014DN08551A/en unknown
- 2013-04-11 AU AU2013245853A patent/AU2013245853B2/en active Active
- 2013-04-11 MY MYPI2014002826A patent/MY164790A/en unknown
- 2013-04-11 CA CA2870314A patent/CA2870314C/en active Active
- 2013-04-11 EP EP13721435.9A patent/EP2836475B1/en active Active
- 2013-04-11 WO PCT/US2013/036158 patent/WO2013155292A2/en not_active Ceased
- 2013-04-11 BR BR112014025188A patent/BR112014025188B1/pt not_active IP Right Cessation
- 2013-04-11 JP JP2015505902A patent/JP2015517999A/ja active Pending
-
2015
- 2015-07-29 US US14/812,113 patent/US20150329462A1/en not_active Abandoned
-
2017
- 2017-01-06 JP JP2017001292A patent/JP2017101046A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CA2870314A1 (en) | 2013-10-17 |
| IN2014DN08551A (enExample) | 2015-05-15 |
| SG11201406509YA (en) | 2014-11-27 |
| EP2836475B1 (en) | 2021-05-26 |
| WO2013155292A3 (en) | 2013-12-05 |
| CN104220410A (zh) | 2014-12-17 |
| EP2836475A2 (en) | 2015-02-18 |
| WO2013155292A4 (en) | 2014-01-23 |
| MY164790A (en) | 2018-01-30 |
| MX2014012303A (es) | 2014-11-10 |
| WO2013155292A2 (en) | 2013-10-17 |
| RU2599640C2 (ru) | 2016-10-10 |
| US20130274520A1 (en) | 2013-10-17 |
| MX380544B (es) | 2025-03-12 |
| US20150329462A1 (en) | 2015-11-19 |
| AU2013245853A1 (en) | 2014-10-30 |
| SG10201703949YA (en) | 2017-06-29 |
| RU2014139950A (ru) | 2016-04-20 |
| AU2013245853B2 (en) | 2016-06-02 |
| JP2015517999A (ja) | 2015-06-25 |
| BR112014025188B1 (pt) | 2020-02-04 |
| JP2017101046A (ja) | 2017-06-08 |
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| US20180127348A1 (en) | Purification Of Bio Based Acrylic Acid To Crude And Glacial Acrylic Acid | |
| AU2013245853B2 (en) | Purification of bio-based acrylic acid to crude and glacial acrylic acid | |
| US10344108B2 (en) | Poly(acrylic acid) from bio-based acrylic acid and its derivatives | |
| AU2013245852B2 (en) | Process for production of acrylic acid or its derivatives | |
| CA2994446C (en) | Catalysts for the dehydration of hydroxypropionic acid and its derivatives | |
| AU2017221889B2 (en) | Catalyst for producing bio-based acrylic acid and its derivatives and the method for making thereof | |
| CA2994448A1 (en) | Catalytic dehydration of hydroxypropionic acid and its derivatives | |
| CN104220410B (zh) | 生物基丙烯酸至粗制丙烯酸和冰丙烯酸的纯化 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20141010 |
|
| MPN | Maintenance fee for patent paid |
Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 12TH ANNIV.) - STANDARD Year of fee payment: 12 |
|
| U00 | Fee paid |
Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED Effective date: 20241224 |
|
| U11 | Full renewal or maintenance fee paid |
Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT DETERMINED COMPLIANT Effective date: 20241224 Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL Effective date: 20241224 |
|
| W00 | Other event occurred |
Free format text: ST27 STATUS EVENT CODE: A-4-4-W10-W00-W100 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: LETTER SENT Effective date: 20260525 |