CA2865989C - Anode et procede d'utilisation de cellule electrolytique - Google Patents
Anode et procede d'utilisation de cellule electrolytique Download PDFInfo
- Publication number
- CA2865989C CA2865989C CA2865989A CA2865989A CA2865989C CA 2865989 C CA2865989 C CA 2865989C CA 2865989 A CA2865989 A CA 2865989A CA 2865989 A CA2865989 A CA 2865989A CA 2865989 C CA2865989 C CA 2865989C
- Authority
- CA
- Canada
- Prior art keywords
- anode
- cell
- electrolyte
- attached
- conductive element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 14
- 210000004027 cell Anatomy 0.000 claims abstract description 68
- 239000003792 electrolyte Substances 0.000 claims abstract description 39
- 238000005363 electrowinning Methods 0.000 claims abstract description 30
- 238000000576 coating method Methods 0.000 claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims abstract description 18
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 230000008569 process Effects 0.000 claims abstract description 15
- 210000002421 cell wall Anatomy 0.000 claims abstract description 12
- 230000035515 penetration Effects 0.000 claims abstract description 7
- 238000004873 anchoring Methods 0.000 claims description 22
- 239000010949 copper Substances 0.000 claims description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- 229910052802 copper Inorganic materials 0.000 claims description 11
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000008151 electrolyte solution Substances 0.000 claims description 3
- 229910052745 lead Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 abstract description 4
- 239000011133 lead Substances 0.000 description 15
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000003319 supportive effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/04—Diaphragms; Spacing elements
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
- C25D17/12—Shape or form
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/38—Electroplating: Baths therefor from solutions of copper
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
La présente invention concerne une anode (1) pour procédé d'extraction électrolytique dans une cellule électrolytique (4) ayant des parois de cellule (2) et un fond de cellule (3) destinés à contenir un électrolyte et des moyens de distribution d'électrolyte (6). L'anode comprend une barre de suspension (7) pour supporter l'anode, une tige conductrice (8) pour distribuer le courant à l'anode, un corps d'anode (9) ayant une structure au moins partiellement conductrice, ce corps d'anode permettant la pénétration dans l'électrolyte et étant au moins partiellement recouvert d'un revêtement électrocatalytique. Lorsque l'anode (1) est fixée dans la cellule électrolytique, elle l'est grâce à un élément non conducteur (10, 12, 14) limité à la structure conductrice du corps d'anode (9) au moins à partir de l'un de ses côtés, et disposé à une distance A du niveau de surface de l'électrolyte (11), lorsque l'élément non conducteur fournit un moyen permettant de fixer l'anode à la cellule (4). L'invention concerne également un procédé d'utilisation d'une cellule électrolytique destinée à être utilisée dans l'extraction électrolytique de métaux. (Fig. 1)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20120075 | 2012-03-09 | ||
FI20120075A FI125808B (en) | 2012-03-09 | 2012-03-09 | Anode and method for operating an electrolytic cell |
PCT/FI2013/050242 WO2013132157A1 (fr) | 2012-03-09 | 2013-03-06 | Anode et procédé d'utilisation de cellule électrolytique |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2865989A1 CA2865989A1 (fr) | 2013-09-12 |
CA2865989C true CA2865989C (fr) | 2016-12-13 |
Family
ID=49115992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2865989A Active CA2865989C (fr) | 2012-03-09 | 2013-03-06 | Anode et procede d'utilisation de cellule electrolytique |
Country Status (10)
Country | Link |
---|---|
US (1) | US20150034491A1 (fr) |
JP (1) | JP5898346B2 (fr) |
CN (1) | CN104204307B (fr) |
CA (1) | CA2865989C (fr) |
CL (1) | CL2014002375A1 (fr) |
ES (1) | ES2524193B1 (fr) |
FI (1) | FI125808B (fr) |
MX (1) | MX355084B (fr) |
PE (1) | PE20142392A1 (fr) |
WO (1) | WO2013132157A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI125515B (en) * | 2013-03-01 | 2015-11-13 | Outotec Oyj | A method of measuring and arranging an electric current flowing at a single electrode of an electrolysis system |
CN105063728A (zh) * | 2015-08-18 | 2015-11-18 | 江苏金曼科技有限责任公司 | 一种防腐蚀铂钛网 |
GB201603224D0 (en) | 2016-02-24 | 2016-04-06 | Barker Michael H And Grant Duncan A | Equipment for a metal electrowinning or liberator process and way of operating the process |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA971505A (en) * | 1970-09-04 | 1975-07-22 | International Nickel Company Of Canada | Electrowinning metal utilizing higher current densities on upper surfaces |
US3979275A (en) * | 1974-02-25 | 1976-09-07 | Kennecott Copper Corporation | Apparatus for series electrowinning and electrorefining of metal |
US4207153A (en) * | 1979-02-16 | 1980-06-10 | Kennecott Copper Corporation | Electrorefining cell with bipolar electrode and electrorefining method |
DE2912524C2 (de) * | 1979-03-29 | 1985-08-29 | Hüttenwerke Kayser AG, 4670 Lünen | Arbeitsverfahren und Vorrichtung zum elektrolytischen Abscheiden von Metallen, insbesondere Kupfer |
US4282082A (en) * | 1980-01-29 | 1981-08-04 | Envirotech Corporation | Slurry electrowinning apparatus |
US5282934A (en) * | 1992-02-14 | 1994-02-01 | Academy Corporation | Metal recovery by batch electroplating with directed circulation |
US5783050A (en) * | 1995-05-04 | 1998-07-21 | Eltech Systems Corporation | Electrode for electrochemical cell |
US7378011B2 (en) * | 2003-07-28 | 2008-05-27 | Phelps Dodge Corporation | Method and apparatus for electrowinning copper using the ferrous/ferric anode reaction |
US20060021880A1 (en) * | 2004-06-22 | 2006-02-02 | Sandoval Scot P | Method and apparatus for electrowinning copper using the ferrous/ferric anode reaction and a flow-through anode |
JP4389846B2 (ja) * | 2005-06-22 | 2009-12-24 | 三菱マテリアル株式会社 | 縁部絶縁部材 |
JP5168907B2 (ja) * | 2007-01-15 | 2013-03-27 | 東京エレクトロン株式会社 | プラズマ処理装置、プラズマ処理方法及び記憶媒体 |
JP2009161810A (ja) * | 2008-01-07 | 2009-07-23 | Sumitomo Metal Mining Co Ltd | 脱銅板の積載設備 |
US8022004B2 (en) * | 2008-05-24 | 2011-09-20 | Freeport-Mcmoran Corporation | Multi-coated electrode and method of making |
US20100065433A1 (en) * | 2008-09-12 | 2010-03-18 | Victor Vidaurre Heiremans | System and apparatus for enhancing convection in electrolytes to achieve improved electrodeposition of copper and other non ferrous metals in industrial electrolytic cells |
EP2370078A1 (fr) * | 2008-12-01 | 2011-10-05 | Novartis AG | Méthode d optimisation du traitement de la leucémie philadelphie positive avec du mésylate d imatinib |
WO2012051446A2 (fr) * | 2010-10-14 | 2012-04-19 | Freeport-Mcmoran Corporation | Procédé amélioré d'extraction par voie électrolytique |
-
2012
- 2012-03-09 FI FI20120075A patent/FI125808B/en not_active IP Right Cessation
-
2013
- 2013-03-06 CN CN201380013068.7A patent/CN104204307B/zh active Active
- 2013-03-06 US US14/382,709 patent/US20150034491A1/en not_active Abandoned
- 2013-03-06 JP JP2014560418A patent/JP5898346B2/ja active Active
- 2013-03-06 WO PCT/FI2013/050242 patent/WO2013132157A1/fr active Application Filing
- 2013-03-06 CA CA2865989A patent/CA2865989C/fr active Active
- 2013-03-06 MX MX2014010731A patent/MX355084B/es active IP Right Grant
- 2013-03-06 ES ES201450004A patent/ES2524193B1/es active Active
- 2013-03-06 PE PE2014001366A patent/PE20142392A1/es active IP Right Grant
-
2014
- 2014-09-08 CL CL2014002375A patent/CL2014002375A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
CA2865989A1 (fr) | 2013-09-12 |
JP5898346B2 (ja) | 2016-04-06 |
FI125808B (en) | 2016-02-29 |
CN104204307A (zh) | 2014-12-10 |
CN104204307B (zh) | 2017-06-09 |
ES2524193B1 (es) | 2015-09-02 |
ES2524193R1 (es) | 2014-12-29 |
US20150034491A1 (en) | 2015-02-05 |
PE20142392A1 (es) | 2015-02-02 |
ES2524193A2 (es) | 2014-12-04 |
MX2014010731A (es) | 2015-04-10 |
JP2015509558A (ja) | 2015-03-30 |
CL2014002375A1 (es) | 2015-01-16 |
WO2013132157A1 (fr) | 2013-09-12 |
MX355084B (es) | 2018-04-04 |
FI20120075A (fi) | 2013-09-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request |
Effective date: 20140829 |