CA2823431C - Distributed combustion process and burner - Google Patents
Distributed combustion process and burner Download PDFInfo
- Publication number
- CA2823431C CA2823431C CA2823431A CA2823431A CA2823431C CA 2823431 C CA2823431 C CA 2823431C CA 2823431 A CA2823431 A CA 2823431A CA 2823431 A CA2823431 A CA 2823431A CA 2823431 C CA2823431 C CA 2823431C
- Authority
- CA
- Canada
- Prior art keywords
- oxidant
- fuel
- burner
- injection
- secondary oxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 80
- 239000007800 oxidant agent Substances 0.000 claims abstract description 290
- 230000001590 oxidative effect Effects 0.000 claims abstract description 287
- 239000000446 fuel Substances 0.000 claims abstract description 183
- 238000002347 injection Methods 0.000 claims abstract description 144
- 239000007924 injection Substances 0.000 claims abstract description 144
- 239000012530 fluid Substances 0.000 claims abstract description 76
- 238000000034 method Methods 0.000 claims description 36
- 239000007789 gas Substances 0.000 claims description 23
- 230000003247 decreasing effect Effects 0.000 claims description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 12
- 239000003245 coal Substances 0.000 claims description 11
- 238000004891 communication Methods 0.000 claims description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 6
- 239000003546 flue gas Substances 0.000 claims description 6
- 239000003345 natural gas Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000295 fuel oil Substances 0.000 claims description 4
- 230000013011 mating Effects 0.000 claims description 2
- 239000000376 reactant Substances 0.000 description 20
- 239000013256 coordination polymer Substances 0.000 description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 14
- 239000001301 oxygen Substances 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 12
- 230000007704 transition Effects 0.000 description 11
- 238000013461 design Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C5/00—Disposition of burners with respect to the combustion chamber or to one another; Mounting of burners in combustion apparatus
- F23C5/08—Disposition of burners
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C7/00—Combustion apparatus characterised by arrangements for air supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C7/00—Combustion apparatus characterised by arrangements for air supply
- F23C7/02—Disposition of air supply not passing through burner
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/006—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber the recirculation taking place in the combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C99/00—Subject-matter not provided for in other groups of this subclass
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D1/00—Burners for combustion of pulverulent fuel
- F23D1/005—Burners for combustion of pulverulent fuel burning a mixture of pulverulent fuel delivered as a slurry, i.e. comprising a carrying liquid
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
- F23L7/007—Supplying oxygen or oxygen-enriched air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23M—CASINGS, LININGS, WALLS OR DOORS SPECIALLY ADAPTED FOR COMBUSTION CHAMBERS, e.g. FIREBRIDGES; DEVICES FOR DEFLECTING AIR, FLAMES OR COMBUSTION PRODUCTS IN COMBUSTION CHAMBERS; SAFETY ARRANGEMENTS SPECIALLY ADAPTED FOR COMBUSTION APPARATUS; DETAILS OF COMBUSTION CHAMBERS, NOT OTHERWISE PROVIDED FOR
- F23M5/00—Casings; Linings; Walls
- F23M5/02—Casings; Linings; Walls characterised by the shape of the bricks or blocks used
- F23M5/025—Casings; Linings; Walls characterised by the shape of the bricks or blocks used specially adapted for burner openings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
- F23C2900/99001—Cold flame combustion or flameless oxidation processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Pre-Mixing And Non-Premixing Gas Burner (AREA)
- Nozzles For Spraying Of Liquid Fuel (AREA)
- Air Supply (AREA)
- Combustion Of Fluid Fuel (AREA)
- Gas Burners (AREA)
- Spray-Type Burners (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/982,818 US8915731B2 (en) | 2010-12-30 | 2010-12-30 | Flameless combustion burner |
| US12/982,818 | 2010-12-30 | ||
| PCT/US2011/066527 WO2012092069A2 (en) | 2010-12-30 | 2011-12-21 | Distributed combustion process and burner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2823431A1 CA2823431A1 (en) | 2012-07-05 |
| CA2823431C true CA2823431C (en) | 2017-05-09 |
Family
ID=45478590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2823431A Expired - Fee Related CA2823431C (en) | 2010-12-30 | 2011-12-21 | Distributed combustion process and burner |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US8915731B2 (enExample) |
| EP (1) | EP2659186B1 (enExample) |
| JP (2) | JP5996552B2 (enExample) |
| CN (1) | CN103547864B (enExample) |
| BR (1) | BR112013016987A2 (enExample) |
| CA (1) | CA2823431C (enExample) |
| PL (1) | PL2659186T3 (enExample) |
| RU (1) | RU2570963C2 (enExample) |
| WO (1) | WO2012092069A2 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6070323B2 (ja) * | 2013-03-21 | 2017-02-01 | 大陽日酸株式会社 | 燃焼バーナ、バーナ装置、及び原料粉体加熱方法 |
| US9360257B2 (en) | 2014-02-28 | 2016-06-07 | Air Products And Chemicals, Inc. | Transient heating burner and method |
| GB201408459D0 (en) * | 2014-05-13 | 2014-06-25 | Doosan Babcock Ltd | Flameless oxidtion device and method |
| ES2821325T3 (es) * | 2015-03-31 | 2021-04-26 | Mitsubishi Power Ltd | Quemador de combustión y caldera |
| MX388162B (es) | 2015-03-31 | 2025-03-19 | Mitsubishi Power Ltd | Quemador de combustión y caldera proporcionada con este |
| JP6642912B2 (ja) | 2015-09-11 | 2020-02-12 | 三菱日立パワーシステムズ株式会社 | 燃焼バーナ及びこれを備えたボイラ |
| JP6399458B2 (ja) * | 2015-09-14 | 2018-10-03 | 大陽日酸株式会社 | 酸素バーナ及び酸素バーナの運転方法 |
| WO2017113162A1 (en) * | 2015-12-30 | 2017-07-06 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method for injecting fluid-propelled particulate solid fuel and oxidant and injector for same |
| JP6121024B1 (ja) * | 2016-04-22 | 2017-04-26 | 大阪瓦斯株式会社 | 溶解炉用の燃焼装置、及びそれを備えた溶解炉 |
| JP6482513B2 (ja) * | 2016-09-16 | 2019-03-13 | 大陽日酸株式会社 | バーナ |
| US10584051B2 (en) * | 2017-02-22 | 2020-03-10 | Air Products And Chemicals, Inc. | Double-staged oxy-fuel burner |
| JP6633028B2 (ja) * | 2017-07-10 | 2020-01-22 | 大陽日酸株式会社 | 酸素富化バーナ及び酸素富化バーナを用いた加熱方法 |
| JP6756683B2 (ja) * | 2017-08-30 | 2020-09-16 | 大陽日酸株式会社 | 酸素富化バーナ及び酸素富化バーナを用いた加熱方法 |
| JP6568192B2 (ja) * | 2017-12-19 | 2019-08-28 | 中外炉工業株式会社 | バーナ |
| US10974219B2 (en) | 2017-12-20 | 2021-04-13 | Bd Energy Systems, Llc | Micro reformer |
| CN108980831A (zh) * | 2018-08-22 | 2018-12-11 | 佛山市科皓燃烧设备制造有限公司 | 一种超低NOx的蓄热式烧嘴 |
| US10845052B1 (en) | 2019-12-20 | 2020-11-24 | Jupiter Oxygen Corporation | Combustion system comprising an annular shroud burner |
| US12359807B2 (en) | 2019-12-20 | 2025-07-15 | Jupiter Oxygen Corporation | Combustion system comprising an annular shroud burner |
| CN113385025B (zh) * | 2021-06-23 | 2024-07-26 | 苏州西热节能环保技术有限公司 | 一种干粉水雾三流体喷枪及使用方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS5228165Y2 (enExample) * | 1974-01-28 | 1977-06-27 | ||
| US4539034A (en) * | 1984-07-19 | 1985-09-03 | Ppg Industries, Inc. | Melting of glass with staged submerged combustion |
| JPH0765730B2 (ja) * | 1989-08-02 | 1995-07-19 | 日本ファーネス工業株式会社 | 低ＮＯｘ燃焼装置 |
| SU1758340A1 (ru) * | 1989-10-06 | 1992-08-30 | Институт газа АН УССР | Комбинированна многотопливна горелка |
| US5242110A (en) * | 1991-12-02 | 1993-09-07 | Praxair Technology, Inc. | Method for changing the direction of an atomized flow |
| BR9404470A (pt) | 1993-11-17 | 1997-03-11 | Praxair Technology Inc | Processo para conduçao de combustao com simultânea geraçao reduzida de oxidos de nitrogênio |
| DE4419332A1 (de) | 1994-06-02 | 1995-12-14 | Wuenning Joachim | Industriebrenner mit geringer NO¶x¶-Emission |
| US5601425A (en) * | 1994-06-13 | 1997-02-11 | Praxair Technology, Inc. | Staged combustion for reducing nitrogen oxides |
| US5516279A (en) * | 1994-07-06 | 1996-05-14 | The Boc Group, Inc. | Oxy-fuel burner system designed for alternate fuel usage |
| US5636977A (en) | 1994-10-13 | 1997-06-10 | Gas Research Institute | Burner apparatus for reducing nitrogen oxides |
| PL179614B1 (pl) | 1994-10-27 | 2000-10-31 | Isentropic Sys Ltd | Sposób spalania gazów opalowych oraz komora spalania PL PL PL |
| US5772421A (en) | 1995-05-26 | 1998-06-30 | Canadian Gas Research Institute | Low nox burner |
| US5758823A (en) * | 1995-06-12 | 1998-06-02 | Georgia Tech Research Corporation | Synthetic jet actuator and applications thereof |
| US5688115A (en) | 1995-06-19 | 1997-11-18 | Shell Oil Company | System and method for reduced NOx combustion |
| JP3557028B2 (ja) | 1996-02-14 | 2004-08-25 | Ｊｆｅスチール株式会社 | 燃焼バーナ及びその炉内燃焼方法 |
| EP0898687B1 (en) | 1996-05-17 | 2002-08-14 | Xothermic, Inc. | Burner apparatus |
| US6007326A (en) | 1997-08-04 | 1999-12-28 | Praxair Technology, Inc. | Low NOx combustion process |
| JP3522506B2 (ja) * | 1997-09-01 | 2004-04-26 | 東京瓦斯株式会社 | 酸素燃焼バーナと該バーナを持つ燃焼炉 |
| FR2784449B1 (fr) | 1998-10-13 | 2000-12-29 | Stein Heurtey | Bruleur a combustible fluide notamment pour fours de rechauffage de produits siderurgiques |
| JP4132409B2 (ja) * | 1999-06-02 | 2008-08-13 | 大陽日酸株式会社 | 燃焼装置 |
| US6126438A (en) * | 1999-06-23 | 2000-10-03 | American Air Liquide | Preheated fuel and oxidant combustion burner |
| DE60025924D1 (de) | 1999-08-17 | 2006-04-20 | Nippon Furnace Kogyo K K | Verbrennungsverfahren und brenner |
| US6206685B1 (en) * | 1999-08-31 | 2001-03-27 | Ge Energy And Environmental Research Corporation | Method for reducing NOx in combustion flue gas using metal-containing additives |
| DE10060951A1 (de) | 2000-12-06 | 2002-06-27 | Messer Griesheim Gmbh | Verfahren zum Einschmelzen von Metallschrott |
| US6702569B2 (en) * | 2001-01-11 | 2004-03-09 | Praxair Technology, Inc. | Enhancing SNCR-aided combustion with oxygen addition |
| FR2823290B1 (fr) * | 2001-04-06 | 2006-08-18 | Air Liquide | Procede de combustion comportant des injections separees de combustible et d oxydant et ensemble bruleur pour la mise en oeuvre de ce procede |
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| SE0202836D0 (sv) | 2002-09-25 | 2002-09-25 | Linde Ag | Method and apparatus for heat treatment |
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| NL1023570C2 (nl) | 2003-05-30 | 2004-12-01 | Nederlandse Gasunie Nv | Homogene oxidatie. |
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| DE102005031231B3 (de) * | 2005-07-01 | 2007-01-11 | J. Eberspächer GmbH & Co. KG | Wandstruktur für einen Brenner |
| US20070269755A2 (en) | 2006-01-05 | 2007-11-22 | Petro-Chem Development Co., Inc. | Systems, apparatus and method for flameless combustion absent catalyst or high temperature oxidants |
| US8696348B2 (en) | 2006-04-26 | 2014-04-15 | Air Products And Chemicals, Inc. | Ultra-low NOx burner assembly |
| FR2903479A1 (fr) * | 2006-07-06 | 2008-01-11 | Air Liquide | Bruleur a flamme orientable et procede de mise en oeuvre |
| ITMI20061636A1 (it) | 2006-08-22 | 2008-02-23 | Danieli & C Officine Meccaniche Spa | Bruciatore |
| US20080096146A1 (en) * | 2006-10-24 | 2008-04-24 | Xianming Jimmy Li | Low NOx staged fuel injection burner for creating plug flow |
| WO2008127765A2 (en) | 2007-02-08 | 2008-10-23 | Praxair Technology, Inc. | Multi-output valve useful to promote non-stationary flame |
| EP1995515B1 (de) | 2007-05-23 | 2013-10-30 | WS-Wärmeprozesstechnik GmbH | Unterstützter FLOX-Betrieb und Brenner dafür |
| DE102008047489B4 (de) | 2008-09-17 | 2010-05-12 | Messer Group Gmbh | Brenner und Verfahren zum Betreiben eines Brenners |
| JP5386230B2 (ja) * | 2009-05-22 | 2014-01-15 | 三菱重工業株式会社 | 燃料バーナ及び旋回燃焼ボイラ |
| JP5801675B2 (ja) * | 2011-10-03 | 2015-10-28 | 大陽日酸株式会社 | バーナおよびバーナ燃焼方法 |
-
2010
- 2010-12-30 US US12/982,818 patent/US8915731B2/en not_active Expired - Fee Related
-
2011
- 2011-12-21 CN CN201180068732.9A patent/CN103547864B/zh not_active Expired - Fee Related
- 2011-12-21 WO PCT/US2011/066527 patent/WO2012092069A2/en not_active Ceased
- 2011-12-21 RU RU2013135480/06A patent/RU2570963C2/ru not_active IP Right Cessation
- 2011-12-21 CA CA2823431A patent/CA2823431C/en not_active Expired - Fee Related
- 2011-12-21 BR BR112013016987-7A patent/BR112013016987A2/pt not_active Application Discontinuation
- 2011-12-21 PL PL11808534T patent/PL2659186T3/pl unknown
- 2011-12-21 JP JP2013547560A patent/JP5996552B2/ja not_active Expired - Fee Related
- 2011-12-21 EP EP11808534.9A patent/EP2659186B1/en not_active Not-in-force
-
2014
- 2014-11-06 US US14/534,918 patent/US9285113B2/en not_active Expired - Fee Related
- 2014-12-22 JP JP2014258874A patent/JP6022531B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN103547864A (zh) | 2014-01-29 |
| PL2659186T3 (pl) | 2019-09-30 |
| JP5996552B2 (ja) | 2016-09-21 |
| RU2013135480A (ru) | 2015-02-10 |
| BR112013016987A2 (pt) | 2020-08-04 |
| EP2659186A2 (en) | 2013-11-06 |
| EP2659186B1 (en) | 2019-06-05 |
| JP2014505851A (ja) | 2014-03-06 |
| JP6022531B2 (ja) | 2016-11-09 |
| US9285113B2 (en) | 2016-03-15 |
| JP2015121398A (ja) | 2015-07-02 |
| WO2012092069A2 (en) | 2012-07-05 |
| CN103547864B (zh) | 2016-05-04 |
| RU2570963C2 (ru) | 2015-12-20 |
| US20120171629A1 (en) | 2012-07-05 |
| CA2823431A1 (en) | 2012-07-05 |
| US8915731B2 (en) | 2014-12-23 |
| US20150068437A1 (en) | 2015-03-12 |
| WO2012092069A3 (en) | 2013-10-24 |
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