CA2820097C - Flue gas scrubbing - Google Patents

Flue gas scrubbing Download PDF

Info

Publication number
CA2820097C
CA2820097C CA2820097A CA2820097A CA2820097C CA 2820097 C CA2820097 C CA 2820097C CA 2820097 A CA2820097 A CA 2820097A CA 2820097 A CA2820097 A CA 2820097A CA 2820097 C CA2820097 C CA 2820097C
Authority
CA
Canada
Prior art keywords
mercury
flue gas
copper
lime
clay
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2820097A
Other languages
English (en)
French (fr)
Other versions
CA2820097A1 (en
Inventor
Zhen Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amcol International Corp
Original Assignee
Amcol International Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amcol International Corp filed Critical Amcol International Corp
Priority to CA3000330A priority Critical patent/CA3000330A1/en
Publication of CA2820097A1 publication Critical patent/CA2820097A1/en
Application granted granted Critical
Publication of CA2820097C publication Critical patent/CA2820097C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/10—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/025—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with wetted adsorbents; Chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/83—Solid phase processes with moving reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8665—Removing heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0233—Compounds of Cu, Ag, Au
    • B01J20/0237—Compounds of Cu
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/045—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing sulfur, e.g. sulfates, thiosulfates, gypsum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/02—Processes using inorganic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/14—Base exchange silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/306—Alkali metal compounds of potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/11—Clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Gas Separation By Absorption (AREA)
CA2820097A 2011-01-31 2011-08-05 Flue gas scrubbing Expired - Fee Related CA2820097C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA3000330A CA3000330A1 (en) 2011-01-31 2011-08-05 Flue gas scrubbing

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/017,539 2011-01-31
US13/017,539 US8420561B2 (en) 2009-06-16 2011-01-31 Flue gas scrubbing
PCT/US2011/046726 WO2012106007A1 (en) 2011-01-31 2011-08-05 Flue gas scrubbing

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA3000330A Division CA3000330A1 (en) 2011-01-31 2011-08-05 Flue gas scrubbing

Publications (2)

Publication Number Publication Date
CA2820097A1 CA2820097A1 (en) 2012-08-09
CA2820097C true CA2820097C (en) 2018-07-03

Family

ID=44504266

Family Applications (2)

Application Number Title Priority Date Filing Date
CA2820097A Expired - Fee Related CA2820097C (en) 2011-01-31 2011-08-05 Flue gas scrubbing
CA3000330A Abandoned CA3000330A1 (en) 2011-01-31 2011-08-05 Flue gas scrubbing

Family Applications After (1)

Application Number Title Priority Date Filing Date
CA3000330A Abandoned CA3000330A1 (en) 2011-01-31 2011-08-05 Flue gas scrubbing

Country Status (11)

Country Link
US (1) US8420561B2 (enExample)
EP (2) EP2670510B1 (enExample)
JP (1) JP5923526B2 (enExample)
KR (1) KR101986270B1 (enExample)
CN (1) CN103313770B (enExample)
AU (1) AU2011357684B2 (enExample)
BR (1) BR112013013784A2 (enExample)
CA (2) CA2820097C (enExample)
MX (2) MX2013008784A (enExample)
PL (2) PL2870990T3 (enExample)
WO (1) WO2012106007A1 (enExample)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8268744B2 (en) * 2009-06-16 2012-09-18 Amcol International Corporation High shear method for manufacturing a synthetic smectite mineral
US8420561B2 (en) * 2009-06-16 2013-04-16 Amcol International Corporation Flue gas scrubbing
GB2547364B8 (en) * 2010-10-05 2017-11-29 The Queen's Univ Of Belfast Process for removing metals from hydrocarbons
US9227172B2 (en) * 2011-10-07 2016-01-05 Ecolab Usa Inc. Silica containing basic sorbent for acid gas removal
WO2013052876A1 (en) * 2011-10-07 2013-04-11 Nalco Company Gas stream treatment process
US9802154B2 (en) * 2012-03-30 2017-10-31 Fuel Tech, Inc. Process for sulfur dioxide, hydrochloric acid and mercury mediation
US8992868B2 (en) * 2012-05-01 2015-03-31 Fuel Tech, Inc. Dry processes, apparatus compositions and systems for reducing mercury, sulfur oxides and HCl
US10166507B2 (en) * 2012-03-30 2019-01-01 Fuel Tech, Inc. Process for hydrochloric acid mediation
CN104822433A (zh) * 2012-03-30 2015-08-05 燃料技术公司 用于减少硫氧化物和HCl的干法、装置、组合物和系统
WO2014015122A1 (en) * 2012-07-20 2014-01-23 Novinda Corp. Enhanced fly ash collection
DE102012214065A1 (de) * 2012-08-08 2014-02-13 EnBW Energie Baden-Württemberg AG Verfahren zum Entfernen von Quecksilber aus Rauchgas in einem Nasswäscher
US9387434B2 (en) 2012-08-20 2016-07-12 Ecolab Usa Inc. Mercury sorbents
US9289721B2 (en) 2013-02-27 2016-03-22 Fuel Tech, Inc. Process and apparatus for improving the operation of wet scrubbers
CN105142758A (zh) * 2013-02-27 2015-12-09 燃料技术公司 用于降低HCl和/或和硫氧化物排放的方法、设备、组合物和系统
US20160030915A1 (en) * 2013-03-13 2016-02-04 Novinda Corporation Supported Sulfides for Mercury Capture
AU2014248855A1 (en) * 2013-03-13 2015-10-01 Novinda Corporation Multicomponent compositions for mercury removal
US9399597B2 (en) * 2013-04-01 2016-07-26 Fuel Tech, Inc. Ash compositions recovered from coal combustion gases having reduced emissions of HCI and/or mercury
US9446351B2 (en) 2013-11-25 2016-09-20 Milliken & Company Filtration medium and process for filtering a fluid stream
GB201322464D0 (en) 2013-12-18 2014-02-05 Johnson Matthey Plc Method for preparing a sorbent
GB201322462D0 (en) 2013-12-18 2014-02-05 Johnson Matthey Plc Method for preparing a sorbent
WO2016184518A1 (en) * 2015-05-20 2016-11-24 S.A. Lhoist Recherche Et Developpement Lime-based sorbent composition for mercury removal and its manufacturing process
US10124290B2 (en) 2015-08-21 2018-11-13 Ecolab Usa Inc. Complexation and removal of mercury from flue gas desulfurization systems
AU2016343711A1 (en) * 2015-10-30 2018-03-29 Amcol International Corporation Improved method of making a mercury sorbent
CN106822972A (zh) * 2015-12-07 2017-06-13 山东联星能源集团有限公司 一种空气净化剂的制备方法
CN111097374B (zh) * 2018-10-25 2022-05-06 中国科学院生态环境研究中心 载氧+吸附复合功能材料的制备方法及其在水体修复中的应用
CN111097373B (zh) * 2018-10-25 2022-05-06 中国科学院生态环境研究中心 多孔吸附材料和载氧+吸附复合功能材料及它们的应用
CN113731113B (zh) * 2021-09-15 2022-05-17 北京工大环能科技有限公司 一种用于降低燃煤电站空气预热器硫酸氢铵堵塞的系统

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3807702A (en) * 1971-06-21 1974-04-30 Huber Corp J M An improved apparatus for encapsulating a finely divided clay within an organic polymeric material
DE2656803C2 (de) * 1975-12-18 1986-12-18 Institut Français du Pétrole, Rueil-Malmaison, Hauts-de-Seine Verfahren zur Entfernung von in einem Gas oder in einer Flüssigkeit vorhandenem Quecksilber
US4361493A (en) * 1980-06-30 1982-11-30 Eastman Kodak Company Hydrophilic substrate for sorbing heavy metals
CA1220773A (en) 1983-11-03 1987-04-21 Thomas M. Matviya Mercury adsorbent carbon molecular sieves
JPS61293531A (ja) * 1985-06-21 1986-12-24 Mitsubishi Heavy Ind Ltd 廃棄物焼却排ガスの処理方法
JPH0661424B2 (ja) * 1986-03-19 1994-08-17 三菱重工業株式会社 燃焼排ガス中の水銀及び酸性ガス除去方法
US5248641A (en) * 1990-09-17 1993-09-28 Southern Clay Products, Inc. Process for producing bentonite clays exhibiting enhanced solution viscosity properties
GB9022060D0 (en) 1990-10-10 1990-11-21 Ici Plc Mercury removal
FR2668465B1 (fr) * 1990-10-30 1993-04-16 Inst Francais Du Petrole Procede d'elimination de mercure ou d'arsenic dans un fluide en presence d'une masse de captation de mercure et/ou d'arsenic.
JPH04330917A (ja) * 1991-05-01 1992-11-18 Kubota Corp 排ガス集塵方法
JP3285692B2 (ja) * 1994-01-26 2002-05-27 日立造船株式会社 焼却炉における飛灰処理装置
JPH09308817A (ja) * 1996-05-22 1997-12-02 Babcock Hitachi Kk 排ガス処理方法および装置
WO2001000317A1 (en) * 1999-06-30 2001-01-04 Phillips Petroleum Company Sulfur sorbent composition and sorption process
US7048781B1 (en) * 2002-10-07 2006-05-23 Ada Technologies, Inc. Chemically-impregnated silicate agents for mercury control
US7288499B1 (en) * 2001-04-30 2007-10-30 Ada Technologies, Inc Regenerable high capacity sorbent for removal of mercury from flue gas
US6719828B1 (en) * 2001-04-30 2004-04-13 John S. Lovell High capacity regenerable sorbent for removal of mercury from flue gas
US7081434B2 (en) * 2001-11-27 2006-07-25 Sinha Rabindra K Chemical formulations for the removal of mercury and other pollutants present in fluid streams
US7060233B1 (en) * 2002-03-25 2006-06-13 Tda Research, Inc. Process for the simultaneous removal of sulfur and mercury
WO2006006978A1 (en) 2004-06-28 2006-01-19 Nox Ii International, Ltd. Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels
JP2006015290A (ja) * 2004-07-05 2006-01-19 Pollars Laboratory Corp 混合、混練装置を用いない飛灰中の重金属固定化処理方法
AU2005291790B2 (en) * 2004-10-01 2010-12-09 William Digdon Composition and method for oxidizing mercury in combustion processes
CN103759249A (zh) * 2005-03-17 2014-04-30 Noxii国际有限公司 降低煤燃烧中的汞排放量
CN102352274B (zh) * 2005-03-17 2015-01-21 Noxii国际有限公司 吸附剂组合物及使用其降低煤燃烧过程中的汞排放量的方法
US7575629B2 (en) * 2005-11-30 2009-08-18 Basf Catalysts Llc Pollutant emission control sorbents and methods of manufacture
US7704920B2 (en) * 2005-11-30 2010-04-27 Basf Catalysts Llc Pollutant emission control sorbents and methods of manufacture
US7578869B2 (en) * 2005-11-30 2009-08-25 Basf Catalysts Llc Methods of manufacturing bentonite pollution control sorbents
US7468170B2 (en) * 2005-12-21 2008-12-23 Douglas C Comrie Nitrogenous sorbent for coal combustion
US20070140943A1 (en) * 2005-12-21 2007-06-21 Comrie Douglas C Sorbent composition to reduce emissions from the burning of carbonaceous fuels
US7572421B2 (en) * 2006-06-19 2009-08-11 Basf Catalysts Llc Mercury sorbents and methods of manufacture and use
US7753992B2 (en) * 2006-06-19 2010-07-13 Basf Corporation Methods of manufacturing mercury sorbents and removing mercury from a gas stream
KR20080029351A (ko) * 2006-09-29 2008-04-03 (주)엘케이전자 엘이디 백라이트 장치 및 그 제조방법
WO2008064360A2 (en) 2006-11-22 2008-05-29 Sorbent Technologies Corporation Compositions and methods to sequester flue gas mercury in concrete
CA2695275A1 (en) 2007-08-02 2009-02-05 The Benthamite Company, Llc Composition, production and use of sorbent particles for flue gas desulfurization
JP2009213999A (ja) * 2008-03-10 2009-09-24 Taiheiyo Cement Corp 水銀含有廃棄物の処理装置及び処理方法
JP2009291734A (ja) * 2008-06-06 2009-12-17 Hitachi Plant Technologies Ltd 排ガス処理装置およびその方法
JP2012509758A (ja) * 2008-11-25 2012-04-26 ジョンソン、マッセイ、パブリック、リミテッド、カンパニー 重金属除去用還元型硫化銅収着剤
US8420561B2 (en) 2009-06-16 2013-04-16 Amcol International Corporation Flue gas scrubbing
US8268744B2 (en) 2009-06-16 2012-09-18 Amcol International Corporation High shear method for manufacturing a synthetic smectite mineral
CN101628201A (zh) * 2009-08-19 2010-01-20 福建龙净脱硫脱硝工程有限公司 玻璃窑炉烟气污染物脱除装置及其脱除方法

Also Published As

Publication number Publication date
CA2820097A1 (en) 2012-08-09
JP2014508638A (ja) 2014-04-10
US20110123422A1 (en) 2011-05-26
CA3000330A1 (en) 2012-08-09
WO2012106007A1 (en) 2012-08-09
AU2011357684A1 (en) 2013-06-27
US8420561B2 (en) 2013-04-16
EP2870990A1 (en) 2015-05-13
MX2013008784A (es) 2014-02-06
PL2870990T3 (pl) 2017-09-29
CN103313770A (zh) 2013-09-18
CN103313770B (zh) 2016-03-16
KR20130141591A (ko) 2013-12-26
EP2670510A1 (en) 2013-12-11
EP2870990B1 (en) 2017-04-12
PL2670510T3 (pl) 2015-07-31
MX340227B (es) 2016-07-01
AU2011357684B2 (en) 2016-10-27
BR112013013784A2 (pt) 2016-09-13
JP5923526B2 (ja) 2016-05-24
KR101986270B1 (ko) 2019-06-05
EP2670510B1 (en) 2015-02-11

Similar Documents

Publication Publication Date Title
CA2820097C (en) Flue gas scrubbing
US8268744B2 (en) High shear method for manufacturing a synthetic smectite mineral
USRE44124E1 (en) Regenerable high capacity sorbent for removal of mercury from flue gas
US6719828B1 (en) High capacity regenerable sorbent for removal of mercury from flue gas
US8961821B2 (en) Gas stream treatment process
US20180304229A1 (en) Improved method of making a mercury sorbent
CA2905382C (en) Multicomponent compositions for mercury removal
Tseng et al. The study of modified calcium hydroxides with surfactants for acid gas removal during incineration
HK1210088B (en) Mercury sorbent material comprising a sheared, ion-exchanged clay material
Koech The dissolution of limestone, coal fly ash and bottom ash in wet flue gas desulphurization

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20160503

MKLA Lapsed

Effective date: 20220301

MKLA Lapsed

Effective date: 20200831