CA2802296C

CA2802296C - Reinforced nonwoven fabric

Info

Publication number: CA2802296C
Application number: CA2802296A
Authority: CA
Inventors: Martin Danzer
Original assignee: SGL Automotive Carbon Fibers GmbH and Co KG
Current assignee: SGL Automotive Carbon Fibers GmbH and Co KG
Priority date: 2010-11-03
Filing date: 2011-11-03
Publication date: 2015-03-24
Anticipated expiration: 2031-11-03
Also published as: PT2635417E; KR101494507B1; CN103025942A; BR112012031770A2; JP2013535588A; ES2544991T3; MX2012014598A; MX2012014614A; US20130287991A1; JP5745052B2; CN103025494A; PL2635417T3; JP2013534278A; KR20130042504A; KR20130054968A; CN103025942B; WO2012059538A1; MX2012014612A; KR101497788B1; CA2802296A1

Abstract

A flat textile structure comprising a reinforcing grid and at least one pile layer which is situated in a flat manner on at least one surface of the reinforcing grid, characterized in that the flat textile structure has a weight per unit area of from 40 to 140 g/m2, the pile layer consists predominantly of carbon fibres, the carbon fibres in the flat textile structure have a proportion of the weight per unit area of from 60 to 97%, the reinforcing grid has a proportionate weight per unit area of from 2.5 to 12.5 g/m2 and the flat textile structure is strengthened.

Description

-WO 2012/059538 Al REINFORCED NONWOVEN FABRIC
AREA OF THE INVENTION
The present invention relates to a woven material that has been reinforced for improved handling during the manufacturing process, a component incorporating the reinforced nonwoven material, and its use. In particular, the present invention relates to a carbon fiber nonwoven with a reinforcing grid contained therein.
BACKGROUND OF THE INVENTION
During the manufacture of flat textile structures with a relatively low cohesion among the textile fibers, for example in the case of nonwoven or pile, the simplest handling processes can pose a problem, such as rolling the flat structures on and off, and automatically feeding them to additional production stages. One possible way of countering this problem is to integrate a reinforcing grid into the flat structure. This basic structure of reinforcing layers incorporated between pile layers represents the starting point of the present invention.
Disclosed in DE 92 07 367 Ul is a laminate whose surfaces were formed using spunbonded fabric, and which consists of at least two layers of spunbonded fabric and at least one scrim layer, preferably a scrim layer made out of reinforcing yarns, wherein the scrim layers or scrim layer lie(s) between a respective two spunbonded fabric layers (DE 92 07 367 Ul, page 2, 2'd complete sentence).
DE 10 2006 060 241 Al discloses a carrier insert comprised of a flat textile structure and a reinforcement, in which the flat textile structure, which already exhibits the reinforcement, was solidified hydrodynamically. Described in particular are spunbonded fabrics, which are generated

- 2 -by randomly depositing freshly melt-spun filaments, and consist of endless synthetic fibers made up of melt-spinnable polymer materials (DE 10 2006 060 241 Al, paragraph [0036]).
EP 1 584 737 Al discloses a strengthened, flat nonwoven, which encompasses at least two layers of endless fiber nonwoven made of polyester and a glass fiber grid secured between the nonwoven layers.
The cited publications relate primarily to the use of the flat textile structures for manufacturing bituminized roof or liner sheeting. Primarily melt spinnable polymers are here used for the nonwoven materials, and not carbon fibers. However, no special requirements on weight reduction and mechanical stability are necessary in such applications. For this reason, the known instructions are inadequate for the manufacture of components subject to more stringent requirements in this regard, for example in the automotive or aviation industries.
Therefore, these applications also require thin flat textile structures, which allow the finished component that ultimately integrates the flat textile structure to withstand the highest possible mechanical loads. As a result, the present invention is geared toward flat textile structures made up completely or predominantly of carbon fibers.
One difficultly posed by carbon fibers in terms of manufacturing technique has to do with the composition of the carbon fiber surface. In comparison to other polymer fibers, carbon fibers have a very smooth surface. As a consequence, carbon fibers in flat textile structures exhibit a very weak adhesion between the fibers, and hence lead to a low cohesion between the flat textile structures.
This low adhesion or low cohesion finally impacts the

- 3 -manufacturing process for flat textile structures comprised of carbon fibers, thus necessitating a reinforcing grid.
Also required is a flat textile structure that satisfies certain optical and tactile requirements. The reinforcing grid contained in the nonwoven material must be as inconspicuous as possible from outside, and the meshes of the reinforcing grid should not produce any troughs on the surface of the flat textile structure.
However, primarily the nonwoven layers are responsible for the mechanical stability of the final component that integrates the flat textile structure owing to their percentage of carbon fibers, so that the presence of a reinforcing grid has a detrimental effect on the strength-weight ratio for the component.
In addition, the use of a reinforcing grid influences the draping characteristics of the nonwoven material. The draping ability here deteriorates as the strength of the reinforcing grid rises.
At the same time, however, the reinforcing grid must satisfy the purpose for which used, specifically provide adequate reinforcement for the flat textile structure, so as to ensure an improved handling of the latter in the manufacturing process.
Therefore, the object of some aspects of the present invention is to prepare a flat textile structure that exhibits the mentioned desired characteristics, while largely avoiding the mentioned shortcomings.
SUMMARY OF THE INVENTION
The object of the present invention is achieved in some aspects by an advantageous combination of layer thickness or weight per =

- 4 -unit area for the flat textile structure, the proportion of carbon fibers in the weight per unit area, and the proportionate weight per unit area of the reinforcing grid.
One aspect of the present invention involves a flat textile structure encompassing a reinforcing grid and at least one pile layer flatly situated on at least one surface of the reinforcing grid, characterized in that - the flat textile structure exhibits a weight per unit area of from 40 to 140 g/cm2, - the pile layer consists predominantly of carbon fibers, - the carbon fibers in the flat textile structure make up 60 to 97% of the weight per unit area, - the reinforcing grid exhibits a proportionate weight per unit area of from 2.5 to 12.5 g/m2, and - the flat textile structure is solidified.
Another aspect of the present invention is an article that , encompasses at least two flat textile structures flatly joined together according to the present invention.
Another aspect of the present invention is a component that encompasses the flat textile structure according to the invention or the article according to the invention impregnated with a polymer 'matrix.
Another aspect of the present invention is the use of the component according to the invention for manufacturing parts of an automobile.

- 4a -Another aspect of the present invention is a flat textile structure encompassing a reinforcing grid and at least one pile layer flatly situated on at least one surface of the reinforcing grid, wherein the flat textile structure exhibits a weight per unit area of from 40 to 140 g/cm2, the pile layer consists predominantly of carbon fibers, the carbon fibers in the flat textile structure make up 60 to 97% of the weight per unit area, the reinforcing grid exhibits a proportionate weight per unit area of from 2.5 to 12.5 g/m2, and the flat textile structure is solidified, and wherein the reinforcing grid is located between two consecutive pile layers.
Another aspect of the present invention is an article encompassing at least two flatly joined flat textile structures as described herein.
Another aspect of the present invention is a component encompassing a flat textile structure as described herein, wherein the flat textile structure is impregnated with a polymer matrix.
Another aspect of the present invention is a component encompassing an article as described herein, wherein the article is impregnated with a polymer matrix.
Another aspect of the present invention is use of the component as described herein to manufacture automobile parts.
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

- 5 Fig. 1 shows the schematic structural design of a flat textile structure (1) according to one aspect of the present invention. The reinforcing grid (3) according to the invention, as represented by its grid braces (30), is here secured between two pile layers (2) according to the invention, as represented by its fibers (20).
Fig. 2 shows the schematic structural design of a preferred embodiment of the flat textile structure (1) according to the invention. Two vertically stacked pile layers (2) here lie on one side of the reinforcing grid (3), while one pile layer (2) lies on the other side. This embodiment is preferred because the surface of the flat textile structure (1) exhibits better optical and tactile characteristics on the side with the two vertically stacked pile layers (2).
This becomes advantageous when primarily only one side of the Component is visible in the subsequent component that integrates the flat textile structure (1), for example in the case of vehicle doors.
Fig. 3 shows the schematic structural design of an embodiment of the flat textile structure (1) according to the invention. Two vertical;y stacked pile layers (2) here lie on one side of the reinforcing grid (3), while the other side of the reinforcing grid (3) remains clear. This embodiment is advantageous in particular when the optical and tactile requirements relate exclusively to one side of the flat textile structure (1).
DETAILED DESCRIPTION
The term "pile layer" is known to the expert. It refers to a loose layer of randomly intertwined single fibers that has not been solidified, for example through needling.
Methods for manufacturing a pile layer (2) are known to the expert, for example willowing or carding. Depending on the method, the alignments for the single fibers (20) in the =

- 6 -pile layer (2) are more or less homogenously distributed.
However, the fibers (20) in the pile layer (2) exhibit a preferred direction in some methods, for example in the carding method. This means that the alignment of the fibers (20) in the pile layer (2) is more often encountered in one specific direction than in other directions. This is because the fibers (20) are always combed back and forth in the same direction in the carding process. As a consequence, the resulting pile layer (2) frequently exhibits a greater strength longitudinally to the preferred direction of the fibers (20) than perpendicular thereto. In the present invention, the term "preferred direction" of the pile layer (2) must be understood in the light of the definition provided here.
A "woven" or "woven material" or a "woven layer" or "woven material layer" refers to a pile layer (2) that has been solidified, for example through needling.
Methods for solidifying a pile layer (2) into a woven layer, for example needling, are known to the expert.
Solidification methods can be thermal, mechanical or chemical in nature. Thermal solidification typically involves melting open a medium that is already added to the flat textile structure before the pile is manufactured, for example. However, mechanical methods encompass needling and stitching. The chemical method typically involves spraying on an adhesive. The methods relating to the pile layer (2) are also applied during the solidification of the flat textile structure (1) according to the invention. All pile layers (2) present in the flat textile structure (1) and the reinforcing grid (3) are here joined together. During mechanical solidification, this occurs in such a way as to intertwine the grid braces of the reinforcing grid (3) with individual fibers of the adjoining pile layers (2), which yields a stronger connection between the reinforcing grid (3) and pile layers (2).

- 7 -If the pile layer (2) that was further processed into a woven exhibits a preferred direction for the fibers (20), this can often also be discerned from the surface of the woven material, for example after the pile layer (2) has been needled.
Within the framework of this invention, the flat textile structure (1) according to the invention is referred to as "nonwoven plies" in certain contexts.
In a preferred embodiment of the present invention, the flat textile structure (1) exhibits a weight per unit area of 80-110 g/m2, wherein the carbon fibers in the flat textile structure (1) have a proportionate weight per unit area of 65 to 84%, and the reinforcing grid (3) has a proportionate weight per unit area of 3 to 10 g/m2. This embodiment is especially suited for use in components in the automotive industry to replace thin metal sheets, for example engine hoods, doors, fenders, etc.
The reinforcing grid (3) can be located between two consecutive pile layers (2) inside the flat textile structure (1). The advantage here is that the desired optical and tactile composition can be ensured on both surfaces of the flat textile structure (1).
Aside from that, it can also be advantageous for the reinforcing grid (3) to be located on the outside of the flat textile structure (1). Very thin flat textile structures (1) can here be fabricated, at least one side of which exhibits the desired optical and tactile composition.
As a result, this embodiment is especially suited for use in components according to the invention, which as intended are visible only from one side in the finished product, for example, vehicle doors.

=

- 8 -According to the invention, the pile layers (2) are comprised predominantly of carbon fibers. Within the framework of this invention, the portion that does not consist of carbon fibers is referred to as the "foreign fiber portion". Depending on the context, the foreign fiber portion can relate both to the entire flat textile structure, as well as only to the pile layer (2). A low foreign fiber portion is basically desired, since the stability of the component according to the invention drops as the foreign fiber portion rises. However, carbon fibers are very cost-intensive. Therefore, once a sufficient stability has been reached for the component, foreign fibers can be added to the fibers to be processed in a targeted manner, specifically in such a way that the carbon fibers make up a percentage of the overall weight per unit area of the flat textile structure (1) according to the subject matter of the present invention, preferably a percentage measuring 65 to 84%.
No special limitations are placed on the material and composition of the reinforcing grid (3). It preferably consists of threads of endless fibers (30), which are present as scrims, wovens, knots or knits, wherein scrims are preferred, since they are the easiest to fabricate, and exhibit the smallest layer thickness at the intersecting points by comparison to knits.
For example, the fibers in the reinforcing grid (3) can consist of polyester, glass, polyamide, polyethylene, aramide fibers and/or carbon, wherein polyester and glass represent preferred materials for reasons of cost in conjunction with the ratio between strength and fiber thickness.
Regardless of whether the reinforcing grid (3) is comprised of scrims, wovens, knots or knits, the structural constituents of the reinforcing grid (3) are referred to as

- 9 -"braces" or "grid braces" and "intersecting points" within the framework of this invention, in keeping with the general meaning ascribed to a grid.
The preferred titers for the braces (30) in the reinforcing grid (3) preferably measure 120 to 350 dtex. Also preferred are titers between 150 and 280 dtex, since optimal results are achieved in this range with respect to the strength and scope of the troughs, which are formed by the meshes of the reinforcing grid (3) on the surface of the flat textile structure (1) according to the invention, and a sufficient draping ability is ensured.
The intersecting points of the reinforcing grid (3) can exhibit a binding agent. If the reinforcing grid (3) is a scrim layer, it is preferred that a binding agent be used at the intersecting points. No special limitations are placed on the selection of binding agent. However, PVAC-based binding agents are preferred, since they are hot sealable, and make it especially easy and inexpensive to manufacture the reinforcing grid (3).
In terms of structural design, the reinforcing grid (3) preferably consists of two to three blades of parallel braces (30). However, more than three blades are also possible.
If the structural design consists of two blades of parallel braces (5a), the checkerboard structure (5) is preferred, i.e., the reinforcing grid (3) exhibits square meshes. Fig.
provides a schematic view depicting a cutout from this structure. The advantage here has to do with a maximum isotropy for the strength of the flat structure, meaning with a directionally independent strength. The distance between the braces (5a) preferably measures 10 to 50 mm in this embodiment, more preferably 10 to 18 mm, since the

- 10 -troughs described above are less pronounced given smaller meshes.
If the structural design consists of three blades of parallel braces (4a, 4b, 4c), the braces of one blade are referred to as "longitudinal braces" (4a), and the braces of the two other blades are referred to as "diagonal braces" (4b, 4c). Fig. 4 provides a schematic view depicting a cutout from this structure. Preference here goes to a structural design in which one blade of diagonal braces (4b) is situated at an angle greater than 450 and less than 90 relative to the longitudinal braces (4a), while these angles are less than -450 and greater than -90 for the other blade of diagonal braces (4c), and the angles for both blades of diagonal braces (4b, 4c) relative to the longitudinal braces (4a) are each numerically equal. Viewed in isolation, the blades of the diagonal braces (4b, 4c) thus form rhomboid meshes. In this embodiment, the distance between the longitudinal braces (4a) preferably measures 5 to 20 mm. In this embodiment, the distance between the diagonal braces (4b, 4c) within a blade preferably measures 7 to 50 mm, since the troughs described above are sparingly pronounced as a result, while a sufficient strength is ensured at the same time.
Regardless of how the grid (3) is designed, a blade of parallel braces (30) of the reinforcing grid (3) is preferably aligned longitudinally to the preferred direction of the fibers (20) in the pile layers (2), if any, while combining the reinforcing grid (3) and pile layers (2). This helps to simplify the manufacturing process.
A method for manufacturing the flat textile structure (1) according to the invention in which the reinforcing grid (3,) is situated between two consecutive pile layers (2)

- 11 -typically encompasses the same steps, preferably within a continuous process:
a) Manufacturing a pile layer (2) with the desired weight per unit area, b) Manufacturing additional pile layers (2) as needed, and applying the latter to the pile layer (2) manufactured in a), c) Applying the reinforcing grid (3) to the pile layer (2) manufactured in a), or on the stack of pile layers (2) manufactured in a) and b), if necessary, d) Applying at least one additional pile layer (2) on the reinforcing grid (3) prepared in c), e) Solidifying the plies placed one on top of the other in a) to d), for example through needling, and f) Gathering the flat structure (1) created in e), for example on a roller.
A method for manufacturing the flat textile structure (1) according to the invention in which the reinforcing grid (3) is secured to the outside of the flat textile structure (1) typically encompasses the following steps, preferably within a continuous process.
a) Applying at least one pile layer (2) on a reinforcing grid (3), b) Solidifying the plies placed one on top of the other in a), for example through needling, and c) Gathering the flat structure (1) created in b), for example on a roller.

- 12 -The term "ply" in conjunction with the method described above refers to both a pile layer (2) and the reinforcing grid (3).
In another aspect of the present invention, several plies of the flat textile structure (1) according to the invention, hereinafter referred to as "nonwoven plies", can be flatly joined together, thereby giving rise to the article according to the invention.
The preferred directions of the individual nonwoven plies (1), if any, can be aligned parallel to each other.
However, depending on how and where the article is used, it can also be advantageous to flatly join the nonwoven plies (1) at different angles to each other with respect to their preferred direction. One preferred embodiment provides a composite of three nonwoven plies (1), wherein the preferred direction of the middle and upper nonwoven ply (1) is aligned at an angle of 45 or -45 to the preferred direction of the lower nonwoven ply (1). This yields an increased isotropy for the strength of the article and components fabricated from the latter.
For example, the connection between the nonwoven plies (1) according to the invention can be achieved by simply stitching them together, or through renewed needling.
However, other types of joining are also possible.
In a preferred embodiment, at least one grid ply can be provided between two or more nonwoven plies (1) of the article according to the invention. During the impregnation process, e.g., while injecting a fluid polymer matrix, for manufacturing the component according to the invention, this allows the polymer material to better penetrate into the complex of several nonwoven plies and optimally impregnate the latter, without the individual nonwoven

- 13 -plies (1) slipping relative to each other. The grid ply can be structured based on the reinforcing grid (3) according to the invention. However, a grid with a different structural design can also be used. Knits or scrims consisting of polyester threads are here preferred, since they are easy and inexpensive to manufacture.
In another aspect of the present invention, the flat textile structure (1) according to the invention or article according to the invention is impregnated with a polymer matrix, leading to the component according to the invention.
No special limitations are placed on the materials in the polymer matrix. Suitable materials for the polymer matrix usually include resins, such as polyester resins, epoxy resins and vinyl ester resins, which are used in the manufacture of fiber composite materials.
Suitable methods for impregnating flat textile structures (1), for example resin injection or infusion methods, are known to the expert. Subsequent hardening, for example through exposure to an elevated temperature, yields a component in the desired form. As a result, it is most often necessary to drape the flat textile structure (1) on a rigid mold beforehand. The flat textile structure (1) according to the invention is here distinguished by an optimal draping ability due to its configuration.
In another aspect of the present invention, the component according to the invention is used to manufacture automobile parts. No special limitations are here placed on the type and functionality of the components. Non-load bearing parts are here preferred.
Load-bearing parts in an automobile, such as A, B or C
columns, are highly stressable components. If they consist

- 14 -of fiber composite materials, use is usually made of woven matting or scrims, wherein the fiber bundles in the woven matting or scrims are aligned in such a way as to optimally absorb or divert acting forces, i.e., fiber bundles in the woven matting of scrims are preferably aligned in the direction of applied force. In nonwoven materials, the strength is distributed in all directions owing to the structure, wherein the preferred directions generated by combing the pile can again elevate the anisotropy for the strength of the nonwoven material. This is why fiber composite materials fabricated out of nonwovens can be used in highly stressable components of a vehicle. However, the combined use of nonwoven materials and woven matting or scrims is also possible, for example in the form of nonwoven scrim complexes.

Claims

CLAIMS:

1. A flat textile structure encompassing a reinforcing grid and at least one pile layer flatly situated on at least one surface of the reinforcing grid, wherein - the flat textile structure exhibits a weight per unit area of from 40 to 140 g/cm2, - the pile layer consists predominantly of carbon fibers, - the carbon fibers in the flat textile structure make up 60 to 97% of the weight per unit area, - the reinforcing grid exhibits a proportionate weight per unit area of from 2.5 to 12.5 g/m2, and - the flat textile structure is solidified, and wherein the reinforcing grid is located between two consecutive pile layers.

2. The flat textile structure according to claim 1, wherein - the flat textile structure exhibits a weight per unit area of 80-110 g/m2, - the carbon fibers in the flat textile structure have a proportionate weight per unit area of 65 to 84%, and - the reinforcing grid has a proportionate weight per unit area of 3 to 10 g/m2.

3. The flat textile structure according to claim 1 or 2, wherein the material of the reinforcing grid encompasses polyester and/or glass.

4. The flat textile structure according to any one of claims 1 to 3, wherein the braces of the reinforcing grid exhibit a titer of 120 to 350 dtex.

5. The flat textile structure according to any one of claims 1 to 4, wherein the intersecting points of the reinforcing grid exhibit a binding agent.

6. The flat textile structure according to any one of claims 1 to 5, wherein the reinforcing grid is designed as a laid scrim.

7. The flat textile structure according to any one of claims 1 to 6, wherein the reinforcing grid exhibits a blade of parallel longitudinal braces in a specific direction, and blades of parallel diagonal braces diagonal to the parallel longitudinal braces, wherein one blade of parallel diagonal braces is situated at an angle greater than 45° and less than 90° relative to the parallel longitudinal braces, while these angles are less than -45° and greater than -90° for the other blade of parallel diagonal braces, and the angles for both blades of parallel diagonal braces relative to the parallel longitudinal braces are each numerically equal.

8. The flat textile structure according to claim 7, wherein the longitudinal braces are spaced 5 to 20 mm apart from each other, and the diagonal braces are spaced 7 to 50 mm apart from each other.

9. The flat textile structure according to any one of claims 1 to 6, wherein the reinforcing grid has a checkerboard design.

10. The flat textile structure according to claim 9, wherein the respectively parallel braces are spaced 10 to 50 mm apart from each other.

11. The flat textile structure according to any one of claims 1 to 10, wherein the pile layers consist predominantly of staple fibers.

12. An article encompassing at least two flatly joined flat textile structures according to any one of claims 1 to 11.

13. A component encompassing a flat textile structure according to any one of claims 1 to 11, wherein the flat textile structure is impregnated with a polymer matrix.

14. A component encompassing an article according to claim 12, wherein the article is impregnated with a polymer matrix.

15. Use of the component according to any one of claims 13 or 14 to manufacture automobile parts.