CA2787482C - Process for reforming hydrocarbons - Google Patents

Process for reforming hydrocarbons Download PDF

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Publication number
CA2787482C
CA2787482C CA2787482A CA2787482A CA2787482C CA 2787482 C CA2787482 C CA 2787482C CA 2787482 A CA2787482 A CA 2787482A CA 2787482 A CA2787482 A CA 2787482A CA 2787482 C CA2787482 C CA 2787482C
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Canada
Prior art keywords
heat exchange
reformer
synthesis gas
stream
temperature
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CA2787482A
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English (en)
French (fr)
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CA2787482A1 (en
Inventor
Pat A. Han
Niklas Bengt Jakobsson
Anders Helbo Hansen
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Topsoe AS
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Haldor Topsoe AS
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Publication of CA2787482A1 publication Critical patent/CA2787482A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/007Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067Heating or cooling the reactor
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382Multi-step processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212Plates; Jackets; Cylinders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00504Controlling the temperature by means of a burner
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/0004Processes in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094Jackets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00157Controlling the temperature by means of a burner
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816Heating by flames
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0883Methods of cooling by indirect heat exchange
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143Three or more reforming, decomposition or partial oxidation steps in series
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA2787482A 2010-01-19 2011-01-18 Process for reforming hydrocarbons Active CA2787482C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DKPA201000039 2010-01-19
DKPA201000039 2010-01-19
PCT/EP2011/000178 WO2011088981A1 (en) 2010-01-19 2011-01-18 Process for reforming hydrocarbons

Publications (2)

Publication Number Publication Date
CA2787482A1 CA2787482A1 (en) 2011-07-28
CA2787482C true CA2787482C (en) 2018-11-13

Family

ID=43778227

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2787482A Active CA2787482C (en) 2010-01-19 2011-01-18 Process for reforming hydrocarbons

Country Status (10)

Country Link
US (1) US8696935B2 (enExample)
EP (1) EP2526044B1 (enExample)
JP (1) JP5980686B2 (enExample)
KR (1) KR101820336B1 (enExample)
CN (2) CN102844267A (enExample)
BR (1) BR112012017633B1 (enExample)
CA (1) CA2787482C (enExample)
PL (1) PL2526044T3 (enExample)
RU (1) RU2560363C2 (enExample)
WO (1) WO2011088981A1 (enExample)

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US8882890B2 (en) 2012-12-27 2014-11-11 Uop Llc Apparatuses and methods for separating liquefiable hydrocarbons from hydrogen-, hydrocarbon-containing gas streams
US20150175416A1 (en) * 2013-01-14 2015-06-25 Haldor Topsoe A/S Feed ratio control for hter
MY177060A (en) * 2014-04-08 2020-09-03 Haldor Tops?E As A process for heating an atr
US9592487B2 (en) 2014-06-25 2017-03-14 Zoneflow Reactor Technologies, LLC Steam methane reformer system and method of performing a steam methane reforming process
DE102015004214A1 (de) 2015-03-31 2016-10-06 Linde Aktiengesellschaft Verfahren zur Erzeugung von Synthesegas aus einem CO2-reichen, kohlenwasserstoffhaltigen Einsatzgas
DE102015004215A1 (de) 2015-03-31 2016-10-06 Linde Aktiengesellschaft Verfahren zur Erzeugung von Synthesegas
GB201519139D0 (en) * 2015-10-29 2015-12-16 Johnson Matthey Plc Process
CN105623716B (zh) * 2016-02-23 2017-08-25 石玉林 一种半再生催化重整反应系统及方法
MY201333A (en) 2017-07-25 2024-02-16 Haldor Topsoe As Method for the preparation of synthesis gas
KR102596309B1 (ko) * 2017-07-25 2023-10-31 토프쉐 에이/에스 합성 가스의 제조 방법
CA3070745A1 (en) 2017-07-25 2019-01-31 Haldor Topsoe A/S Process for the co-production of methanol and ammonia
PE20200524A1 (es) 2017-07-25 2020-03-09 Haldor Topsoe As Metodo para la preparacion de gas de sintesis de amoniaco
EA202091418A1 (ru) * 2017-12-08 2020-10-29 Хальдор Топсёэ А/С Система и способ для получения синтез-газа
EP3574991A1 (en) 2018-05-31 2019-12-04 Haldor Topsøe A/S Steam reforming heated by resistance heating
WO2019228798A1 (en) 2018-05-31 2019-12-05 Haldor Topsøe A/S Endothermic reactions heated by resistance heating
GB201908450D0 (en) 2019-06-12 2019-07-24 Johnson Matthey Davy Technologies Ltd Process for synthesising methanol
GB201908449D0 (en) * 2019-06-12 2019-07-24 Johnson Matthey Davy Technologies Ltd Process for synthesising methanol
CN114173918B (zh) 2019-09-03 2025-02-11 托普索公司 具有经支撑的重整器管的重整炉
AU2020360057A1 (en) 2019-10-01 2022-03-24 Haldor Topsøe A/S On demand hydrogen from methanol
CA3148730A1 (en) 2019-10-01 2021-04-08 Haldor Topsoe A/S Cyanide on demand
WO2021063793A1 (en) 2019-10-01 2021-04-08 Haldor Topsøe A/S Offshore reforming installation or vessel
CN114450083A (zh) 2019-10-01 2022-05-06 托普索公司 由氨按需制氢
WO2021063796A1 (en) 2019-10-01 2021-04-08 Haldor Topsøe A/S On demand synthesis gas from methanol
KR20220077135A (ko) 2019-10-01 2022-06-08 할도르 토프쉐 에이/에스 맞춤형 합성 가스
WO2021094346A1 (en) 2019-11-12 2021-05-20 Haldor Topsøe A/S Electric steam cracker
KR102531992B1 (ko) * 2023-01-30 2023-05-15 고등기술연구원연구조합 이산화탄소 무포집 온실가스 저감 합성가스 생산 공정
EP4559870A1 (de) * 2023-11-21 2025-05-28 Linde GmbH Verfahren und anlage zur gewinnung eines wasserstoff enthaltenden produkts

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US4079017A (en) 1976-11-19 1978-03-14 Pullman Incorporated Parallel steam reformers to provide low energy process
JPS5382690A (en) * 1976-12-29 1978-07-21 Chiyoda Chem Eng & Constr Co Ltd Improved preparation of synthetic gas for ammonia
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IT1141031B (it) 1980-08-29 1986-10-01 Snam Progetti Procedimento per la preparazione di gas contenenti idrogeno ed azoto
FR2522473B2 (fr) 1981-04-02 1985-07-26 Agro Technics Internal Ltd Procede de culture fourragere hors sol et dispositif pour sa realisation
JPS59217605A (ja) 1983-05-26 1984-12-07 Babcock Hitachi Kk 水素発生装置
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US5011625A (en) 1989-12-11 1991-04-30 The M. W. Kellogg Company Autothermal steam reforming process
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DE69736438T2 (de) 1996-10-03 2007-08-02 Kato, Hajime, Kawasaki Methode zur dampfreformierung von kohlenwasserstoffen
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EP1106570B1 (en) 1999-12-02 2013-08-28 Haldor Topsoe A/S Process for carrying out non-adiabatic catalytic reactions
JP4477432B2 (ja) * 2004-06-29 2010-06-09 東洋エンジニアリング株式会社 改質器
JP5191888B2 (ja) * 2005-06-14 2013-05-08 サソール テクノロジー(プロプライエタリー)リミテッド 合成ガスの製造方法及び変換方法
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PL2101906T3 (pl) * 2007-01-09 2010-12-31 Air Liquide Sposób wymiany rur katalizatora urządzenia do reformowania węglowodorów
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Also Published As

Publication number Publication date
WO2011088981A1 (en) 2011-07-28
EP2526044A1 (en) 2012-11-28
CN102844267A (zh) 2012-12-26
RU2012135380A (ru) 2014-02-27
RU2560363C2 (ru) 2015-08-20
CN105771812A (zh) 2016-07-20
EP2526044B1 (en) 2018-12-05
BR112012017633A2 (pt) 2016-04-12
JP2013517197A (ja) 2013-05-16
CA2787482A1 (en) 2011-07-28
JP5980686B2 (ja) 2016-08-31
PL2526044T3 (pl) 2019-05-31
US8696935B2 (en) 2014-04-15
US20120326090A1 (en) 2012-12-27
KR20120127454A (ko) 2012-11-21
BR112012017633B1 (pt) 2021-10-13
KR101820336B1 (ko) 2018-01-19

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